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31.发明授权公开(公告)号：US06824899B2
公开(公告)日：2004-11-30
申请号：US10040502
申请日：2001-11-09
IPC分类号： H01M800
CPC分类号： H01M8/04194 , H01M8/04291
摘要： Apparatus and methods for regulating methanol concentration in a direct methanol fuel cell system without the need for a methanol concentration sensor. One or more operating characteristics of the fuel cell, such as the potential across the load, open circuit potential, potential at the anode proximate to the end of the fuel flow path or short circuit current of the fuel cell, are used to actively control the methanol concentration.
摘要翻译： 在直接甲醇燃料电池系统中调节甲醇浓度的装置和方法，而不需要甲醇浓度传感器。 燃料电池的一个或多个操作特性，例如负载电位，开路电位，靠近燃料流路端部的阳极电位或燃料电池的短路电流，被用于主动地控制 甲醇浓度。
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32.发明授权Catalyst coated membrane (CCM) and catalyst film/layer for alkaline membrane fuel cells and methods of making same 有权催化剂涂膜（CCM）和碱性膜燃料电池用催化膜/层及其制备方法公开(公告)号：US08304368B2
公开(公告)日：2012-11-06
申请号：US12710539
申请日：2010-02-23
IPC分类号： B01J23/48
CPC分类号： H01M4/886 , H01M4/8605 , H01M4/8663 , H01M4/881 , H01M4/8814 , H01M4/8835 , H01M4/92 , H01M8/0289 , H01M2008/1095
摘要： Alkaline membrane fuel cells designed with silver cathode catalysts include a catalyst layer comprising silver metal nano-particles and an anion-conducting ionomer. The silver nano-particles are mixed with a solution of the ionomer to form a catalyst ink that is applied to an alkaline membrane to form an ultra-thin cathode catalyst layer on the membrane surface.
摘要翻译： 用银阴极催化剂设计的碱性膜燃料电池包括包含银金属纳米颗粒和阴离子导电离聚物的催化剂层。 将银纳米颗粒与离聚物的溶液混合以形成催化剂油墨，该催化剂油墨施加到碱性膜上以在膜表面上形成超薄的阴极催化剂层。
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33.发明申请Systems and Methods of Securing Immunity to Air CO2 in Alkaline Fuel Cells 有权确保碱性燃料电池中空气二氧化碳的免疫系统和方法公开(公告)号：US20110212370A1
公开(公告)日：2011-09-01
申请号：US12862746
申请日：2010-08-24
申请人： Shimshon Gottesfeld
发明人： Shimshon Gottesfeld
IPC分类号： H01M8/06
CPC分类号： H01M8/0668 , H01M8/0693 , H01M8/083 , H01M8/1007 , H01M10/46 , H01M2300/0014 , H01M2300/0082 , H02J7/0063 , Y02E60/50
摘要： An air CO2 filtration assembly or system is provided that includes CO2 filters or traps designed and configured with a limited, but high capacity, volume to maximize filtration/absorption of CO2 from an air stream supplied to an alkaline fuel cell to thereby minimize the CO2 level in the air stream fed into the fuel cell cathode. The CO2 filters or traps include at least one thermally regenerative CO2 chemical filter or trap arranged in a tandem configuration with a strongly bonding CO2 chemical filter or trap. The combination of the two types of filters or traps sequentially filter/absorb CO2 from the air stream and reduce the level of CO2 in the air stream fed into the cathode. The air CO2 filtration assembly or system may be used in conjunction with electrochemical purging of the alkaline fuel cell that enables removal of CO2 from the fuel cell by anodic decomposition of accumulated carbonate ions in the fuel cell anode and release of CO2 through the anode exhaust stream.
摘要翻译： 提供了一种空气CO2过滤组件或系统，其包括设计和配置有限但容量大的二氧化碳过滤器或阱，以最大限度地从供应到碱性燃料电池的空气流中过滤/吸收二氧化碳，从而最小化CO2水平 在进入燃料电池阴极的空气流中。 二氧化碳过滤器或捕集器包括至少一个热再生CO 2化学过滤器或捕集器，其布置成具有强粘结的CO 2化学过滤器或阱的串联配置。 两种类型的过滤器或捕集阱的组合顺序地从空气流中过滤/吸收CO 2并且降低进入阴极的空气流中的CO 2水平。 空气CO 2过滤组件或系统可以与碱性燃料电池的电化学清洗结合使用，其能够通过阳极分解燃料电池阳极中的碳酸根离子并通过阳极排气流释放CO 2从燃料电池中除去CO 2 。
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公开(公告)号：US06991865B2
公开(公告)日：2006-01-31
申请号：US10970396
申请日：2004-10-21
IPC分类号： H01M8/04
CPC分类号： H01M8/04194 , H01M8/04291
摘要： Apparatus and methods for regulating methanol concentration in a direct methanol fuel cell system without the need for a methanol concentration sensor. One or more operating characteristics of the fuel cell, such as the potential across the load, open circuit potential, potential at the anode proximate to the end of the fuel flow path or short circuit current of the fuel cell, are used to actively control the methanol concentration.
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公开(公告)号：US20050196666A1
公开(公告)日：2005-09-08
申请号：US10791101
申请日：2004-03-02
CPC分类号： H01M8/0273 , H01M8/0297 , H01M8/04201 , H01M8/1011 , H01M8/242 , H01M8/246 , H01M2008/1095 , Y02E60/523
摘要： A conformable fuel cell is provided which includes a basic structure that provides flexibility while providing a high compression along the active surface of the fuel cell's membrane electrode assembly, which can be achieved by an injection-molded frame. A suitable fuel is delivered to the anode aspect of the fuel cell. Effective water management could also be provided by appropriate diffusion layers. The fuel cell can be contour-molded to a desired shape, or can be constructed of an array of flexibly connected individual fuel cells that overall have a curvilinear shape, or can be constructed as a pliable fuel cell that can be incorporated into an application device or an article of clothing.
摘要翻译： 提供了一种适应性的燃料电池，其包括提供柔性的基本结构，同时沿着燃料电池的膜电极组件的活性表面提供高压缩性，这可以通过注射成型的框架来实现。 合适的燃料被输送到燃料电池的阳极方面。 有效的水管理也可以由适当的扩散层提供。 燃料电池可以被轮廓模制成所需的形状，或者可以由整体上具有曲线形状的柔性连接的单个燃料电池的阵列构成，或者可以被构造为可并入到应用装置中的柔性燃料电池 或一件衣服。
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公开(公告)号：US5368717A
公开(公告)日：1994-11-29
申请号：US32959
申请日：1993-03-17
CPC分类号： C25D5/56 , H05K3/188 , H05K2201/0329
摘要： An electroplated element is formed to include an insulating substrate, a conducting polymer polymerized in situ on the substrate, and a metal layer deposited on the conducting polymer. In one application a circuit board is formed by polymerizing pyrrole on an epoxy-fiberglass substrate in a single step process and then electrodepositing a metal over the resulting polypyrrole polymer. No chemical deposition of the metal is required prior to electroplating and the resulting layer of substrate-polymer-metal has excellent adhesion characteristics. The metal deposition is surprisingly smooth and uniform over the relatively high resistance film of polypyrrole. A continuous manufacturing process is obtained by filtering the solution between successive substrates to remove polymer formed in the solution, by maintaining the solution oxidizing potential within selected limits, and by adding a strong oxidant, such as KMnO.sub.4 at periodic intervals to maintain a low sheet resistivity in the resulting conducting polymer film.
摘要翻译： 电镀元件形成为包括绝缘基板，在基板上原位聚合的导电聚合物和沉积在导电聚合物上的金属层。 在一个应用中，电路板是通过在环氧树脂 - 玻璃纤维基材上以一步法聚合吡咯然后在所得聚吡咯聚合物上电沉积金属形成的。 在电镀之前不需要金属的化学沉积，并且所得到的基底 - 聚合物 - 金属层具有优异的粘附特性。 金属沉积在聚吡咯的相对高的电阻膜上令人惊讶地平滑和均匀。 通过在连续的底物之间过滤溶液以除去在溶液中形成的聚合物，通过将溶液氧化势保持在选择的范围内，并且通过以周期性间隔加入强氧化剂如KMnO 4以保持低的薄层电阻率来获得连续的制造方法 在所得的导电聚合物膜中。
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公开(公告)号：US5108573A
公开(公告)日：1992-04-28
申请号：US533551
申请日：1990-06-05
摘要： A conducting polymer film with an improved space filling is formed on a metal electrode surface. A self-assembling monolayer is formed directly on the metal surface where the monolayer has a first functional group that binds to the metal surface and a second chemical group that forms a chemical bonding site for molecules forming the conducting polymer. The conducting polymer is then conventioonally deposited by electrochemical deposition. In one example, a conducting film of polyaniline is formed on a gold electrode surface with an intermediate monolayer of p-aminothiophenol.
摘要翻译： 在金属电极表面上形成具有改善的空间填充的导电聚合物膜。 直接在金属表面上形成自组装单层，其中单层具有结合金属表面的第一官能团和形成导电聚合物分子的化学键合位点的第二化学基团。 然后通过电化学沉积将导电聚合物固化沉积。 在一个实例中，聚苯胺的导电膜在金电极表面上形成有中间单层对氨基苯硫酚。
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公开(公告)号：US5082550A
公开(公告)日：1992-01-21
申请号：US448475
申请日：1989-12-11
IPC分类号： G01N27/327 , C12Q1/00
CPC分类号： C12Q1/002 , Y10S435/817
摘要： An electrochemical sensor electrode is formed from an electronic conductor coated with a casting solution containing a perfluorosulfonic acid ionomer and a selected enzyme. The selected enzyme catalyzes a reaction between a predetermined substance in a solution and oxygen to form an electrochemically active compound that is detected at the electronic conductor. The resulting perfluorosulfonic acid polymer provides a stable matrix for the enzyme for long lived enzyme activity, wherein only thin coatings are required on the metal conductor. The polymer also advantageously repels interfering substances from contacting the enzyme and contains quantities of oxygen to maintain a sensing capability during conditions of oxygen depletion in the sample. In one particular embodiment, glucose oxidase is mixed with the perfluorosulfonic acid ionomer to form an electrode for glucose detection.
摘要翻译： 电化学传感器电极由涂覆有含有全氟磺酸离聚物和选定酶的流延溶液的电子导体形成。 所选择的酶催化溶液中的预定物质与氧之间的反应，以形成在电子导体处检测到的电化学活性化合物。 所得的全氟磺酸聚合物为长寿命酶活性的酶提供稳定的基质，其中在金属导体上仅需要薄涂层。 该聚合物还有利地排除干扰物质接触酶，并含有一定量的氧以在样品中的氧耗尽条件下保持感测能力。 在一个具体实施方案中，葡萄糖氧化酶与全氟磺酸离聚物混合以形成用于葡萄糖检测的电极。
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公开(公告)号：US4910099A
公开(公告)日：1990-03-20
申请号：US279694
申请日：1988-12-05
申请人： Shimshon Gottesfeld
发明人： Shimshon Gottesfeld
IPC分类号： H01M8/04
CPC分类号： H01M8/04089 , H01M2300/0082
摘要： Proton exchange membrane (PEM) fuel cell performance with CO contamination of the H.sub.2 fuel stream is substantially improved by injecting O.sub.2 into the fuel stream ahead of the fuel cell. It is found that a surface reaction occurs even at PEM operating temperatures below about 100.degree. C. to oxidatively remove the CO and restore electrode surface area for the H.sub.2 reaction to generate current. Using an O.sub.2 injection, a suitable fuel stream for a PEM fuel cell can be formed from a methanol source using conventional reforming processes for producing H.sub.2.
摘要翻译： 质子交换膜（PEM）燃料电池性能与H2燃料流的CO污染通过将O 2喷射到燃料电池前面的燃料流中而显着提高。 发现即使在低于约100℃的PEM操作温度下也发生表面反应，以氧化除去CO并恢复H 2反应的电极表面积以产生电流。 使用O 2注入，可以使用用于生产H 2的常规重整方法从甲醇源形成用于PEM燃料电池的合适的燃料流。
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40.发明授权Alkaline membrane fuel cells and apparatus and methods for supplying water thereto 有权碱性膜燃料电池及其供给水的设备及方法公开(公告)号：US08637196B2
公开(公告)日：2014-01-28
申请号：US13598035
申请日：2012-08-29
IPC分类号： H01M8/06
CPC分类号： H01M8/103 , H01M4/8605 , H01M4/8807 , H01M4/881 , H01M4/8825 , H01M4/8853 , H01M4/886 , H01M4/8871 , H01M4/8892 , H01M8/023 , H01M8/0289 , H01M8/083 , H01M8/106 , H01M8/1062 , H01M8/1067 , H01M8/1088 , H01M8/1093 , Y02P70/56
摘要： A device to produce electricity by a chemical reaction without the addition of liquid electrolyte comprises an anode electrode, a polymer membrane electrolyte fabricated to conduct hydroxyl (OH—) ions, the membrane being in physical contact with the anode electrode on a first side of the membrane, and a cathode electrode in physical contact with a second side of the membrane. The anode electrode and cathode electrode contain catalysts, and the catalysts are constructed substantially entirely from non-precious metal catalysts. Water may be transferred to the cathode side of the membrane from an external source of water.
摘要翻译： 在没有添加液体电解质的情况下通过化学反应产生电的装置包括阳极电极，制造成进行羟基（OH-）离子的聚合物膜电解质），所述膜在阳极电极的第一面上与阳极电极物理接触 膜和与膜的第二侧物理接触的阴极电极。 阳极电极和阴极电极含有催化剂，催化剂基本上完全由非贵金属催化剂构成。 水可以从外部水源转移到膜的阴极侧。
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