Abstract:
Coatings suitable for use as protective oxide-forming coatings on Nb-based substrates exposed to high temperatures and oxidative environments. The coatings contain chromium and/or molybdenum, preferably contains silicon, and optionally contains niobium, titanium, hafnium, iron, rhenium, tantalum, and/or tungsten, which in combination form multiple intermetallic phases, which in combination form one or more intermetallic phases that promote the formation of a slow-growing oxide scale. Depending on the particular coating composition, the intermetallic phases may be: a silicon-modified Cr2Nb Laves phase and optionally a chromium solid solution phase, a CrNbSi intermetallic phase, and/or an M3Si intermetallic phase where M is niobium, titanium, and/or chromium; or M5Si3, MSi2 and/or M3Si2 where M is molybdenum, niobium, titanium, chromium, hafnium, iron, rhenium, tantalum, and/or tungsten.
Abstract translation:适用于暴露于高温和氧化环境的Nb基基底上的保护性氧化物形成涂层的涂料。 涂层含有铬和/或钼,优选含有硅,并且任选地包含铌,钛,铪,铁,铼,钽和/或钨,其组合形成多个金属间相,其组合形成一个或多个金属间相 促进形成缓慢生长的氧化皮。 根据特定的涂料组合物,金属间相可以是:硅改性的Cr 2 Nb Laves相和任选的铬固溶相,CrNbSi金属间相和/或M3Si金属间相,其中M是铌,钛和/或 铬; 或M5Si3,MSi2和/或M3Si2,其中M是钼,铌,钛,铬,铪,铁,铼,钽和/或钨。
Abstract:
An article including a monolithic body including iron, cobalt, and nitrogen is provided. The monolithic body includes a matrix phase and a plurality of particles disposed within the matrix phase. The particles include a phase comprising nitrogen.
Abstract:
Articles suitable for use in high temperature applications, such as turbomachinery components, and methods for making such articles, are provided. One embodiment is an article. The article comprises a material comprising a plurality of L12-structured gamma-prime phase precipitates distributed within a matrix phase at a concentration of at least 20% by volume, wherein the gamma-prime phase precipitates are less than 1 micrometer in size, and a plurality of A3-structured eta phase precipitates distributed within the matrix phase at a concentration in the range from about 1% to about 25% by volume. The solvus temperature of the eta phase is higher than the solvus temperature of the gamma-prime phase. Moreover, the material has a median grain size less than 10 micrometers. The method comprises providing a workpiece, the workpiece comprising at least about 40% nickel, from about 1.5% to about 8% titanium, and from about 1.5% to about 4.5% aluminum. A weight ratio of titanium to aluminum is in the range from about 1 to about 4, and the workpiece further comprises a plurality of A3-structured ordered eta phase precipitates distributed within the matrix phase at a concentration in the range from about 1% to about 25% by volume. The method further comprises mechanically working the workpiece at a temperature below a solvus temperature of the eta phase; and heat treating the workpiece at a temperature sufficiently high to dissolve any gamma prime phase present in the workpiece but below the solvus temperature of the eta phase.
Abstract:
A system, in certain embodiments, includes a backing plate, a tungsten-based member disposed along the backing plate, wherein the tungsten-based member defines a welding work surface, and the tungsten-based member comprises curved grooves configured to secure the tungsten-based member to the backing plate. The system also includes a drive. The system includes a pin tool movable by the drive to create friction along one or more workpieces disposed on the welding work surface, wherein the frictional heating and mechanical stirring is configured to create a stir weld along the one or more workpieces. The system, in some embodiments, also may include a backing plate comprising liquid passages and gas passages and a tungsten-based member disposed along the backing plate, wherein the tungsten-based member defines a welding work surface.
Abstract:
A soft magnetic alloy including iron, cobalt, and at least one alloying addition including a platinum group metal, rhenium, or combinations thereof is provided. A device which is formed from such an alloy is also described.
Abstract:
A system, in certain embodiments, includes a backing plate, a tungsten-based member disposed along the backing plate, wherein the tungsten-based member defines a welding work surface, and the tungsten-based member comprises curved grooves configured to secure the tungsten-based member to the backing plate. The system also includes a drive. The system includes a pin tool movable by the drive to create friction along one or more workpieces disposed on the welding work surface, wherein the frictional heating and mechanical stirring is configured to create a stir weld along the one or more workpieces. The system, in some embodiments, also may include a backing plate comprising liquid passages and gas passages and a tungsten-based member disposed along the backing plate, wherein the tungsten-based member defines a welding work surface.
Abstract:
An article is presented where the article comprises an alloy having a minor phase dispersed within a matrix phase and a plurality of substantially equiaxed grains. The article further comprises a continuous gradient in grain size from a first grain size at an outer surface of the article to a second grain size at an inner portion of the article, wherein the first grain size is less than the second grain size. Methods for forming the article using high deformation processing are also presented, where the processing includes extruding the feedstock material through a die having a twist channel configured to apply a torsional strain to the feedstock material as it passes through the die to form an extruded billet.
Abstract:
A metallic structure having a graded microstructure is provided. The metallic structure comprises a graded region comprising a plurality of grains having a gradient in grain size varying as a function of position between a first median grain size at an outer region and a second median grain size at an inner region and a plurality of dispersoids dispersed within the microstructure. The first median grain size is different from the second median grain size. A method of forming a metallic structure having a graded microstructure is also provided. The method comprises: providing a metallic structure comprising at least one reactive species; diffusing at least one reactant at a controlled rate from an outer region of the metallic structure towards an inner region of the metallic structure to form a gradient in reactant activity; reacting the reactant with the reactive species to form a plurality of dispersoids; and heat treating the metallic structure to achieve grain growth so as to form a graded microstructure.
Abstract:
A method of making a soft magnetic material with fine grain structure is provided. The method includes the steps of providing a soft magnetic starting material; heating the soft magnetic starting material to a temperature at which the material has a microstructure comprising at least two solid phases; and deforming the soft magnetic starting material. An electrical device comprising a magnetic component is provided. The magnetic component comprises a soft magnetic material having a grain size less than about 3 micrometers. The material has a composition that comprises at least two solid phases at temperatures greater than about 500° C.
Abstract:
A soft magnetic alloy including iron, cobalt, and at least one alloying addition including a platinum group metal, rhenium, or combinations thereof is provided. A device including an article including a soft magnetic alloy including iron, cobalt, and at least one alloying addition including a platinum group metal, rhenium, or combinations thereof is provided.