公开(公告)号：US20050054554A1

公开(公告)日：2005-03-10

申请号：US10897703

申请日：2004-07-23

Applicant: Georg Borchers ,  Alexander Lerch ,  Gerd Reinhardt

Inventor： Georg Borchers ,  Alexander Lerch ,  Gerd Reinhardt

IPC: A61K8/00 ,  A61K8/66 ,  A61Q11/02 ,  C11D3/39 ,  C11D3/42 ,  C11D7/22 ,  C11D7/42 ,  C11D7/54 ,  C11D7/60 ,  C11D3/00

CPC classification number: C11D3/3935 ,  C11D3/3907 ,  C11D3/42

Abstract: Detergent additives which are in granule form and are composed essentially of a) an active substance for detergents and b) an optical brightener.

Abstract translation: 颗粒状洗涤剂添加剂，主要由a）用于洗涤剂的活性物质和b）荧光增白剂组成。

公开(公告)号：US06545147B1

公开(公告)日：2003-04-08

申请号：US09658831

申请日：2000-09-08

Applicant: Michael Seebach ,  Gerd Reinhardt ,  Thomas Schönherr ,  Edwin Weber

Inventor： Michael Seebach ,  Gerd Reinhardt ,  Thomas Schönherr ,  Edwin Weber

IPC: C07D25502

CPC classification number: C11D3/3932 ,  C07D255/02 ,  D21C9/1042

Abstract: Compounds of the formula I [LnMmXp]ZYq  (1) are claimed, where L is a ligand of the formula II and the individual symbols have the meanings defined in the description. The metal complexes are suitable as bleaching catalysts in detergents, cleaners and disinfectants which comprise peroxy compounds.

Abstract translation: 式I所示的化合物，其中L是式II的配体，各符号具有说明书中定义的含义。 金属络合物适合作为漂白催化剂在洗涤剂，清洁剂和包含过氧化合物的消毒剂中。

公开(公告)号：US6066365A

公开(公告)日：2000-05-23

申请号：US63985

申请日：1993-05-19

Applicant: Frank Jaekel ,  Gerd Reinhardt ,  Gerhard Noltner

Inventor： Frank Jaekel ,  Gerd Reinhardt ,  Gerhard Noltner

IPC: B01J2/16 ,  B01J2/30 ,  C11D3/39 ,  C11D7/54 ,  C11D11/00 ,  C11D17/00 ,  C11D17/06 ,  D06L3/02 ,  B05D7/00

CPC classification number: C11D3/3907 ,  C11D11/0082 ,  C11D11/0088 ,  C11D17/0039 ,  C11D17/06 ,  C11D3/3935 ,  C11D3/3945

Abstract: The present invention relates to a process for the preparation of low-dust granules, which comprises applying an aqueous solution or suspension of a hydrate-forming compound to a particulate starting material, the particulate starting material being at a temperature below the transition temperature of the hydrate-forming compound during the application of the aqueous solution or suspension and the aqueous solution being at a temperature above the transition temperature, effecting granulation subsequently or simultaneously and, if desired, drying the granules obtained.

Abstract translation: 本发明涉及一种制备低灰尘颗粒的方法，其包括将水合物形成化合物的水溶液或悬浮液施加到颗粒起始材料上，所述颗粒起始材料的温度低于 在施用水溶液或悬浮液期间水合物形成化合物和水溶液处于高于转变温度的温度下，随后或同时进行造粒，如果需要，干燥所获得的颗粒。

公开(公告)号：US5100588A

公开(公告)日：1992-03-31

申请号：US154057

申请日：1988-02-09

Applicant: Fritz-Feo Grabley ,  Gerd Reinhardt ,  Roland Steinl

Inventor： Fritz-Feo Grabley ,  Gerd Reinhardt ,  Roland Steinl

IPC: C07C309/42 ,  C07C20060101 ,  C07C67/00 ,  C07C301/00 ,  C07C303/02 ,  C07C303/04 ,  C07C303/06 ,  C07C303/14 ,  C07C303/30 ,  C07C303/32 ,  C07C309/58 ,  C11D1/22 ,  C11D3/34

CPC classification number: C07C309/00

Abstract: The process for the preparation of acyloxybenzenesulfonic acids of the general formula ##STR1## in which R denotes a (C.sub.1 -C.sub.17)-alkyl or (C.sub.2 -C.sub.17)-alkenyl radical, or alkali metal, alkaline earth metal or ammonium salts thereof, is carried out in the following stages: (a) sulfonation of phenol, (b) heat treatment of the phenolsulfonic acid formed as the intermediate product, (c) esterification of the phenolsulfonic acid and, if appropriate, (d) neutralization of the resulting (C.sub.2 -C.sub.18)-acyloxybenzenesulfonic acid. As a result of the incorporation of stage (b), the process affords products in which the proportion of the 1,4-isomer compared with the 1,2-isomer is markedly increased, as a result of which these products can be used, in particular, as perborate activators in detergents.

Abstract translation: 其中R表示（C1-C17） - 烷基或（C2-C17） - 烯基或其碱金属，碱土金属或铵盐的通式为“IMAGE”的酰氧基苯磺酸的制备方法为 在以下阶段进行：（a）苯酚的磺化，（b）作为中间产物形成的酚磺酸的热处理，（c）苯酚磺酸的酯化，如果合适的话，（d）中和所得的（ C2-C18） - 酰氧基苯磺酸。 作为阶段（b）的结合，该方法提供了与1,2-异构体相比的1,4-异构体的比例显着增加的产物，由此可以使用这些产物， 特别是作为洗涤剂中的过硼酸盐活化剂。

公开(公告)号：US08889611B2

公开(公告)日：2014-11-18

申请号：US13513729

申请日：2010-11-30

Applicant: Gerd Reinhardt ,  Michael Best

Inventor： Gerd Reinhardt ,  Michael Best

IPC: C11D7/26 ,  C11D7/32 ,  C11D7/54 ,  C07F13/00 ,  C11D17/06 ,  C11D17/00 ,  C11D3/16 ,  C11D3/39 ,  D21C9/10 ,  D21C9/16

CPC classification number: C07F13/005 ,  C11D3/168 ,  C11D3/3932 ,  C11D17/0052 ,  C11D17/06 ,  C11D17/065 ,  D21C9/10 ,  D21C9/163

Abstract: The invention relates to compounds in solid form, containing a) one or more manganese complex compounds of the general formula (1), where M is independently selected from manganese in the III or IV oxidation state, X is independently a co-ordinating or bridging species selected from H2O, O22−, O2−, O2−, OH−, HO2−, SH−, S2−, SO, Cl−, N3−, SCN−, N3−, RCOO−, NH2− and NR3, where R is a radical selected from H, alkyl and aryl, L are independently organic ligands, each of which contains at least two nitrogen atoms co-ordinated on manganese, z is an integer from −4 to +4, Y is a monovalent or multivalent counter-ion selected from chloride, sulphate, hydrogen sulphate, nitrate and acetate, which leads to charge neutrality of the complex, and q is an integer from 1 to 4, and b) one or more salts of the general formula R′—C6H4—SO3Me, where R′ is CH3 or C2H5 and denotes Me, Na, K, Ca or Mg, characterized in that the molar ratio of the manganese complex compound of the general formula (1) to salt of the general formula R′—C6H4—SO3Me is 1:0.5 to 1:5. The invention also describes a method for producing the compounds and to the use thereof as oxidation catalysts or bleach catalysts, in particular in detergents or cleaning agents.

Abstract translation: 本发明涉及固体形式的化合物，其包含a）一种或多种通式（1）的锰络合物，其中M独立地选自III或IV氧化态的锰，X独立地为配位或桥接 选自H2O，O22-，O​​2-，O2-，OH-，HO2-，SH-，S2-，SO，Cl-，N3-，SCN-，N3-，RCOO-，NH2-和NR3的物质，其中R 是选自H，烷基和芳基的基团，L独立为有机配体，每个含有至少两个在锰上配位的氮原子，z为-4至+4的整数，Y为单价或多价计数器 其选自氯化物，硫酸盐，硫酸氢盐，硝酸盐和乙酸盐，这导致络合物的电荷中性，q是1至4的整数，b）一种或多种通式R'-C6H4- SO 3 Me，其中R'是CH 3或C 2 H 5，并且表示Me，Na，K，Ca或Mg，其特征在于锰络合物 通式（1）表示的化合物与通式R'-C6H4-SO3Me的盐为1:0.5至1:5。 本发明还描述了一种制备化合物的方法及其用作氧化催化剂或漂白催化剂的用途，特别是在洗涤剂或清洁剂中。

公开(公告)号：US08846921B2

公开(公告)日：2014-09-30

申请号：US13877567

申请日：2011-10-06

Applicant: Christian Sidot ,  Audrey Caron ,  Miriam Ladwig ,  Gerd Reinhardt

Inventor： Christian Sidot ,  Audrey Caron ,  Miriam Ladwig ,  Gerd Reinhardt

IPC: C07F15/02 ,  C07F13/00

CPC classification number: C07F15/02 ,  C07F13/00 ,  C07F13/005 ,  C07F15/025

Abstract: The invention relates to a method for producing metal complexes of formula (2) [MaLxXn]Ym (2), where M is a metal from the group consisting of Mn(II), Mn(III), Mn(IV), Fe(II), Fe(III) or Fe(IV), X is a coordinating compound selected from mono-, bi- or tri-charged anions or neutral molecules which can coordinate to a metal in mono-, bi- or tri-dentate form, Y represents a non-coordinating counter-ion which ensures charge equalization of the complex, L represents a ligand of formula (1) or the protonized or de-protonized form thereof, and a, x, n, m, R, R1, R2, R3 and z have the meanings described in claim 1. Said method is characterized in that the reaction of one or more ligands of formula (1) with an iron salt or manganese salt is carried out in an acetone/water mixture in a temperature range from 0 to 50° C. and for this purpose a solution or a suspension of the one or more ligands of formula (1) in acetone is brought in contact with an aqueous metal salt solution of the iron salt or manganese salt in the temperature range in which the reaction takes place.

Abstract translation: 本发明涉及一种制备式（2）[MaLxXn] Ym（2）的金属配合物的方法，其中M是由Mn（II），Mn（III），Mn（IV），Fe（ II），Fe（III）或Fe（IV），X是选自单，双或三电荷阴离子或中性分子的配位化合物，其可以以单，双或三齿形式与金属配位 ，Y表示非配位抗衡离子，其确保络合物的电荷均衡，L表示式（1）的配体或其质子化或去质子化形式，和a，x，n，m，R，R 1， R2，R3和z具有权利要求1所述的含义。所述方法的特征在于，式（1）的一种或多种配体与铁盐或锰盐的反应在丙酮/水混合物中在温度 范围为0至50℃，为此目的，将式（1）的一种或多种配体在丙酮中的溶液或悬浮液与铁盐水溶液的金属盐溶液接触 r锰盐在发生反应的温度范围内。

公开(公告)号：US20120302490A1

公开(公告)日：2012-11-29

申请号：US13513729

申请日：2010-11-30

Applicant: Gerd Reinhardt ,  Michael Best

Inventor： Gerd Reinhardt ,  Michael Best

IPC: B01J31/22 ,  C11D3/30

CPC classification number: C07F13/005 ,  C11D3/168 ,  C11D3/3932 ,  C11D17/0052 ,  C11D17/06 ,  C11D17/065 ,  D21C9/10 ,  D21C9/163

Abstract: The invention relates to compounds in solid form, containing a) one or more manganese complex compounds of the general formula (I), where M is independently selected from manganese in the III or IV oxidation state, X is independently a co-ordinating or bridging species selected from H2O, O22−, O2−, O2−, OH−, HO2−, SH−, S2−, SO, Cl−, N3−, SCN−, N3−, RCOO−, NH2− and NR3, where R is a radical selected from H, alkyl and aryl, L are independently organic ligands, each of which contains at least two nitrogen atoms co-ordinated on manganese, z is an integer from −4 to +4, Y is a monovalent or multivalent counter-ion selected from chloride, sulphate, hydrogen sulphate, nitrate and acetate, which leads to charge neutrality of the complex, and q is an integer from 1 to 4, and b) one or more salts of the general formula R′—C6H4—SO3Me, where R′ is CH3 or C2H5 and denotes Me, Na, K, Ca or Mg, characterised in that the molar ratio of the manganese complex compound of the general formula (1) to salt of the general formula R′—C6H4—SO3Me is 1:0.5 to 1:5. The invention also describes a method for producing the compounds and to the use thereof as oxidation catalysts or bleach catalysts, in particular in detergents or cleaning agents.

Abstract translation: 本发明涉及固体形式的化合物，其包含a）一种或多种通式（I）的锰络合物，其中M独立地选自III或IV氧化态的锰，X独立地为配位或桥接 选自H2O，O22-，O​​2-，O2-，OH-，HO2-，SH-，S2-，SO，Cl-，N3-，SCN-，N3-，RCOO-，NH2-和NR3的物质，其中R 是选自H，烷基和芳基的基团，L独立为有机配体，每个含有至少两个在锰上配位的氮原子，z为-4至+4的整数，Y为单价或多价计数器 其选自氯化物，硫酸盐，硫酸氢盐，硝酸盐和乙酸盐，其导致络合物的电荷中性，q是1至4的整数，b）一种或多种通式R'-C6H4- SO 3 Me，其中R'是CH 3或C 2 H 5，并且表示Me，Na，K，Ca或Mg，其特征在于锰络合物 通式（1）表示的化合物与通式R'-C6H4-SO3Me的盐为1:0.5至1:5。 本发明还描述了一种制备化合物的方法及其用作氧化催化剂或漂白催化剂的用途，特别是在洗涤剂或清洁剂中。

公开(公告)号：US20100087674A1

公开(公告)日：2010-04-08

申请号：US12598229

申请日：2008-04-29

Applicant: Gerd Reinhardt ,  Peter Newmann ,  Lars Cuypers

Inventor： Gerd Reinhardt ,  Peter Newmann ,  Lars Cuypers

IPC: C07C309/00

CPC classification number: C07C303/44 ,  C07C303/14 ,  C07C309/04

Abstract: The invention relates to a method for isolating concentrated paraffin sulfonic acids from reaction mixtures that are produced during the sulfoxidation of n-paraffins, from which a major part of the sulfuric acid and the paraffin was removed by phase separation and which contain, in addition to the free paraffin sulfonic acids, n-paraffins, water and optionally minor amounts of sulfuric acids. The method according to the invention is characterized by removing paraffin and optionally residual water by vacuum distillation. The paraffin sulfonic acids obtained by distillation have a content of more than 85% by weight of the active substance. The material is pale, odorless and low in sulfuric acid and paraffin.

Abstract translation: 本发明涉及一种从正链烷烃的亚磺氧化反应中产生的反应混合物中分离浓缩的链烷磺酸的方法，其中大部分硫酸和石蜡通过相分离从其中除去，除了含有 游离的链烷烃磺酸，正链烷烃，水和任选的少量硫酸。 根据本发明的方法的特征在于通过真空蒸馏除去石蜡和任选的残余水。 通过蒸馏获得的链烷磺酸含量大于活性物质的85重量％。 该材料为浅灰色，无臭，硫酸和石蜡含量低。

公开(公告)号：US20090289221A1

公开(公告)日：2009-11-26

申请号：US12376423

申请日：2007-07-31

Applicant: Gerd Reinhardt ,  Georg Borchers ,  Michael Seebach

Inventor： Gerd Reinhardt ,  Georg Borchers ,  Michael Seebach

IPC: C11D3/395

CPC classification number: C11D3/392 ,  C11D3/3917 ,  C11D3/3927 ,  C11D17/0034

Abstract: The use is claimed of aminoacetones or salts thereof of the general formulae (I) and (II) in which R1 and R2 are each independently hydrogen, C1-C22-alkyl, C2-C22-alkenyl, phenyl or C5-C8-cycloalkyl, or R1 and R2, together with the nitrogen atom, form a 5-, 6- or 7-membered ring system, X′ is anion, for example chloride, bromide, iodide, toluenesulfonate, benzenesulfonate, cumenesulfonate, mesitylsulfonate, sulfate, hydrogensulfate, acetate, fatty acid anion or anion of polycarboxylates, as a bleaching booster for inorganic peroxygen compounds in the pH range from 7 to 9.

Abstract translation: 要求使用通式（I）和（II）的氨基丙酮或其盐，其中R 1和R 2各自独立地为氢，C 1 -C 22 - 烷基，C 2 -C 22 - 烯基，苯基或C 5 -C 8 - 环烷基， 或R 1和R 2与氮原子一起形成5-，6-或7-元环体系，X'是阴离子，例如氯化物，溴化物，碘化物，甲苯磺酸盐，苯磺酸盐，磺酸盐，月桂基磺酸盐，硫酸盐，硫酸氢盐， 乙酸盐，脂肪酸阴离子或多羧酸盐阴离子，作为无机过氧化合物的漂白助剂，pH范围为7至9。

公开(公告)号：US07109155B2

公开(公告)日：2006-09-19

申请号：US10727770

申请日：2003-12-04

Applicant: Gerd Reinhardt ,  Irina Geiger ,  Matthias Loeffler ,  Roman Morschhaeuser

Inventor： Gerd Reinhardt ,  Irina Geiger ,  Matthias Loeffler ,  Roman Morschhaeuser

IPC: C11D17/08 ,  C11D9/42 ,  C11D3/37 ,  C11D3/395 ,  C11D7/54

CPC classification number: C11D3/37 ,  C11D3/3719 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/3947

Abstract: Liquid bleaching composition components are claimed which comprise 1) amphiphilic copolymers which include structural units which are derived from a) acryloyldimethyltauric acid in free, partially neutralized or completely neutralized form with mono- or divalent inorganic or organic cations and b) at least one hydrophobic comonomer based on ethylenically unsaturated polyalkylene alkoxylates and optionally c) further at least monovinylically unsaturated comonomers different from a) and b), and 2) at least one bleach activator, bleach catalyst or oxygen transfer agent.

Abstract translation: 要求保护液体漂白组合物组分，其包含1）两亲共聚物，其包括衍生自a）丙烯酰基二甲基牛磺酸的游离，部分中和或完全中和形式的单或二价无机或有机阳离子的结构单元，和b）至少一种疏水性共聚单体 基于烯键式不饱和聚亚烷基烷氧基化物和任选地c）至少一种不同于a）和b）的单乙烯基不饱和共聚单体，和2）至少一种漂白活化剂，漂白催化剂或氧转移剂。