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42 条记录 (耗时 0.03 秒)

    Polymeric metal complex and method of manufacturing the same
    32.
    发明授权
    Polymeric metal complex and method of manufacturing the same 失效
    聚合金属络合物及其制造方法

    公开(公告)号：US4104466A

    公开(公告)日：1978-08-01

    申请号：US555134

    申请日：1975-03-04

    申请人： Eishun Tsuchida ,  Kenji Honda

    发明人： Eishun Tsuchida ,  Kenji Honda

    IPC分类号： C08F8/42 ,  C08G69/48 ,  C08G73/02 ,  C08G79/00 ,  H01H71/18 ,  H01H71/50 ,  C07D207/20

    CPC分类号： H01H71/18 ,  C08F8/42 ,  C08G69/48 ,  C08G73/0206 ,  C08G79/00 ,  H01H71/505

    摘要： A polymeric metal complex capable of reversibly adsorbing oxygen to itself and desorbing oxygen therefrom, whose central metal is a low valency transition metal selected from the group consisting of metals belonging to Groups VIA, VIIA, VIII, IB and IIB of the fourth to the sixth periods of the periodic table; whose panar ligand is a chelate ligand selected from the group consisting of bi-, ter- and quadri-dentate monomeric ligands; and whose axial ligand is a polymeric ligand containing a functional group having a coordinating capacity. The subject polymeric metal complex is manufactured by the method which is characterized in that (A) a monomeric metal complex whose central metal is a low or high valency transition metal selected from the group consisting of metals belonging to Groups VIA, VIIA, VIII, IB and IIB of the fourth to the sixth periods of the periodic table and whose ligand is a chelate ligand of any of the bi-, ter- and quadri-dentate ligands is reacted with a polymeric ligand to replace the axial ligand of said monomeric metal complex by said polymeric ligand, or (B) the central metal of said monomeric metal complex is combined with the residual group of a polymeric compound to provide a .alpha. bond between carbon and metal, and that where the central metal of said monomeric metal complex is a high valency transition metal, then said central metal is reduced to a low valency state by a chemical reaction using a reducing agent or another form of reaction using an electrode before, after or simultaneously with the aforesaid reaction (A) or (B).

    摘要翻译： 能够向其自身可逆地吸附氧并从其中解吸氧的聚合物金属络合物，其中心金属是选自属于第四至第六组VIA，VIIA，VIII，IB和IIB族的金属的低价过渡金属 周期表的周期; 其全配体是选自由双，三和四齿单体配体组成的组的螯合配体; 并且其轴向配体是含有具有配位能力的官能团的聚合配体。 本发明的聚合物金属络合物是通过以下方法制造的：其特征在于：（A）单体金属络合物，其中心金属是选自属于VIA，VIIA，VIII，IB族的金属的低价或高价过渡金属 和周期表第四至第六周期的IIB和其配体是任何二元配位体，三齿和四齿配体的螯合配体与聚合配体反应以取代所述单体金属络合物的轴向配体 通过所述聚合物配体，或（B）将所述单体金属络合物的中心金属与残留的聚合化合物组合以提供碳与金属之间的α键，以及所述单体金属络合物的中心金属为 高价过渡金属，则所述中心金属通过使用还原剂的化学反应或使用电极在其之前，之后或之后的另一种形式的反应被还原成低价态 上述反应（A）或（B）。

    Polyion complex and method for preparing the same
    34.
    发明授权
    Polyion complex and method for preparing the same 失效
    Polyion复合物及其制备方法

    公开(公告)号：US4137217A

    公开(公告)日：1979-01-30

    申请号：US790085

    申请日：1977-04-22

    申请人： Eishun Tsuchida ,  Yoshihito Osada

    发明人： Eishun Tsuchida ,  Yoshihito Osada

    IPC分类号： C08G73/02 ,  C08J3/24 ,  C08F8/32 ,  C08G69/28 ,  C08G69/34

    CPC分类号： C08G73/024 ,  C08G73/02 ,  C08G73/0226 ,  C08G73/0273 ,  C08J3/246

    摘要： A fibrous polyion complex or a polyion complex shapable to a mass or a film is prepared by reacting polycation having polymerization degree of not less than 5 or polyamine having polymerization degree of not less than 6 with polycarboxylic acid having polymerization degree of not less than 5. At least one of the reactants may preferably be of long chain polymer if fibrous polyion complex is desired.

    摘要翻译： 通过聚合度不小于5的聚阳离子或聚合度不低于6的聚胺与聚合度不小于5的聚羧酸反应制备纤维状聚离子络合物或可形成质量或膜的聚离子络合物。 如果需要纤维状聚离子络合物，则至少一种反应物可优选为长链聚合物。

    Selectively permeable film and ion sensor
    37.
    发明授权
    Selectively permeable film and ion sensor 失效
    选择性渗透膜和离子传感器

    公开(公告)号：US4563263A

    公开(公告)日：1986-01-07

    申请号：US339715

    申请日：1982-01-15

    申请人： Noboru Oyama ,  Hiroaki Matsuda ,  Eishun Tsuchida ,  Yukio Ohnuki ,  Takeshi Shimomura ,  Norihiko Ushizawa

    发明人： Noboru Oyama ,  Hiroaki Matsuda ,  Eishun Tsuchida ,  Yukio Ohnuki ,  Takeshi Shimomura ,  Norihiko Ushizawa

    IPC分类号： G01N27/333 ,  G01N27/26

    CPC分类号： G01N27/3335

    摘要： A selectively permeable film directly applied to coat the surface of an electroconductive element, said electively permeable film comprising a polymer which is derived from at least one aromatic compound selected from the group of nitrogen-containing aromatic compounds or from the group of hydroxy aromatic compounds. The nitrogen-containing aromatic compounds are aniline, 2-aminobenzotrifluoride, 2-aminopyridine, 2,3-diaminopyridine, 4,4'-diaminodiphenyl ether, 4,4'-methylenedianiline, tyramine, N-(o-hydroxybenzyl)-aniline and pyrrole. The film coated on the electrode surfaces permits selective passage of ions and the electrode can be used as an ions sensor for measuring the concentration of ions in solutions.

    摘要翻译： 选择性渗透膜直接施加以涂覆导电元件的表面，所述选择性渗透膜包含衍生自至少一种选自含氮芳族化合物的芳族化合物或羟基芳族化合物的聚合物。 含氮芳族化合物为苯胺，2-氨基三氟甲苯，2-氨基吡啶，2,3-二氨基吡啶，4,4'-二氨基二苯醚，4,4'-亚甲基二苯胺，酪胺，N-（邻羟基苄基） - 苯胺和 吡咯。 涂覆在电极表面上的膜允许离子的选择性通过，并且电极可以用作用于测量溶液中离子浓度的离子传感器。

    Porphyrin-metal complexes and oxygen infusions containing the same
    40.
    发明授权
    Porphyrin-metal complexes and oxygen infusions containing the same 有权
    卟啉金属络合物和含有相同的氧气输注物

    公开(公告)号：US07125862B2

    公开(公告)日：2006-10-24

    申请号：US10485381

    申请日：2002-07-30

    申请人： Eishun Tsuchida ,  Teruyuki Komatsu ,  Yasuko Matsukawa

    发明人： Eishun Tsuchida ,  Teruyuki Komatsu ,  Yasuko Matsukawa

    IPC分类号： C07B47/00 ,  C07F5/10 ,  A61K31/555 ,  A61K31/40 ,  A61B10/00

    CPC分类号： C07D487/22

    摘要： A porphyrin metal complex that can form a stable oxygen complex and acts effectively as an oxygen infusion, which comprises: a transition metal ion M of period 4 or 5 coordinating to a porphyrin derivative represented by the following general wherein R1 is an alicyclic hydrocarbon group which may contain a substituent, R2 is an alkylene group and R3 is a group which does not hinder the coordination of an imidazolyl group to M.

    摘要翻译： 一种卟啉金属络合物，其可以形成稳定的氧络合物并且作为氧输入有效地起作用，其包括：与由下列通式表示的卟啉衍生物配位的周期为4或5的过渡金属离子M，其中R 1， SUP>是可以含有取代基的脂环烃基，R 2是亚烷基，R 3是不阻碍咪唑基的配位的基团 M.