Substituted 1,2,5-oxadiazole compounds and their use as herbicides III

    公开(公告)号:US20140309115A1

    公开(公告)日:2014-10-16

    申请号:US14357899

    申请日:2012-11-16

    IPC分类号: A01N43/82

    摘要: The present invention relates to substituted 1,2,5-oxadiazole compounds of the formula I and the N-oxides and salts thereof and to compositions comprising the same. The invention also relates to the use of the 1,2,5-oxadiazole compounds or of the compositions comprising such compounds for controlling unwanted vegetation. wherein X1 is N or CR1; X2 is N or CR2; X4 is N or CR4; provided that a least one of X1, X2 and X4 is N; R is e.g. selected from the group consisting of hydrogen, cyano, nitro, halogen, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, O—Ra, Z—S(O)n—Rb, Z—C(═O)—Rc, Z—C(═O)—ORd, Z—C(═O)—NReRf, Z—NRgRh, Z-phenyl and Z-heterocyclyl; R1 is e.g. selected from the group consisting of Z1-cyano, halogen, nitro, C1-C8-alkyl, C2-C8-alkenyl, C2-C8-alkynyl, C1-C8-haloalkyl, C1-C8-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, Z1—C1-C4-alkoxy-C1-C4-alkoxy, C1-C4-alkylthio-C1-C4-alkyl, Z1—C1-C4-alkylthio-C1-C4-alkylthio, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-haloalkoxy, C1-C4-haloalkoxy-C1-C4-alkyl, Z1—C1-C4-haloalkoxy-C1-C4-alkoxy, Z1—S(O)k—R1b, Z1-phenoxy and Z1-heterocyclyloxy; R2, R3 are identical or different and e.g. selected from the group consisting of hydrogen, halogen, Z2—OH, Z2—NO2, Z2-cyano, C1-C6-alkyl, C2-C8-alkenyl, C2-C8-alkynyl, Z2—C3-C10-cycloalkyl, Z2—C3-C10-cycloalkoxy, C1-C8-haloalkyl, Z2—C1-C8-alkoxy, Z2—C1-C8-haloalkoxy, Z2—C1-C4-alkoxy-C1-C4-alkoxy, Z2—C1-C4-alkylthio-C1-C4-alkylthio, etc., R4 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C1-C4-alkyl and C1-C4-haloalkyl; R5 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C1-C4-alkyl and C1-C4-haloalkyl.

    Agrochemical Formulations Comprising Co-Polymers Based on Ethylenically Unsaturated Dicarboxylic Mono and Diesters
    36.
    发明申请
    Agrochemical Formulations Comprising Co-Polymers Based on Ethylenically Unsaturated Dicarboxylic Mono and Diesters 有权
    基于烯键式不饱和二羧酸单酯和二酯的共聚物的农药组合物

    公开(公告)号:US20100063167A1

    公开(公告)日:2010-03-11

    申请号:US12516450

    申请日:2007-11-09

    IPC分类号: A01N25/10

    CPC分类号: A01N25/10 A01N25/30 A61K8/90

    摘要: The present invention comprises the use of formulations comprising at least one pesticide and at least one co-polymer comprising (a) at least one comonomer (a) selected from the group consisting of olefins, vinylethers, vinyl pyrrolidone and styrene; and (b) at least one comonomer (b) selected from the group consisting of ethylenically unsaturated dicarboxylic mono and diesters, wherein the alcohol moiety of the mono- or diester has the structure of formula I wherein R1 is 1,2-propylene or 2,3 propylene R2 is ethylene; R3 is hydrogen, branched or linear C1-C40, preferably C1-C24 alkyl, phenyl, phenyl substituted with C1-C20 alkyl, benzyl, benzyl substituted with C1-C20 alkyl; n corresponds to a value from 0 to 140, preferably 0-50, more preferably 0-20. p corresponds to a value from 0 to 100 wherein the sum of n and p is at least 1, preferably 1-60, most preferably 5-40. in polymerized form, for increasing the systemicity of pesticides, methods for treatment of seeds, methods of improving the health of plants and methods of combating harmful insects and/or phytopathogenic fungi based on the afore-mentioned formulations.

    摘要翻译: 本发明包括使用包含至少一种农药和至少一种共聚物的制剂,所述共聚物包含(a)至少一种选自烯烃,乙烯基醚,乙烯基吡咯烷酮和苯乙烯的共聚单体(a); 和(b)选自烯属不饱和二羧酸单酯和二酯的至少一种共聚单体(b),其中单酯或二酯的醇部分具有式I的结构,其中R 1是1,2-亚丙基或2 3丙烯R2是乙烯; R 3是氢,支链或直链C 1 -C 40,优选C 1 -C 24烷基,苯基,被C 1 -C 20烷基取代的苯基,苄基,被C 1 -C 20烷基取代的苄基; n对应于0至140,优选0-50,更优选0-20的值。 p对应于0至100的值,其中n和p的和为至少1,优选1-60,最优选5-40。 聚合形式,用于提高农药的系统性,种子处理方法,改善植物健康的方法和基于上述制剂对抗有害昆虫和/或植物病原真菌的方法。

    Agrochemical formulations comprising co-polymers based on diisocyanates
    37.
    发明授权
    Agrochemical formulations comprising co-polymers based on diisocyanates 有权
    包含基于二异氰酸酯的共聚物的农药制剂

    公开(公告)号:US09149034B2

    公开(公告)日:2015-10-06

    申请号:US12515569

    申请日:2007-11-23

    CPC分类号: A01N25/10

    摘要: The present invention comprises formulations comprising at least one pesticide and at least one block copolymer of formula (I) wherein Ra is branched or linear C6-C24 alkyl, C3-C8 cycloalkyl, C3-C8 cycloalkyl substituted with C1-C6 alkyl, phenyl, phenyl substituted with C1-C6 alkyl, benzyl, benzyl substituted with C1-C6 alkyl, C4-C6 alkyl substituted with C4-C12 alkoxy or C1-C4 alkyl substituted with di (C1-C4 alkyl) amino; Rb is derived from a diisocyanate and Rc is a compound of formula II (R1)n—X—(CHR2CH2O)w—(CHR3CH2O)χ—(CHR4(CH2)yO)z— (II), in which R1 is hydrogen, or branched or linear, saturated or unsaturated C1-40-alkyl; R2, R3, R4 independently of one another are hydrogen or C1-4-alkyl; w, x, z independently of one another correspond to a value of from 0 to 300; y corresponds to a value of from 1 to 20; X is N or O, where n=1 if X=O, or n=2 if X=N; and the total of w, x and z amounts to at least 1; methods of combating harmful insects and/or phytopathogenic fungi, a method of controlling undesired vegetation and methods of improving the health of plants based on the afore-mentioned formulations.

    摘要翻译: 本发明包括包含至少一种农药和至少一种式(I)的嵌段共聚物的制剂,其中R a是支链或直链的C 6 -C 24烷基,C 3 -C 8环烷基,被C 1 -C 6烷基取代的C 3 -C 8环烷基,苯基, 被C 1 -C 6烷基取代的苯基,被C 1 -C 6烷基取代的苄基,被C 4 -C 12烷氧基取代的C 1 -C 6烷基或被二(C 1 -C 4烷基)氨基取代的C 1 -C 4烷基; Rb衍生自二异氰酸酯,Rc是式II(R1)n-X-(CHR2CH2O)w-(CHR3CH2O)χ-(CHR4(CH2)yO)z-(Ⅱ)的化合物,其中R1是氢, 或支链或直链,饱和或不饱和的C 1-40 - 烷基; R 2,R 3,R 4彼此独立地是氢或C 1-4 - 烷基; w,x,z彼此独立地对应于0至300的值; y对应于1至20的值; X是N或O,如果X = O,其中n = 1,如果X = N,则n = 2; w,x和z的总和至少为1; 防治有害昆虫和/或植物病原真菌的方法,根据上述制剂控制不需要的植物的方法和改善植物健康的方法。

    Agrochemical Formulations Comprising N-vinylamid Co-polymers
    39.
    发明申请
    Agrochemical Formulations Comprising N-vinylamid Co-polymers 有权
    包含N-乙烯基酰胺共聚物的农药组合物

    公开(公告)号:US20100075850A1

    公开(公告)日:2010-03-25

    申请号:US12516683

    申请日:2007-11-09

    IPC分类号: A01N25/26 A61K47/32

    CPC分类号: A01N25/10 A01N2300/00

    摘要: The present invention comprises formulations comprising at least one pesticide and at least one co-polymer comprising (a) a N-vinylamid comonomer a) of formula (I) wherein R1 and R2 are independently of one another hydrogen or C1-C4 alkyl, preferably hydrogen or R1 and R2 represent together a —(CH2)x mojety, which forms together with the nitrogen and the carbonyl-moiety a 5-8 membered ring, and (b) at least one comonomer b) selected from the group consisting of vinylpyrridin, vinylpyrridin derivatives and N-vinlyimidazole in polymerized form, methods of combating harmful insects and/or phytopathogenic fungi, a method of controlling undesired vegetation and methods of improving the health of plants based on the afore-mentioned formulations.

    摘要翻译: 本发明包括包含至少一种农药和至少一种共聚物的制剂,其包含(a)式(I)的N-乙烯基酰胺共聚单体a),其中R 1和R 2彼此独立地为氢或C 1 -C 4烷基,优选 氢或R 1和R 2共同表示与氮和羰基部分一起形成5-8元环的 - (CH 2)x摩尔,和(b)至少一种选自乙烯基吡啶的共聚单体b) ,聚合形式的乙烯基吡啶衍生物和N-二苯乙烯咪唑,防治有害昆虫和/或植物病原性真菌的方法,根据上述制剂控制不需要的植物的方法和改善植物健康的方法。