公开(公告)号：US08940846B2

公开(公告)日：2015-01-27

申请号：US13704335

申请日：2011-06-22

申请人： Luca Merlo ,  Alessandro Veneroni ,  Elvira Pagano ,  Claudio Oldani

发明人： Luca Merlo ,  Alessandro Veneroni ,  Elvira Pagano ,  Claudio Oldani

IPC分类号： C08F128/02 ,  C08F228/02

CPC分类号： C08F116/14 ,  B01D71/32 ,  B01D71/68 ,  C08F128/02 ,  C08F214/182 ,  C08F228/02 ,  C08F261/06 ,  C08J5/18 ,  C08J5/2237 ,  C08J2327/18 ,  H01M8/1027 ,  H01M2300/0082

摘要： A process for reducing the amount of soluble polymeric fractions in a sulfonyl fluoride polymer. The process comprises contacting the sulfonyl fluoride polymer with a fluorinated fluid followed by separation of the polymer from the fluid. The fluorinated fluid is selected from hydrofluoroethers and hydrofluoropolyethers. The invention further relates to sulfonyl fluoride polymers obtainable by the process and having a heat of fusion not exceeding 4 J/g and containing less than 15% by weight of polymeric fractions having an average content of monomeric units comprising a sulfonyl functional group exceeding 24 mole %.The sulfonyl fluoride polymers so obtained are particularly suitable for the preparation of ionomeric membranes for use in electrochemical devices.

摘要翻译： 用于减少磺酰氟聚合物中可溶性聚合物级分的量的方法。 该方法包括使磺酰氟聚合物与氟化流体接触，然后将聚合物与流体分离。 氟化流体选自氢氟醚和氢氟聚醚。 本发明还涉及通过该方法获得的磺化氟化物聚合物，其熔融热不超过4J / g，并且含有少于15％重量的具有包含超过24摩尔的磺酰基官能团的单体单元的平均含量的聚合物部分 ％。 如此获得的磺酰氟聚合物特别适用于制备用于电化学装置的离聚物膜。

公开(公告)号：US20140350181A1

公开(公告)日：2014-11-27

申请号：US14118312

申请日：2012-05-24

申请人： Vito Tortelli ,  Ivan Wlassics ,  Cristiano Monzani ,  Bradley Lane Kent ,  Alessandro Veneroni

发明人： Vito Tortelli ,  Ivan Wlassics ,  Cristiano Monzani ,  Bradley Lane Kent ,  Alessandro Veneroni

IPC分类号： C07C59/135 ,  C08K3/20 ,  C07C51/377

CPC分类号： C07C59/135 ,  C07C51/00 ,  C07C51/377 ,  C07C51/41 ,  C07C59/115 ,  C08K3/20

摘要： The invention pertains to certain hydro-fluorocompounds of the following formula (I): RfO—RH—O—(CH2)m-[CF(X)n]—COOXa wherein: —Xa is H, a monovalent metal (preferably an alkaline metal) or an ammonium group of formula —N(R′n)4, wherein each of R′n, equal to or different from each other, independently represents a hydrogen atom or a C1-6 hydrocarbon group (preferably an alkyl group); —Rf is a C1-C6 (per)fluoroalkyl optionally comprising one or more catenary oxygen atoms, preferably Rf is a group of formula Rf—CH2—, wherein R′f is a C1-C5 perfluorinated group, possibly comprising one or more ethereal oxygens, preferably a C1-C3 perfluorinated group, possibly comprising one or more ethereal oxygens; —RH is a fluorine-free hydrocarbon group optionally comprising one or more catenary oxygen atoms; —X is F or CF3, preferably X is F; -m is 0 or 1; -n is 1 to 3, to a process for the manufacture of said hydro-fluorocompounds, to a method of making fluoropolymers in the presence of said hydro-fluorocompounds, and to fluoropolymer dispersions comprising said hydro-fluorocompound.

摘要翻译： 本发明涉及以下式（I）的某些含氟化合物：RfO-RH-O-（CH2）m- [CF（X）n] -COOXa其中：-Xa为H，一价金属（优选碱 金属）或式-N（R'n）4的铵基，其中R'n彼此相同或不同，各自独立地表示氢原子或C1-6烃基（优选烷基） ; -R f是任选地包含一个或多个链状氧原子的C 1 -C 6（全）氟代烷基，优选Rf是式Rf-CH 2 - 的基团，其中R 1f是C 1 -C 5全氟化基团，可能包含一个或多个醚 氧，优选C1-C3全氟化基团，可能包含一个或多个醚类氧; -RH是任选地包含一个或多个链状氧原子的无氟烃基; -X是F或CF 3，优选X是F; -m为0或1; -n为1至3，涉及一种制备所述含氟化合物的方法，涉及一种在所述含氟化合物存在下制备含氟聚合物的方法，以及含有所述氢氟化合物的含氟聚合物分散体。

公开(公告)号：US20140121321A1

公开(公告)日：2014-05-01

申请号：US14125940

申请日：2012-06-15

申请人： Bradley Lane Kent ,  Valeriy Kapelyushko ,  Giulio Brinati ,  Alessandro Veneroni

发明人： Bradley Lane Kent ,  Valeriy Kapelyushko ,  Giulio Brinati ,  Alessandro Veneroni

IPC分类号： C08K5/42

CPC分类号： C08K5/42 ,  C08F14/22 ,  C08F214/22 ,  C08F2/16

摘要： A process for manufacturing a dispersion of a vinylidene fluoride (VDF) thermoplastic polymer [polymer (F)], said process comprising polymerizing VDF in an aqueous phase comprising from 0.5 to 1.5 g/l of at least one surfactant of formula F—(CF2CF2)3—CH2CH2—SO3Xa, wherein Xa is H, a alkali metal or a NRH4 group, with RH being H or a C1-C6 hydrocarbon group [surfactant (T)] and an organic oxidizing agent [agent (O)] as polymerization initiator.

摘要翻译： 一种制备偏二氟乙烯（VDF）热塑性聚合物[聚合物（F）]的分散体的方法，所述方法包括在包含0.5至1.5g / l的至少一种式F-（CF 2 CF 2）的表面活性剂的水相中聚合VDF ）3-CH 2 CH 2 -SO 3 Xa，其中Xa为H，碱金属或NRH4基，RH为H或C1-C6烃基[表面活性剂（T）]和有机氧化剂[试剂（O）]为聚合 发起人

公开(公告)号：US09534106B2

公开(公告)日：2017-01-03

申请号：US14125940

申请日：2012-06-15

申请人： Bradley Lane Kent ,  Valeriy Kapelyushko ,  Giulio Brinati ,  Alessandro Veneroni

发明人： Bradley Lane Kent ,  Valeriy Kapelyushko ,  Giulio Brinati ,  Alessandro Veneroni

IPC分类号： C08K5/42 ,  C08F14/22 ,  C08F214/22

CPC分类号： C08K5/42 ,  C08F14/22 ,  C08F214/22 ,  C08F2/16

摘要： A process for manufacturing a dispersion of a vinylidene fluoride (VDF) thermoplastic polymer [polymer (F)], said process comprising polymerizing VDF in an aqueous phase comprising from 0.5 to 1.5 g/l of at least one surfactant of formula F—(CF2CF2)3—CH2CH2—SO3Xa, wherein Xa is H, a alkali metal or a NRH4 group, with RH being H or a C1-C6 hydrocarbon group [surfactant (T)] and an organic oxidizing agent [agent (O)] as polymerization initiator.

摘要翻译： 一种制备偏二氟乙烯（VDF）热塑性聚合物[聚合物（F）]的分散体的方法，所述方法包括在包含0.5至1.5g / l的至少一种式F-（CF 2 CF 2）的表面活性剂的水相中聚合VDF ）3-CH 2 CH 2 -SO 3 Xa，其中Xa为H，碱金属或NRH4基，RH为H或C1-C6烃基[表面活性剂（T）]和有机氧化剂[试剂（O）]为聚合 发起人

公开(公告)号：US20130211026A1

公开(公告)日：2013-08-15

申请号：US13704335

申请日：2011-06-22

申请人： Luca Merlo ,  Alessandro Veneroni ,  Elvira Pagano ,  Claudio Oldani

发明人： Luca Merlo ,  Alessandro Veneroni ,  Elvira Pagano ,  Claudio Oldani

IPC分类号： C08F128/02 ,  C08F228/02

CPC分类号： C08F116/14 ,  B01D71/32 ,  B01D71/68 ,  C08F128/02 ,  C08F214/182 ,  C08F228/02 ,  C08F261/06 ,  C08J5/18 ,  C08J5/2237 ,  C08J2327/18 ,  H01M8/1027 ,  H01M2300/0082

摘要： A process for reducing the amount of soluble polymeric fractions in a sulfonyl fluoride polymer. The process comprises contacting the sulfonyl fluoride polymer with a fluorinated fluid followed by separation of the polymer from the fluid. The fluorinated fluid is selected from hydrofluoroethers and hydrofluoropolyethers. The invention further relates to sulfonyl fluoride polymers obtainable by the process and having a heat of fusion not exceeding 4 J/g and containing less than 15% by weight of polymeric fractions having an average content of monomeric units comprising a sulfonyl functional group exceeding 24 mole %.The sulfonyl fluoride polymers so obtained are particularly suitable for the preparation of ionomeric membranes for use in electrochemical devices.

公开(公告)号：US20120202946A1

公开(公告)日：2012-08-09

申请号：US13502478

申请日：2010-10-22

申请人： Alessandro Veneroni ,  Claudio Oldani ,  Martina Corasaniti ,  Alessandro Ghielmi

发明人： Alessandro Veneroni ,  Claudio Oldani ,  Martina Corasaniti ,  Alessandro Ghielmi

IPC分类号： C08F28/02 ,  C08F2/16

CPC分类号： C08F6/22 ,  C08F2/22 ,  C08F14/18 ,  C08F214/18 ,  C08F214/26 ,  C08J5/18 ,  C08J5/225 ,  C08J2327/12 ,  C08J2327/18 ,  C08L27/12 ,  C08F2/04

摘要： The invention relates to a process for the isolation of (per)fluorinated polymers containing sulfonyl fluoride functional groups from a polymerization latex. The process comprises adding the polymerization latex to an aqueous electrolyte solution under high shear stirring at a temperature equal to or lower than the glass transition temperature of the polymer. The invention further relates to the (per)fluorinated polymers containing sulfonyl fluoride functional groups isolated by the process and characterised by a loss of weight at 200° C. lower than 1% as determined by thermogravimetric analysis.

摘要翻译： 本发明涉及从聚合胶乳中分离含有磺酰氟官能团的（全）氟化聚合物的方法。 该方法包括在等于或低于聚合物的玻璃化转变温度的温度的高剪切搅拌下将聚合胶乳加入到电解质水溶液中。 本发明还涉及通过该方法分离的含有磺酰氟官能团的（全）氟化聚合物，其特征在于通过热重分析测定，其在200℃下的重量损失低于1％。