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    Agrochemical formulations comprising co-polymers based on diisocyanates
    2.
    发明授权
    Agrochemical formulations comprising co-polymers based on diisocyanates 有权
    包含基于二异氰酸酯的共聚物的农药制剂

    公开(公告)号：US09149034B2

    公开(公告)日：2015-10-06

    申请号：US12515569

    申请日：2007-11-23

    申请人： Yvonne Dieckmann ,  Michael Ishaque ,  Ingo Münster ,  Laurent Picard ,  Wolfgang Kerl ,  Jürgen Langewald ,  Klaus Kreuz ,  Harald Köhle ,  Felix Christian Görth

    发明人： Yvonne Dieckmann ,  Michael Ishaque ,  Ingo Münster ,  Laurent Picard ,  Wolfgang Kerl ,  Jürgen Langewald ,  Klaus Kreuz ,  Harald Köhle ,  Felix Christian Görth

    IPC分类号： A01N47/28 ,  A01C1/06 ,  A01N37/18 ,  A01N25/10

    CPC分类号： A01N25/10

    摘要： The present invention comprises formulations comprising at least one pesticide and at least one block copolymer of formula (I) wherein Ra is branched or linear C6-C24 alkyl, C3-C8 cycloalkyl, C3-C8 cycloalkyl substituted with C1-C6 alkyl, phenyl, phenyl substituted with C1-C6 alkyl, benzyl, benzyl substituted with C1-C6 alkyl, C4-C6 alkyl substituted with C4-C12 alkoxy or C1-C4 alkyl substituted with di (C1-C4 alkyl) amino; Rb is derived from a diisocyanate and Rc is a compound of formula II (R1)n—X—(CHR2CH2O)w—(CHR3CH2O)χ—(CHR4(CH2)yO)z— (II), in which R1 is hydrogen, or branched or linear, saturated or unsaturated C1-40-alkyl; R2, R3, R4 independently of one another are hydrogen or C1-4-alkyl; w, x, z independently of one another correspond to a value of from 0 to 300; y corresponds to a value of from 1 to 20; X is N or O, where n=1 if X=O, or n=2 if X=N; and the total of w, x and z amounts to at least 1; methods of combating harmful insects and/or phytopathogenic fungi, a method of controlling undesired vegetation and methods of improving the health of plants based on the afore-mentioned formulations.

    摘要翻译： 本发明包括包含至少一种农药和至少一种式（I）的嵌段共聚物的制剂，其中R a是支链或直链的C 6 -C 24烷基，C 3 -C 8环烷基，被C 1 -C 6烷基取代的C 3 -C 8环烷基，苯基， 被C 1 -C 6烷基取代的苯基，被C 1 -C 6烷基取代的苄基，被C 4 -C 12烷氧基取代的C 1 -C 6烷基或被二（C 1 -C 4烷基）氨基取代的C 1 -C 4烷基; Rb衍生自二异氰酸酯，Rc是式II（R1）n-X-（CHR2CH2O）w-（CHR3CH2O）χ-（CHR4（CH2）yO）z-（Ⅱ）的化合物，其中R1是氢， 或支链或直链，饱和或不饱和的C 1-40 - 烷基; R 2，R 3，R 4彼此独立地是氢或C 1-4 - 烷基; w，x，z彼此独立地对应于0至300的值; y对应于1至20的值; X是N或O，如果X = O，其中n = 1，如果X = N，则n = 2; w，x和z的总和至少为1; 防治有害昆虫和/或植物病原真菌的方法，根据上述制剂控制不需要的植物的方法和改善植物健康的方法。

    Agrochemical Formulations Comprising N-vinylamid Co-polymers
    4.
    发明申请
    Agrochemical Formulations Comprising N-vinylamid Co-polymers 有权
    包含N-乙烯基酰胺共聚物的农药组合物

    公开(公告)号：US20100075850A1

    公开(公告)日：2010-03-25

    申请号：US12516683

    申请日：2007-11-09

    申请人： Yvonne Dieckmann ,  Michael Ishaque ,  Ingo Münster ,  Laurent Picard ,  Wolfgang Kerl ,  Jürgen Langewald ,  Klaus Kreuz ,  Harald Köhle ,  Felix Christian Görth

    发明人： Yvonne Dieckmann ,  Michael Ishaque ,  Ingo Münster ,  Laurent Picard ,  Wolfgang Kerl ,  Jürgen Langewald ,  Klaus Kreuz ,  Harald Köhle ,  Felix Christian Görth

    IPC分类号： A01N25/26 ,  A61K47/32

    CPC分类号： A01N25/10 ,  A01N2300/00

    摘要： The present invention comprises formulations comprising at least one pesticide and at least one co-polymer comprising (a) a N-vinylamid comonomer a) of formula (I) wherein R1 and R2 are independently of one another hydrogen or C1-C4 alkyl, preferably hydrogen or R1 and R2 represent together a —(CH2)x mojety, which forms together with the nitrogen and the carbonyl-moiety a 5-8 membered ring, and (b) at least one comonomer b) selected from the group consisting of vinylpyrridin, vinylpyrridin derivatives and N-vinlyimidazole in polymerized form, methods of combating harmful insects and/or phytopathogenic fungi, a method of controlling undesired vegetation and methods of improving the health of plants based on the afore-mentioned formulations.

    摘要翻译： 本发明包括包含至少一种农药和至少一种共聚物的制剂，其包含（a）式（I）的N-乙烯基酰胺共聚单体a），其中R 1和R 2彼此独立地为氢或C 1 -C 4烷基，优选 氢或R 1和R 2共同表示与氮和羰基部分一起形成5-8元环的 - （CH 2）x摩尔，和（b）至少一种选自乙烯基吡啶的共聚单体b） ，聚合形式的乙烯基吡啶衍生物和N-二苯乙烯咪唑，防治有害昆虫和/或植物病原性真菌的方法，根据上述制剂控制不需要的植物的方法和改善植物健康的方法。

    Agrochemical Formulations Comprising Co-Polymers Based on Ethylenically Unsaturated Dicarboxylic Mono and Diesters
    6.
    发明申请
    Agrochemical Formulations Comprising Co-Polymers Based on Ethylenically Unsaturated Dicarboxylic Mono and Diesters 有权
    基于烯键式不饱和二羧酸单酯和二酯的共聚物的农药组合物

    公开(公告)号：US20100063167A1

    公开(公告)日：2010-03-11

    申请号：US12516450

    申请日：2007-11-09

    申请人： Yvonne Dieckmann ,  Michael Ishaque ,  Ingo Münster ,  Laurent Picard ,  Wolfgang Kerl ,  Jürgen Langewald ,  Klaus Kreuz ,  Harald Köhle ,  Felix Christian

    发明人： Yvonne Dieckmann ,  Michael Ishaque ,  Ingo Münster ,  Laurent Picard ,  Wolfgang Kerl ,  Jürgen Langewald ,  Klaus Kreuz ,  Harald Köhle ,  Felix Christian

    IPC分类号： A01N25/10

    CPC分类号： A01N25/10 ,  A01N25/30 ,  A61K8/90

    摘要： The present invention comprises the use of formulations comprising at least one pesticide and at least one co-polymer comprising (a) at least one comonomer (a) selected from the group consisting of olefins, vinylethers, vinyl pyrrolidone and styrene; and (b) at least one comonomer (b) selected from the group consisting of ethylenically unsaturated dicarboxylic mono and diesters, wherein the alcohol moiety of the mono- or diester has the structure of formula I wherein R1 is 1,2-propylene or 2,3 propylene R2 is ethylene; R3 is hydrogen, branched or linear C1-C40, preferably C1-C24 alkyl, phenyl, phenyl substituted with C1-C20 alkyl, benzyl, benzyl substituted with C1-C20 alkyl; n corresponds to a value from 0 to 140, preferably 0-50, more preferably 0-20. p corresponds to a value from 0 to 100 wherein the sum of n and p is at least 1, preferably 1-60, most preferably 5-40. in polymerized form, for increasing the systemicity of pesticides, methods for treatment of seeds, methods of improving the health of plants and methods of combating harmful insects and/or phytopathogenic fungi based on the afore-mentioned formulations.

    摘要翻译： 本发明包括使用包含至少一种农药和至少一种共聚物的制剂，所述共聚物包含（a）至少一种选自烯烃，乙烯基醚，乙烯基吡咯烷酮和苯乙烯的共聚单体（a）; 和（b）选自烯属不饱和二羧酸单酯和二酯的至少一种共聚单体（b），其中单酯或二酯的醇部分具有式I的结构，其中R 1是1,2-亚丙基或2 3丙烯R2是乙烯; R 3是氢，支链或直链C 1 -C 40，优选C 1 -C 24烷基，苯基，被C 1 -C 20烷基取代的苯基，苄基，被C 1 -C 20烷基取代的苄基; n对应于0至140，优选0-50，更优选0-20的值。 p对应于0至100的值，其中n和p的和为至少1，优选1-60，最优选5-40。 聚合形式，用于提高农药的系统性，种子处理方法，改善植物健康的方法和基于上述制剂对抗有害昆虫和/或植物病原真菌的方法。

    Agrochemical Formulations Comprising Co-polymers Based on Diisocyanates
    9.
    发明申请
    Agrochemical Formulations Comprising Co-polymers Based on Diisocyanates 有权
    包含基于二异氰酸酯的共聚物的农药组合物

    公开(公告)号：US20100029480A1

    公开(公告)日：2010-02-04

    申请号：US12515569

    申请日：2007-11-23

    申请人： Yvonne Dieckmann ,  Michael Ishaque ,  Ingo Münster ,  Laurent Picard ,  Wolfgang Kerl ,  Jürgen Langewald ,  Klaus Kreuz ,  Harald Köhle ,  Felix Christian Görth

    发明人： Yvonne Dieckmann ,  Michael Ishaque ,  Ingo Münster ,  Laurent Picard ,  Wolfgang Kerl ,  Jürgen Langewald ,  Klaus Kreuz ,  Harald Köhle ,  Felix Christian Görth

    IPC分类号： A01C1/06 ,  A01N47/28 ,  A01N37/18

    CPC分类号： A01N25/10

    摘要： The present invention comprises formulations comprising at least one pesticide and at least one block copolymer of formula (I) wherein Ra is branched or linear C6-C24 alkyl, C3-C8 cycloalkyl, C3-C8 cycloalkyl substituted with C1-C6 alkyl, phenyl, phenyl substituted with C1-C6 alkyl, benzyl, benzyl substituted with C1-C6 alkyl, C4-C6 alkyl substituted with C4-C12 alkoxy or C1-C4 alkyl substituted with di(C1-C4 alkyl)amino; Rb is derived from a diisocyanate and Rc is a compound of formula II (R1)n—X—(CHR2CH2O)w—(CHR3CH2O)χ—(CHR4(CH2)yO)z— (II), in which R1 is hydrogen, or branched or linear, saturated or unsaturated C1-40-alkyl; R2, R3, R4 independently of one another are hydrogen or C1-4-alkyl; w, x, z independently of one another correspond to a value of from 0 to 300; y corresponds to a value of from 1 to 20; X is N or O, where n=1 if X=O, or n=2 if X=N; and the total of w, x and z amounts to at least 1; methods of combating harmful insects and/or phytopathogenic fungi, a method of controlling undesired vegetation and methods of improving the health of plants based on the afore-mentioned formulations.

    摘要翻译： 本发明包括包含至少一种农药和至少一种式（I）的嵌段共聚物的制剂，其中R a是支链或直链的C 6 -C 24烷基，C 3 -C 8环烷基，被C 1 -C 6烷基取代的C 3 -C 8环烷基，苯基， 被C 1 -C 6烷基取代的苯基，被C 1 -C 6烷基取代的苄基，被C 4 -C 12烷氧基取代的C 1 -C 6烷基或被二（C 1 -C 4烷基）氨基取代的C 1 -C 4烷基; Rb衍生自二异氰酸酯，Rc是式II（R1）nX-（CHR2CH2O）w-（CHR3CH2O）chi-（CHR4（CH2）yO）z-（Ⅱ）的化合物，其中R1是氢或支链 或直链，饱和或不饱和的C 1-4 - 烷基; R 2，R 3，R 4彼此独立地是氢或C 1-4 - 烷基; w，x，z彼此独立地对应于0至300的值; y对应于1至20的值; X是N或O，如果X = O，其中n = 1，如果X = N，则n = 2; w，x和z的总和至少为1; 防治有害昆虫和/或植物病原真菌的方法，根据上述制剂控制不需要的植物的方法和改善植物健康的方法。

    Method and device for protein delivery into cells
    10.
    发明申请
    Method and device for protein delivery into cells 失效

    公开(公告)号：US20060105371A1

    公开(公告)日：2006-05-18

    申请号：US11261198

    申请日：2005-10-27

    申请人： Ye Fang ,  Fang Lai ,  Laurent Picard ,  Brian Webb

    发明人： Ye Fang ,  Fang Lai ,  Laurent Picard ,  Brian Webb

    IPC分类号： C12Q1/70 ,  C12Q1/68

    CPC分类号： C12N5/0068 ,  C12N2503/00 ,  C12N2535/10

    摘要： Methods for performing surface-mediated protein delivery into living cells, and fabricating protein-transfected cell cluster arrays are provided. The method comprises providing a protein-containing mixture; depositing said protein-containing mixture onto a surface at defined locations; affixing the protein-containing mixture to the surface as microspots; and plating cells onto the surface in sufficient density and under conditions for the proteins to be delivered into the cells. The protein-containing mixture comprises any suitable amino acid sequence, including peptides, proteins, protein-domains, antibodies, or protein-nucleic acid conjugates, etc., with a carrier reagent. Protein-transfected cell arrays may be used for rapid and direct, screening of protein or enzymatic functions or any given intracellular protein interaction in the natural environment of a living cell, as well as for high-throughput screening of other biological and chemical analytes, which affect the functions of these proteins.