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公开(公告)号:US11407952B2
公开(公告)日:2022-08-09
申请号:US17045669
申请日:2019-04-18
Applicant: SABIC Global Technologies B.V. , Saudi Arabian Oil Company
Inventor: Guillermo Leal , Mohammed Bismillah Ansari , Kareemuddin Mahaboob Shaik , Hiren Shethna , Zhonglin Zhang
Abstract: A method of producing a fuel additive includes: passing a first process stream comprising C4 hydrocarbons through a methyl tertiary butyl ether synthesis unit producing a first recycle stream; passing the first recycle stream through a hydration unit producing the fuel additive and a second recycle stream; passing the second recycle stream through a recycle hydrogenation unit and a deisobutanizer unit; and recycling the second recycle stream to the methyl tertiary butyl ether synthesis unit.
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公开(公告)号:US11370729B2
公开(公告)日:2022-06-28
申请号:US16604215
申请日:2018-05-01
Applicant: SABIC Global Technologies B.V.
Inventor: Mohammed Bismillah Ansari , Vijay Dinkar Bodas , Guillermo Leal , Sultan Al-Otaibe
Abstract: Systems and methods of dehydrogenating a hydrocarbon in a fixed bed dehydrogenation unit. A method for dehydrogenating a hydrocarbon is applied to a fixed bed reactor. The hydrocarbon flows to a fixed bed reactor to be dehydrogenated in presence of a catalyst in the fixed bed reactor. The catalyst in the fixed bed reactor is then regenerated. The period for dehydrogenation, the period for catalyst regeneration and the period for total slack time are controlled such that total slack time is less than both half of the period for dehydrogenation and half of the period for regeneration. One of the advantages of the process comes from optimization of the slack time, thereby increasing the catalyst utilization rate and number of reactors concurrently online.
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公开(公告)号:US11358917B2
公开(公告)日:2022-06-14
申请号:US16954381
申请日:2018-12-12
Applicant: SABIC Global Technologies B.V.
Inventor: Khaja Aliuddin Sharif , Mohammed Bismillah Ansari , Guillermo Leal
Abstract: Systems and processes for producing isomerized alkenes are disclosed. The systems mainly include an isomerization unit, a dehydrogenation unit, and a MTBE synthesis unit. A hydrocarbon stream is fed into the isomerization unit to form iso-alkanes in a sulfur free hydrocarbon stream. The sulfur free hydrocarbon stream is heated and then combined with a sulfur-containing hydrocarbon stream comprising sulfur containing compounds to form a reactant feed stream to the dehydrogenation unit. The iso-alkanes is dehydrogenated to form iso-alkenes. The formed iso-alkenes comprising isobutylene can be used as a feed stock for the MTBE synthesis unit.
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公开(公告)号:US11332684B2
公开(公告)日:2022-05-17
申请号:US16487222
申请日:2018-02-24
Applicant: SABIC GLOBAL TECHNOLOGIES B.V. , SAUDI ARABIAN OIL COMPANY
Inventor: Guillermo Leal , Kareemuddin M. Shaik , Mohammed Bismillah Ansari , Hassan Babiker , Somak Paul , Kamalakar Gunda
Abstract: An octane-enhancing additive includes a mixed butanol composition, sec-butyl ether, methanol, methyl tert-butyl ether, and a C4-dimer, the mixed butanol composition comprising sec-butanol and tert-butanol, and the C4-dimer comprising di-isobutylene, 2,2,4 trimethylpentane, 2,3,3 trimethylpentane, or a combination comprising at least one of the foregoing.
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35.
公开(公告)号:US20210380515A1
公开(公告)日:2021-12-09
申请号:US17292261
申请日:2019-11-20
Applicant: SABIC Global Technologies B.V.
Inventor: Vijay Dinkar Bodas , Guillermo Leal , Mohammed Bismillah Ansari
Abstract: A process for producing ethylene and at least one of butanol and an alkyl tert-butyl ether from field butane includes separating the field butane into an n-butane stream and an isobutane stream; cracking the n-butane stream to obtain a cracked product stream comprising n-butane, 1-butene, 2-butene, butadienes, or a combination comprising at least one of the foregoing; and at least one of the following: (1) separating the cracked product stream to obtain a butane stream and a butene stream, and reacting the butene stream with water to obtain a fuel additive comprising butanol, and (2) dehydrogenating the isobutane stream in a dehydrogenation unit to form an isobutene stream and reacting the isobutene stream with an aliphatic alcohol to produce an alkyl tert-butyl ether.
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公开(公告)号:US20210214290A1
公开(公告)日:2021-07-15
申请号:US17054906
申请日:2019-05-06
Applicant: SABIC Global Technologies B.V.
Inventor: Mohammed Bismillah Ansari , Guillermo Leal , Vijay Dinkar Bodas , Naif Mohammed Al-Naddah Al-Otaibi
Abstract: A method of producing a fuel additive includes: passing a raffinate stream comprising C4 hydrocarbons through a hydrogenation unit, forming a first process stream; passing the first process stream through an extractive distillation unit, forming a C4 olefin stream; passing the C4 olefin stream through a stripper column, forming a purified C4 olefin stream; and forming the fuel additive by passing the purified C4 olefin stream through a hydration unit.
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公开(公告)号:US10995283B2
公开(公告)日:2021-05-04
申请号:US16497908
申请日:2018-03-29
Applicant: SABIC Global Technologies B.V.
Inventor: Vijay Dinkar Bodas , Sultan Al-Otaibe , Guillermo Leal , Mohammed Bismillah Ansari
IPC: C10G61/06
Abstract: A process for producing natural gasoline. The process includes increasing the n-pentane concentration of debutanized natural gasoline. The process may include a first concentration process that includes distillation and a second concentration process that includes simulated moving bed adsorption.
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公开(公告)号:US20180118653A1
公开(公告)日:2018-05-03
申请号:US15562234
申请日:2016-03-18
Applicant: SABIC Global Technologies B.V.
Inventor: Vinodkumar Vasudevan , Guillermo Leal , Nedumbamana Sankaran , Syed Azhar Hashmi
IPC: C07C51/487 , C07C51/43 , C07C51/265
CPC classification number: C07C51/487 , C07C51/265 , C07C51/43 , C07C63/26
Abstract: A method of removing an aromatic carboxy-aldehyde from an aromatic acid or the corresponding anhydride includes reacting a hydroxylamine-containing compound with the aromatic carboxy-aldehyde to form a reaction mixture including the corresponding nitrone. A phthalic acid or corresponding anhydride prepared according to the method is also described herein. A method for the manufacture of a phenyl dicarboxylic acid includes oxidizing a xylene to provide a stream including the phenyl dicarboxylic acid and the corresponding carboxybenzaldehyde and toluic acid contaminants, reacting a hydroxylamine-containing compound with the carboxybenzaldehyde in the stream to form a reaction mixture including the corresponding nitrone, wherein the nitrone is water soluble, and crystallizing the phenyl dicarboxylic acid or the corresponding anhydride from water to provide the purified phenyl dicarboxylic acid or the corresponding anhydride. A phenyl dicarboxylic acid prepared according to the above method represents another embodiment.
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公开(公告)号:US20170073289A1
公开(公告)日:2017-03-16
申请号:US15308884
申请日:2015-05-07
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Guillermo Leal , Zeeshan Nawaz , Renaat Hennus , Antonio Matarredona , Faisal Baksh
CPC classification number: C07C41/06 , C07C7/005 , C07C7/04 , C07C7/13 , C07C7/163 , C07C7/167 , C07C43/046 , C07C11/08 , C07C11/09
Abstract: The present invention provides, among other things, new processes for separating and purifying C4 fractions from a crude C4 stream. Compared to prior methods, the processes of the present invention simplify the C4 separation processes, afford more possible configurations for separation and purification, and are more cost effective. The processes and systems provided herein can be used as part of a cost-effective and efficient method for synthesizing methyl tertiary-butyl ether.
Abstract translation: 本发明尤其提供了从粗C4流分离和纯化C4级分的新方法。 与现有方法相比,本发明的方法简化了C4分离过程,提供了更多可能的分离和纯化配置,并且更具成本效益。 本文提供的方法和系统可以用作合成甲基叔丁基醚的成本有效和有效方法的一部分。
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