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    Three-Phase Hydroprocessing Without A Recycle Gas Compressor
    31.
    发明申请
    Three-Phase Hydroprocessing Without A Recycle Gas Compressor 有权
    没有循环气体压缩机的三相加氢处理

    公开(公告)号：US20090321310A1

    公开(公告)日：2009-12-31

    申请号：US12165499

    申请日：2008-06-30

    申请人： Peter Kokayeff ,  John Anthony Petri

    发明人： Peter Kokayeff ,  John Anthony Petri

    IPC分类号： C10G65/02

    CPC分类号： C10G65/02

    摘要： In general, methods of hydroprocessing a hydrocarbonaceous feed stock are provided that do not use a costly recycle gas compressor, but are still able to use the more efficient reaction systems provided in a substantially three-phase hydroprocessing zone. The method combines a substantially liquid-phase hydroprocessing zone with the substantially three-phase hydroprocessing zone in a manner so that the hydrogen requirements for both reaction zones can be provided from an external source thereto without the use of a hydrogen recycle or recycle gas compressor to the substantially three-phase reaction zone.

    摘要翻译： 通常，提供加氢处理烃原料的方法，其不使用昂贵的循环气体压缩机，但仍然能够使用在基本上三相的加氢处理区域中提供的更有效的反应系统。 该方法将基本上液相加氢处理区域与基本上三相的加氢处理区域结合，使得可以从外部来源向两个反应区域提供氢气需求，而不需要使用氢循环或再循环气体压缩机 基本上是三相反应区。

    Hydrotreating olefin stream with complete destruction of oxygenates
    33.
    发明授权
    Hydrotreating olefin stream with complete destruction of oxygenates 有权
    加氢处理烯烃流完全破坏含氧化合物

    公开(公告)号：US06548721B1

    公开(公告)日：2003-04-15

    申请号：US09862897

    申请日：2001-05-22

    申请人： Beth Mc Culloch ,  Jennifer L. Gordon ,  Peter Kokayeff ,  Suheil F. Abdo ,  Daniel H. Wei

    发明人： Beth Mc Culloch ,  Jennifer L. Gordon ,  Peter Kokayeff ,  Suheil F. Abdo ,  Daniel H. Wei

    IPC分类号： C07C502

    CPC分类号： C07C7/163 ,  C07C2523/85 ,  C07C2523/883 ,  C07C2527/02 ,  C07C11/02

    摘要： Disclosed is a process for completely destroying oxygenates in a feed stream. The feed stream of oxygenates typically includes olefins and it is reacted with hydrogen over a catalyst comprising a top row of Group VIII metal and a Group VI-B metal. Olefins are essentially completely saturated and any sulfur compounds present in the feed are completely converted to hydrogen sulfide. A preferred catalyst includes 2 to 5 wt-% nickel, 5 to 15 wt-% molybdenum, at least 5.5 wt-% sulfur, less than 0.05 wt-% phosphorus and no more than 0.3 wt-% silicon. The catalyst has low acidity and therefore does not promote the cracking of desired oligomeric products. The deoxygenation process is preferably a saturation process that follows an oligomerization process in which light olefins are oligomerized to heavy olefins. The saturation catalyst preferably has lower acidity which causes minimal cracking of desired oligomeric products. However, by optimally raising the temperature of the outlet of the saturation reaction zone, excessively heavy oligomers can be cracked down to desirable heavy oligomers.

    摘要翻译： 公开了一种在进料流中完全破坏含氧化合物的方法。 含氧化合物的进料流通常包括烯烃，并且其与氢气在包含第一排VIII族金属和VI-B族金属的催化剂上反应。 烯烃基本上完全饱和，并且进料中存在的任何硫化合物完全转化成硫化氢。 优选的催化剂包括2至5重量％的镍，5至15重量％的钼，至少5.5重量％的硫，小于0.05重量％的磷和不超过0.3重量％的硅。 催化剂具有低酸度，因此不促进所需低聚产物的裂化。 脱氧方法优选是在轻烯烃低聚至重质烯烃的低聚方法之后的饱和方法。 饱和催化剂优选具有较低的酸度，这导致所需低聚产物的最小裂化。 然而，通过最佳地提高饱和反应区的出口的温度，过量的低聚物可以被裂化成所需的重低聚物。

    Hydrotreating with silicon removal
    34.
    发明授权
    Hydrotreating with silicon removal 失效
    加氢处理除硅

    公开(公告)号：US5118406A

    公开(公告)日：1992-06-02

    申请号：US693369

    申请日：1991-04-30

    申请人： Peter Kokayeff ,  Danford E. Clark ,  Howard D. Simpson

    发明人： Peter Kokayeff ,  Danford E. Clark ,  Howard D. Simpson

    IPC分类号： C10G45/08

    CPC分类号： C10G45/08

    摘要： A catalytic hydrotreating process wherein silicon-containing contaminants contained in a hydrocarbon feedstream are deposited onto a hydrotreating catalyst bed during hydrotreating in a manner providing improved catalyst stability. Hydrotreating catalysts having relatively high activities and low surface areas are located downstream of upstream hydrotreating catalysts having relatively low activities and high surface areas.

    摘要翻译： 催化加氢处理方法，其中包含在烃进料流中的含硅污染物以提供改进的催化剂稳定性的方式在加氢处理期间沉积在加氢处理催化剂床上。 具有较高活性和低表面积的加氢处理催化剂位于具有较低活性和高表面积的上游加氢处理催化剂的下游。

    Hydrotreating Processes for Fabricating Petroleum Distillates from Light Fischer-Tropsch Liquids
    35.
    发明申请
    Hydrotreating Processes for Fabricating Petroleum Distillates from Light Fischer-Tropsch Liquids 审中-公开
    从轻的费 - 托液制造石油馏分的加氢处理方法

    公开(公告)号：US20120269695A1

    公开(公告)日：2012-10-25

    申请号：US13534586

    申请日：2012-06-27

    申请人： Peter Kokayeff

    发明人： Peter Kokayeff

    IPC分类号： B01J8/00 ,  B01J19/00 ,  B01J10/00

    CPC分类号： C10G47/20 ,  C10G2/30 ,  C10G45/06 ,  C10G45/10 ,  C10G45/12 ,  C10G45/62 ,  C10G45/64 ,  C10G47/18 ,  C10G65/043 ,  C10G65/12 ,  C10G2300/1022 ,  C10G2300/304 ,  C10G2300/307 ,  C10G2400/04

    摘要： A method for obtaining a petroleum distillate product is provided, the method includes subjecting an untreated light Fischer-Tropsch liquid to a two-step hydrogenation process, each step to be carried in the presence of a catalyst comprising an amorphous substrate having a metallic composition embedded therein. After the first step of hydrogenation, an intermediate hydrotreated light Fischer-Tropsch liquid is obtained, followed by the second step of hydrogenation thereof, obtaining the petroleum distillate product as a result. An apparatus for carrying out the method is also provided.

    摘要翻译： 提供了一种获得石油馏出物产品的方法，该方法包括使未经处理的费 - 托液体进行两步氢化处理，每个步骤在催化剂存在下进行，该催化剂包含嵌入金属组成的非晶基材 其中。 在氢化的第一步骤之后，获得中间体加氢处理的费 - 托液，随后进行第二步氢化，得到石油馏分产物。 还提供了一种用于执行该方法的装置。

    METHODS FOR PRODUCING DIESEL RANGE MATERIALS HAVING IMPROVED COLD FLOW PROPERTIES
    36.
    发明申请
    METHODS FOR PRODUCING DIESEL RANGE MATERIALS HAVING IMPROVED COLD FLOW PROPERTIES 审中-公开
    用于生产具有改进的冷流特性的柴油机系列材料的方法

    公开(公告)号：US20120090223A1

    公开(公告)日：2012-04-19

    申请号：US12903874

    申请日：2010-10-13

    申请人： Peter Kokayeff ,  Suheil Abdo

    发明人： Peter Kokayeff ,  Suheil Abdo

    IPC分类号： C10L1/18 ,  C10L1/182 ,  C10G35/04 ,  C10L1/188

    CPC分类号： C10G45/60 ,  C10G3/42 ,  C10G3/50 ,  C10G45/58 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1022 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2300/304 ,  C10G2300/70 ,  C10G2400/04 ,  C10L1/026 ,  C10L1/08 ,  Y02P30/20

    摘要： Embodiments of a method for producing a diesel range material having improved cold flow properties are provided. In one embodiment, the method includes the steps of providing a waxy diesel range feedstock, producing an intermediary product stream containing a predetermined amount of oxygenated organocompounds from the waxy diesel range feedstock, and contacting the intermediary product stream with a dewaxing catalyst under process conditions at which the oxygenated organocompounds chemically interact with the dewaxing catalyst to convert a portion of the n-paraffins within the intermediary product stream to iso-paraffins while minimizing cracking of the diesel range material.

    摘要翻译： 提供了具有改善的冷流特性的柴油范围材料的制造方法的实施例。 在一个实施方案中，该方法包括以下步骤：提供蜡质柴油范围原料，产生含有来自蜡质柴油范围原料的预定量的含氧有机化合物的中间产物流，并在中间产物流与脱蜡催化剂在工艺条件下接触 其中氧化的有机化合物与脱蜡催化剂化学相互作用以将中间产物流中的一部分正链烷烃转化为异链烷烃，同时使柴油范围材料的破裂最小化。

    Hydrocarbon conversion process to improve cetane number
    39.
    发明授权
    Hydrocarbon conversion process to improve cetane number 有权
    烃转化过程提高十六烷值

    公开(公告)号：US07790020B2

    公开(公告)日：2010-09-07

    申请号：US11872102

    申请日：2007-10-15

    申请人： Peter Kokayeff ,  Laura Elise Leonard ,  Michael Roy Smith

    发明人： Peter Kokayeff ,  Laura Elise Leonard ,  Michael Roy Smith

    IPC分类号： C10G45/44 ,  C10G65/02

    CPC分类号： C10G45/02 ,  C10G2400/04

    摘要： A process is provided for producing low sulfur diesel having a high cetane number where the temperature and pressure requirements for obtaining low levels of sulfur is separated from the temperature and pressure requirements for improving cetane. In one aspect, a low pressure hydrodesulfurization zone and a high pressure aromatic saturation zone are employed to sequentially achieve the desired sulfur and cetane levels. In another aspect, the process first converts a diesel boiling range hydrocarbonaceous stream in a hydrotreating zone at conditions effective to produce a hydrotreating zone effluent having a reduced concentration of sulfur with minimal saturation of aromatics. Hydrogen is then admixed with the hydrotreating zone effluent, which is then reacted in a substantially liquid-phase continuous reaction zone substantially undiluted with other streams to effect saturation of aromatics to provide a liquid-phase continuous reaction zone effluent having an improved cetane number.

    摘要翻译： 提供了一种生产具有高十六烷值的低硫柴油的方法，其中获得低水平硫的温度和压力要求与用于改善十六烷的温度和压力要求分离。 一方面，使用低压加氢脱硫区和高压芳族饱和区来顺序地获得所需的硫和十六烷值。 在另一方面，该方法首先在加氢处理区中转化柴油沸程烃流，其条件是有效地产生具有降低的硫浓度并且具有最小芳烃饱和度的加氢处理区流出物。 然后将氢气与加氢处理区流出物混合，然后将其在基本上液相连续的反应区中与基本上未稀释的其它流反应，以实现芳族化合物的饱和，以提供具有改进的十六烷值的液相连续反应区流出物。

    Hydrodesulfurization process
    40.
    发明授权
    Hydrodesulfurization process 失效
    加氢脱硫工艺

    公开(公告)号：US07749375B2

    公开(公告)日：2010-07-06

    申请号：US11852174

    申请日：2007-09-07

    申请人： Peter Kokayeff ,  Laura Elise Leonard

    发明人： Peter Kokayeff ,  Laura Elise Leonard

    IPC分类号： C10G45/04 ,  C10G45/08

    CPC分类号： B01J37/0221 ,  B01J23/85 ,  B01J23/882 ,  B01J35/008 ,  C10G2400/02

    摘要： In one aspect, a hydrodesulfurization process is provided that selectively desulfurizes a hydrocarbon stream with minimal olefin saturation and minimal recombination of sulfur into mercaptans. In another aspect, the process includes a multi-stage reaction zone including at least first and second serial hydrodesulfurization reaction zones that sequentially remove sulfur from a hydrocarbon stream. In yet another aspect, the process is particularly suited to selectively desulfurize an olefinic naphtha hydrocarbon stream, such as FCC naphtha, steam cracked naphtha, coker naphtha, or other gasoline boiling hydrocarbon streams.

    摘要翻译： 在一个方面，提供加氢脱硫方法，其选择性地使烃流以最少的烯烃饱和度和硫的最小重组硫化为硫醇。 在另一方面，该方法包括多级反应区，其包括至少第一和第二连续加氢脱硫反应区，其顺序地从烃流中除去硫。 在另一方面，该方法特别适用于烯烃石脑油烃流选择性脱硫，例如FCC石脑油，蒸汽裂解石脑油，焦化石脑油或其他汽油沸腾烃流。