公开(公告)号：US06660144B2

公开(公告)日：2003-12-09

申请号：US09958371

申请日：2002-03-25

申请人： Lothar Diehl ,  Harald Neumann

发明人： Lothar Diehl ,  Harald Neumann

IPC分类号： G01N27407

CPC分类号： G01N27/4071

摘要： An electrochemical sensor has a sensor element, and is used to determine a gas concentration of a gas to be analyzed. The sensor element has a first solid electrolyte layer, an electrode that includes an electrode surface and an electrode lead, and a second solid electrolyte layer; a gas channel being introduced into the first solid electrolyte layer in such a manner, that the electrode is situated in a first, clamped region between the first and the second solid electrolyte layers, and in a second, open region between the second solid electrolyte layer and the gas compartment. In a transition region between the clamped region and the open region, the electrode borders on a layer pattern, which is constructed in such a manner, that the electrode is subjected to a lower pressure during a laminating procedure.

摘要翻译： 电化学传感器具有传感器元件，用于确定待分析气体的气体浓度。 传感器元件具有第一固体电解质层，包括电极表面和电极引线的电极和第二固体电解质层; 以这样的方式将气体通道引入第一固体电解质层中，使得电极位于第一和第二固体电解质层之间的第一夹持区域中，并且在第二固态电解质层之间的第二开放区域中 和气室。 在夹持区域和开放区域之间的过渡区域中，电极在层状图案上接合，其以这种方式构造，使得电极在层压过程中经受较低的压力。

公开(公告)号：US06613207B1

公开(公告)日：2003-09-02

申请号：US09460465

申请日：1999-12-14

申请人： Claudio De La Prieta ,  Jens Stefan Schneider ,  Carsten Springhorn ,  Thomas Schulte ,  Olaf Jach ,  Ulrich Eisele ,  Carmen Schmiedel ,  Lothar Diehl

发明人： Claudio De La Prieta ,  Jens Stefan Schneider ,  Carsten Springhorn ,  Thomas Schulte ,  Olaf Jach ,  Ulrich Eisele ,  Carmen Schmiedel ,  Lothar Diehl

IPC分类号： G01N27407

CPC分类号： G01N27/4071

摘要： An electrochemical sensor for ascertaining gas concentrations in gases, particularly in exhaust gases of combustion engines, includes an oxygen-ion-conductive solid electrolyte which is provided with electrode layers arranged at a distance from one another and with at least one resistance heating element that is separated from the solid electrolyte by an electrical insulating layer, a foil binder layer being provided between the electrical insulating layer and the solid electrolyte. At least one electron-conductive intermediate layer is provided between the electrode-side electrical insulating layer and the adjacent solid electrolyte.

摘要翻译： 用于确定气体，特别是在内燃机废气中的气体浓度的电化学传感器包括一个氧离子传导固体电解质，其设置有彼此间隔一定距离设置的电极层，以及至少一个电阻加热元件， 通过电绝缘层与固体电解质分离，在电绝缘层和固体电解质之间设置箔粘合剂层。 在电极侧电绝缘层和相邻的固体电解质之间设置至少一个电子传导中间层。

公开(公告)号：US06436277B2

公开(公告)日：2002-08-20

申请号：US09247737

申请日：1999-02-09

申请人： Eberhard Schnaibel ,  Harald Neumann ,  Johann Riegel ,  Lothar Diehl

发明人： Eberhard Schnaibel ,  Harald Neumann ,  Johann Riegel ,  Lothar Diehl

IPC分类号： G01N27407

CPC分类号： G01N27/417

摘要： An electrochemical sensor for ascertaining a gas concentration of a measuring gas includes an electrochemical element, including a first solid electrolyte body having an electrochemical pump cell and a first and a second electrode, and having a gas compartment which is connected via a gas access opening to the measuring-gas compartment, and in which one of the two electrodes is arranged. The electrochemical element further includes a second solid electrolyte body having an electrochemical sensor cell (Nernst cell) and a third and a fourth electrode. The surface of the first solid electrolyte body faces the measuring-gas compartment, and the gas access opening is covered by a porous protective layer. The electrochemical sensor includes a layer that exhibits a higher density or a lower porosity compared to the protective layer and that is allocated to the porous protective layer.

摘要翻译： 用于确定测量气体的气体浓度的电化学传感器包括电化学元件，其包括具有电化学泵电池的第一固体电解质体和第一和第二电极，并且具有通过气体进入开口连接的气室， 测量气体室，并且其中布置两个电极中的一个。 电化学元件还包括具有电化学传感器单元（能斯特电池）和第三和第四电极的第二固体电解质体。 第一固体电解质体的表面面向测量气体隔室，并且气体进入口被多孔保护层覆盖。 电化学传感器包括与保护层相比表现出更高密度或更低孔隙率并分配给多孔保护层的层。

公开(公告)号：US09234869B2

公开(公告)日：2016-01-12

申请号：US13395563

申请日：2010-07-27

申请人： Jens Schneider ,  Frank Stanglmeier ,  Marc Rosenland ,  Lothar Diehl

发明人： Jens Schneider ,  Frank Stanglmeier ,  Marc Rosenland ,  Lothar Diehl

IPC分类号： G01M15/10 ,  G01N27/406 ,  G01N27/407

CPC分类号： G01N27/4065 ,  F02D41/1444 ,  F02D41/1454 ,  F02D41/1494 ,  F02D41/2435 ,  F02D41/2451 ,  G01N27/4062 ,  G01N27/407 ,  G01N27/4175

摘要： The invention relates to an exhaust gas probe (120) for measuring properties of the exhaust gas of internal combustion engines, wherein at least one data storage unit (135) is arranged in a circuit associated with the probe, in particular arranged in a probe plug (130) or a connecting element associated therewith. The following properties and/or adaption functions characterizing the probe (120) are stored or storable in said data storage unit: —fluctuations of heating resistances that are due to the production process and/or—parameters that characterize the aging of the probe (120), and/or—the shut-off state, in particular data that characterize the execution of an interval measurement for regenerating the exhaust gas probe or of a delayed shut-off and/or—data for adapting the probe (120) to different control devices (140) of internal combustion engines and/or—the number of operating hours of the probe and/or—the operating parameters of the probe in a previous specifiable time period.

摘要翻译： 本发明涉及一种用于测量内燃机排气性能的排气探测器（120），其中至少一个数据存储单元（135）布置在与探头相关的电路中，特别地布置在探头塞 （130）或与其相关联的连接元件。 表征探针（120）的以下性质和/或适应功能被存储或存储在所述数据存储单元中： - 由于生产过程导致的加热电阻的差异和/或参数，其表征探针的老化（120 ）和/或关闭状态，特别是表征用于再生排气探针的间隔测量的执行的数据或用于使探针（120）适应不同的延迟关闭和/或数据的数据 内部燃烧发动机的控制装置（140）和/或 - 在先前可指定的时间段内的探针的运行时间和/或探针的操作参数。

公开(公告)号：US08900432B2

公开(公告)日：2014-12-02

申请号：US12521705

申请日：2007-11-22

申请人： Goetz Reinhardt ,  Henrico Runge ,  Holger Reinshagen ,  Lothar Diehl

发明人： Goetz Reinhardt ,  Henrico Runge ,  Holger Reinshagen ,  Lothar Diehl

IPC分类号： G01N27/407 ,  G01N27/41

CPC分类号： G01N27/4071 ,  G01N27/41

摘要： A sensor element, which may be used as Lambda probe and/or inside a Lambda probe, for example, is provided for determining at least one physical property of a gas mixture in at least one gas chamber. The sensor element has at least one first electrode, at least one second electrode and at least one solid state electrolyte, which connects the at least one first electrode and the at least one second electrode. The at least one first electrode and the at least one second electrode are situated inside the sensor element. The at least one second electrode is connected to at least one reference gas chamber via at least one discharge air channel.

摘要翻译： 提供了例如可以用作λ探针和/或在λ探针内部的传感器元件，用于确定至少一个气室中的气体混合物的至少一种物理性质。 传感器元件具有连接至少一个第一电极和至少一个第二电极的至少一个第一电极，至少一个第二电极和至少一个固态电解质。 所述至少一个第一电极和所述至少一个第二电极位于所述传感器元件的内部。 至少一个第二电极经由至少一个排出空气通道连接到至少一个参考气体室。

公开(公告)号：US20090152112A1

公开(公告)日：2009-06-18

申请号：US12093681

申请日：2006-10-16

申请人： Lothar Diehl ,  Thomas Seiler

发明人： Lothar Diehl ,  Thomas Seiler

IPC分类号： G01N27/26

CPC分类号： F02D41/1456 ,  G01N27/4072 ,  G01N27/419

摘要： Disclosed is a gas sensor, particularly a lambda probe, for determining the oxygen concentration in the exhaust gas of an internal combustion engine that is operated using a fuel-air mixture. Said gas sensor comprises a pump cell with an outer electrode that is exposed to the exhaust gas, an inner electrode located in a measuring chamber which is separated from the exhaust gas by means of a first diffusion barrier, and an electronic circuit for generating a voltage applied between the outer electrode and the inner electrode as well as for measuring and evaluating a pump current that is generated in said process in order to draw a conclusion therefrom about the composition of the fuel-air mixture. The inventive gas sensor is characterized in that the outer electrode is arranged in an independent measuring volume which is separated by means of an additional, second diffusion barrier whose coefficient of diffusion is different from that of the first diffusion barrier while the circuit is configured so as to preferably repeatedly reverse the polarity of the voltage.

摘要翻译： 公开了一种用于确定使用燃料 - 空气混合物操作的内燃机的废气中的氧气浓度的气体传感器，特别是λ探针。 所述气体传感器包括具有暴露于废气的外部电极的泵电池，位于通过第一扩散阻挡件与废气分离的测量室中的内部电极和用于产生电压的电子电路 施加在外电极和内电极之间，以及用于测量和评估在所述过程中产生的泵电流，以便从其中得出关于燃料 - 空气混合物的组成的结论。 本发明的气体传感器的特征在于，外部电极被布置成独立的测量体积，其通过附加的第二扩散阻挡层分离，其扩散系数与第一扩散阻挡层的系数不同，而电路被配置为 以优选地重复地反转电压的极性。

公开(公告)号：US20090116534A1

公开(公告)日：2009-05-07

申请号：US12293238

申请日：2007-02-12

申请人： Eric Tabery ,  Raphaelle Laure Satet ,  Ulrich Eisele ,  Lothar Diehl ,  Sascha Klett

发明人： Eric Tabery ,  Raphaelle Laure Satet ,  Ulrich Eisele ,  Lothar Diehl ,  Sascha Klett

IPC分类号： G01N25/00

CPC分类号： G01N27/4118 ,  F02D41/1494

摘要： The invention relates to a method for operating a sensor, in particular a sensor made of ceramic material. Said sensor is heated to a shock-resistance temperature which is higher than a specific temperature.

摘要翻译： 本发明涉及一种用于操作传感器的方法，特别是一种由陶瓷材料制成的传感器。 所述传感器被加热到​​高于特定温度的耐冲击温度。

公开(公告)号：US20090095627A1

公开(公告)日：2009-04-16

申请号：US12090792

申请日：2006-09-29

申请人： Lothar Diehl ,  Thomas Hermann Seiler

发明人： Lothar Diehl ,  Thomas Hermann Seiler

IPC分类号： G01N27/26

CPC分类号： G01N27/419

摘要： Disclosed is a sensor for measuring the concentration of a gas component in a gas mixture. Said sensor comprises a solid electrolyte and electrodes which are separated from each other by means of the solid electrolyte and of which an outer electrode is exposed to the gas mixture while an inner electrode is disposed in a hollow space that is separated from the gas mixture with the aid of a diffusion barrier. The inventive sensor is characterized in that an additional outer electrode is exposed to the exhaust gas, said additional outer electrode being impinged upon by a current whose sign is the opposite of the current by which the outer electrode is impinged upon.

摘要翻译： 公开了一种用于测量气体混合物中气体成分浓度的传感器。 所述传感器包括固体电解质和通过固体电解质彼此分离的电极，并且外电极暴露于气体混合物，而内电极设置在与气体混合物分离的中空空间中， 辅助扩散屏障。 本发明的传感器的特征在于，附加的外部电极暴露于废气中，所述附加的外部电极被其外部电极撞击的电流相反的电流撞击。

公开(公告)号：US07404880B2

公开(公告)日：2008-07-29

申请号：US10515619

申请日：2003-05-20

申请人： Johannes Kanters ,  Lothar Diehl ,  Stefan Rodewald

发明人： Johannes Kanters ,  Lothar Diehl ,  Stefan Rodewald

IPC分类号： G01N27/26 ,  H05B1/02

CPC分类号： G01N27/4067

摘要： A layered sensor element used in a gas measuring sensor for measuring a physical property of a measuring gas, preferably for determining the temperature of the measuring gas or the concentration of a component of the measuring gas. The sensor element contains a wave-form heater, which is embedded in a porous heater insulation. At least one separating element having a lower porosity than the porous heater insulation is provided between two adjacent sections of the wave-form heater.

摘要翻译： 用于气体测量传感器的层状传感器元件，用于测量测量气体的物理性能，优选用于确定测量气体的温度或测量气体的组分的浓度。 传感器元件包含波形加热器，其嵌入多孔加热器绝缘体中。 在波形加热器的两个相邻部分之间提供至少一个具有比多孔加热器绝缘体低的孔隙率的分离元件。

公开(公告)号：US20070125648A1

公开(公告)日：2007-06-07

申请号：US10571869

申请日：2004-09-30

申请人： Johann Riegel ,  Lothar Diehl

发明人： Johann Riegel ,  Lothar Diehl

IPC分类号： G01N27/26

CPC分类号： G01N27/419

摘要： A sensor element for a sensor for determining the concentration of a gas component in a gas mixture, in particular the oxygen concentration in the exhaust gas of internal combustion engines, has two electrodes which, together with a solid electrolyte, form a pump cell, and one of these electrodes is exposed to the gas mixture via a porous protective layer. The sensor element also has a reference electrode which is situated on the solid electrolyte and is exposed to a reference gas. One of the two electrodes, with a reference electrode and the solid electrolyte, forms a concentration cell or a Nernst cell. To make the measured values produced by the sensor element insensitive to pressure fluctuations in the gas mixture, the electrode surface of the second electrode facing away from the solid electrolyte is coated with a finely porous diffusion layer, which is directly exposed to the gas mixture, and the second electrode is used as the reference electrode of the Nernst cell. It is also provided that the porous protective layer may be configured as a coarsely porous diffusion layer, and either of the two electrodes may be used as a reference electrode of the Nernst cell.

摘要翻译： 用于确定气体混合物中的气体组分的浓度的传感器的传感器元件，特别是内燃机的废气中的氧气浓度，具有两个与固体电解质一起形成泵浦电池的电极， 这些电极中的一个通过多孔保护层暴露于气体混合物。 传感器元件还具有参考电极，该参考电极位于固体电解质上并暴露于参考气体。 具有参考电极和固体电解质的两个电极中的一个形成浓缩电池或能斯特电池。 为了使由传感器元件产生的测量值对气体混合物中的压力波动不敏感，第二电极的背离固体电解质的电极表面涂覆有直接暴露于气体混合物的细孔扩散层， 并且第二电极用作能斯特电池的参考电极。 还可以将多孔保护层构成为粗大孔扩散层，并且两电极中的任一个可以用作能斯特电池的参比电极。