公开(公告)号：US12071592B2

公开(公告)日：2024-08-27

申请号：US17856853

申请日：2022-07-01

Applicant: Magēmā Technology LLC

Inventor： Michael Joseph Moore ,  Bertrand Ray Klussmann ,  Carter James White

IPC: C10G45/04 ,  B01D3/34 ,  B01D53/14 ,  B01J8/00 ,  B01J8/02 ,  B01J8/04 ,  B01J21/04 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  C10G7/00 ,  C10G25/00 ,  C10G25/02 ,  C10G45/02 ,  C10G45/06 ,  C10G45/08 ,  C10G45/22 ,  C10G47/02 ,  C10G65/04 ,  C10G65/16 ,  C10G67/02 ,  C10G67/06 ,  C10G69/02 ,  C10L1/04 ,  C10L1/12 ,  C10L1/14 ,  C10L1/16

CPC classification number: C10G45/04 ,  B01D3/343 ,  B01D53/1481 ,  B01J8/008 ,  B01J8/0278 ,  B01J8/0292 ,  B01J8/0457 ,  B01J8/0492 ,  B01J21/04 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  C10G7/00 ,  C10G25/003 ,  C10G25/02 ,  C10G45/02 ,  C10G45/06 ,  C10G45/08 ,  C10G45/22 ,  C10G47/02 ,  C10G65/04 ,  C10G65/16 ,  C10G67/02 ,  C10G67/06 ,  C10G69/02 ,  C10L1/04 ,  C10L1/12 ,  C10L1/14 ,  C10L1/1608 ,  B01J2208/00557 ,  B01J2208/02 ,  B01J2208/025 ,  C10G2300/1037 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/1059 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/201 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/206 ,  C10G2300/207 ,  C10G2300/208 ,  C10G2300/30 ,  C10G2300/302 ,  C10G2300/308 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/4062 ,  C10G2300/70 ,  C10G2300/80 ,  C10G2400/04 ,  C10G2400/06 ,  C10L2200/0263 ,  C10L2200/0438 ,  C10L2270/02 ,  C10L2270/026

Abstract: A multi-stage process for the production of a Product Heavy Marine Fuel Oil compliant with ISO 8217: 2017 as a Table 2 residual marine fuel from a high sulfur Feedstock Heavy Marine Fuel Oil compliant with ISO 8217: 2017 as a Table 2 residual marine fuel except for the sulfur level, involving hydrotreating under reactive distillation conditions in a Reaction System composed of one or more reaction vessels. The reactive distillation conditions allow more than 75% by mass of the Process Mixture to exit the bottom of the reaction vessel as Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a maximum sulfur content (ISO 14596 or ISO 8754) less than 0.5 mass %. A process plant for conducting the process for conducting the process is disclosed.

公开(公告)号：US11912945B2

公开(公告)日：2024-02-27

申请号：US18074212

申请日：2022-12-02

Applicant: Magēmā Technology LLC

Inventor： Michael Joseph Moore ,  Bertrand Ray Klussmann ,  Carter James White

IPC: C10G45/04 ,  C10G67/06 ,  C10G45/22 ,  C10G45/08 ,  B01J8/04 ,  C10G65/04 ,  C10G45/06 ,  C10G45/02 ,  C10G67/02 ,  B01J8/00 ,  B01J21/04 ,  C10G25/02 ,  C10G25/00 ,  B01D3/34 ,  C10L1/12 ,  C10L1/14 ,  C10L1/16 ,  B01D53/14 ,  C10G7/00 ,  C10L1/04 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  C10G65/16 ,  B01J8/02 ,  C10G47/02 ,  C10G69/02

CPC classification number: C10G45/04 ,  B01D3/343 ,  B01D53/1481 ,  B01J8/008 ,  B01J8/0278 ,  B01J8/0292 ,  B01J8/0457 ,  B01J8/0492 ,  B01J21/04 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  C10G7/00 ,  C10G25/003 ,  C10G25/02 ,  C10G45/02 ,  C10G45/06 ,  C10G45/08 ,  C10G45/22 ,  C10G47/02 ,  C10G65/04 ,  C10G65/16 ,  C10G67/02 ,  C10G67/06 ,  C10G69/02 ,  C10L1/04 ,  C10L1/12 ,  C10L1/14 ,  C10L1/1608 ,  B01J2208/00557 ,  B01J2208/02 ,  B01J2208/025 ,  C10G2300/107 ,  C10G2300/1037 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/1059 ,  C10G2300/1077 ,  C10G2300/201 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/206 ,  C10G2300/207 ,  C10G2300/208 ,  C10G2300/30 ,  C10G2300/302 ,  C10G2300/308 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/4062 ,  C10G2300/70 ,  C10G2300/80 ,  C10G2400/04 ,  C10G2400/06 ,  C10L2200/0263 ,  C10L2200/0438 ,  C10L2270/02 ,  C10L2270/026 ,  C10L1/1608 ,  C10L2200/0438

Abstract: A multi-stage process for transforming a high sulfur ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process that produces a Product Heavy Marine Fuel Oil that can be used as a feedstock for subsequent refinery process such as anode grade coking, needle coking and fluid catalytic cracking. The Product Heavy Marine Fuel Oil exhibits multiple properties desirable as a feedstock for those processes including a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process is also disclosed.

公开(公告)号：US20190185768A1

公开(公告)日：2019-06-20

申请号：US16225738

申请日：2018-12-19

Applicant: IFP Energies nouvelles

Inventor： Thibaut CORRE ,  Alberto SILVA SERVIA ,  Laurent SIMON ,  Frederic BAZER-BACHI

IPC: C10G69/04 ,  C10G45/08 ,  C10G11/18 ,  C10G11/02 ,  B01J23/882

CPC classification number: C10G69/04 ,  B01J23/882 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/845 ,  B01J2523/847 ,  C10G11/02 ,  C10G11/18 ,  C10G45/06 ,  C10G45/08 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/70 ,  C10G2300/703

Abstract: A method for hydrotreatment of a vacuum-distillate-type hydrocarbon feedstock that contains sulfur and nitrogen compounds is described, with said method for hydrotreatment of a vacuum-distillate-type feedstock comprising a specific concatenation of catalysts that makes it possible to increase the overall activity and the overall stability of the method.

公开(公告)号：US09994779B2

公开(公告)日：2018-06-12

申请号：US15182319

申请日：2016-06-14

Applicant: INSTITUTO MEXICANO DEL PETROLEO

Inventor： Jorge Ancheyta Juarez ,  Sergio Ramirez Amador ,  Zenaida Carolina Leyva Inzunza ,  Alexander Quitian Arciniegas

IPC: C10G47/02 ,  C10G47/04 ,  C10G47/24 ,  C10G45/04 ,  C10G45/06 ,  C10G45/08 ,  C10G45/14 ,  C10G49/10 ,  C10G65/14

CPC classification number: C10G47/04 ,  C10G45/04 ,  C10G45/06 ,  C10G45/08 ,  C10G45/14 ,  C10G47/02 ,  C10G47/24 ,  C10G49/10 ,  C10G65/14 ,  C10G2300/302 ,  C10G2300/308

Abstract: The present invention relates to a catalytic hydroconversion process in dispersed phase of extra-heavy and heavy crude oils for upgrading their transport properties, that operates at low severity conditions, in such a way that the obtained product can be transported by conventional pumping to the distribution and refining centers.The main technical contributions of the hydroconversion process in dispersed phase of this invention to upgrade the transport properties of heavy and extra-heavy crudes are: Compact size and can be localized next to the production facilities on ground or offshore Use of operating conditions at low severity Reduction of the viscosity and increase of the API gravity at values that allow the transportation by pipeline of heavy or extra-heavy crude Upgrading of the crude oil properties in a permanent way Hydrocarbon and gases from production centers are used as supplies Operation in dispersed phase avoiding plugging problems Use of low-cost disposable catalysts at low concentrations.

公开(公告)号：US09745524B2

公开(公告)日：2017-08-29

申请号：US14439458

申请日：2013-09-26

Applicant: IFP Energies nouvelles

Inventor： Olivier Touzalin ,  Philibert Leflaive ,  Diamantis Asteris ,  Delphine Largeteau ,  Jean Luc Nocca

IPC: C10G45/38 ,  C10G29/20 ,  C10G45/32 ,  C10G45/06 ,  C10G45/08 ,  C10G45/36

CPC classification number: C10G45/38 ,  C10G29/205 ,  C10G45/06 ,  C10G45/08 ,  C10G45/32 ,  C10G45/36 ,  C10G2300/4087

Abstract: This invention relates to a process for treatment of a gasoline that comprises diolefins, olefins and sulfur-containing compounds including mercaptans, consisting of a stage for treatment of the gasoline in a distillation column (2) comprising at least one reaction zone (3) including at least one catalyst that makes it possible to carry out the addition of mercaptans to the olefins that are contained in the gasoline that distills toward the top of the catalytic column.

公开(公告)号：US09663728B2

公开(公告)日：2017-05-30

申请号：US14525477

申请日：2014-10-28

Applicant: Pallassana S. Venkataraman ,  Gordon F. Stuntz ,  Jonathan Martin McConnachie ,  Faiz Pourarian

Inventor： Pallassana S. Venkataraman ,  Gordon F. Stuntz ,  Jonathan Martin McConnachie ,  Faiz Pourarian

IPC: B01J21/06 ,  B01J21/08 ,  B01J29/076 ,  C10G45/00 ,  C10G45/22 ,  C10L1/00 ,  C10G49/04 ,  B01J31/12 ,  C10G45/60 ,  C10G47/02 ,  C10G1/00 ,  C10G45/04 ,  C10G45/06 ,  C10G49/02

CPC classification number: C10G49/04 ,  B01J31/121 ,  B01J2231/64 ,  B01J2531/0222 ,  B01J2531/42 ,  B01J2531/48 ,  B01J2531/52 ,  B01J2531/56 ,  C10G1/002 ,  C10G45/04 ,  C10G45/06 ,  C10G45/60 ,  C10G47/02 ,  C10G49/02 ,  C10G2300/1011 ,  Y02E50/13 ,  Y02P30/20

Abstract: The present invention relates to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride comprised of at least one chemical element selected from Groups 3-11 (including the lanthanides, atomic numbers 58 to 71), and at least one chemical element selected from Groups 13-15 from the IUPAC Periodic Table of Elements. These interstitial metal hydrides, their catalysts and processes using these interstitial metal hydrides and catalysts of the present invention improve overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams.

公开(公告)号：US09556088B2

公开(公告)日：2017-01-31

申请号：US13691181

申请日：2012-11-30

Applicant: Iowa State University Research Foundation, Inc.

Inventor： Igor Ivan Slowing ,  Kapil Kandel

IPC: C07C7/12 ,  C07C1/22 ,  B01J31/12 ,  C07C1/207 ,  C10G25/00 ,  C10G25/06 ,  C10G45/06 ,  C10G3/00 ,  B01J31/08 ,  B01J31/10 ,  B01J31/16 ,  B01J27/185 ,  B01J29/03 ,  B82Y30/00 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02

CPC classification number: C07C7/12 ,  B01J27/1853 ,  B01J29/0308 ,  B01J29/0325 ,  B01J29/0333 ,  B01J29/0341 ,  B01J31/08 ,  B01J31/10 ,  B01J31/1616 ,  B01J35/0013 ,  B01J35/0033 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1061 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0209 ,  B01J2231/641 ,  B82Y30/00 ,  C07C1/2078 ,  C07C1/22 ,  C07C2521/08 ,  C07C2523/755 ,  C10G3/44 ,  C10G3/45 ,  C10G3/48 ,  C10G3/50 ,  C10G25/003 ,  C10G25/06 ,  C10G45/06 ,  C10G2300/1011 ,  Y02E50/13 ,  Y02P20/52 ,  C07C9/22

Abstract: The present invention provides an adsorbent catalytic nanoparticle including a mesoporous silica nanoparticle having at least one adsorbent functional group bound thereto. The adsorbent catalytic nanoparticle also includes at least one catalytic material. In various embodiments, the present invention provides methods of using and making the adsorbent catalytic nanoparticles. In some examples, the adsorbent catalytic nanoparticles can be used to selectively remove fatty acids from feedstocks for biodiesel, and to hydrotreat the separated fatty acids.

Abstract translation: 本发明提供一种吸附剂催化纳米颗粒，其包括具有至少一个与其结合的吸附官能团的介孔二氧化硅纳米颗粒。 吸附剂催化纳米颗粒还包括至少一种催化材料。 在各种实施方案中，本发明提供了使用和制备吸附剂催化纳米颗粒的方法。 在一些实例中，吸附剂催化纳米颗粒可用于从用于生物柴油的原料中选择性除去脂肪酸，并加氢处理分离的脂肪酸。

公开(公告)号：US09376636B2

公开(公告)日：2016-06-28

申请号：US13995800

申请日：2011-12-15

Applicant: Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

Inventor： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC: C10G45/04 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  C10G45/10 ,  B01J29/03 ,  B01J35/00 ,  B01J35/10 ,  B01J37/03 ,  B01J37/10 ,  B01J37/20 ,  C10G45/06 ,  B01J27/195 ,  B01J27/198

CPC classification number: C10G45/10 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  B01J29/0333 ,  B01J29/0341 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/033 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/20 ,  C10G45/04 ,  C10G45/06 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/4018 ,  C10G2400/02

Abstract: A process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, wherein X is an element selected from phosphorus, silicon, boron, nickel and cobalt, M is one or more element(s) selected from molybdenum, tungsten, nickel and cobalt, h is an integer from 0-12, x is an integer from 0-4, m is an integer 5, 6, 7, 8, 9, 10, 11, 12 and/or 18, y is an integer of 17-72 and q is an integer of 1-20, the polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size of 1.5-50 nm and having amorphous walls of thickness 1-30 nm, the catalyst being sulphured before use in the process.

Abstract translation: 至少一种汽油切割加氢脱硫的方法，其实施催化剂，其以其氧化物形式包含至少一种以至少一种形式存在的来自VIB族组分和/或至少一种来自元素周期表Ⅷ族的金属的金属 式（HhXxMmOy）q-的多金属氧酸盐，其中X是选自磷，硅，硼，镍和钴的元素，M是选自钼，钨，镍和钴的一种或多种元素，h是整数 从0-12，x是0-4的整数，m是整数5,6,7,8,9,10,11,12和/或18，y是17-72的整数，q是 整数为1-20，多金属氧酸盐存在于孔径为1.5-50nm的介孔结构的氧化硅基质中，并且具有厚度为1-30nm的无定形壁，催化剂在该方法使用前被硫化。

公开(公告)号：US09347006B2

公开(公告)日：2016-05-24

申请号：US14149274

申请日：2014-01-07

Applicant: SAUDI ARABIAN OIL COMPANY ,  JGC CATALYSTS AND CHEMICALS LTD. ,  JAPAN COOPERATION CENTER, PETROLEUM

Inventor： Omer Refa Koseoglu ,  Adnan Al-Hajji ,  Hendrik Muller ,  Masaru Ushio ,  Koji Nakano

IPC: C10G47/12 ,  C10G47/14 ,  C10G47/16 ,  C10G47/18 ,  C10G47/20 ,  C10G65/02 ,  C10G65/12 ,  C10G45/04 ,  C10G45/06 ,  C10G45/10 ,  C10G45/12 ,  C10G45/32 ,  C10G45/44 ,  C10G47/02 ,  C10G49/00 ,  C10G49/02 ,  C10G49/04 ,  C10G49/06 ,  C10G49/08 ,  B01J35/00 ,  B01J23/882 ,  B01J23/883 ,  B01J29/08 ,  B01J29/16

CPC classification number: C10G65/12 ,  B01J23/882 ,  B01J23/883 ,  B01J29/084 ,  B01J29/166 ,  B01J35/0006 ,  C10G45/04 ,  C10G45/06 ,  C10G45/10 ,  C10G45/12 ,  C10G45/32 ,  C10G45/44 ,  C10G47/02 ,  C10G49/002 ,  C10G49/02 ,  C10G49/04 ,  C10G49/06 ,  C10G49/08 ,  C10G2300/1074 ,  C10G2300/202

Abstract: The invention relates to a method for optimizing layered catalytic processes. This is accomplished by testing various catalysts with a compound found in a feedstock to be tested, to determine the facility of the catalyst in hydrogenating, hydrosulfurizing, or hydrodenitrogenating the molecule, and hence the feedstock. In a preferred embodiment, the Double Bond Equivalence of the feedstock and molecule are determined, and catalysts are pre-selected based upon their known ability to work with materials of this DBE value.

Abstract translation: 本发明涉及一种用于优化分层催化过程的方法。 这是通过用待测试的原料中发现的化合物测试各种催化剂来实现的，以确定催化剂在分子氢化，加氢硫化或加氢脱氮中的设备，从而确定催化剂的原料。 在优选的实施方案中，确定原料和分子的双键等价性，并且基于其已知的与该DBE值的材料一起使用的能力预先选择催化剂。

公开(公告)号：US09333492B2

公开(公告)日：2016-05-10

申请号：US12161634

申请日：2006-01-23

Applicant: Focco Cornelis Bijlsma ,  Jan Lodewijk Maria Dierickx ,  Arend Hoek ,  Frans Joris Antonius Kellendonk ,  Anna Elisabeth Maria Oud

Inventor： Focco Cornelis Bijlsma ,  Jan Lodewijk Maria Dierickx ,  Arend Hoek ,  Frans Joris Antonius Kellendonk ,  Anna Elisabeth Maria Oud

IPC: B01J21/00 ,  B01J23/00 ,  B01J25/00 ,  B01J29/00 ,  B01J23/755 ,  B01J21/04 ,  B01J35/10 ,  B01J37/02 ,  C10G45/00 ,  C10G3/00 ,  C10G45/06 ,  C10G45/12 ,  C10G2/00

CPC classification number: B01J23/755 ,  B01J21/04 ,  B01J35/10 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0205 ,  C10G2/332 ,  C10G3/45 ,  C10G3/50 ,  C10G45/00 ,  C10G45/06 ,  C10G45/12 ,  C10G2300/1022 ,  C10G2300/4018 ,  Y02P30/20

Abstract: A hydrogenation catalyst particularly suitable for hydrogenating oxygenates in a hydrogenation unit of a Fischer-Tropsch plant is disclosed. A preferred embodiment comprises more than 5% and less than 20% nickel based on a wide pore alumina support. The catalyst successfully hydrogenates oxygenates which otherwise tend to poison a catalyst in a hydroconversion unit downstream. Moreover, the temperature at which the unwanted hydrogenolysis of long chain paraffins to methane occurs is higher for one catalyst disclosed herein than a comparable known catalyst. This allows the hydrogenation plant to operate at a higher temperature.

Abstract translation: 公开了一种特别适用于在费 - 托工厂的氢化单元中氢化含氧化合物的氢化催化剂。 优选的实施方案包括基于宽孔氧化铝载体的超过5％且小于20％的镍。 催化剂成功地氢化含氧化合物，否则其倾向于在下游的加氢转化单元中毒催化剂。 此外，与可比较的已知催化剂相比，长链烷烃对甲烷的不期望的氢解发生的温度比本文公开的一种催化剂更高。 这允许氢化装置在较高的温度下运行。