公开(公告)号：US12195664B2

公开(公告)日：2025-01-14

申请号：US18630986

申请日：2024-04-09

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Ryan Hulse ,  Rajiv Ratna Singh ,  Justin Becker ,  Robert Gerard Richard ,  Rajat S. Basu ,  Hang T. Pham ,  Ian Shankland

IPC: C09K5/04 ,  F25B9/00

Abstract: Compositions comprising multi-fluorinated olefins and HFC-32 are disclosed. Such compositions are useful particularly for in stationary refrigeration and air conditioning equipment.

公开(公告)号：US20220363968A1

公开(公告)日：2022-11-17

申请号：US17774055

申请日：2020-11-05

Applicant: Honeywell International Inc.

Inventor： Haiyou Wang ,  Hang T. Pham ,  Hsueh Sung Tung ,  Rajiv Ratna Singh

IPC: C09K5/04

Abstract: Heterogenous azeotrope or azeotrope-like compositions comprising 3,3,3-trifluoropropyne (TFPY) and hydrogen fluoride (HF) which may include from about 71.5 wt. % to about 98.8 wt. % 3,3,3-trifluoropropyne (TFPY) and from about 1.2 wt. % to about 28.5 wt. % hydrogen fluoride and have a boiling point between about −10.0° C. and about 25.0° C. at a pressure of between about 61 psia and about 171 psia. The azeotrope or azeotrope-like compositions may be used to separate 3,3,3-trifluoropropyne (TFPY) as an impurity from compositions of 2-chloro-3,3,3-trifluoropropene (1233xf), 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb), or 2,3,3,3-tetrafluoropropene (HFO-1234yf).

公开(公告)号：US11459284B2

公开(公告)日：2022-10-04

申请号：US17181479

申请日：2021-02-22

Applicant: Honeywell International Inc.

Inventor： Haridasan K. Nair ,  Glenn Matthies ,  Rajiv Ratna Singh ,  Terris Yang ,  Haiyou Wang ,  Ryan J. Hulse ,  Rajiv Banavali

IPC: C07C17/20 ,  C07C17/35 ,  B01J27/224 ,  C07C19/16

Abstract: The present disclosure provides a process for producing trifluoroiodomethane, the process comprising providing a reactant stream comprising hydrogen iodide and at least one trifluoroacetyl halide selected from the group consisting of trifluoroacetyl chloride, trifluoroacetyl fluoride, trifluoroacetyl bromide, and combinations thereof, reacting the reactant stream in the presence of a first catalyst at a first reaction temperature from about 25° C. to about 400° C. to produce an intermediate product stream comprising trifluoroacetyl iodide, and reacting the intermediate product stream in the presence of a second catalyst at a second reaction temperature from about 200° C. to about 600° C. to produce a final product stream comprising the trifluoroiodomethane.

公开(公告)号：US20220177759A1

公开(公告)日：2022-06-09

申请号：US17550560

申请日：2021-12-14

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： David Nalewajek ,  Rajiv Ratna Singh ,  Rajiv Banavali ,  Gregory Laurence Smith

IPC: C09K5/04

Abstract: The present invention provides a composition comprising 2,3,3,3-tetrafluoropropene and α-terpinene particularly useful in automotive air conditioning systems and devices, commercial refrigeration systems and devices, chillers, residential refrigerator and freezers, general air conditioning systems, heat pumps, and the like.

公开(公告)号：US11214720B2

公开(公告)日：2022-01-04

申请号：US16868785

申请日：2020-05-07

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Ryan Hulse ,  Rajiv Ratna Singh ,  Justin Becker ,  Robert Gerard Richard ,  Rajat S. Basu ,  Hang T. Pham ,  Ian Shankland

IPC: C09K5/04 ,  F25B9/00

Abstract: Compositions comprising multi-fluorinated olefins and HFC-32 are disclosed. Such compositions are useful particularly for in stationary refrigeration and air conditioning equipment.

公开(公告)号：US11208582B2

公开(公告)日：2021-12-28

申请号：US16874319

申请日：2020-05-14

Applicant: Honeywell International Inc.

Inventor： Hang T. Pham ,  Ryan J. Hulse ,  Rajiv Ratna Singh ,  Haridasan K. Nair

IPC: C09K5/04 ,  B01D3/36 ,  C07C53/48 ,  C07C19/16

Abstract: The present disclosure provides azeotrope or azeotrope-like compositions including trifluoroiodomethane (CF3I) and trifluoroacetyl chloride (CF3COCl), and a method of forming an azeotrope or azeotrope-like composition comprising the step of combining trifluoroacetyl chloride (CF3COCl) and trifluoroiodomethane (CF3I) to form an azeotrope or azeotrope-like composition.

公开(公告)号：US10954177B2

公开(公告)日：2021-03-23

申请号：US16549412

申请日：2019-08-23

Applicant: Honeywell International Inc.

Inventor： Haridasan K. Nair ,  Glenn Matthies ,  Rajiv Ratna Singh ,  Terris Yang ,  Haiyou Wang ,  Ryan J. Hulse ,  Rajiv Banavali

IPC: C07C17/20 ,  C07C17/35 ,  B01J27/224 ,  C07C19/16

Abstract: The present disclosure provides a process for producing trifluoroiodomethane, the process comprising providing a reactant stream comprising hydrogen iodide and at least one trifluoroacetyl halide selected from the group consisting of trifluoroacetyl chloride, trifluoroacetyl fluoride, trifluoroacetyl bromide, and combinations thereof, reacting the reactant stream in the presence of a first catalyst at a first reaction temperature from about 25° C. to about 400° C. to produce an intermediate product stream comprising trifluoroacetyl iodide, and reacting the intermediate product stream in the presence of a second catalyst at a second reaction temperature from about 200° C. to about 600° C. to produce a final product stream comprising the trifluoroiodomethane.

公开(公告)号：US20200369933A1

公开(公告)日：2020-11-26

申请号：US16874319

申请日：2020-05-14

Applicant: Honeywell International Inc.

Inventor： Hang T. Pham ,  Ryan J. Hulse ,  Rajiv Ratna Singh ,  Haridasan K. Nair

IPC: C09K5/04 ,  B01D3/36

Abstract: The present disclosure provides azeotrope or azeotrope-like compositions including trifluoroiodomethane (CF3I) and trifluoroacetyl chloride (CF3COCl), and a method of forming an azeotrope or azeotrope-like composition comprising the step of combining trifluoroacetyl chloride (CF3COCl) and trifluoroiodomethane (CF3I) to form an azeotrope or azeotrope-like composition.

公开(公告)号：US10752716B2

公开(公告)日：2020-08-25

申请号：US15978103

申请日：2018-05-12

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Changqing Lu ,  Pascal Bolomey ,  Rajiv Ratna Singh ,  Paul Todaro

IPC: C08F214/24 ,  C08F214/06

Abstract: Disclosed are copolymers and terpolymers chlorotrifluoroethylene and vinyl chloride having improved properties, and particularly a high glass transition temperature, for use in membranes, coatings, barrier films, and other applications and process for forming such copolymers and terpolymers, which are useful in reverse osmosis desalination, nanofiltration, ultrafiltration, microfiltration, membrane distillation, pervaporation, selective gas separation, batteries and fuel cells.

公开(公告)号：US20190241489A1

公开(公告)日：2019-08-08

申请号：US16267722

申请日：2019-02-05

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Haridasan K. Nair ,  Rajiv Ratna Singh ,  Glenn Matthies

IPC: C07C17/23

CPC classification number: C07C17/23

Abstract: The present invention relates to a process for the preparation of haloethylenes, and preferably perhaloethylenes, by the gas-phase dechlorination of haloethanes in the presence of a catalyst and optionally in the presence of an alkene or an alkane. In particular aspects, the invention relates to a gas-phase process for preparing chlorotrifluoroethylene (CTFE). More particularly, the present invention relates to a gas-phase process for preparing CTFE from 1,1,2-trichloro-1,2,2-trifluoroethane (CFC-113) by dechlorination in the presence of an alkene or an alkane and a catalyst.