利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

49 条记录 (耗时 0.03 秒)

    Microbicidal benzotriazole compounds
    31.
    发明授权
    Microbicidal benzotriazole compounds 失效
    杀菌剂苯并三唑化合物

    公开(公告)号：US5322853A

    公开(公告)日：1994-06-21

    申请号：US52313

    申请日：1993-04-23

    申请人： Peter Ackermann ,  Max Schellenbaum

    发明人： Peter Ackermann ,  Max Schellenbaum

    IPC分类号： A01N43/647 ,  C07D249/18

    CPC分类号： C07D249/18 ,  A01N43/647

    摘要： Novel benzotriazolesulfonic acid derivatives of formula ##STR1## wherein: R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy having at least two identical or different halogen atoms, CF.sub.3, nitro or the group N(R')R", wherein R' and R" are each independently of the other C.sub.1 -C.sub.4 alkyl;R.sub.2 is phenoxy or phenylthio each of which is unsubstituted or mono- to tri-substituted by halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy having at least two identical or different halogen atoms, cyano, nitro, C.sub.2 -C.sub.4 alkenyl, C.sub.2 -C.sub.4 alkynyl, phenyl, 2-phenylethynyl or by a further phenoxy radical that is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl and/or by C.sub.1 -C.sub.4 alkoxy; or R.sub.2 is the radical O--CH.sub.2 --O;R.sub.3 is alkyl, aryl or aralkyl having a maximum of 14 carbon atoms, these radicals can be substituted by halogen, C.sub.1 -C.sub.4 alkyl and/or by nitro;including the position isomers of R.sub.1 and R.sub.2, insofar as those substituents occupy positions 5 and 6.The novel compounds have plant-protecting properties and are suitable especially for protecting plants against attack by phytopathogenic microorganisms such as fungi, especially Oomycetes.

    摘要翻译： 其中：R1是氢，卤素，C1-C4烷基，C1-C4烷氧基，具有至少两个相同或不同的卤素原子的C 1 -C 4卤代烷氧基，CF 3，硝基或基团N（R'）R的新的苯并三唑磺酸衍生物 “其中R'和R”各自独立地为C 1 -C 4烷基; R 2是苯氧基或苯硫基，其各自是未被取代的或被卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，具有至少两个相同或不同卤素原子的C 1 -C 4卤代烷氧基，氰基，硝基，C 2 -C 4链烯基，C 2 C 1-4炔基，苯基，2-苯基乙炔基或未被取代或被卤素，C 1 -C 4烷基和/或被C 1 -C 4烷氧基取代的另外的苯氧基; 或R 2是基团O-CH 2 -O; R3是具有最多14个碳原子的烷基，芳基或芳烷基，这些基团可以被卤素，C 1 -C 4烷基和/或被硝基取代; 包括R1和R2的位置异构体，只要这些取代基占据位置5和6.新化合物具有植物保护性质，特别适用于保护植物免受植物病原微生物如真菌，尤其是卵菌的攻击。

    Triorganotin-isocyanuric compounds and the use thereof for combating pests
    32.
    发明授权
    Triorganotin-isocyanuric compounds and the use thereof for combating pests 失效
    三有机锡异氰脲酸化合物及其用于防治害虫的用途

    公开(公告)号：US4472396A

    公开(公告)日：1984-09-18

    申请号：US432480

    申请日：1982-10-04

    申请人： Wolfgang Wehner ,  Peter Ackermann

    发明人： Wolfgang Wehner ,  Peter Ackermann

    IPC分类号： A01N55/04 ,  C07F7/22 ,  A01N43/64

    CPC分类号： A01N55/04 ,  C07F7/2284

    摘要： There are described triorganotin-isocyanuric compounds of the formula ##STR1## wherein R is C.sub.1 -C.sub.6 -alkyl, phenyl, C.sub.5 -C.sub.8 -cycloalkyl or ##STR2## X is oxygen or sulfur, and Y.sub.1 and Y.sub.2 are each hydrogen or --Sn--R).sub.3,as well as a process for producing this compound, and the use thereof for combating pests.

    摘要翻译： 描述了式（I）的三有机锡异氰脲酸化合物，其中R是C 1 -C 6 - 烷基，苯基，C 5 -C 8 - 环烷基或X是氧或硫，并且Y 1和Y 2各自是氢或 -Sn-R）3，以及该化合物的制造方法及其对抗害虫的用途。

    Process for the preparation of substituted difluorobenzo-1,3-dioxoles
    34.
    发明授权
    Process for the preparation of substituted difluorobenzo-1,3-dioxoles 失效
    制备取代的二氟苯-1,3-二氧杂环戊烯的方法

    公开(公告)号：US5281718A

    公开(公告)日：1994-01-25

    申请号：US987902

    申请日：1992-12-04

    申请人： Peter Ackermann ,  Hans-Ruedi Kanel ,  Bruno Schaub

    发明人： Peter Ackermann ,  Hans-Ruedi Kanel ,  Bruno Schaub

    IPC分类号： C07D317/46 ,  C07D405/04 ,  C07F1/00 ,  C07F1/02 ,  C07F3/00 ,  C07F5/02 ,  C07F7/08 ,  C07F7/10 ,  C07F19/00 ,  C07D207/36

    CPC分类号： C07D405/04 ,  C07D317/46 ,  C07F1/00 ,  C07F1/02 ,  C07F19/00 ,  C07F3/00 ,  C07F5/025 ,  C07F7/0814 ,  C07F7/10 ,  Y02P20/55

    摘要： The reaction of 2,2-difluorobenzo-1,3-dioxole with (a) an alkali metal or an alkali metal compound and then (b) a compound R.sup.1 -Z.sup.1 in which Z.sup.1 is a leaving group, or with an aldehyde produces compounds of formula I ##STR1## wherein R.sup.1 is --OH, --SH, --CHO, --CN, --COOH, --B(OH).sub.2, --COX, with X being Cl or Br, or is --COOR.sup.2, --SiR.sub.3.sup.2 or --B(OR.sup.2).sub.2, with R.sup.2 being a C.sub.1 -C.sub.12 alcohol moiety without the hydroxy group, wherein R.sup.1 is further --C.sub.n H.sub.2n COOR.sup.2, with n being an integer from 1 to 4, or linear or branched C.sub.1 -C.sub.12 hydroxyalkyl which is unsubstituted or is substituted by --F, --CN, C.sub.1 -C.sub.6 alkoxy, phenyl, fluorophenyl, C.sub.1 -C.sub.4 alkoxy-phenyl, C.sub.1 -C.sub.4 alkylthio-phenyl, C.sub.1 -C.sub.4 alkylphenyl, C.sub.1 -C.sub.4 fluoroalkyl-phenyl, nitrophenyl or by cyanophenyl, or wherein R.sup.1 is a benzyl alcohol which is unsubstituted or is substituted by F, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 fluoroalkyl, nitro or by cyano, or is C.sub.1 -C.sub.12 acyl, or wherein R.sup. 1 is a radical of formula II ##STR2## wherein R.sup.5 is --CN, --CF.sub.3, --COOR.sup.2, --CONH.sup.2, --CO--NHR.sup.2 or --CONR.sub.2.sup.2, R.sup.3 and R.sup.4 are a direct bond or each is H, or R.sup.3 is H and R.sup.4 independently has the meanings of R.sup.5, or R.sup.3 and R.sup.4 together are --CH.sub.2 --NR.sup.6 --CH.sub.2 --, --CH.sub.2 --NR.sup.6 --CO-- or --CO--NR.sup.6 --CO-- wherein R.sup.6 is the radical of a removable protecting group, or wherein further R.sup.1 is a radical of formula III ##STR3## Insecticides or fungicides can be prepared from the compounds of formula I. 3-(2,2-difluorobenzodioxol-4-yl)-4-cyanopyrrole can be prepared by reacting 4-metallo-2,2-difluorobenzodioxole (III) with an unsaturated nitrile and then with a sulfonylmethyl isocyanide in a one-pot process. The compounds III are novel intermediates.

    摘要翻译： 2,2-二氟苯-1,3-二氧杂环戊烯与（a）碱金属或碱金属化合物反应，然后（b）其中Z 1为离去基团的化合物R1-Z1或与醛反应生成化合物 其中R 1是-OH，-SH，-CHO，-CN，-COOH，-B（OH）2，-COX，X是Cl或Br，或者是 - COOR 2，-SiR 32或-B（OR 2）2，其中R 2为不含羟基的C 1 -C 12醇部分，其中R 1还为-C n H 2n NOR 2，n为1至4的整数，或直链或支链C 1 -C 12羟烷基， 被未取代或被-F，-CN，C 1 -C 6烷氧基，苯基，氟苯基，C 1 -C 4烷氧基 - 苯基，C 1 -C 4烷硫基 - 苯基，C 1 -C 4烷基苯基，C 1 -C 4氟烷基 - 苯基，硝基苯基或氰基苯基取代，或其中R 1 是未被取代或被F，C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基，C 1 -C 4氟烷基，硝基或氰基取代的苯甲醇，或是C 1 -C 12酰基，或其中R 1是式II的基团 （*化学结构*）（II）其中R5为 -CN，-CF 3，-COOR 2，-CONH 2，-CO-NHR 2或-CONR 22，R 3和R 4为直接键或各自为H或R 3为H，且R 4独立地具有R 5或R 3和R 4的含义 是-CH 2 -NR 6 -CH 2 - ， - CH 2 -NR 6 -CO-或-CO-NR 6 -CO-，其中R 6是可除去保护基团的基团，或其中R 1是式III基团（*化学结构* ）（III）杀虫剂或杀真菌剂可以由式I化合物制备。3-（2,2-二氟苯并二氧杂环戊烯-4-基）-4-氰基吡咯可以通过4-金属-2,2-二氟苯并二氧杂环戊烯（III） ）与不饱和腈，然后在一锅法中与磺酰基甲基异氰化物反应。 化合物III是新的中间体。

    Microbicidal compositions
    36.
    发明授权
    Microbicidal compositions 失效

    公开(公告)号：US5068359A

    公开(公告)日：1991-11-26

    申请号：US537196

    申请日：1990-06-12

    申请人： Alica Huxley ,  Walter Kunz ,  Peter Ackermann ,  Marius Sutter

    发明人： Alica Huxley ,  Walter Kunz ,  Peter Ackermann ,  Marius Sutter

    IPC分类号： A01N43/12 ,  A01N43/36 ,  C07D307/79 ,  C07D333/54 ,  C07D333/62 ,  C07D405/04 ,  C07D409/04

    CPC分类号： C07D333/54 ,  A01N43/36 ,  C07D307/79 ,  C07D333/62 ,  C07D405/04 ,  C07D409/04

    摘要： Novel benzothiophene and benzofuran derivatives of the general formula I ##STR1## wherein X is oxygen or sulfur, R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 haloalkyl, R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 haloalkyl, R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or halogen and R is a 4-cyano-3-pyrrole radical of which the N atom carries one of the following substituents:A: hydrogen or CO--R.sub.4 in which R.sub.4 is unsubstituted C.sub.1 C.sub.6 alkyl or C.sub.1 -C.sub.6 alkyl substituted by halogen or by C.sub.1 -C.sub.3 alkoxy; C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, unsubstituted C.sub.1 -C.sub.6 alkoxy or C.sub.1 -C.sub.6 alkoxy substituted by halogen or by C.sub.1 -C.sub.3 alkoxy; C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 cycloalkyl or tetrahydrofur2-yl;B: S-R.sub.5 in which R.sub.5 is C.sub.1 -C.sub.3 haloalkyl;C: CH(Y)R.sub.6 in which R.sub.6 is hydrogen or C.sub.1 -C.sub.8 haloalkyl and Y is hydroxy, halogen or OC(O)R.sub.7 in which R.sub.7 is C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 haloalkyl, C.sub.2 -C.sub.6 -alkenyl, 2-tetrahydrofuryl, 2-tetrahydropyranyl or C.sub.1 -C.sub.6 alkoxycarbonyl;D: CH.sub.2 -Z in which Z is one of the groups ##STR2## wherein R.sub.8 and R.sub.9 are each, independently of the other, hydrogen, unsubstituted C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkyl substituted by cyano or by C.sub.1 -C.sub.6 alkoxycarbonyl; C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.7 cycloalkyl, unsubstituted phenyl or phenyl substituted by halogen, by C.sub.1 -C.sub.6 alkyl, by C.sub.1 -C.sub.6 haloalkyl and/or by C.sub.1 -C.sub.6 alkoxy, with the proviso that only R.sub.8 or R.sub.9 may be hydrogen; R.sub.10 and R.sub.11 are each, independently of the other, hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxycarbonyl; R.sub.12 and R.sub.13 are each, independently of the other, hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxycarbonyl; and R.sub.15 is oxygen, sulfur, >C.dbd.0 or >N--R.sub.14, wherein R.sub.14 is hydrogen, C.sub.1 -C.sub.6 alkyl, formyl, C.sub.1 -C.sub.6 alkanoyl or C.sub.1 -C.sub.6 alkoxycarbonyl; and n is one of the numbers 0 or 1.The novel active ingredients serve to control harmful microorganisms, especially phytophathogenic fungi. They can be used together with suitable formulation adjuvants in the form of compositions, and are suitable also for preventing attack on cultivated plants by harmful microorganisms.

    .alpha.-methyl-(6-phenoxy)-2-picolyl cyclopropanecarboxylates having pesticidal properties
    37.
    发明授权
    .alpha.-methyl-(6-phenoxy)-2-picolyl cyclopropanecarboxylates having pesticidal properties 失效
    具有杀虫性能的α-甲基 - （6-苯氧基）-2-甲基吡咯烷基环丙烷羧酸酯

    公开(公告)号：US4661497A

    公开(公告)日：1987-04-28

    申请号：US688123

    申请日：1984-12-31

    申请人： Peter Ackermann

    发明人： Peter Ackermann

    IPC分类号： A01N53/00 ,  A01N53/08 ,  C07D213/64 ,  C07D213/647 ,  A01N43/40

    CPC分类号： C07D213/647 ,  A01N53/00

    摘要： The invention relates to .alpha.-methyl-(6-phenoxy)-2-picolyl cyclopropanecarboxylates of the formula ##STR1## wherein X.sub.1 is methyl or halogen,R.sub.1 is hydrogen or halogen, andR.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.2 -C.sub.4 alkenyl, C.sub.2 -C.sub.4 alkynyl, nitro or cyano.The invention also relates to the preparation of these esters and to the use thereof in pest control.

    摘要翻译： 本发明涉及式（I）的α-甲基 - （6-苯氧基）-2-甲基吡咯烷基环丙烷羧酸酯，其中X 1是甲基或卤素，R 1是氢或卤素，R 2是氢，卤素，C 1 -C 4烷基 C1-C4烷氧基，C1-C4烷硫基，C1-C4卤代烷基，C1-C4卤代烷氧基，C1-C4卤代烷硫基，C2-C4链烯基，C2-C4炔基，硝基或氰基。 本发明还涉及这些酯的制备及其在害虫防治中的应用。

    Process for the preparation of substituted difluorobenzo-1,3-dioxoles
    40.
    发明授权
    Process for the preparation of substituted difluorobenzo-1,3-dioxoles 失效
    制备取代的二氟苯-1,3-二氧杂环戊烯的方法

    公开(公告)号：US5514816A

    公开(公告)日：1996-05-07

    申请号：US440172

    申请日：1995-05-12

    申请人： Peter Ackermann ,  Hans-Ruedi Kanel ,  Bruno Schaub

    发明人： Peter Ackermann ,  Hans-Ruedi Kanel ,  Bruno Schaub

    IPC分类号： A61K31/33 ,  C07D317/06 ,  C07D317/46 ,  C07D405/04 ,  C07F1/00 ,  C07F1/02 ,  C07F3/00 ,  C07F5/02 ,  C07F7/08 ,  C07F7/10 ,  C07F19/00

    CPC分类号： C07D405/04 ,  C07D317/46 ,  C07F1/00 ,  C07F1/02 ,  C07F19/00 ,  C07F3/00 ,  C07F5/025 ,  C07F7/0814 ,  C07F7/10 ,  Y02P20/55

    摘要： The reaction of 2,2-difluorobenzo-1,3-dioxole with (a) an alkali metal or an alkali metal compound and then (b) a compound R.sup.1 -Z.sup.1 in which Z.sup.1 is a leaving group, or with an aldehyde produces compounds of formula I ##STR1## wherein R.sup.1 is --OH, --SH, --CHO, --CN, --COOH, --B(OH).sub.2, --COX, with X being C1 or Br, or is --COOR.sup.2, --SiR.sup.2.sub.3 or --B(OR.sup.2).sub.2, with R.sup.2 being a C.sub.1 -C.sub.12 alcohol moiety without the hydroxy group, wherein R.sup.1 is further --C.sub.n H.sub.2n COOR.sup.2, with n being an integer from 1 to 4, or linear or branched C.sub.1 -C.sub.12 hydroxyalkyl which is unsubstituted or is substituted by --F, --CN, C.sub.1 -C.sub.6 alkoxy, phenyl, fluorophenyl, C.sub.1 -C.sub.4 alkoxy-phenyl, C.sub.1 -C.sub.4 alkylthio-phenyl, C.sub.1 -C.sub.4 alkylphenyl, C.sub.1 -C.sub.4 fluoroalkyl-phenyl, nitrophenyl or by cyanophenyl, or wherein R.sup.1 is a benzyl alcohol which is unsubstituted or is substituted by F, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 fluoroalkyl, nitro or by cyano, or is C.sub.1 -C.sub.12 acyl, or wherein R.sup.1 is a radical of formula II ##STR2## wherein R.sup.5 is --CN, --CF.sub.3, --COOR.sup.2, --CONH.sup.2, --CO--NHR.sup.2 or --CONR.sup.2.sub.2, R.sup.3 and R.sup.4 are a direct bond or each is H, or R.sup.3 is H and R.sup.4 independently has the meanings of R.sup.5, or R.sup.3 and R.sup.4 together are --CH.sub.2 --NR.sup.6 --CH.sub.2 --, --CH.sub.2 --NR.sup.6 --CO-- or --CO--NR.sup.6 --CO-- wherein R.sup.6 is the radical of a removable protecting group, or wherein further R.sup.1 is a radical of formula III ##STR3## Insecticides or fungicides can be prepared from the compounds of formula I.

    摘要翻译： 2,2-二氟苯-1,3-二氧杂环戊烯与（a）碱金属或碱金属化合物反应，然后（b）其中Z 1为离去基团的化合物R1-Z1或与醛反应生成化合物 其中R 1是-OH，-SH，-CHO，-CN，-COOH，-B（OH）2，-COX，X是C1或Br，或是-COOR2， - SiR 23或-B（OR 2）2，其中R 2是没有羟基的C 1 -C 12醇部分，其中R 1还是-C n H 2n COOR 2，n是1至4的整数，或未被取代的直链或支链C 1 -C 12羟基烷基 或被-F，-CN，C 1 -C 6烷氧基，苯基，氟苯基，C 1 -C 4烷氧基 - 苯基，C 1 -C 4烷硫基 - 苯基，C 1 -C 4烷基苯基，C 1 -C 4氟烷基 - 苯基，硝基苯基或氰基苯基取代，或其中R 1是 未被取代或被F，C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基，C 1 -C 4氟烷基，硝基或氰基取代的苯甲醇，或者是C 1 -C 12酰基，或其中R 1是式II基团 -CONH 2，-CO-NHR 2或-CONR 22，R 3和R 4是直接键 或各自为H或R 3为H且R 4独立地具有R 5的含义，或者R 3和R 4一起为-CH 2 -NR 6 -CH 2 - ， - CH 2 -NR 6 -CO-或-CO-NR 6 -CO-，其中R 6为 可除去的保护基团的基团，或其中R 1为式III的基团。（III）杀虫剂或杀真菌剂可由式I化合物制备。