摘要:
A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure: M--Q.sub.n --Z--OA(R.sup.1 R.sup.2 R.sup.3) wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenylsubstituted aromatic hydrocarbons; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; A is an element selected from carbon and silicon; R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and n is an integer from 1 to 5, monofunctional ethers produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译:一种制备以下一般结构的单官能醚引发剂的烃溶液的方法:M-Qn-Z-OA(R1R2R3)其中M定义为碱金属,选自锂,钠和钾,Q 是通过引入选自共轭二烯烃和烯基取代的芳族烃的化合物衍生的饱和或不饱和烃基; Z是含有3-25个碳原子的支链或直链烃基,任选含有芳基或取代的芳基; A是选自碳和硅的元素; R 1,R 2和R 3独立地选自氢,烷基,含有低级烷基,低级烷硫基和低级二烷基氨基的取代烷基,含有低级烷基,低级烷硫基和低级二烷基氨基的芳基或取代芳基,n是 1至5的整数,通过该方法产生的单官能醚,在聚合方法中使用引发剂和通过聚合方法制备的聚合物。
摘要:
A process for preparing easily separable solutions of organolithium compounds comprising the steps of reacting lithium metal, in the form of cast or extruded ingots or pieces cut therefrom, with an organo halide in mole ratios ranging from 3:1 to 20:1 in a solvent selected form a group of liquid hydrocarbons, alkyl ethers, and mixtures thereof under an inert atmosphere for one to ten hours with moderate stirring, cooling the resulting product, and separating the solution of the organolithium compound from the reacted lithium metal and by-product lithium chloride in the reactor.
摘要:
The present invention provides protected functionalized polymerization initiators having less than one molar equivalent chain extension agent introduced therein to provide hydrocarbon solubility.
摘要:
This invention relates to aryloxy dihydrobenzofuran, oxoindole or benzofuranone derivatives having herbicidal activity and to the use of such compounds to control the growth of noxious plants, i.e., weeds.
摘要:
Imidazolidinone imines are provided as well as a process for preparing same including corresponding imidazolidinone amines which compounds are useful as herbicides.
摘要:
A process for preparing high purity solutions of highly substituted lithium amide bases by direct reaction of lithium metal with highly substituted amine bases alone or in an ether solvent, a hydrocarbon solvent or in a mixed ether/hydrocarbon solvent mixture, optionally in the presence of a catalyst selected from tin salts and transition metal salts of Groups 4B, 5B, 6B, 7B, and 8 of the Periodic Table.
摘要:
This invention relates to certain herbicidally active substituted diphenyl ether oxime derivatives, herbidical compositions of the same and the use thereof for preemergence and postermergence control of noxious plants, i.e., weeds.
摘要:
The invention relates to certain 3-isoxazolyl-2-imidazolidinone derivatives, namely 3-[5- or 3-substituted-3- or 5-isoxazolyl]-1-substituted-4-substituted amino-2-imidazolidinones and the uses thereof for preemergence or postemergence control of noxious plants, i.e., weeds.
摘要:
The invention relates to herbicidally active 3-oxadiazolyl-2-imidazolidinone derivatives, including herbicidal formulation and the use thereof to control the growth of noxious plants, i.e., weeds.
摘要:
The present invention provides novel anionic polymerization amine initiators having a tertiary amine group pendant to the polymer chain and processes for making the same. The initiators can be useful in the preparation of tertiary amine containing polymers, including linear, homotelechelic, heterotelechelic and radial polymers.