Abstract:
Methods and systems are provided for manufacturing a bipolar plate for a redox flow battery. In one example, the bipolar plate is fabricated by a roll-to-roll process. The bipolar plate includes a non-conductive substrate that is coupled to a negative electrode on a first surface and coupled to a positive electrode on a second surface, the first surface opposite of the second surface.
Abstract:
A rebalancing reactor for a redox flow battery system may include a first side through which hydrogen gas is flowed, a second side through which electrolyte from the redox flow battery system is flowed, and a porous layer separating and fluidly coupled to the first side and the second side, wherein, the hydrogen gas and the electrolyte are fluidly contacted at a surface of the porous layer, and a pressure drop across the second side is less than a pressure drop across the porous layer. In this way, rebalancing of electrolyte charges in a redox flow battery system may be performed with increased efficiency and cost effectiveness as compared to conventional rebalancing reactors.
Abstract:
A leaf spring compression system comprising a mechanical assembly for securing a plurality of leaf springs on a battery cell stack of a flow battery system is disclosed. The cell stack may, comprise: a plurality of cells stacked together to form a flow battery; and a compression system comprising at least two tie rods extending through the plurality of cells clamping a spring acting at opposite ends to compress the cells together, the spring contacting at least two fulcrum elements positioned between the tie rods. In this way, the compression system may exert uniform loading on the battery cell stack, while minimizing deflection of pressure plates attached to the cell stack.
Abstract:
An iron redox flow battery system, comprising a redox electrode, a plating electrolyte tank, a plating electrode, a redox electrolyte tank with additional acid additives that may be introduced into the electrolytes in response to electrolyte pH. The acid additives may act to suppress undesired chemical reactions that create losses within the battery and may be added in response to sensor indications of these reactions.
Abstract:
A redox flow battery may include: a membrane interposed between a first electrode positioned at a first side of the membrane and a second electrode positioned at a second side of the membrane opposite to the first side; a first flow field plate comprising a plurality of positive flow field ribs, each of the plurality of positive flow field ribs contacting the first electrode at first supporting regions on the first side; and the second electrode, including an electrode spacer positioned between the membrane and a second flow field plate, the electrode spacer comprising a plurality of main ribs, each of the plurality of main ribs contacting the second flow field plate at second supporting regions on the second side, each of the second supporting regions aligned opposite to one of the plurality of first supporting regions. As such, a current density distribution at a plating surface may be reduced.
Abstract:
A redox flow battery system is provided. The system includes a positive electrode in fluid communication with a positive electrolyte comprising a first metal ion and a negative electrode in fluid communication with a negative electrolyte comprising a second metal ion. An electrically insulating ion conducting surface is provided separating the positive electrode from the negative electrode. Further, the system includes a catalyst surface in fluid communication with the first metal ion, the second metal ion, or a combination thereof, and hydrogen gas, wherein the hydrogen gas and the first metal ion, the second metal ion, or a combination thereof are fluidly contacted at the catalyst surface.
Abstract:
A method of rebalancing electrolytes in a redox flow battery system comprises directing hydrogen gas generated on the negative side of the redox flow battery system to a catalyst surface, and fluidly contacting the hydrogen gas with an electrolyte comprising a metal ion at the catalyst surface, wherein the metal ion is chemically reduced by the hydrogen gas at the catalyst surface, and a state of charge of the electrolyte and pH of the electrolyte remain substantially balanced.
Abstract:
A method for a redox flow battery system may include flowing an electrolyte from an electrolyte storage tank to a multi-stage rebalancing reactor, the multi-stage rebalancing reactor comprising reactor vessels grouped to form stages. Hydrogen gas may be injected into the electrolyte upstream of the multi-stage rebalancing reactor via a gas line and a metal ion of the electrolyte may be chemically reduced by oxidizing the hydrogen gas at a catalyst bed of each of the reactor vessels to maintain a charge balance of the electrolyte and a pH of the electrolyte within a predetermined range.
Abstract:
A redox flow battery and battery system are provided. In one example, the redox flow battery includes a cell stack assembly interposed by two endplates and comprising a plurality of mated membrane frame plates and bipolar frame plates forming, at a mated interface, a plurality of negative and positive flow channels configured to distribute negative and positive electrolyte into a plurality of bipolar plates. In the battery a membrane is coupled to each of the plurality of membrane frame plates and positioned sequentially between two of the bipolar plates included in the plurality of bipolar plates.
Abstract:
A method of rebalancing electrolytes in a redox flow battery system comprises directing hydrogen gas generated on the negative side of the redox flow battery system to a catalyst surface, and fluidly contacting the hydrogen gas with an electrolyte comprising a metal ion at the catalyst surface, wherein the metal ion is chemically reduced by the hydrogen gas at the catalyst surface, and a state of charge of the electrolyte and pH of the electrolyte remain substantially balanced.