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    Carbon nanotubes for fuel cells, method for manufacturing the same, and fuel cell using the same
    31.
    发明授权
    Carbon nanotubes for fuel cells, method for manufacturing the same, and fuel cell using the same 有权
    燃料电池用碳纳米管及其制造方法以及使用该碳纳米管的燃料电池

    公开(公告)号：US08083905B2

    公开(公告)日：2011-12-27

    申请号：US12511468

    申请日：2009-07-29

    申请人： Won-bong Choi ,  Jae-uk Chu ,  Chan-ho Pak ,  Hyuk Chang

    发明人： Won-bong Choi ,  Jae-uk Chu ,  Chan-ho Pak ,  Hyuk Chang

    IPC分类号： C01B31/00 ,  D01F9/12

    CPC分类号： H01M4/8605 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  H01M4/9083 ,  H01M4/926 ,  H01M2008/1095 ,  Y10S977/70 ,  Y10S977/701 ,  Y10S977/72 ,  Y10S977/743 ,  Y10S977/843 ,  Y10S977/847

    摘要： The internal and external walls of the carbon nanotubes are doped with nano-sized metallic catalyst particles uniformly to a degree of 0.3-5 mg /cm2. The carbon nanotubes are grown over a carbon substrate using chemical vapor deposition or plasma enhanced chemical vapor deposition. Since the carbon nanotubes have a large specific surface area, and metallic catalyst particles are uniformly distributed over the internal and external walls thereof, the reaction efficiency in an electrode becomes maximal when the carbon nanotubes are used for the electrode of a fuel cell. The carbon nanotubes fabricated using the method can be applied to form a large electrode. The carbon nanotubes grown over the carbon substrate can be readily applied to an electrode of a fuel cell, providing economical advantages and simplifying the overall electrode manufacturing process. A fuel cell using as the carbon nanotubes for its electrode provides improved performance.

    摘要翻译： 碳纳米管的内壁和外壁均匀掺杂有纳米尺寸的金属催化剂颗粒至0.3-5mg / cm2的程度。 使用化学气相沉积或等离子体增强化学气相沉积在碳衬底上生长碳纳米管。 由于碳纳米管具有大的比表面积，并且金属催化剂颗粒均匀地分布在其内壁和外壁上，所以当将碳纳米管用于燃料电池的电极时，电极中的反应效率最大。 使用该方法制造的碳纳米管可以应用于形成大电极。 生长在碳基板上的碳纳米管可以容易地应用于燃料电池的电极，提供经济的优点并简化整个电极的制造过程。 使用作为其电极的碳纳米管的燃料电池提供改进的性能。

    ELECTRODE CATALYST, AND MEMBRANE ELECTRODE ASSEMBLY AND FUEL CELL INCLUDING THE ELECTRODE CATALYST
    32.
    发明申请
    ELECTRODE CATALYST, AND MEMBRANE ELECTRODE ASSEMBLY AND FUEL CELL INCLUDING THE ELECTRODE CATALYST 审中-公开
    电极催化剂和膜电极组件和包含电极催化剂的燃料电池

    公开(公告)号：US20110053039A1

    公开(公告)日：2011-03-03

    申请号：US12634142

    申请日：2009-12-09

    申请人： Chan-ho Pak ,  Dong Jin Ham ,  Jae-sung Lee ,  Hyuk Chang ,  Gang-hong Bae

    发明人： Chan-ho Pak ,  Dong Jin Ham ,  Jae-sung Lee ,  Hyuk Chang ,  Gang-hong Bae

    IPC分类号： H01M8/10 ,  B01J27/22 ,  H01M4/88

    CPC分类号： H01M4/921 ,  H01M4/925 ,  H01M4/926 ,  H01M2008/1095

    摘要： An electrode catalyst for a fuel cell having comparable electrochemical activity as a platinum electrode catalyst but is much cheaper than the platinum electrode catalyst has a structure in which palladium and at least one metal catalyst selected from the group consisting of nickel, gold, iron, and silver, and combinations thereof, are supported on a tungsten carbide and carbon mesoporous composite support. A membrane electrode assembly and a fuel cell including the electrode catalyst also has comparable electrochemical activity as a platinum electrode catalyst but is also much cheaper than the platinum electrode catalyst.

    摘要翻译： 用于具有与铂电极催化剂相当的电化学活性但比铂电极催化剂便宜的燃料电池的电极催化剂具有钯和至少一种选自镍，金，铁和 银及其组合被支撑在碳化钨和碳介孔复合载体上。 膜电极组件和包括电极催化剂的燃料电池也具有与铂电极催化剂相当的电化学活性，但也比铂电极催化剂便宜得多。

    Method of preparing carbon nanocages
    33.
    发明授权
    Method of preparing carbon nanocages 失效
    碳纳米线的制备方法

    公开(公告)号：US07518045B2

    公开(公告)日：2009-04-14

    申请号：US11140979

    申请日：2005-06-01

    申请人： Chan-ho Pak ,  Hyuk Chang ,  Jian Nong Wang

    发明人： Chan-ho Pak ,  Hyuk Chang ,  Jian Nong Wang

    IPC分类号： C01B31/04

    CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/18 ,  Y10S977/843

    摘要： The present invention provides a simple method of mass producing high purity carbon nanocages. The method of preparing carbon nanocages comprises introducing an inert gas into a reactor equipped with a spray nozzle and raising the temperature of the reactor to a pyrolysis temperature of a catalyst compound. The method further comprises spraying a reactant including the catalyst compound and a carbon-containing compound into the reactor through the spray nozzle, wherein the ratio of a space velocity of the inert gas to a space velocity of the reactant is 100 or more.

    摘要翻译： 本发明提供了大规模生产高纯碳纳米笼的简单方法。 制备碳纳米笼的方法包括将惰性气体引入装有喷嘴的反应器中，并将反应器的温度升高至催化剂化合物的热解温度。 该方法还包括通过喷嘴将包含催化剂化合物和含碳化合物的反应物喷射到反应器中，其中惰性气体的空速与反应物的空速之比为100以上。

    SUPPORTED CATALYST AND METHOD OF PREPARING THE SAME
    36.
    发明申请
    SUPPORTED CATALYST AND METHOD OF PREPARING THE SAME 有权
    支持的催化剂及其制备方法

    公开(公告)号：US20100081034A1

    公开(公告)日：2010-04-01

    申请号：US12615514

    申请日：2009-11-10

    申请人： Chan-ho PAK ,  Hyuk Chang ,  Dae-jung Yoo ,  Seol ah Lee ,  Gongquan Sun ,  Luhua Jiang ,  Qin Xin

    发明人： Chan-ho PAK ,  Hyuk Chang ,  Dae-jung Yoo ,  Seol ah Lee ,  Gongquan Sun ,  Luhua Jiang ,  Qin Xin

    IPC分类号： H01M4/90 ,  B01J31/06

    CPC分类号： B82Y30/00 ,  B01J21/18 ,  B01J21/185 ,  B01J23/42 ,  B01J37/035 ,  B01J37/16 ,  H01M4/9083 ,  H01M4/926 ,  H01M8/1011 ,  H01M2008/1095 ,  Y02E60/523 ,  Y02P70/56

    摘要： A method of preparing a supported catalyst includes dissolving a cation exchange polymer in alcohol to prepare a solution containing cation exchange polymer; mixing the cation exchange polymer containing solution with a catalytic metal precursor or a solution containing catalytic metal precursor; heating the mixture after adjusting its pH to a predetermined range; adding a reducing agent to the resultant and stirring the solution to reduce the catalytic metal precursor; mixing the resultant with a catalyst support; adding a precipitating agent to the resultant to form precipitates; and filtering and drying the precipitates. The method of preparing a supported catalyst can provide a highly dispersed supported catalyst containing catalytic metal particles with a reduced average size regardless of the type of catalyst support, which provides better catalytic activity than conventional catalysts at the same loading amount of catalytic metal.

    摘要翻译： 制备负载型催化剂的方法包括将阳离子交换聚合物溶解在醇中以制备含有阳离子交换聚合物的溶液; 将含阳离子交换聚合物的溶液与催化金属前体或含有催化金属前体的溶液混合; 将其pH调节至预定范围后加热混合物; 向所得物中加入还原剂并搅拌溶液以还原催化金属前体; 将所得物与催化剂载体混合; 向所得物中加入沉淀剂形成析出物; 并过滤并干燥沉淀物。 制备负载型催化剂的方法可以提供高分散的载体催化剂，其含有平均尺寸较小的催化金属颗粒，而不管催化剂载体的类型如何，这在催化金属的相同负载量下提供比常规催化剂更好的催化活性。

    Supported catalyst and method of preparing the same
    38.
    发明授权
    Supported catalyst and method of preparing the same 有权
    负载催化剂及其制备方法

    公开(公告)号：US07867940B2

    公开(公告)日：2011-01-11

    申请号：US11334472

    申请日：2006-01-19

    申请人： Chan-ho Pak ,  Hyuk Chang ,  Dae-Jong Yoo ,  Seol ah Lee ,  Gongguan Sun ,  Luhua Jiang ,  Qin Xin

    发明人： Chan-ho Pak ,  Hyuk Chang ,  Dae-Jong Yoo ,  Seol ah Lee ,  Gongguan Sun ,  Luhua Jiang ,  Qin Xin

    IPC分类号： H01M4/02 ,  H01M4/88 ,  B01J31/00 ,  B01J21/18 ,  B01J23/00 ,  B01J23/40 ,  B01J23/74 ,  H01M4/36 ,  H01M4/92 ,  H01M4/90 ,  B01J37/00 ,  C08F4/02 ,  C08F4/60

    CPC分类号： B82Y30/00 ,  B01J21/18 ,  B01J21/185 ,  B01J23/42 ,  B01J37/035 ,  B01J37/16 ,  H01M4/9083 ,  H01M4/926 ,  H01M8/1011 ,  H01M2008/1095 ,  Y02E60/523 ,  Y02P70/56

    摘要： A method of preparing a supported catalyst includes dissolving a cation exchange polymer in alcohol to prepare a solution containing cation exchange polymer; mixing the cation exchange polymer containing solution with a catalytic metal precursor or a solution containing catalytic metal precursor; heating the mixture after adjusting its pH to a predetermined range; adding a reducing agent to the resultant and stirring the solution to reduce the catalytic metal precursor; mixing the resultant with a catalyst support; adding a precipitating agent to the resultant to form precipitates; and filtering and drying the precipitates. The method of preparing a supported catalyst can provide a highly dispersed supported catalyst containing catalytic metal particles with a reduced average size regardless of the type of catalyst support, which provides better catalytic activity than conventional catalysts at the same loading amount of catalytic metal.

    摘要翻译： 制备负载型催化剂的方法包括将阳离子交换聚合物溶解在醇中以制备含有阳离子交换聚合物的溶液; 将含阳离子交换聚合物的溶液与催化金属前体或含有催化金属前体的溶液混合; 将其pH调节至预定范围后加热混合物; 向所得物中加入还原剂并搅拌溶液以还原催化金属前体; 将所得物与催化剂载体混合; 向所得物中加入沉淀剂形成析出物; 并过滤并干燥沉淀物。 制备负载型催化剂的方法可以提供高分散的载体催化剂，其含有平均尺寸较小的催化金属颗粒，而不管催化剂载体的类型如何，这在催化金属的相同负载量下提供比常规催化剂更好的催化活性。

    Carbon nanotubes for fuel cells, method for manufacturing the same, and fuel cell using the same
    40.
    发明授权
    Carbon nanotubes for fuel cells, method for manufacturing the same, and fuel cell using the same 有权
    燃料电池用碳纳米管及其制造方法以及使用该碳纳米管的燃料电池

    公开(公告)号：US07585584B2

    公开(公告)日：2009-09-08

    申请号：US10601872

    申请日：2003-06-24

    申请人： Won-bong Choi ,  Jae-uk Chu ,  Chan-ho Pak ,  Hyuk Chang

    发明人： Won-bong Choi ,  Jae-uk Chu ,  Chan-ho Pak ,  Hyuk Chang

    IPC分类号： H01M4/00

    CPC分类号： H01M4/8605 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  H01M4/9083 ,  H01M4/926 ,  H01M2008/1095 ,  Y10S977/70 ,  Y10S977/701 ,  Y10S977/72 ,  Y10S977/743 ,  Y10S977/843 ,  Y10S977/847

    摘要： Carbon nanotubes for use in a fuel cell, a method for fabricating the same, and a fuel cell using the carbon nanotubes for its electrode are provided. The internal and external walls of the carbon nanotubes are doped with nano-sized metallic catalyst particles uniformly to a degree of 0.3-5 mg/cm2. The carbon nanotubes are grown over a carbon substrate using chemical vapor deposition or plasma enhanced chemical vapor deposition. Since the carbon nanotubes have a large specific surface area, and metallic catalyst particles are uniformly distributed over the internal and external walls thereof, the reaction efficiency in an electrode becomes maximal when the carbon nanotubes are used for the electrode of a fuel cell. The carbon nanotubes fabricated using the method can be applied to form a large electrode. The carbon nanotubes grown over the carbon substrate can be readily applied to an electrode of a fuel cell, providing economical advantages and simplifying the overall electrode manufacturing process. A fuel cell using as the carbon nanotubes for its electrode provides improved performance.

    摘要翻译： 提供了用于燃料电池的碳纳米管，其制造方法和使用该碳纳米管作为其电极的燃料电池。 碳纳米管的内壁和外壁均匀掺杂有纳米尺寸的金属催化剂颗粒至0.3-5mg / cm2的程度。 使用化学气相沉积或等离子体增强化学气相沉积在碳衬底上生长碳纳米管。 由于碳纳米管具有大的比表面积，并且金属催化剂颗粒均匀地分布在其内壁和外壁上，所以当将碳纳米管用于燃料电池的电极时，电极中的反应效率最大。 使用该方法制造的碳纳米管可以应用于形成大电极。 生长在碳基板上的碳纳米管可以容易地应用于燃料电池的电极，提供经济的优点并简化整个电极的制造过程。 使用作为其电极的碳纳米管的燃料电池提供改进的性能。