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    CATALYTIC PROCESS FOR PREPARING (METH)ACRYLIC ESTERS OF N-HYDROXYALKYLATED LACTAMS
    31.
    发明申请
    CATALYTIC PROCESS FOR PREPARING (METH)ACRYLIC ESTERS OF N-HYDROXYALKYLATED LACTAMS 失效

    公开(公告)号：US20100010236A1

    公开(公告)日：2010-01-14

    申请号：US12525826

    申请日：2008-02-11

    申请人： Hermann Bergmann ,  Frank Hoefer ,  Maximilian Angel

    发明人： Hermann Bergmann ,  Frank Hoefer ,  Maximilian Angel

    IPC分类号： C07D201/08

    CPC分类号： C07D207/12

    摘要： A process for preparing (meth)acrylic esters (F) of N-hydroxyalkylated lactams, in which cyclic N-hydroxyalkylated lactams (L) in whichR1 is C1-C5-alkylene, or C2-C20-alkylene interrupted by one or more oxygen and/or sulfur atoms and/or one or more substituted or unsubstituted imino groups and/or by one or more cycloalkyl, —(CO)—, —O(CO)O—, —(NH)(CO)O—, —O(CO)(NH)—, —O(CO)— or —(CO)O— groups, where the radicals mentioned may each be substituted by aryl, alkyl, aryloxy, alkyloxy, heteroatoms and/or heterocycles,with the proviso that R1 must not have any atom other than a carbon atom directly adjacent to the lactam carbonyl group,R2 is C1-C20-alkylene, C5-C12-cycloalkylene, C6-C12-arylene, or C2-C20-alkylene interrupted by one or more oxygen and/or sulfur atoms and/or one or more substituted or unsubstituted imino groups and/or by one or more cycloalkyl, —(CO)—, —O(CO)O—, —(NH)(CO)O—, —O(CO)(NH)—, —O(CO)— or —(CO)O— groups, where the radicals mentioned may each be substituted by aryl, alkyl, aryloxy, alkyloxy, heteroatoms and/or heterocycles, orR2—OH is a group of the formula —[Xi]k—H,k is from 1 to 50 andXi, for each i=1 to k, may each independently be selected from the group of —CH2—CH2—O—, —CH2—CH2—N(H)—, —CH2—CH2—CH2—N(H)—, —CH2—CH(NH2)—, —CH2—CH(NHCHO)—, —CH2—CH(CH3)—O—, —CH(CH3)—CH2—O—, —CH2—C(CH3)2—O—, —C(CH3)2—CH2—O—, —CH2—CH2—CH2—O—, —CH2—CH2—CH2—CH2—O—, —CH2—CHVin—O—, —CHVin—CH2—O—, —CH2—CHPh—O— and —CHPh—CH2—O—, in which Ph is phenyl and Vin is vinyl,in the presence of at least one metal salt of C1-C10-alkoxides (A), is esterified with (meth)acrylic acid (S) or transesterified with at least one (meth)acrylic ester (D), in which the metal salt of C1-C10-alkoxides (A) used as a catalyst is added in the absence of solvents and completely at the start of the reaction.

    Process for preparing aqueous dispersions of copolymers from hydrophilic and hydrophilic monomers, copolymers obtainable therefrom and uses thereof
    33.
    发明授权
    Process for preparing aqueous dispersions of copolymers from hydrophilic and hydrophilic monomers, copolymers obtainable therefrom and uses thereof 失效
    从亲水和亲水单体制备共聚物的水性分散体的方法，可从其获得的共聚物及其用途

    公开(公告)号：US06552142B1

    公开(公告)日：2003-04-22

    申请号：US09505708

    申请日：2000-02-17

    申请人： Helmut Meffert ,  Maximilian Angel

    发明人： Helmut Meffert ,  Maximilian Angel

    IPC分类号： C08F2608

    CPC分类号： C08F226/02 ,  C08F226/06

    摘要： A description is given of a process for preparing aqueous copolymer dispersions by free-radical polymerization of ethylenically unsaturated monomers in an aqueous solution in which (a) from 10 to 90% by weight of at least one hydrophilic monomer A which has an N-vinyl group and whose polymerisation rate possesses a maximum at pH levels above 7, and (b) from 10 to 90% by weight of at least-one monoethylenically unsaturated hydrophobic monomer B whose polymerisation rate possesses a maximum at pH levels below 7, are copolymerised in the presence of a free-radical initiator system such that in the course of the polymerization the pH falls by from 2 to 5 units. The copolymer dispersions prepared in this way and the copolymers obtainable therefrom are suitable as auxiliaries for pharmaceutical, cosmetic or agrochemical formulations and for preparing paints, coating compositions, sizes, and adhesives.

    摘要翻译： 描述了通过烯键式不饱和单体在水溶液中的自由基聚合制备含水共聚物分散体的方法，其中（a）10至90重量％的至少一种亲水单体A，其具有N-乙烯基 并且其聚合速率在pH值高于7时具有最大值，和（b）10至90重量％的聚合速率在pH值低于7时具有最大值的至少一种单烯属不饱和单体B，其共聚合 自由基引发剂体系的存在使得在聚合过程中pH下降2至5单位。以这种方式制备的共聚物分散体和可从其获得的共聚物适合作为药物，化妆品或农药制剂的助剂 并用于制备涂料，涂料组合物，尺寸和粘合剂。

    Aqueous synthetic resin dispersions
    35.
    发明授权
    Aqueous synthetic resin dispersions 失效
    水性合成树脂分散体

    公开(公告)号：US5081178A

    公开(公告)日：1992-01-14

    申请号：US503925

    申请日：1990-04-04

    申请人： Maximilian Angel ,  Andreas Einwiller

    发明人： Maximilian Angel ,  Andreas Einwiller

    IPC分类号： C08J3/03 ,  C08F2/22 ,  C08J3/00 ,  D04H1/64 ,  D06M15/21 ,  D06M15/693

    CPC分类号： D06M15/693

    摘要： Aqueous synthetic resin dispersions are obtainable by combining an aqueous starting dispersion of a polymer A, which has a glass transition temperature of from -50.degree. to +60.degree. C. and is composed of monoethtylenically unsaturated monomers which, apart from carboxyl groups and their derivatives, carry no further groups which are polymerizable or condensable with one another, with or without butadiene, and an aqueous solution of a polymer B, which is essentially composed of N-hydroxycarboxymethylamides of acrylic and/or methacrylic acid and/or water-soluble salts of these N-hydroxycarboxymethylamides, at the beginning, in the course of, and/or after completion of, the preparation of the aqueous starting dispersion, with the proviso that the solids content of polymer B is from 0.5 to 10% by weight, based on the total amount of polymer A and polymer B.

    摘要翻译： 水合物树脂分散体可通过将聚合物A的起始分散体水溶液组合而得到，聚合物A的玻璃化转变温度为-50℃至+ 60℃，并由除了羧基及其衍生物之外的单乙烯基不饱和单体组成 不带有或不具有丁二烯可聚合或可冷凝的其它基团和聚合物B的水溶液，其基本上由丙烯酸和/或甲基丙烯酸和/或水溶性盐的N-羟基羧甲基酰胺组成 的这些N-羟基羧甲基酰胺，在起始分散体水溶液的制备过程中，在完成过程中和/或完成之后，条件是聚合物B的固体含量为0.5至10重量％，基于 聚合物A和聚合物B的总量。

    Catalytic process for preparing (meth)acrylic esters of N-hydroxyalkylated lactams
    37.
    发明授权
    Catalytic process for preparing (meth)acrylic esters of N-hydroxyalkylated lactams 失效
    用于制备N-羟烷基化内酰胺的（甲基）丙烯酸酯的催化方法

    公开(公告)号：US08476387B2

    公开(公告)日：2013-07-02

    申请号：US12525826

    申请日：2008-02-11

    申请人： Hermann Bergmann ,  Frank Hoefer ,  Maximilian Angel

    发明人： Hermann Bergmann ,  Frank Hoefer ,  Maximilian Angel

    IPC分类号： C08F26/08

    CPC分类号： C07D207/12

    摘要： Provided is a process for preparing a (meth)acrylic ester (F) of an N-hydroxyalkylated lactam, in which a cyclic N-hydroxyalkylated lactam (L): where the structural variables as defined herein, in the presence of at least one metal salt of C1-C10-alkoxides (A), is esterified with (meth)acrylic acid (S) or transesterified with at least one (meth)acrylic ester (D), in which the metal salt of C1-C10-alkoxides (A) used as a catalyst is added in the absence of solvents and completely at the start of the reaction.

    摘要翻译： 提供制备N-羟烷基化内酰胺的（甲基）丙烯酸酯（F）的方法，其中环状N-羟烷基化内酰胺（L）：其中本文所定义的结构变量在存在至少一种金属 C1-C10-醇盐（A）的盐被（甲基）丙烯酸（S）酯化，或与至少一种（甲基）丙烯酸酯（D）进行酯交换，其中C1-C10-醇盐（A）的金属盐 ）作为催化剂，在不存在溶剂的情况下加入，并在反应开始时完全。

    Acrylate polymers based on tert-butyl acrylate and/or tert-butyl methacrylate
    40.
    发明授权
    Acrylate polymers based on tert-butyl acrylate and/or tert-butyl methacrylate 有权
    基于丙烯酸叔丁酯和/或甲基丙烯酸叔丁酯的丙烯酸酯聚合物

    公开(公告)号：US07015294B2

    公开(公告)日：2006-03-21

    申请号：US10399498

    申请日：2001-11-09

    申请人： Wilma M. Dausch ,  Katrin Zeitz ,  Tanja Schneider ,  Maximilian Angel ,  Bernd de Potzolli ,  Claudia Wood

    发明人： Wilma M. Dausch ,  Katrin Zeitz ,  Tanja Schneider ,  Maximilian Angel ,  Bernd de Potzolli ,  Claudia Wood

    IPC分类号： C08F116/14

    CPC分类号： A61Q5/06 ,  A61K8/8188 ,  C08F220/18

    摘要： The invention relates to acrylate polymers comprising a K-value ranging from 10 to 60, which can be obtained by the radical polymerization of: 30 to 99 wt. % of tert-butyl acrylate and/or tert-butyl methacrylate designated as monomer A; 1 to 28 wt. % of acrylic acid and/or methacrylic acid designated as monomer B, and; 0 to 60 wt. % of a radically copolymerizable monomer or of a radically copolymerizable monomer mixture designated as monomer C, whereby at least one of monomers C yields a homopolymer with a glass-transition temperature lower than 30° C., with the provision that the wt. %'s total 100. The radical polymerization is carried out in the presence of alkane thiols with a C chain length of C 14 to C 22. The invention also relates to acrylate polymers comprising a K-value ranging from 10 to 60, which can be obtained by the radical polymerization of: 30 to 99 wt. % of tert-butyl acrylate and/or tert-butyl methacrylate designated as monomer A; 1 to 28 wt. % of acrylic acid and/or methacrylic acid designated as monomer B, and; 0 to 60 wt. % of a radically copolymerizable monomer or of a radically copolymerizable monomer mixture designated as monomer C, whereby at least one of monomers C yields a homopolymer with a glass-transition temperature lower than 30° C., with the provision that the wt. %'s total 100. The radical polymerization is carried out in the presence of alkane thiols with a C chain length of C 10 to C 22 followed by a hydrogen peroxide treatment. The invention also relates to the use of these acrylate polymers as film formers as well as to their use in cosmetic preparations.

    摘要翻译： 本发明涉及包含K值范围为10至60的丙烯酸酯聚合物，其可通过自由基聚合获得：30至99重量％ ％的丙烯酸叔丁酯和/或称为单体A的甲基丙烯酸叔丁酯; 1至28wt。 ％为指定为单体B的丙烯酸和/或甲基丙烯酸，以及; 0〜60重量％ ％的自由基共聚单体或称为单体C的自由基共聚单体混合物，其中至少一种单体C产生玻璃化转变温度低于30℃的均聚物，其条件是wt。 ％的总量为100.自由基聚合在C链长度为C 14至C 22的烷烃硫醇的存在下进行。本发明还涉及包含K值为10至60的丙烯酸酯聚合物，其可以 通过自由基聚合得到：30〜99wt。 ％的丙烯酸叔丁酯和/或称为单体A的甲基丙烯酸叔丁酯; 1至28wt。 ％为指定为单体B的丙烯酸和/或甲基丙烯酸，以及; 0〜60重量％ ％的自由基共聚单体或称为单体C的自由基共聚单体混合物，其中至少一种单体C产生玻璃化转变温度低于30℃的均聚物，其条件是wt。 ％的总量为100.自由基聚合在C链长为C 10〜C 22的烷烃硫醇存在下进行，然后进行过氧化氢处理。 本发明还涉及这些丙烯酸酯聚合物作为成膜剂的用途以及它们在化妆品制剂中的用途。