摘要:
The invention relates to a method for the production of organic salts containing bis(perfluoroalkyl)phosphinate anions. According to said method, a tris(perfluoroalkyl)phosphine oxide is reacted with an alcohol and an organic base, which is stronger than the alcohol. The invention also relates to the salts which are produced according to said method and to the use thereof as ionic liquids.
摘要:
The present invention relates to acids of the general formula [I], [RyPF6-y]−H+ [I], where y=1, 2 or 3, and in which the ligands R may be identical or different and R is a perfluorinated C1-8-alkyl or aryl group or R is a partially fluorinated C1-8-alkyl or aryl group, in which some of the F or H may have been substituted by chlorine. The present invention furthermore relates to a process for the preparation of the acids according to the invention, to salts comprising a cation and the anion of the acid according to the invention, and to a process for the preparation of the salts. The invention furthermore relates to the use of the acids and salts according to the invention.
摘要:
The invention relates to boron-containing acids of the general formula (I) [B(RF)4-x-y(CN)xFy]−H+ (I), where x=0, 1, 2, 3 or 4, y=0, 1, 2 or 3 x+y≦4, and in which the ligands RF may be identical or different and RF stands for a perfluorinated or partially fluorinated C1-12-alkyl group and where the CN group is bonded to the B atom via the C atom, and complexes thereof with a solvent, to salts comprising a cation and the anion of a selection of the acids according to the invention, and to processes for the preparation of the salts.
摘要翻译:本发明涉及通式(I)[B(RF)4-xy(CN)x F y] -H +(I)的含硼酸,其中x = 0,1,2,3或4,y = 0 ,1,2或3个x + y @ 4,并且其中配体RF可以相同或不同,RF代表全氟化或部分氟化的C1-12烷基,其中CN基团通过 C原子及其与溶剂的络合物,以及包含阳离子和根据本发明的酸选择阴离子的盐,以及盐的制备方法。
摘要:
The present invention relates to a two-step process for the preparation of guanidinium salts of the formula (1), where the substituents R have a meaning indicated in Claim, and A− is a sulfonate, alkyl- or arylsulfate, hydrogensulfate, imide, methanide, carboxylate, phosphate, phosphinate, phosphonate, borate, thiocyanate, perchlorate, fluorosilicate or nitrate, and to intermediate compounds from this process.
摘要:
The present invention relates to a two-step process for the preparation of guanidinium salts of the formula (1), where the substituents R have a meaning indicated in claim, and A− is a sulfonate, alkyl- or arylsulfate, hydrogensulfate, imide, methanide, carboxylate, phosphate, phosphinate, phosphonate, borate, thiocyanate, perchlorate, fluorosilicate or nitrate, and to intermediate compounds from this process.
摘要:
The invention relates to salts having alkoxytris(fluoroalkyl)borate anions which on the one hand are used for the synthesis of ionic liquids, but on the other hand can be employed per se as ionic liquid, and to processes for the preparation thereof.
摘要:
The invention relates to salts having alkoxytris(fluoroalkyl)borate anions which on the one hand are used for the synthesis of ionic liquids, but on the other hand can be employed per se as ionic liquid, and to processes for the preparation thereof.
摘要:
The present invention relates to salts having guanidinium cations, to processes for the preparation thereof, and to the use thereof as ionic liquids.
摘要:
The invention relates to salts having alkoxytris(fluoroalkyl)borate anions which on the one hand are used for the synthesis of ionic liquids, but on the other hand can be employed per se as ionic liquid, and to processes for the preparation thereof.
摘要:
The invention relates to a process for the preparation of onium salts having a low chloride content by reaction of an onium chloride with an acid, where the hydrochloric acid forming is removed by azeotropic distillation by coordination to an organic solvent which forms an azeotropic mixture with water.