Dental materials with improved hydrolysis stability based on phthalic acid monomers
    2.
    发明申请
    Dental materials with improved hydrolysis stability based on phthalic acid monomers 有权
    具有改善的基于邻苯二甲酸单体的水解稳定性的牙科材料

    公开(公告)号:US20130090404A1

    公开(公告)日:2013-04-11

    申请号:US13630491

    申请日:2012-09-28

    IPC分类号: A61K6/083

    摘要: Dental material which contains a polymerizable phthalic acid derivative of the general Formula I: with R1═H, methyl or a C1-C5 alkyl residue; R2═H, a phenyl, benzyl or C1-C8 alkyl residue; Q1=is absent or is a C1-C15 alkylene residue, wherein the carbon chain can be interrupted by O or S; Q2=is absent or a (n+1)-valent aliphatic C1-C20 residue, wherein the carbon chain can be interrupted by O or S and wherein Q1 and Q2 cannot be absent simultaneously; X=is absent, is O, S or (—CO—NR4—)—, wherein R4 is H, CH3 or C2H5; Y=is absent, is O, S or (—CO—NR5—)—, wherein R5 is H, CH3 or C2H5; n, m=independently of one another in each case mean 1, 2 or 3; R3═H, CH3, C2H5, Cl, Br or OCH3, and wherein the two carboxyl groups of the benzene ring can together form an anhydride group.

    摘要翻译: 含有通式I的可聚合邻苯二甲酸衍生物的牙科材料:其中R 1 = H,甲基或C 1 -C 5烷基残基; R2 = H,苯基,苄基或C1-C8烷基残基; Q1 =不存在或是C1-C15亚烷基残基,其中碳链可被O或S间隔; Q2 =不存在或(n + 1)价的脂族C1-C20残基,其中碳链可以被O或S中断,并且其中Q1和Q2不能同时存在; X =不存在,为O,S或(-CO-NR 4 - ) - ,其中R 4为H,CH 3或C 2 H 5; Y =不存在,是O,S或(-CO-NR 5 - ) - ,其中R 5是H,CH 3或C 2 H 5; 在每种情况下,n,m =彼此独立,意指1,2或3; R3 = H,CH3,C2H5,Cl,Br或OCH3,其中苯环的两个羧基可以一起形成酸酐基团。

    Polymerizable bicyclic cyclopropane derivatives and their use for the preparation of dental materials
    4.
    发明授权
    Polymerizable bicyclic cyclopropane derivatives and their use for the preparation of dental materials 有权
    可聚合双环环丙烷衍生物及其在牙科材料制备中的应用

    公开(公告)号:US07585901B2

    公开(公告)日:2009-09-08

    申请号:US11752652

    申请日:2007-05-23

    IPC分类号: A61K6/083 A61C5/00 C08F232/08

    摘要: Bicyclic cyclopropane derivatives of the general Formula (I) in which n+m is 0 to 8; r is 1 to 4; R1 is absent or is a C1-C20 alkylene radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C4-C12 radical, a C6-C14 arylene or C7-C20 alkylenearylene radical; R2 is for r=1 a C1-C20 alkyl radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C4-C12 radical, a C6-C14 aryl or a C7-C20 alkylaryl radical; is for r>1 an r-times substituted aliphatic C1 to C20 radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, an aromatic C6-C14 radical or aliphatic-aromatic C7-C20 radical; X is absent or is —CO—O—, —CO—NH— or —O—CO—NH—, and Y is CH2, O or S which is suitable in particular for the preparation of dental materials.

    摘要翻译: 通式(I)的双环环丙​​烷衍生物,其中n + m为0至8; r为1〜4; R1不存在或是可被O或S间隔的C 1 -C 20亚烷基,脂环族C 4 -C 12基团,双环C 4 -C 12基团,C 6 -C 14亚芳基或C 7 -C 20亚烷基亚芳基基团; R2为r = 1,可被O或S间隔的C1-C20烷基,脂环族C 4 -C 12基,双环C 4 -C 12基,C 6 -C 14芳基或C 7 -C 20烷基芳基; 对于r> 1,可以被O或S间隔的r-次取代的脂族C1至C20基团,脂环族C 4 -C 12基团,芳族C 6 -C 14基团或脂族 - 芳族C 7 -C 20基团; X不存在或是-CO-O-,-CO-NH-或-O-CO-NH-,Y是CH2,O或S,其特别适用于制备牙科材料。

    Dental materials having low polymerization shrinkage
    5.
    发明申请
    Dental materials having low polymerization shrinkage 审中-公开
    具有低聚合收缩率的牙科材料

    公开(公告)号:US20080058443A1

    公开(公告)日:2008-03-06

    申请号:US11897228

    申请日:2007-08-29

    IPC分类号: A61K6/08

    摘要: The present invention relates to dental materials composed of calix[n]arenes and also to the use thereof for cements, composites, adhesives and coating materials in the dental field. The materials include (a) 0.5 to 90% by weight of at least one polymerizable calix[n]arene according to formula (I), (b) 0.01 to 5% by weight of initiator, (c) 0 to 90% by weight of at least one additional monomer which can polymerize under cationic and/or radical conditions and/or which can polymerize by ring opening, (d) 0 to 85% by weight of filler, (e) 0.01 to 5% by weight of additive and (f) 0 to 70% by weight of solvent.

    摘要翻译: 本发明涉及由杯形[n]芳烃组成的牙科用材料,以及其在牙科领域中用于粘合剂,复合材料,粘合剂和涂层材料的用途。 这些材料包括:(a)0.5至90重量%的至少一种根据式(I)的可聚合杯[n]芳烃,(b)0.01至5重量%的引发剂,(c)0至90重量% 的至少一种可在阳离子和/或自由基条件下聚合的另外的单体和/或可以通过开环聚合,(d)0至85重量%的填料,(e)0.01至5重量%的添加剂和 (f)0〜70重量%的溶剂。

    Urethane di(meth)acrylate derivatives of 1,3-bis(1-isocyanato-1-methylethyl)benzene
    7.
    发明授权
    Urethane di(meth)acrylate derivatives of 1,3-bis(1-isocyanato-1-methylethyl)benzene 有权
    苯乙烯的聚氨酯二(甲基)丙烯酸酯衍生物,1,3-双(1-异氰酸基-1-甲基乙基)苯

    公开(公告)号:US06653375B2

    公开(公告)日:2003-11-25

    申请号:US09236787

    申请日:1999-01-25

    IPC分类号: A61K6083

    摘要: The invention relates to urethane di(meth)acrylate derivatives of 1-3-bis(1-isocyanato-1-methylethyl)benzene according to Formula (I) in which R is hydrogen or a straight-chained C1-C8 alkyl radical; X and Y independently of each other stand for R1 being a substituted or unsubstituted C6- to C12-aryl or C7- to C16-alkyl aryl radical; R2 hydrogen, a C1- to C5-alkyl or a substituted or unsubstituted C6- to C12-aryl radical; R3 hydrogen or a methyl radical; R4 a C1- to C8-alkylene radical which can be broken by oxygen atoms, or a phenylene radical; R5 hydrogen or a methyl radical; R6 a substituted or unsubstituted C6- to C12-aryl or C7- to C16-alkyl aryl radical; Z being —CO— or a chemical bond and W standing for oxygen, sulphur or NR7, R7 being hydrogen or a straight-chained C1- to C6-alkyl radical. The substances are suitable in particular for the production of dental materials.

    摘要翻译: 本发明涉及式(I)的1,3-双(1-异氰酸基-1-甲基乙基)苯的氨基甲酸酯二(甲基)丙烯酸酯衍生物,其中R为氢或直链C1-C8烷基; X和Y彼此独立地代表R 1是取代或未取代的C 6 -C 12 - 芳基或C 7 -C 16烷基芳基; R 2为氢,C 1至C 5 - 烷基或取代或未取代的C 6至C 12 - 芳基; R 3氢或甲基; R 4可以被氧原子断裂的C1-至C8-亚烷基或亚苯基; R 5氢或甲基; R 6取代或未取代的C 6 -C 12 - 芳基或C 7 -C 16烷基芳基; Z是-CO-或化学键,W代表氧,硫或NR 7,R 7是氢或直链C 1至C 6烷基。 这些物质特别适用于生产牙科材料。

    Dental materials based on dimer acid derivatives with ring opening polymerizable groups
    9.
    发明授权
    Dental materials based on dimer acid derivatives with ring opening polymerizable groups 有权
    基于具有开环聚合基团的二聚酸衍生物的牙科材料

    公开(公告)号:US08921450B2

    公开(公告)日:2014-12-30

    申请号:US13175988

    申请日:2011-07-05

    摘要: The invention relates to a radically polymerizable monomer of formula (I) wherein W1 and W2 in each case independently represent H or X—R—Y—PG, wherein at least one of W1 and W2 represents X—R—Y—PG, X in each case independently is missing or represents an ether, ester, amide, urethane or urea group, Y in each case independently is missing or represents an ether, ester, amide, urethane or urea group, R in each case independently is missing or represents a C1-C16 alkylene radical which can be interrupted by one or more O atoms, wherein R can be missing only if X and/or Y is simultaneously also missing, and PG in each case independently represents a cyclic, ring-opening polymerizable group, a, b, c and d independently of each other can take the values 3 to 10. The invention also relates to polymerizable compositions which comprise the monomers according to the invention, as well as their use as dental materials and for the preparation of dental materials, in particular composites, cements, adhesives or coatings.

    摘要翻译: 本发明涉及式(I)的自由基聚合性单体,其中W1和W2各自独立地表示H或X-R-Y-PG,其中W1和W2中的至少一个表示X-R-Y-PG,X 在每种情况下都独立地缺失或表示醚,酯,酰胺,氨基甲酸酯或脲基,Y在每种情况下独立地缺失或表示醚,酯,酰胺,氨基甲酸酯或脲基,R各自独立地缺失或表示 可以被一个或多个O原子中断的C1-C16亚烷基,其中只有当X和/或Y同时缺失时,R只能缺失,并且每种情况下PG都独立地表示环状的开环聚合基团, a,b,c和d可以取值为3至10.本发明还涉及包含根据本发明的单体的可聚合组合物,以及它们作为牙科材料和用于制备牙科材料的用途 ,特别是composi 水泥,粘合剂或涂料。

    Dental materials based on dimer acid derivatives with ring opening polymerizable groups
    10.
    发明申请
    Dental materials based on dimer acid derivatives with ring opening polymerizable groups 有权
    基于具有开环聚合基团的二聚酸衍生物的牙科材料

    公开(公告)号:US20120010322A1

    公开(公告)日:2012-01-12

    申请号:US13175988

    申请日:2011-07-05

    摘要: The invention relates to a radically polymerizable monomer of formula (I) wherein W1 and W2 in each case independently represent H or X—R—Y—PG, wherein at least one of W1 and W2 represents X—R—Y—PG, X in each case independently is missing or represents an ether, ester, amide, urethane or urea group, Y in each case independently is missing or represents an ether, ester, amide, urethane or urea group, R in each case independently is missing or represents a C1-C16 alkylene radical which can be interrupted by one or more O atoms, wherein R can be missing only if X and/or Y is simultaneously also missing, and PG in each case independently represents a cyclic, ring-opening polymerizable group, a, b, c and d independently of each other can take the values 3 to 10. The invention also relates to polymerizable compositions which comprise the monomers according to the invention, as well as their use as dental materials and for the preparation of dental materials, in particular composites, cements, adhesives or coatings.

    摘要翻译: 本发明涉及式(I)的自由基聚合性单体,其中W1和W2各自独立地表示H或X-R-Y-PG,其中W1和W2中的至少一个表示X-R-Y-PG,X 在每种情况下都独立地缺失或表示醚,酯,酰胺,氨基甲酸酯或脲基,Y在每种情况下独立地缺失或表示醚,酯,酰胺,氨基甲酸酯或脲基,R各自独立地缺失或表示 可以被一个或多个O原子中断的C1-C16亚烷基,其中只有当X和/或Y同时缺失时,R只能缺失,并且每种情况下PG都独立地表示环状的开环聚合基团, a,b,c和d可以取值为3至10.本发明还涉及包含根据本发明的单体的可聚合组合物,以及它们作为牙科材料和用于制备牙科材料的用途 ,特别是composi 水泥,粘合剂或涂料。