公开(公告)号：US11490620B2

公开(公告)日：2022-11-08

申请号：US16632180

申请日：2018-08-09

Applicant: SYNGENTA PARTICIPATIONS AG

Inventor： Denis Gribkov ,  Myriem El Qacemi ,  André Stoller ,  André Jeanguenat ,  Aurelien Bigot

IPC: A01N43/56 ,  A01N25/02 ,  A01N25/04 ,  A01N25/12 ,  A01N25/14 ,  A01N43/647 ,  C07D409/04

Abstract: Compounds of formula (I), as defined herein, to processes for preparing them, to pesticidal, in particular insecticidal, acaricidal, molluscicidal and nematicidal compositions comprising them and to methods of using them to combat and control pests such as insect, acarine, molluse and nematode pests.

公开(公告)号：US11384074B2

公开(公告)日：2022-07-12

申请号：US16754016

申请日：2018-10-04

Applicant: Syngenta Participations AG

Inventor： Aurelien Bigot ,  Myriem El Qacemi ,  Denis Gribkov ,  André Stoller

IPC: C07D409/14 ,  C07D403/04 ,  C07D413/04 ,  A01N43/56 ,  A01N43/80

Abstract: Compounds of formula (I) as defined herein, to processes for preparing them, to pesticidal, in particular insecticidal, acaricidal, molluscicidal and nematicidal compositions comprising them and to methods of using them to combat and control pests such as insect, acarine, mollusc and nematode pests.

公开(公告)号：US11213032B2

公开(公告)日：2022-01-04

申请号：US16496679

申请日：2018-03-22

Applicant: SYNGENTA PARTICIPATIONS AG

Inventor： Myriem El Qacemi ,  Jérôme Yves Cassayre ,  André Stoller

IPC: A01N43/80 ,  C07D413/12 ,  C07D417/12

Abstract: Compounds of formula (I) wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds, and their uses as insecticides.

公开(公告)号：US11001577B2

公开(公告)日：2021-05-11

申请号：US16471497

申请日：2017-12-18

Applicant: SYNGENTA PARTICIPATIONS AG

Inventor： Myriem El Qacemi ,  Jérôme Yves Cassayre ,  Thomas Pitterna ,  André Stoller ,  Peter Renold

IPC: C07D413/12 ,  A01N43/80

Abstract: Compounds of formula (I) wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds, can be used as insecticides and can be prepared in a manner known per se.

公开(公告)号：US10588317B2

公开(公告)日：2020-03-17

申请号：US15762502

申请日：2016-09-22

Applicant: SYNGENTA PARTICIPATIONS AG

Inventor： Jérôme Yves Cassayre ,  André Stoller ,  Thomas Pitterna ,  Myriem El Qacemi

IPC: A01N43/80 ,  C07D261/02 ,  C07D413/12 ,  C07D261/04 ,  C07D413/14

Abstract: The present invention relates to compounds of formula (I) wherein A1, A2, A3, A4, R1, R2, R3, R4 and n are as defined in claim 1; or a tautomer, isomer, enantiomer, salt or N-oxide thereof; to intermediates for preparing compounds of formula (I), to compositions comprising them and to methods of using them to combat and control insect, acarine, nematode and mollusc pests.

公开(公告)号：US10287281B2

公开(公告)日：2019-05-14

申请号：US15628804

申请日：2017-06-21

Applicant: Syngenta Participations AG

Inventor： Long Lu ,  Jerome Yves Cassayre ,  Guillaume Berthon ,  Myriem El Qacemi ,  Yaming Wu

IPC: C07D413/12 ,  C07D231/36 ,  C07D409/12 ,  A01N43/78 ,  A01N53/00 ,  A01N43/56 ,  A01N43/58 ,  A01N43/60 ,  A01N43/90 ,  A01N43/16 ,  C07D231/06 ,  A01N43/80

Abstract: The present invention relates to compounds of formula I wherein P is selected from P1 and P2, or P and R5 together are P3 or P is a heterocycle H, selected from H1 to H9 wherein Y1, Y2, and Y3 are independently of each other C—H, C—R5, or nitrogen; and G1, G2, G3, Z, R1, R2, R3, R4, R5, R6a, R6b, R7, R8, R9, R10, R11, p, n and k are as defined in the claims. The invention also relates to methods of controlling insects, acarines, nematodes or molluscs which comprises applying to a pest, to a locus of a pest, or to a plant susceptible to attack by a pest an insecticidally, acaricidally, nematicidally or molluscicidally effective amount of a compound of formula I.

公开(公告)号：US20180255780A1

公开(公告)日：2018-09-13

申请号：US15762502

申请日：2016-09-22

Applicant: SYNGENTA PARTICIPATIONS AG

Inventor： Jérôme Yves Cassayre ,  André Stoller ,  Thomas Pitterna ,  Myriem El Qacemi

IPC: A01N43/80 ,  C07D261/02 ,  C07D413/12

CPC classification number: A01N43/80 ,  C07D261/02 ,  C07D261/04 ,  C07D413/12 ,  C07D413/14

Abstract: The present invention relates to compounds of formula (I) wherein A1, A2, A3, A4, R1, R2, R3, R4 and n are as defined in claim 1; or a tautomer, isomer, enantiomer, salt or N-oxide thereof; to intermediates for preparing compounds of formula (I), to compositions comprising them and to methods of using them to combat and control insect, acarine, nematode and mollusc pests.

公开(公告)号：US09776994B2

公开(公告)日：2017-10-03

申请号：US14762319

申请日：2014-01-23

Applicant: SYNGENTA PARTICIPATIONS AG

Inventor： Long Lu ,  Jerome Yves Cassayre ,  Guillaume Berthon ,  Myriem El Qacemi ,  Yaming Wu

IPC: C07D413/12 ,  C07D231/06 ,  C07D409/12 ,  A01N43/56 ,  A01N43/80 ,  A01N43/58 ,  A01N43/60 ,  A01N43/90 ,  A01N53/00 ,  A01N43/16 ,  A01N43/78

CPC classification number: C07D413/12 ,  A01N43/16 ,  A01N43/56 ,  A01N43/58 ,  A01N43/60 ,  A01N43/78 ,  A01N43/80 ,  A01N43/90 ,  A01N53/00 ,  C07D231/06 ,  C07D409/12

Abstract: The present invention relates to compounds of formula (I) wherein P is selected from P1 and P2, or P and R5 together are P3 or P is a heterocycle H, selected from H1 to H9 wherein Y1, Y2 and Y3 are independently of each other C—H, C—R5, or nitrogen; and G1, G2, G3, Z, R1, R2, R3, R4, R5, R6a, R6b, R7, R8, R9, R10, R11, p, n and k are as defined in the claims. The invention also relates to methods of controlling insects, acarines, nematodes or molluscs which comprises applying to a pest, to a locus of a pest, or to a plant susceptible to attack by a pest an insecticidally, acaricidally, nematicidally or molluscicidally effective amount of a compound of formula (I).

公开(公告)号：US09675073B2

公开(公告)日：2017-06-13

申请号：US14442952

申请日：2013-11-21

Applicant: Syngenta Participations AG

Inventor： Girish Rawal ,  Rupesh Patre ,  Guillaume Berthon ,  Jerome Yves Cassayre ,  Myriem El Qacemi

IPC: A01N43/80 ,  A01N43/10 ,  C07D333/24 ,  C07D261/04 ,  C07D413/12 ,  C07C317/32 ,  A01N43/36 ,  C07D333/18 ,  A01N43/08

CPC classification number: A01N43/80 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  C07C317/32 ,  C07D261/04 ,  C07D333/18 ,  C07D333/24 ,  C07D413/12

Abstract: The present invention provides compounds of formula (I) wherein R1, R2, R3, R4, n, A1, A2, A3, A4, Y1, Y2 and Y3 are as defined in the claims. The invention also relates to processes and intermediates for preparing these compounds, to insecticidal, acaricidal, nematicidal and molluscicidal compositions comprising these compounds and to methods of using these compounds to control insect, acarine, nematode and mollusc pests.

公开(公告)号：US09469633B2

公开(公告)日：2016-10-18

申请号：US14346773

申请日：2012-09-28

Applicant: SYNGENTA PARTICIPATIONS AG

Inventor： Tomas Smejkal ,  Helmars Smits ,  Sebastian Volker Wendeborn ,  Guillaume Berthon ,  Jerome Yves Cassayre ,  Myriem El Qacemi

IPC: C07D207/408 ,  C07D207/40 ,  C07D207/404 ,  C08F8/32 ,  C07D207/412 ,  C07D207/325 ,  C07C255/41 ,  C07C253/10 ,  C07C253/30 ,  C07D453/04 ,  C07D409/12 ,  C07D207/08 ,  C07D207/267 ,  C07D207/333 ,  C07D307/46 ,  C07C255/40 ,  C07D207/12

CPC classification number: C07D453/04 ,  C07C253/10 ,  C07C253/30 ,  C07C255/40 ,  C07C255/41 ,  C07D207/08 ,  C07D207/12 ,  C07D207/267 ,  C07D207/325 ,  C07D207/333 ,  C07D207/40 ,  C07D307/46 ,  C07D409/12

Abstract: The present invention relates to processes for the enantio-selective preparation of spyrrolidine derivatives useful in the manufacture of pesticidally active compounds, as well as to intermediates in the processes. The processes include those comprising(a-i) reacting a compound of formula Ia wherein P is alkyl, aryl or heteroaryl, each optionally substituted, wherein the heteroaryl is connected at P via a ring carbon atom; R1 is chlorodifluoromethyl or trifluoromethyl; R2 is aryl or heteroaryl, each optionally substituted; with a source of cyanide in the presence a chiral catalyst to give a compound of formula IIa wherein P, R1 and R2 are as defined for the compound of formula Ia; and (a-ii) oxidizing the compound of formula IIa with a peroxy acid, or peroxide in the presence of an acid to give a compound of formula VI wherein R1 and R2 are as defined for the compound of formula Ia.