High-compacted-density positive electrode material and electrochemical energy storage apparatus

    公开(公告)号:US11177468B2

    公开(公告)日:2021-11-16

    申请号:US17135552

    申请日:2020-12-28

    Abstract: This application relates to the field of battery technologies, and in particular, to a high-compacted-density positive electrode material and an electrochemical energy storage apparatus. The positive electrode material includes a lithium-nickel transition metal oxide A and a lithium-nickel transition metal oxide B. The lithium-nickel transition metal oxide A is secondary particles, whose chemical formula is shown in formula I: Lia1(Nib1Coc1Mnd1)x1M1-x1O2-e1Xe1. The lithium-nickel transition metal oxide B is a monocrystalline structure or a monocrystalline-like structure, whose chemical formula is shown in formula II: Lia2(Nib2Coc2Mnd2)x2M′1-x2O2-e2X′e2 (II). The positive electrode material of this application includes the large-particle lithium-nickel transition metal oxide A and the small-particle lithium-nickel transition metal oxide B to improve an energy density of the battery. A degree of crystallinity and particle size distribution of the mixed positive electrode material can improve a compacted density of the high-nickel active material, and ensure lower gassing and good cycle performance.

    Preparation method of modified positive electrode active material

    公开(公告)号:US10784508B2

    公开(公告)日:2020-09-22

    申请号:US15976713

    申请日:2018-05-10

    Abstract: The present disclosure provides a preparation method of a modified positive electrode active material preparation method, which comprising steps of: dispersing a positive electrode active material matrix into an alcohol solvent to form a positive electrode active material matrix suspension; dissolving an alcohol-soluble aluminum salt in an alcohol solvent to form an alcohol-soluble aluminum salt solution; dissolving an alcohol-soluble phosphorous compound in an alcohol solvent to form an alcohol-soluble phosphorous compound solution; mixing the alcohol-soluble aluminum salt solution and the alcohol-soluble phosphorous compound solution and heating to react, obtaining a liquid-phase coating solution which contains aluminum phosphate after the reaction is finished; mixing and stirring the positive electrode active material matrix suspension and the liquid-phase coating solution which contains aluminum phosphate, extraction filtrating and obtaining a filter cake after the stirring is finished, then drying and baking the filter cake, finally obtaining a modified positive electrode active material.

    POSITIVE ELECTRODE MATERIAL FOR LITHIUM ION BATTERY, METHOD FOR PREPARING THE SAME AND LITHIUM ION BATTERY

    公开(公告)号:US20180212242A1

    公开(公告)日:2018-07-26

    申请号:US15877403

    申请日:2018-01-23

    Abstract: The present invention provides a positive electrode material for a lithium ion battery including a nickel-containing positive electrode material and a coating layer coated on the nickel-containing positive electrode material, wherein the nickel-containing positive electrode material has a chemical formula of LiNixM1-xO2, 0.5≤x≤1, M is at least one of Co, Mn and Al, and the coating layer contains lithium vanadium phosphate and silica. Compared with the prior art, the coating layer containing lithium vanadium phosphate and silica coated on the nickel-containing positive electrode material of the present invention can remarkably improve the dynamic performances and the cycle performances at high voltage of the lithium ion battery. In addition, the present invention also provides a method for preparing the positive electrode material a lithium ion battery containing the positive electrode material.

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