Abstract:
Polymerizable dental material which contains at least one radically-polymerizable monomer and at least one bisacylphosphine oxide of the Formula I, in which R1 is a linear or branched C2 to C14 alkyl residue, which can be interrupted by one or more O atoms, PG-Y-R2-X- or a substituted or unsubstituted, aromatic C6 to C14 radical; R2 is absent or a linear or branched C1 to C20 alkylene radical, which can be interrupted by one or more O atoms; R3 is H, a linear or branched C1 to C6 alkyl residue or PG-Y-R2-X-; R4 is a linear or branched C1-C6 alkyl or —O—C1-C6 alkyl residue; R5 is H or PG-Y-R2-X-; R6 is H or PG-Y-R2-X-; PG is a polymerizable group; X is absent, O or S; Y is absent, O, S, an ester, amide or urethane group; the bisacylphosphine oxide having at least one PG-Y-R2-X group and X and/or Y being absent if R2 is absent.
Abstract translation:含有至少一种可自由基聚合的单体和至少一种式I的双酰基氧化膦的可聚合的牙科材料,其中R 1是直链或支链C 2〜C 可以被一个或多个O原子间隔的烷基残基,PG-YR 2 -X-或取代或未取代的芳族C 6 - SUB>至C 14 u>基团; R 2不存在或可以被一个或多个O原子中断的直链或支链C 1至C 20亚烷基; R 3是H,直链或支链C 1至C 6烷基或PG-YR 2 - X-; R 4是直链或支链C 1 -C 6烷基或-OC 1 -C 1 -C 6烷基, 6个烷基残基; R 5是H或PG-Y-R 2 -X-; R 6是H或PG-Y-R 2 -X-; PG是可聚合基团; X不存在,O或S; Y不存在,O,S,酯,酰胺或氨基甲酸酯基; 具有至少一个PG-Y-R 2 -X基团的双酰基氧化膦和如果R 2不存在X和/或Y不存在。
Abstract:
Filler which is surface-modified with a compound of the formula [(PG)—R1—Z]n—SP—[Y—R2—(AG)]m, in which AG is —COOH, —P(═O)(OH)2, —O—P(═O)(OH)2, —SO2OH, —SiR3R4X, or a chelating group; R1 is a C1-C3 alkylene group or cyclopropylene group or is absent; R2 is a C1-C10 alkylene group or is absent; R3 is a C1-C8 alkyl group, chlorine or OR5; R4 is a C1-C8 alkyl group, phenyl, chlorine or OR5; R5 is a C1-C6 alkyl group; X is OR5 or chlorine; Y is O, S, CO—NH, O—CO—NH, NH—CO—NH or is absent, Y being absent if R2 is absent; Z is O, S, CO—NR6, O—CO—NH, NH—CO—NH or is absent, R6 being H or C1-C6 alkyl; PG is a radically polymerizable group of the formula in which R9 is H, C1-C3 alkyl, C1-C3 hydroxyalkyl or COOR10; R10 is H, C1-C10 alkyl, 1,6-dimethylphenyl or mesityl; R11 is H or phenyl; m is 1 or 2; n is 1, 2, 3 or 4; SP is absent or is an (n+m)-valent linear or branched aliphatic C1-C30 radical, in which the carbon chain can be interrupted by O, S, CO—NH, O—CO—NH or NH—CO—NH, an (n+m)-valent aromatic C6-C18 radical, an (n+m)-valent cycloaliphatic C3-C18 radical or an (n+m)-valent heterocyclic C3-C18 radical, where the radicals can be substituted or unsubstituted; in which, if AG is a silyl radical of the formula —SiR3R4X and PG is a vinyl group of the formula H2C═CH—, R1 and Z are not absent simultaneously.
Abstract:
The invention relates to iminooxadiazine dione derivatives with the formula (I) in which X, Y and Z represent a (meth)acrylic acid radical of the formula (II) in which R1 is hydrogen, an aliphatic hydrocarbon radical with 1 to 14 carbon atoms, which can be interrupted by oxygen atoms, or an aromatic hydrocarbon radical with to 16 carbon atoms; R2 is hydrogen, an aliphatic hydrocarbon radical with 1 to 5 carbon atoms or an aromatic hydrocarbon radical with 6 carbon atoms, n is 1 or 2; where the (meth)acrylic acid radical of formula (II) is bound to the radical of formula (I) by R1 or R2 and the binding point remaining at R2 or R1 is saturated by hydrogen and X, Y and Z can be the same or different; the individual radicals R being able to be the same or different and selected from alicyclic or aromatic hydrocarbon radicals with 5 to 10 or aliphatic hydrocarbon radicals with 1 to 10 carbon atoms.
Abstract translation:本发明涉及式(I)的亚氨基恶二嗪二酮衍生物,其中X,Y和Z表示式(II)的(甲基)丙烯酸基,其中R 1是氢,脂族 可以被氧原子中断的具有1至14个碳原子的烃基或具有16个碳原子的芳族烃基; R 2是氢,具有1至5个碳原子的脂族烃基或具有6个碳原子的芳族烃基,n是1或2; 其中式(II)的(甲基)丙烯酸基团通过R 1或R 2 2与式(I)的基团结合,并且R H 2和R 1可以被氢饱和,X,Y和Z可以相同或不同; 各个基团R能够相同或不同,并且选自具有5-10个碳原子的脂族或芳族烃基或具有1-10个碳原子的脂族烃基。
Abstract:
Dental composition containing (i) at least one acid (meth)acrylamide monomer which has two or more polymerizable groups, (ii) at least one acid monomer which has only one polymerizable group and (iii) at least one polymerization initiator.
Abstract:
Dental material being polymerizable by ring-opening metathesis polymerization comprising (i) at lest one ruthenium complex bearing at least one N-heterocyclic carbene ligand or precursors which generate a ruthenium complex bearing at least one N-heterocyclic carbene ligand in situ; and (ii) at least one cyclic olefin capable of metathesis.
Abstract:
The invention relates to compositions, polymerizable by ring-opening metathesis, which contain (a) at least one monomer and/or oligomer which is polymerizable by ring-opening metathesis polymerization, (b) at least one filler and (c) at least one initiator for the ring-opening metathesis polymerization. The compositions are characterized in that the initiator is chemically or physically bound to the filler.
Abstract:
Methylene dithiepane silanes according to Formula I in which R1 is a saturated or unsaturated aliphatic or alicyclic hydrocarbon radical with 1 to 10 carbon atoms, which can be interrupted by one or more oxygen and/or sulphur atoms and can contain one or more ester, carbonyl, amide and/or urethane groups, or is an aromatic or heteroaromatic hydrocarbon radical with 6 to 18 carbon atoms, the hydrocarbon radicals being able to be substituted or unsubstituted; R2 has one of the meanings given for R1 or is absent; R3 has one of the meanings given for R1 or is absent; R4 is equal to —(CHR6)n—, —Y—CO—NH—(CHR6)n—, —Y—CO—NH—R5—, —(CHR6)n—S—R5—, —S—R5—, —CO—O—R5— or is absent, with n being equal to 1 to 4, R6 is hydrogen, C1 to C10 alkyl or C6 to C10 aryl, R5 has one of the meanings given for R1 and Y stands for an O or S atom or is absent; with R5 and R6 being able to be substituted or unsubstituted; X is a hydrolyzable group; a, b, c and x each independently of each other being 1, 2 or 3; and the sum of a+x=2 to 4. The silanes are particularly suitable for the preparation of dental materials.
Abstract:
The invention relates to dental materials which contain at least one polysiloxane based on one or several silanes according to formula (I) [(Wq—R6—Z)p—R3]mY—R2—SiXnR13−n Formula (I) in which X stands for a halogen atom, a hydroxyl, alkoxy and/or acyloxy group; n is equal to 1 to 3, R1 stands for an alkyl, alkenyl, aryl, alkylaryl, arylalkyl group; R2 stands for an alkylene group; R3 stands for a p-time substituted, straight, branched or cyclic, saturated or unsaturated, aromatic or aliphatic organic radical with 2 to 40 carbon atoms and optionally 1 to 6 heteroatoms; R6 stands for a q-times substituted, straight, branched or cyclic organic radical with 1 to 20 carbon atoms or is absent; p is equal to 1 to 6; q is equal to 1 to 6; Y stands for —NR4—, N or —(C═O)—NH—; m is equal to 2 for Y═N and equal to 1 for Y═—NR4—, or —(C═O)—NH—; R4 stands for an alkyl or aryl group; Z stands for O, S, —(C═O)—O—, —(C═O)—NH—, —O—(C═O)—NH— or is absent; W stands for CH2═CR5—(C═O)—O—; and R5 stands for a hydrogen atom or an alkyl group and optionally one or several further hydrolytically condensable compounds of silicon, aluminium, zirconium, titanium, boron, tin, vanadium and/or phosphorus.
Abstract:
The invention relates to ion-releasing composite materials on the basis of polymerizable monomers. The material is characterized in that it contains one or more non-acid, non-ionic, hydrophilic crosslinker monomers, one or more non-acid, non-ionic, hydrophilic dilution monomers having a viscosity of ≦1 Pas and at least one ion-releasing filler. The materials are suitable in particular for use as dental materials.
Abstract:
The invention relates to vinylcyclopropane derivatives according to the formula ##STR1## in which A is --[--Y--CO--C(.dbd.CH.sub.2)R.sup.4 ].sub.m or --C(.dbd.CH.sub.2)CO--O--C.sub.1-4 -alkyl, U and X, independently of each other, stand for CO, COO or CONH; Y and Z stand for O or NH or are absent, but Y and Z cannot be absent at the same time; n, m stand for a whole number from 0 to 4, but n and m are not 0 at the same time; R.sup.1 is H, CH.sub.3 or Cl; R.sup.2, R.sup.3 stand for H, a C.sub.1 - to C.sub.10 -alkyl or alkylene radical, which can be interrupted by O, S or NH, for a C.sub.6 - to C.sub.14 -aryl or arylene, C.sub.7 - to C.sub.14 -alkylaryl or alkylarylene or a C.sub.5 - to C.sub.8 -cycloalkyl or cycloalkylene radical; and R.sup.4 is H or a C.sub.1 - to C.sub.10 -alkyl radical, and to processes for their production. The compounds are suitable in particular for the production of adhesives, cements, composites and mouldings.