公开(公告)号：US20100127616A1

公开(公告)日：2010-05-27

申请号：US12533000

申请日：2008-03-26

申请人： Takahiro Kai ,  Toshihiro Yamamoto ,  Masanori Hotta ,  Junya Ogawa

发明人： Takahiro Kai ,  Toshihiro Yamamoto ,  Masanori Hotta ,  Junya Ogawa

IPC分类号： H05B33/14 ,  C07D403/04 ,  C07D251/18 ,  C07D413/14 ,  C07D403/14

CPC分类号： H01L51/0067 ,  C07D239/48 ,  C07D251/18 ,  C07D401/14 ,  C07D403/04 ,  C07D403/14 ,  C07D413/14 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/1022 ,  C09K2211/1029 ,  C09K2211/1059 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/5016 ,  H05B33/14

摘要： Disclosed is an organic electroluminescent device (organic EL device) which is improved in luminous efficiency, fully secured of driving stability, and of simple constitution. Also disclosed is a compound useful for the fabrication of said organic EL device. The organic electroluminescent device comprises organic layers including a light-emitting layer disposed between an anode and a cathode which are piled one upon another on a substrate and at least one of said organic layers comprises a compound for an organic EL device represented by general formula (1). Said organic layer is preferably a light-emitting layer containing a phosphorescent dopant. In general formula (1), X is a substituted or unsubstituted methine group or a nitrogen, Ar4 to Ar7 each is a substituted or unsubstituted aromatic hydrocarbon group or a substituted or unsubstituted aromatic heterocyclic group, and Ar4, Ar5 and the nitrogen to which Ar4 and Ar5 are joined or Ar6, Ar7 and the nitrogen to which Ar6 and Ar7 are joined may together form a nitrogen-containing heterocyclic ring.

摘要翻译： 公开了一种提高发光效率，完全确保驱动稳定性和简单结构的有机电致发光器件（有机EL器件）。 还公开了可用于制造所述有机EL器件的化合物。 有机电致发光器件包括有机层，其包括设置在阳极和阴极之间的发光层，它们在衬底上彼此堆叠，并且至少一个所述有机层包含用于由通式（I）表示的有机EL器件的化合物 1）。 所述有机层优选为含有磷光掺杂剂的发光层。 通式（1）中，X为取代或未取代的次甲基或氮，Ar 4〜Ar 7分别为取代或未取代的芳香族烃基或取代或未取代的芳香族杂环基，Ar 4，​​Ar 5和Ar 4 Ar 5，Ar 6，Ar 7，Ar 6和Ar 7所连接的氮一起形成含氮杂环。

公开(公告)号：US07605277B2

公开(公告)日：2009-10-20

申请号：US10588373

申请日：2005-01-27

申请人： Takahiro Kai ,  Hirokatsu Sekiya ,  Hiroshi Miyazaki ,  Shigetaka Ishikawa

发明人： Takahiro Kai ,  Hirokatsu Sekiya ,  Hiroshi Miyazaki ,  Shigetaka Ishikawa

IPC分类号： C07D319/00

CPC分类号： C09K11/06 ,  C07D319/24 ,  C07D405/12 ,  C07D407/12 ,  C07D409/12 ,  C07D471/04 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1022 ,  C09K2211/1029 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0058 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0073 ,  H01L51/5012 ,  H01L51/5048 ,  H01L51/5088 ,  H05B33/14

摘要： This invention relates to a highly reliable material for an organic electroluminescent element exhibiting high luminance, high luminous efficiency, little deterioration in emission, and suitability for use and storage at high temperatures and to an organic electroluminescent element using said material. The material is a diaminodibenzodioxin derivative represented by general formula (1) wherein Ar1, Ar2, Ar3, and Ar4 are substituted or unsubstituted aryl groups and Ar1, Ar2, and the nitrogen atom bonded thereto or Ar3, Ar4, and the nitrogen atom bonded thereto may form a nitrogen-containing heterocyclic ring; and this diaminodibenzodioxin derivative may be incorporated in the light-emitting layer, the hole-transporting layer, or the hole-injecting layer of an organic electroluminescent element.

摘要翻译： 本发明涉及一种用于有机电致发光元件的高可靠性材料，该材料具有高亮度，高发光效率，极少的发光劣化，以及高温下使用和储存的适用性以及使用所述材料的有机电致发光元件。 该物质是由通式（1）表示的二氨基二苯并二恶英衍生物，其中Ar 1，Ar 2，Ar 3和Ar 4是取代或未取代的芳基和Ar 1，Ar 2，与其结合的氮原子或Ar 3，Ar 4，​​与其结合的氮原子 可形成含氮杂环; 并且该二氨基二苯并二恶英衍生物可以并入有机电致发光元件的发光层，空穴传输层或空穴注入层中。

公开(公告)号：US20070129555A1

公开(公告)日：2007-06-07

申请号：US10588373

申请日：2005-01-27

申请人： Takahiro Kai ,  Hirokatsu Sekiya ,  Hiroshi Miyazaki ,  Shigetaka Ishikawa

发明人： Takahiro Kai ,  Hirokatsu Sekiya ,  Hiroshi Miyazaki ,  Shigetaka Ishikawa

IPC分类号： H01L51/54 ,  C09K11/06

CPC分类号： C09K11/06 ,  C07D319/24 ,  C07D405/12 ,  C07D407/12 ,  C07D409/12 ,  C07D471/04 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1022 ,  C09K2211/1029 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0058 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0073 ,  H01L51/5012 ,  H01L51/5048 ,  H01L51/5088 ,  H05B33/14

摘要： This invention relates to a highly reliable material for an organic electroluminescent element exhibiting high luminance, high luminous efficiency, little deterioration in emission, and suitability for use and storage at high temperatures and to an organic electroluminescent element using said material. The material is a diaminodibenzodioxin derivative represented by general formula (1) wherein Ar1, Ar2, Ar3, and Ar4 are substituted or unsubstituted aryl groups and Ar1, Ar2, and the nitrogen atom bonded thereto or Ar3, Ar4, and the nitrogen atom bonded thereto may form a nitrogen-containing heterocyclic ring; and this diaminodibenzodioxin derivative may be incorporated in the light-emitting layer, the hole-transporting layer, or the hole-injecting layer of an organic electroluminescent element.

摘要翻译： 本发明涉及一种用于有机电致发光元件的高可靠性材料，该材料具有高亮度，高发光效率，极少的发光劣化，以及高温下使用和储存的适用性以及使用所述材料的有机电致发光元件。 该材料是由通式（1）表示的二氨基二苯并二恶英衍生物，其中Ar 1，Ar 2，Ar 3和Ar 4 Ar 3是取代或未取代的芳基和Ar 1，Ar 2，和与它们结合的氮原子，Ar 3，Ar 3， SUB> 4 <！ - SIPO - >，并且与其键合的氮原子可以形成含氮杂环; 并且该二氨基二苯并二恶英衍生物可以并入有机电致发光元件的发光层，空穴传输层或空穴注入层中。

公开(公告)号：US09299947B2

公开(公告)日：2016-03-29

申请号：US13257163

申请日：2010-03-25

申请人： Takahiro Kai ,  Toshihiro Yamamoto ,  Masaki Komori ,  Kazuaki Yoshimura ,  Taishi Tsuji ,  Yasuhiro Takahashi

发明人： Takahiro Kai ,  Toshihiro Yamamoto ,  Masaki Komori ,  Kazuaki Yoshimura ,  Taishi Tsuji ,  Yasuhiro Takahashi

IPC分类号： H01L51/54 ,  C09K11/06 ,  H01L51/50 ,  H01L51/00 ,  H05B33/22

CPC分类号： H01L51/5096 ,  C09K11/06 ,  C09K2211/1029 ,  H01L51/0072 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016 ,  H01L2251/552 ,  H05B33/22

摘要： Provided is an organic electroluminescent device (organic EL device), which has improved luminous efficiency, shows sufficiently ensured driving stability, and has a simple construction. The organic electroluminescent device includes an anode, a cathode, and organic layers including a hole-transporting layer and a light-emitting layer, the organic layers being interposed between the anode and the cathode, in which the light-emitting layer contains a phosphorescent light-emitting material and the hole-transporting layer and the light-emitting layer have an electron- and/or exciton-blocking layer therebetween, the electron- and/or exciton-blocking layer being adjacent to the light-emitting layer and containing an indolocarbazole compound represented by the general formula (2). In the formula, a ring B represents a heterocycle represented by the formula (1c) to be fused with adjacent rings, Z represents an n-valent aromatic hydrocarbon group or an aromatic heterocyclic group, and n represents 1 or 2.

摘要翻译： 提供了一种具有提高的发光效率，充分确保驱动稳定性的有机电致发光器件（有机EL器件），并且具有简单的结构。 有机电致发光器件包括阳极，阴极和包括空穴传输层和发光层的有机层，有机层介于阳极和阴极之间，其中发光层含有磷光 发射材料和空穴传输层和发光层之间具有电子和/或激子阻挡层，电子和/或激子阻挡层邻近发光层并含有吲哚并咔唑 由通式（2）表示的化合物。 在该式中，环B表示与相邻的环稠合的式（1c）表示的杂环，Z表示n价的芳香族烃基或芳香族杂环基，n表示1或2。

公开(公告)号：US09260433B2

公开(公告)日：2016-02-16

申请号：US13512883

申请日：2010-11-18

申请人： Takahiro Kai ,  Toshihiro Yamamoto ,  Masaki Komori ,  Megumi Matsumoto

发明人： Takahiro Kai ,  Toshihiro Yamamoto ,  Masaki Komori ,  Megumi Matsumoto

IPC分类号： H01L51/50 ,  C07D487/04 ,  C09K11/06 ,  H01L51/00 ,  H05B33/14

CPC分类号： C07D487/04 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1074 ,  C09K2211/1088 ,  H01L51/0072 ,  H01L51/0085 ,  H01L51/5016 ,  H05B33/14

摘要： Disclosed is an organic electroluminescent device (organic EL device) which is improved in luminous efficiency, sufficiently secures driving stability, and has a simple configuration. The organic EL device of this invention comprises a light-emitting layer between an anode and a cathode piled one upon another on a substrate and the light-emitting layer contains a phosphorescent dopant and an unsymmetrical indolocarbazole compound as a host material. The unsymmetrical indolocarbazole compound has a structure in which two or more groups having an indolocarbazole structure are linked together by a linking group and at least one of the groups has an isomeric indolocarbazole skeleton different from those of the other groups. Examples of the unsymmetrical indolocarbazole compound include compounds represented by the following formula (2) wherein A is a substituent, each of R1 to R3 is a hydrogen atom or a substituent, and L is a linking group composed of an aromatic group.

摘要翻译： 公开了一种提高发光效率的有机电致发光器件（有机EL器件），足够确保驱动稳定性，并且具有简单的结构。 本发明的有机EL器件包括在基板上彼此堆叠的阳极和阴极之间的发光层，并且发光层含有磷光掺杂剂和作为主体材料的不对称吲哚咔唑化合物。 不对称吲哚并咔唑化合物具有其中两个或更多个具有吲哚并咔唑结构的基团通过连接基团连接在一起的结构，并且至少一个基团具有与其它基团不同的异构吲哚咔唑骨架。 不对称吲哚并咔唑化合物的实例包括其中A是取代基的下式（2）表示的化合物，R 1至R 3各自为氢原子或取代基，L为由芳基组成的连接基团。

公开(公告)号：US09214637B2

公开(公告)日：2015-12-15

申请号：US13877112

申请日：2011-10-03

申请人： Mitsuru Suda ,  Takahiro Kai ,  Megumi Matsumoto

发明人： Mitsuru Suda ,  Takahiro Kai ,  Megumi Matsumoto

IPC分类号： H01L51/00 ,  C07D493/04 ,  C07D495/04 ,  C07D517/04 ,  H01L51/05 ,  H01L51/50

CPC分类号： H01L51/0074 ,  C07D493/04 ,  C07D495/04 ,  C07D517/04 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0061 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0545 ,  H01L51/5012 ,  Y02E10/549

摘要： Provided are a novel chalcogen-containing aromatic compound and an organic electronic device using the compound. This compound is a chalcogen-containing aromatic compound represented by the formula (1). Among the organic electronic devices each using this chalcogen-containing aromatic compound are an organic EL device, an organic TFT device, a photovoltaic device, and the like. In the formula (1): X represents oxygen, sulfur, or selenium; A represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aromatic hydrocarbon group, an aromatic heterocyclic group, or an amino group; and n's each independently represent an integer of 0 to 2, provided that a sum of two n's is 1 to 4.

摘要翻译： 提供了一种新型含硫属化合物的芳族化合物和使用该化合物的有机电子器件。 该化合物是由式（1）表示的含硫属元素的芳族化合物。 在使用这种含硫属化合物的芳族化合物的有机电子器件中，有机EL器件，有机TFT器件，光电器件等。 在式（1）中：X表示氧，硫或硒; A表示烷基，环烷基，烯基，炔基，芳香族烃基，芳香族杂环基或氨基。 n各自独立地表示0〜2的整数，条件是两个n的和为1〜4。

公开(公告)号：US20140209885A1

公开(公告)日：2014-07-31

申请号：US14239835

申请日：2012-07-19

申请人： Masashi Tada ,  Takahiro Kai

发明人： Masashi Tada ,  Takahiro Kai

IPC分类号： H01L51/00

CPC分类号： H01L51/0072 ,  C09B57/00 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  C09K2211/185 ,  H01L51/0073 ,  H01L51/008 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/0088 ,  H05B33/14

摘要： Provided is an organic electroluminescent device (organic EL device) which has improved luminous efficiency and a simple configuration, while ensuring sufficient driving stability. This organic electroluminescent device includes a light-emitting layer between an anode and a cathode that are laminated on a substrate. The light-emitting layer contains a phosphorescent light-emitting dopant, and a carbazole compound represented by the following formula (1) as a host material. In the formula (1), E represents oxygen or sulfur, and R1 to R6 each represent hydrogen, an alkyl group, a cycloalkyl group, or an aromatic group represented by the formula (2). In the formula (2), X represents CR9 or nitrogen.

摘要翻译： 提供了一种在确保足够的驾驶稳定性的同时具有改善的发光效率和简单构造的有机电致发光器件（有机EL器件）。 这种有机电致发光器件包括层叠在基板上的阳极和阴极之间的发光层。 发光层含有磷光发光掺杂剂和由下式（1）表示的咔唑化合物作为主体材料。 在式（1）中，E表示氧或硫，R 1至R 6表示由式（2）表示的氢，烷基，环烷基或芳基。 在式（2）中，X表示CR 9或氮。

公开(公告)号：US08703302B2

公开(公告)日：2014-04-22

申请号：US12991167

申请日：2009-04-30

申请人： Takahiro Kai ,  Masaki Komori ,  Toshihiro Yamamoto

发明人： Takahiro Kai ,  Masaki Komori ,  Toshihiro Yamamoto

IPC分类号： H01L51/54 ,  C09K11/06 ,  C07F9/6561

CPC分类号： H01L51/0072 ,  C07F9/5728 ,  C07F9/65583 ,  C09K11/06 ,  C09K2211/1044 ,  H01L51/5016 ,  H05B33/14

摘要： Disclosed is an organic electroluminescent device (organic EL device) that is improved in the luminous efficiency, fully secured of the driving stability, and of a simple structure and disclosed also is a compound useful therefor. The organic EL device comprises a light-emitting layer disposed between an anode and a cathode piled one upon another on a substrate and the said light-emitting layer comprises a phosphorescent dopant and an indolocarbazole derivative as a host material. The indolocarbazole derivative is represented by the following formula (3) wherein Ar is an aromatic group and L is a direct bond or an aromatic group.

摘要翻译： 公开了提高发光效率的有机电致发光器件（有机EL器件），完全确保了驱动稳定性，并且具有简单的结构，并且还公开了一种有用的化合物。 有机EL器件包括设置在基板上彼此堆叠的阳极和阴极之间的发光层，并且所述发光层包含磷光掺杂剂和作为主体材料的吲哚并咔唑衍生物。 吲哚并咔唑衍生物由下式（3）表示，其中Ar是芳基，L是直接键或芳基。

公开(公告)号：US20130207047A1

公开(公告)日：2013-08-15

申请号：US13877112

申请日：2011-10-03

申请人： Mitsuru Suda ,  Takahiro Kai ,  Megumi Matsumoto

发明人： Mitsuru Suda ,  Takahiro Kai ,  Megumi Matsumoto

IPC分类号： H01L51/00

CPC分类号： H01L51/0074 ,  C07D493/04 ,  C07D495/04 ,  C07D517/04 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0061 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0545 ,  H01L51/5012 ,  Y02E10/549

摘要： Provided are a novel chalcogen-containing aromatic compound and an organic electronic device using the compound. This compound is a chalcogen-containing aromatic compound represented by the formula (1). Among the organic electronic devices each using this chalcogen-containing aromatic compound are an organic EL device, an organic TFT device, a photovoltaic device, and the like. In the formula (1): X represents oxygen, sulfur, or selenium; A represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aromatic hydrocarbon group, an aromatic heterocyclic group, or an amino group; and n's each independently represent an integer of 0 to 2, provided that a sum of two n's is 1 to 4.

摘要翻译： 提供了一种新型含硫属化合物的芳族化合物和使用该化合物的有机电子器件。 该化合物是由式（1）表示的含硫属元素的芳族化合物。 在使用这种含硫属化合物的芳族化合物的有机电子器件中，有机EL器件，有机TFT器件，光电器件等。 在式（1）中：X表示氧，硫或硒; A表示烷基，环烷基，烯基，炔基，芳香族烃基，芳香族杂环基或氨基。 n各自独立地表示0〜2的整数，条件是两个n的和为1〜4。

公开(公告)号：US20120319095A1

公开(公告)日：2012-12-20

申请号：US13578942

申请日：2011-01-27

申请人： Masashi Tada ,  Junya Ogawa ,  Takahiro Kai ,  Megumi Matsumoto ,  Yasuhisa Tsutsumi

发明人： Masashi Tada ,  Junya Ogawa ,  Takahiro Kai ,  Megumi Matsumoto ,  Yasuhisa Tsutsumi

IPC分类号： H01L51/54

CPC分类号： C07D403/10 ,  C07D209/86 ,  C07D401/14 ,  C07D403/14 ,  C07D405/14 ,  C07D409/14 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/0087 ,  H01L51/5016 ,  H01L51/5048 ,  H01L51/5096 ,  Y10S428/917

摘要： Disclosed is an organic electroluminescent device (organic EL device) that is improved in luminous efficiency, sufficiently secures driving stability, and has a simple configuration. This organic EL device comprises organic layers between an anode and a cathode piled one upon another on a substrate and at least one organic layer selected from a light-emitting layer, a hole-transporting layer, an electron-transporting layer, and a hole-blocking layer contains a carbazole compound represented by the following formula (1). In the case where the light-emitting layer of the organic electroluminescent device contains a phosphorescent dopant and a host material, it is the carbazole compound that is contained as the host material. In formula (1), X is C—Y or a nitrogen atom; Y is a hydrogen atom, an alkyl group, a cycloalkyl group, or an aromatic group; n is an integer of 2 to 4: A is an n-valent aromatic group; L is a direct bond or a divalent aromatic group; and R is a hydrogen atom, an alkyl group, or a cycloalkyl group.

摘要翻译： 公开了一种提高发光效率的有机电致发光器件（有机EL器件），足够确保驱动稳定性，并且具有简单的结构。 该有机EL器件包括在基板上彼此堆叠的阳极和阴极之间的有机层以及从发光层，空穴传输层，电子传输层和空穴传输层中选择的至少一个有机层。 阻挡层含有由下式（1）表示的咔唑化合物。 在有机电致发光器件的发光层含有磷光掺杂剂和主体材料的情况下，作为主体材料含有咔唑化合物。 在式（1）中，X是C-Y或氮原子; Y是氢原子，烷基，环烷基或芳基; n为2〜4的整数：A为n价的芳香族基团; L是直接键或二价芳基; R为氢原子，烷基或环烷基。