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    Propenyl ether monomers for photopolymerization
    31.
    发明授权
    Propenyl ether monomers for photopolymerization 失效
    用于光聚合的丙烯基醚单体

    公开(公告)号：US5567858A

    公开(公告)日：1996-10-22

    申请号：US571200

    申请日：1995-12-12

    Applicant: James V. Crivello

    Inventor： James V. Crivello

    IPC: C08F2/46 ,  C08F16/32 ,  C07C43/11

    CPC classification number: C08F16/32

    Abstract: Propenyl ether monomers of formula VA(OCH.dbd.CHCH.sub.3).sub.nwherein n is an integer from one to six and A is selected from cyclic ethers, polyether and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of formula V together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.

    Abstract translation: 式V A（OCH = CHCH 3）n的丙烯基醚单体，其中n是1至6的整数，A选自环醚，聚醚和烷烃。 当阳离子光引发剂暴露于光化辐射时，单体易于聚合形成可用于涂料，密封剂，清漆和粘合剂的聚（丙烯基醚）。 还公开了用于制备包含式V化合物与特定阳离子光引发剂的聚合物涂层的组合物，以及由烯丙基卤化物和容易获得的醇制备单体的方法。 该方法包括将所得烯丙基醚重排为丙烯基醚。

    Photocurable compositions of polyindane and 1,3-diisopropenylbenzene, and coating process
    32.
    发明授权
    Photocurable compositions of polyindane and 1,3-diisopropenylbenzene, and coating process 失效
    聚茚二酮和1,3-二异丙烯基苯的光固化组合物及涂布方法

    公开(公告)号：US5350604A

    公开(公告)日：1994-09-27

    申请号：US988218

    申请日：1992-12-09

    Applicant: James V. Crivello

    Inventor： James V. Crivello

    IPC: C08F12/34 ,  C08F277/00 ,  B05D1/26 ,  B05D3/12

    CPC classification number: C08F12/34 ,  C08F277/00

    Abstract: A process for cationically polymerizing 1,3-diisopropenylbenzene to produce a polymer which is predominantly a polyindane is disclosed. The resulting polyindanes are novel compounds useful as low dielectric constant coatings. Compositions containing 1,3-diisopropenylbenzene and cationic photoinitiators, and optionally containing a polyindane useful for preparing coatings, are disclosed as are processes for coating substrates using the compositions.

    Abstract translation: 公开了一种使1,3-二异丙烯基苯阳离子聚合以产生主要为聚茚的聚合物的方法。 所得聚茚二醇是可用作低介电常数涂层的新型化合物。 公开了包含1,3-二异丙烯基苯和阳离子光引发剂的组合物，以及任选地含有用于制备涂层的聚茚丹酮的组合物，是使用该组合物涂覆基材的方法。

    Preparation of epoxysilicon compounds using rhodium catalysts
    34.
    发明授权
    Preparation of epoxysilicon compounds using rhodium catalysts 失效
    使用铑催化剂制备环氧化合物

    公开(公告)号：US5169962A

    公开(公告)日：1992-12-08

    申请号：US583524

    申请日：1990-09-17

    Applicant: James V. Crivello ,  Ming-Xin Fan

    Inventor： James V. Crivello ,  Ming-Xin Fan

    IPC: B01J31/20 ,  B01J31/22 ,  B01J31/24 ,  B01J31/30 ,  C07B61/00 ,  C07F7/08 ,  C07F7/21 ,  C08G59/20 ,  C08G59/30 ,  C08G77/38 ,  C08L83/06

    CPC classification number: C08G77/38 ,  C07F7/0879 ,  C08L83/06

    Abstract: A method for making an epoxyfunctional organosilicon compound is provided, comprising the step of reacting at a temperature of from about 25.degree. to about 100.degree. C. a mixture comprising (A) an ethylenically unsaturated epoxide; (B) an organohydrogenpolysiloxane or organohydrogensilane; and (C) a rhodium complex catalyst selected from the group consisting of:(i) RhX.sub.3 (SR.sub.2).sub.3 ;(ii) RhX.sub.3 .multidot.xH.sub.2 O;(iii) [RhX(norbornadiene)].sub.2 ;(iv) RhX(CO)(R.sub.3 P).sub.3 ;(v) RhX(R.sub.3 P).sub.3 ; and(vi) [RhCl(cyclooctadiene)].sub.2 ;wherein X is a halogen atom, x is a number equal to 3 or 4, and R is an alkyl radical having from 1 to 8 inclusive carbon atoms, aryl, aralkyl, or alkaryl radical or the R.sub.3.sup.1 SiQ-- group in which Q represents a divalent aliphatic hydrocarbon radical having from 1 to 6 inclusive carbon atoms and R.sup.1 represents an alkyl radical having from 1 to 8 inclusive carbon atoms, aryl, aralkyl, or alkaryl radical or a (CH.sub.3).sub.3 Si-- radical.

    Triaryl sulfonium photoinitiators
    36.
    发明授权
    Triaryl sulfonium photoinitiators 失效
    三芳基锍光引发剂

    公开(公告)号：US5012001A

    公开(公告)日：1991-04-30

    申请号：US516842

    申请日：1990-04-30

    Applicant: James V. Crivello

    Inventor： James V. Crivello

    IPC: C07C321/30 ,  C07C381/12 ,  C07D333/76 ,  C07F9/02

    CPC classification number: C07C381/12 ,  C07D333/76

    Abstract: Triarylsulfonium polyfluoro metal or metalloid salts are provided by effecting the oxidation of a diarylsulfide, while under dehydrating conditions, in the presence of a strong protonic acid. The resulting triarylsulfonium acid salt can thereafter be directly metathesized with an alkali metal or alkaline earth metal polyhalo salt.These compounds have the general formula ##STR1## where Q is selected from .dbd.S.fwdarw.O, --S-- and mixtures thereof, M is a transition metal or metalloid, "c" is an integer of 1 to 3, "d" is an integer of 0 to 3, R.sup.6 is phenyl or naphthyl, R.sup.7 is phenylene or naphthalene optionally substituted with one or more radicals selected from the class consisting of --CH.sub.3, --OCH.sub.3, --CO.sub.2 H, --Br, --Cl, and NO.sub.2.

    Abstract translation: 三芳基锍多氟金属或准金属盐通过在脱水条件下在强质子酸存在下进行二芳基硫醚的氧化来提供。 得到的三芳基锍酸盐之后可以用碱金属或碱土金属的多卤盐直接复分解。 这些化合物具有通式MF6- + R6Q（R7Q）cR7SR7（QR7）dQR6，其中Q选自= S，O，-S-及其混合物，M为过渡金属或准金属，“c”为整数 为1〜3，“d”为0〜3的整数，R6为苯基或萘基，R7为任选被一个或多个选自-CH 3，-OCH 3，-CO 2 H - 的基团取代的亚苯基或萘基， Br，-Cl和NO2。

    Silicone-organic block polymers and method for making
    38.
    发明授权
    Silicone-organic block polymers and method for making 失效
    硅酮 - 有机嵌段聚合物及其制备方法

    公开(公告)号：US4677169A

    公开(公告)日：1987-06-30

    申请号：US840168

    申请日：1986-03-17

    Applicant: James V. Crivello

    Inventor： James V. Crivello

    IPC: C08F4/00 ,  C08F283/12 ,  C08F293/00 ,  C08G77/42 ,  C08G77/442

    CPC classification number: C08F283/124 ,  C08F293/00 ,  C08G77/442

    Abstract: A method is provided for making silicone-organic block polymers, such as polydimethylsiloxane-polystyrene block polymers resulting from the thermal generation of free-radicals in the presence of free-radical polymerizable organic monomer. A silicone prepolymer is used having chemically combined pinacolate groups in the backbone or terminal positions which are capable of generating free-radicals upon thermolysis and which retain chemically combined remnants of such pinacolate diradicals which serve as connecting sites for free-radical polymerized organic blocks.

    Abstract translation: 提供一种制备硅氧烷 - 有机嵌段聚合物的方法，例如在可自由基聚合的有机单体存在下由自由基的热产生产生的聚二甲基硅氧烷 - 聚苯乙烯嵌段聚合物。 使用硅氧烷预聚物，其在骨架或末端位置具有化学结合的频哪醇酸基团，其能够在热解时产生自由基，并且保留作为自由基聚合有机嵌段的连接位点的这种频哪变异构双链体的化学组合残余物。

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