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公开(公告)号:US20160272559A1
公开(公告)日:2016-09-22
申请号:US15034637
申请日:2014-10-14
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: Matthew T. Pretz , Mark W. Stewart
IPC: C07C5/333
CPC classification number: C07C5/3337 , C07C2521/04 , C07C2521/12 , C07C2523/08 , C07C2523/42 , C07C2523/62 , Y02P20/52 , C07C11/06
Abstract: An improved catalytic dehydrogenation process which process comprises contacting an alkane or alkyl aromatic feedstream with a dehydrogenation catalyst under catalytic conditions in an up-flow fluidized reactor, wherein the fluidized reactor comprises one or more reactors, which catalytic conditions include a temperature within a range of from 500 to 800° C., a weight hourly space velocity within a range of from 0.1 to 1000, a gas residence time within a range of from 0.1 to 10 seconds, and, subsequent to the fluidized reactor, effecting separation of entrained catalyst from reactor effluent by use of a cyclonic separation system, wherein the improvement comprises interposing a cooling means between an up-flow fluidized reactor and the cyclonic separation system to substantially halt thermal reactions, thereby effectively increasing overall molar selectivity to alkene product is provided.
Abstract translation: 一种改进的催化脱氢方法,该方法包括在上游流化反应器中在催化条件下使烷烃或烷基芳族原料流与脱氢催化剂接触,其中该流化反应器包括一个或多个反应器,该催化条件包括在 从500至800℃,重时空速在0.1至1000范围内,气体停留时间在0.1至10秒的范围内,并且在流化反应器之后,将夹带的催化剂从 反应器流出物,其中改进包括在上流式流化反应器和旋风分离系统之间插入冷却装置以基本上停止热反应,由此有效地提高了对烯烃产物的总的摩尔选择性。
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公开(公告)号:US20250153130A1
公开(公告)日:2025-05-15
申请号:US18862013
申请日:2023-05-05
Applicant: Dow Global Technologies LLC
Inventor: Matthew T. Pretz , Liwei Li , Yu Liu , Quan Yuan , Rami H. Sabbah , Yuan Yao , Chi-Wei Tsang
IPC: B01J8/18
Abstract: According to embodiments disclosed herein, a method of operating gas distributers may include passing a solid particulate to a processing unit, where the processing unit includes at least a first distributor and a second distributor, wherein the first distributor and second distributor is operable to pass a combustible gas and a decoking gas into the processing unit, passing the combustible gas into the processing unit through the first distributor, wherein the combustible gas is contacted with the solid particulate and coke forms on the first distributor, halting the passing of the combustible gas through the first distributor while the combustible gas is passed through the second distributor, passing the decoking gas through the first distributor while the combustible gas is passed through the second distributor, wherein the decoking gas removes coke formed on the first distributor, and resuming the passing of the combustible gas through the first distributor.
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公开(公告)号:US20230364575A1
公开(公告)日:2023-11-16
申请号:US18246949
申请日:2021-09-30
Applicant: Dow Global Technologies LLC
Inventor: Matthew T. Pretz , Quan Yuan , Pritish M. Kamat , Liwei Li , Lin Luo
CPC classification number: B01J8/1827 , B01J8/0085 , B01J8/44 , B01J2208/00902 , B01J2208/00911
Abstract: According to one or more embodiments, a chemical feed distributor may include a chemical feed inlet, a body, a plurality of primary chemical feed outlets, and a secondary chemical feed outlet. The chemical feed inlet may pass a chemical feed stream into the chemical feed distributor. One or more walls of the body may define an elongated chemical feed stream flow path. The plurality of primary chemical feed outlets may be spaced along at least a portion of the length of the elongated chemical feed stream flow path and may be operable to pass a first portion of the chemical feed stream out of the feed distributor and into a vessel. The secondary chemical feed outlet may be downstream of the plurality of primary chemical feed outlets and may be operable to pass a second portion of the chemical feed stream out of the chemical feed distributor.
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公开(公告)号:US11731924B2
公开(公告)日:2023-08-22
申请号:US17621945
申请日:2020-06-08
Applicant: Dow Global Technologies LLC
Inventor: Hangyao Wang , Lin Luo , Yu Liu , Matthew T. Pretz , Andrzej Malek
CPC classification number: C07C7/167 , B01D3/14 , B01D45/16 , B01J23/62 , C07C4/04 , C07C5/3337 , C07C7/005 , C07C7/04 , C07C2523/62
Abstract: A method for operating an acetylene hydrogenation unit of a steam cracking system that integrates a fluidized catalytic dehydrogenation (FCDh) effluent from a fluidized catalytic dehydrogenation (FCDh) system may include separating a cracked gas from the steam cracking system into at least a hydrogenation feed comprising at least acetylene, CO, and hydrogen, introducing the FCDh effluent to the separation system, combining the FCDh effluent with the cracked gas upstream of the separation system, or both. The method may include hydrogenating acetylene in the hydrogenation feed. Elevated CO concentration in the hydrogenation feed due to the FCDh effluent may reduce a reaction rate of acetylene hydrogenation. The acetylene hydrogenation unit may operate at an elevated temperature relative to normal operating temperatures when the portion of the FCDh effluent is not integrated, such that a concentration of acetylene in the hydrogenated effluent is less than a threshold acetylene concentration.
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公开(公告)号:US11724974B2
公开(公告)日:2023-08-15
申请号:US17271139
申请日:2019-08-27
Applicant: Dow Global Technologies LLC
Inventor: Kevin Blann , Alexey Kirilin , Andrzej Malek , Victor Sussman , Matthew T. Pretz , Brien A. Stears , Barry B. Fish , Eric E. Stangland , Brian W. Goodfellow , Manish Sharma
CPC classification number: C07C5/48 , B01J21/04 , B01J21/06 , B01J21/10 , B01J23/08 , B01J23/26 , B01J23/42 , C07C2521/04 , C07C2521/06 , C07C2521/10 , C07C2523/08 , C07C2523/26 , C07C2523/42
Abstract: According to one or more embodiments described herein, a method for dehydrogenating hydrocarbons may include passing a hydrocarbon feed comprising one or more alkanes or alkyl aromatics into a fluidized bed reactor, contacting the hydrocarbon feed with a dehydrogenation catalyst in the fluidized bed reactor to produce a dehydrogenated product and hydrogen, and contacting the hydrogen with an oxygen-rich oxygen carrier material in the fluidized bed reactor to combust the hydrogen and form an oxygen-diminished oxygen carrier material. In additional embodiments, a dual-purpose material may be utilized which has dehydrogenation catalyst and oxygen carrying functionality.
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公开(公告)号:US11613506B2
公开(公告)日:2023-03-28
申请号:US17496308
申请日:2021-10-07
Applicant: Dow Global Technologies LLC
Inventor: Matthew T. Pretz , Hangyao Wang , Lin Luo
IPC: C07C5/333
Abstract: According to one or more embodiments presently disclosed, a method for processing a chemical stream may include contacting a feed stream with a catalyst in a reactor portion of a reactor system that includes a reactor portion and a catalyst processing portion. Contacting the feed stream with the catalyst may cause a reaction forming an effluent. The method may include separating the effluent stream from the catalyst, passing the catalyst to the catalyst processing portion, and processing the catalyst in the catalyst processing portion. Processing the catalyst may include passing the catalyst to a combustor, combusting a supplemental fuel stream in the combustor to heat the catalyst, and treating the heated catalyst with an oxygen-containing gas. The supplemental fuel stream may include at least 1 mol % of one or more hydrocarbons, and a weight ratio of catalyst to hydrocarbons in the combustor may be at least 300:1.
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公开(公告)号:US11478769B2
公开(公告)日:2022-10-25
申请号:US17325489
申请日:2021-05-20
Applicant: Dow Global Technologies LLC
Inventor: Matthew T. Pretz
Abstract: A method for processing a chemical stream includes contacting a feed stream with a catalyst in an upstream reactor section of a reactor having the upstream reactor section and a downstream reactor section, passing an intermediate product stream to the downstream reactor section, and introducing a riser quench fluid into the downstream reactor section, upstream reactor section, or transition section and into contact with the intermediate product stream and the catalyst to slow or stop the reaction. The method includes separating at least a portion of the catalyst from the product stream, passing the product stream to a product processing section, cooling the product stream, and separating a portion of the riser quench fluid from the product stream. The riser quench fluid separated from the product stream may be recycled back to the downstream reactor section, upstream reactor section, or transition section as the riser quench fluid.
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公开(公告)号:US11459282B2
公开(公告)日:2022-10-04
申请号:US16491331
申请日:2018-03-09
Applicant: Dow Global Technologies LLC
Inventor: Matthew T. Pretz , Yu Liu
Abstract: According to one or more embodiments presently disclosed, light olefins may be formed by a method that may comprise introducing a feed stream into a reactor, reacting the feed stream with a cracking catalyst in the reactor to form a product stream, and processing the cracking catalyst. The reactor may comprise an upstream reactor section and a downstream reactor section. The upstream reactor section may be positioned below the downstream reactor section. The upstream reactor section may have an average cross-sectional area that is at least 150% of the average cross-sectional area of the downstream reactor section.
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公开(公告)号:US20220227687A1
公开(公告)日:2022-07-21
申请号:US17621919
申请日:2020-06-08
Applicant: Dow Global Technologies LLC
Inventor: Lin Luo , Hangyao Wang , Yu Liu , Matthew T. Pretz , Andrzej Malek
Abstract: A method for operating an acetylene hydrogenation unit in an integrated steam cracking-fluidized catalytic dehydrogenation (FCDh) system may include separating a cracked gas from a steam cracking system and an FCDh effluent from an FCDh system into a hydrogenation feed and an acetylene-depleted stream, the hydrogenation feed comprising at least hydrogen, CO, and acetylene. During normal operating conditions, at least 20% of the CO in the hydrogenation feed is from the cracked gas. The method may include contacting the hydrogenation feed with an acetylene hydrogenation catalyst to hydrogenate at least a portion of the acetylene in the hydrogenation feed to produce a hydrogenated effluent. The steam cracking is operated under conditions that increase CO production such that a concentration of CO in the cracked gas is great enough that when a flowrate of the FCDh effluent is zero, a CO concentration in the hydrogenation feed is at least 100 ppmv.
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公开(公告)号:US11298671B2
公开(公告)日:2022-04-12
申请号:US16609905
申请日:2018-05-03
Applicant: Dow Global Technologies LLC
Inventor: Matthew T. Pretz
Abstract: A method for processing a chemical stream includes contacting a feed stream with a catalyst in a reactor portion of a reactor system causing a reaction which forms a product stream. The method includes separating the product stream from the catalyst, passing the catalyst to a catalyst processing portion of the reactor system, processing the catalyst in the catalyst processing portion, and passing a portion of the catalyst from the catalyst processing portion of the reactor system into a catalyst withdrawal system that includes a catalyst withdrawal vessel and a transfer line coupling the catalyst withdrawal vessel to the catalyst processing portion. Each of the catalyst withdrawal vessel and the transfer line include an outer metallic shell and an inner refractory lining. The method further includes cooling the catalyst in the catalyst withdrawal vessel from greater than or equal to 680° C. to less than or equal to 350° C.
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