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公开(公告)号：US06767977B2
公开(公告)日：2004-07-27
申请号：US10324124
申请日：2002-12-20
IPC分类号： C08F11418
CPC分类号： C08F214/184 , C08F216/1466
摘要： Semicrystalline sulphonic fluorinated ionomers having an equivalent weight higher than 700 g/eq, up to 1,700, comprising: (A) monomeric units deriving from one or more fluorinated monomers containing at least one ethylene unsaturation; (B) fluorinated monomeric units containing sulphonyl groups —SO2F in such amount to give the above equivalent weight, deriving from F2C═CF—O—(CF2)q—SO2F, q being an integer equal to 2 or 3; and having the following properties for a TFE/(B) copolymer: hydration, expressed in % of H2O at 100° C. absorbed by the film prepared from the ionomer and after tranformation from the —SO2F form into the —SO3H form, having the following values: at 750 EW higher than 55%, pref. >70% at 850 EW ″ 45%, ″ >55% at 1,000 EW ″ 35%, ″ >40% at 1,100 EW ″ 28%, ″ >32% at 1,200 EW ″ 23%, ″ >25%.
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公开(公告)号：US06639011B2
公开(公告)日：2003-10-28
申请号：US10324123
申请日：2002-12-20
IPC分类号： C08L1102
CPC分类号： C08F214/184 , C08F216/1466
摘要： A polymerization process in aqueous emulsion of: (I) one or more fluorinated monomers containing at least one ethylene unsaturation; (II) one or more fluorinated monomers, containing sulphonyl groups —SO2F; said process comprising the use of a surfactant having the formula: Rf—X−M+ wherein X is equal to —COO, —SO3; M is selected from H, NH4, alkaline metal; Rf represents a (per)fluoropolyether chain, preferably having number average molecular weight comprised between about 230 and about 1,800.
摘要翻译： 水乳液中的聚合方法：（I）含有至少一个乙烯不饱和度的一种或多种氟化单体;（II）含有磺酰基-SO 2 F的一种或多种氟化单体;所述方法包括使用具有下式的表面活性剂： 其中X等于-COO，-SO 3; M选自H，NH 4，碱金属; R f表示（全）氟聚醚链，优选数均分子量在约230至约1800之间。
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公开(公告)号：US20100297523A1
公开(公告)日：2010-11-25
申请号：US12743507
申请日：2008-11-25
申请人： Luca Merlo , Alessandro Ghielmi
发明人： Luca Merlo , Alessandro Ghielmi
CPC分类号： H01M8/1039 , C08J5/2237 , C08J2327/12 , C08L27/12 , C08L27/18 , C08L27/22 , C08L2205/02 , H01M4/8605 , H01M8/04197 , H01M8/1025 , H01M2300/0082 , H01M2300/0091 , C08L2666/04
摘要： A liquid composition comprising: at least one fluoroionomer (I) [fluoroionomer (I-1)], the fluoroionomer (I-1) having a heat of fusion comprised between 4 and 20 J/g; and at least one fluoroionomer (I) [fluoroionomer (I-2)], the fluoroionomer (I-2) being substantially amorphous, that is to say having a heat of fusion of less than 4 J/g, and wherein the water extractable fraction of the fluoroionomer (I-2) is less than 40% wt, the liquid composition comprising the fluoroionomer (I-1) and the fluoroionomer (I-2) in a weight ratio (I-1)/(I-2) of at least 2:1.
摘要翻译： 一种液体组合物，其包含：至少一种氟代离聚物（I）[氟代离聚物（I-1）]，具有4至20J / g的熔化热的氟代离聚物（I-1） 和至少一种氟代离聚物（I）[氟代离聚物（I-2）]，所述氟代离聚物（I-2）基本上是无定形的，也就是说具有小于4J / g的熔化热， 包含重量比（I-1）/（I-2）的氟代离聚物（I-1）和氟代离聚物（I-2）的液体组合物的分数小于40重量％ 至少2：1。
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公开(公告)号：US09217045B2
公开(公告)日：2015-12-22
申请号：US13132611
申请日：2009-12-10
IPC分类号： C08F6/02
摘要： A process for the purification from ionic impurities of a fluoroionomer liquid composition, comprising: providing a liquid composition comprising at least one fluoroionomer (I-1) in a liquid medium, the liquid composition comprising ionic impurities; contacting the liquid composition with a solid particulate comprising at least one fluoroionomer (I-2) having ion exchange groups, wherein H+ or OH− ions are bound to at least a fraction of such ion exchange groups, and separating the liquid composition from the solid particulate.
摘要翻译： 一种用于从氟离子液体组合物的离子杂质中纯化的方法，包括：在液体介质中提供包含至少一种氟代离聚物（I-1）的液体组合物，所述液体组合物包含离子杂质; 使液体组合物与包含至少一种具有离子交换基团的氟代离聚物（I-2）的固体颗粒接触，其中H +或OH-离子与至少一部分这样的离子交换基团结合，并将液体组合物与固体 微粒。
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公开(公告)号：US08409766B2
公开(公告)日：2013-04-02
申请号：US12743507
申请日：2008-11-25
申请人： Luca Merlo , Alessandro Ghielmi
发明人： Luca Merlo , Alessandro Ghielmi
CPC分类号： H01M8/1039 , C08J5/2237 , C08J2327/12 , C08L27/12 , C08L27/18 , C08L27/22 , C08L2205/02 , H01M4/8605 , H01M8/04197 , H01M8/1025 , H01M2300/0082 , H01M2300/0091 , C08L2666/04
摘要： A liquid composition comprising: at least one fluoroionomer (I) [fluoroionomer (I-1)], the fluoroionomer (I-1) having a heat of fusion comprised between 4 and 20 J/g; and at least one fluoroionomer (I) [fluoroionomer (I-2)], the fluoroionomer (I-2) being substantially amorphous, that is to say having a heat of fusion of less than 4 J/g, and wherein the water extractable fraction of the fluoroionomer (I-2) is less than 40% wt, the liquid composition comprising the fluoroionomer (I-1) and the fluoroionomer (I-2) in a weight ratio (I-1)/(I-2) of at least 2:1.
摘要翻译： 一种液体组合物，其包含：至少一种氟代离聚物（I）[氟代离聚物（I-1）]，具有4至20J / g的熔化热的氟代离聚物（I-1） 和至少一种氟代离聚物（I）[氟代离聚物（I-2）]，所述氟代离聚物（I-2）基本上是无定形的，也就是说具有小于4J / g的熔化热， 包含重量比（I-1）/（I-2）的氟代离聚物（I-1）和氟代离聚物（I-2）的液体组合物的分数小于40重量％ 至少2：1。
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公开(公告)号：US20110240559A1
公开(公告)日：2011-10-06
申请号：US13132611
申请日：2009-12-10
IPC分类号： B01J39/00
摘要： A process for the purification from ionic impurities of a fluoroionomer liquid composition, comprising: providing a liquid composition comprising at least one fluoroionomer (I-1) in a liquid medium, the liquid composition comprising ionic impurities; contacting the liquid composition with a solid particulate comprising at least one fluoroionomer (I-2) having ion exchange groups, wherein H+ or OH− ions are bound to at least a fraction of such ion exchange groups, and separating the liquid composition from the solid particulate.
摘要翻译： 一种用于从氟离子液体组合物的离子杂质中纯化的方法，包括：在液体介质中提供包含至少一种氟代离聚物（I-1）的液体组合物，所述液体组合物包含离子杂质; 使液体组合物与包含至少一种具有离子交换基团的氟代离聚物（I-2）的固体颗粒接触，其中H +或OH-离子与至少一部分这样的离子交换基团结合，并将液体组合物与固体 微粒。
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37.发明申请Process for the isolation of sulfonyl fluoride polymers and polymers obtained therefrom 审中-公开用于分离由其获得的磺酰氟聚合物和聚合物的方法公开(公告)号：US20120202946A1
公开(公告)日：2012-08-09
申请号：US13502478
申请日：2010-10-22
CPC分类号： C08F6/22 , C08F2/22 , C08F14/18 , C08F214/18 , C08F214/26 , C08J5/18 , C08J5/225 , C08J2327/12 , C08J2327/18 , C08L27/12 , C08F2/04
摘要： The invention relates to a process for the isolation of (per)fluorinated polymers containing sulfonyl fluoride functional groups from a polymerization latex. The process comprises adding the polymerization latex to an aqueous electrolyte solution under high shear stirring at a temperature equal to or lower than the glass transition temperature of the polymer. The invention further relates to the (per)fluorinated polymers containing sulfonyl fluoride functional groups isolated by the process and characterised by a loss of weight at 200° C. lower than 1% as determined by thermogravimetric analysis.
摘要翻译： 本发明涉及从聚合胶乳中分离含有磺酰氟官能团的（全）氟化聚合物的方法。 该方法包括在等于或低于聚合物的玻璃化转变温度的温度的高剪切搅拌下将聚合胶乳加入到电解质水溶液中。 本发明还涉及通过该方法分离的含有磺酰氟官能团的（全）氟化聚合物，其特征在于通过热重分析测定，其在200℃下的重量损失低于1％。
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公开(公告)号：US09359480B2
公开(公告)日：2016-06-07
申请号：US13262743
申请日：2010-03-31
CPC分类号： C08J3/098 , B01D65/10 , B01D67/0006 , B01D67/0088 , B01D69/02 , B01D69/125 , B01D71/32 , B01D71/36 , B01D2323/02 , B01D2323/30 , B01D2323/40 , B01D2325/20 , B01D2325/36 , C08J2327/12 , C08J2327/18
摘要： Microporous membrane composites that are non-dewetting are disclosed. These microporous membrane composites are wet with solutions of methanol and water and are non-dewetting following autoclave treatment in water. The microporous membrane composites comprise a microporous membrane support that is coated with a crosslinked ionomer comprising hydrophilic groups. Compared to the microporous membrane support, the microporous membrane composite has a flow loss on average in isopropyl alcohol of less than 82%.
摘要翻译： 公开了不去湿的微孔膜复合材料。 这些微孔膜复合物用甲醇和水的溶液润湿，并且在水中经过高压釜处理后不进行除湿。 微孔膜复合材料包括涂覆有包含亲水基团的交联离聚物的微孔膜载体。 与微孔膜相比，微孔膜复合材料在异丙醇中的流动损失平均小于82％。
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公开(公告)号：US20120118816A1
公开(公告)日：2012-05-17
申请号：US13262743
申请日：2010-03-31
CPC分类号： C08J3/098 , B01D65/10 , B01D67/0006 , B01D67/0088 , B01D69/02 , B01D69/125 , B01D71/32 , B01D71/36 , B01D2323/02 , B01D2323/30 , B01D2323/40 , B01D2325/20 , B01D2325/36 , C08J2327/12 , C08J2327/18
摘要： Microporous membrane composites that are non-dewetting are disclosed. These microporous membrane composites are wet with solutions of methanol and water and are non-dewetting following autoclave treatment in water. The microporous membrane composites comprise a microporous membrane support that is coated with a crosslinked ionomer comprising hydrophilic groups. Compared to the microporous membrane support, the microporous membrane composite has a flow loss on average in isopropyl alcohol of less than 82%.
摘要翻译： 公开了不去湿的微孔膜复合材料。 这些微孔膜复合物用甲醇和水的溶液润湿，并且在水中经过高压釜处理后不进行除湿。 微孔膜复合材料包括涂覆有包含亲水基团的交联离聚物的微孔膜载体。 与微孔膜相比，微孔膜复合材料在异丙醇中的流动损失平均小于82％。
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