公开(公告)号：US08083905B2

公开(公告)日：2011-12-27

申请号：US12511468

申请日：2009-07-29

申请人： Won-bong Choi ,  Jae-uk Chu ,  Chan-ho Pak ,  Hyuk Chang

发明人： Won-bong Choi ,  Jae-uk Chu ,  Chan-ho Pak ,  Hyuk Chang

IPC分类号： C01B31/00 ,  D01F9/12

CPC分类号： H01M4/8605 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  H01M4/9083 ,  H01M4/926 ,  H01M2008/1095 ,  Y10S977/70 ,  Y10S977/701 ,  Y10S977/72 ,  Y10S977/743 ,  Y10S977/843 ,  Y10S977/847

摘要： The internal and external walls of the carbon nanotubes are doped with nano-sized metallic catalyst particles uniformly to a degree of 0.3-5 mg /cm2. The carbon nanotubes are grown over a carbon substrate using chemical vapor deposition or plasma enhanced chemical vapor deposition. Since the carbon nanotubes have a large specific surface area, and metallic catalyst particles are uniformly distributed over the internal and external walls thereof, the reaction efficiency in an electrode becomes maximal when the carbon nanotubes are used for the electrode of a fuel cell. The carbon nanotubes fabricated using the method can be applied to form a large electrode. The carbon nanotubes grown over the carbon substrate can be readily applied to an electrode of a fuel cell, providing economical advantages and simplifying the overall electrode manufacturing process. A fuel cell using as the carbon nanotubes for its electrode provides improved performance.

摘要翻译： 碳纳米管的内壁和外壁均匀掺杂有纳米尺寸的金属催化剂颗粒至0.3-5mg / cm2的程度。 使用化学气相沉积或等离子体增强化学气相沉积在碳衬底上生长碳纳米管。 由于碳纳米管具有大的比表面积，并且金属催化剂颗粒均匀地分布在其内壁和外壁上，所以当将碳纳米管用于燃料电池的电极时，电极中的反应效率最大。 使用该方法制造的碳纳米管可以应用于形成大电极。 生长在碳基板上的碳纳米管可以容易地应用于燃料电池的电极，提供经济的优点并简化整个电极的制造过程。 使用作为其电极的碳纳米管的燃料电池提供改进的性能。

公开(公告)号：US07585584B2

公开(公告)日：2009-09-08

申请号：US10601872

申请日：2003-06-24

申请人： Won-bong Choi ,  Jae-uk Chu ,  Chan-ho Pak ,  Hyuk Chang

发明人： Won-bong Choi ,  Jae-uk Chu ,  Chan-ho Pak ,  Hyuk Chang

IPC分类号： H01M4/00

CPC分类号： H01M4/8605 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  H01M4/9083 ,  H01M4/926 ,  H01M2008/1095 ,  Y10S977/70 ,  Y10S977/701 ,  Y10S977/72 ,  Y10S977/743 ,  Y10S977/843 ,  Y10S977/847

摘要： Carbon nanotubes for use in a fuel cell, a method for fabricating the same, and a fuel cell using the carbon nanotubes for its electrode are provided. The internal and external walls of the carbon nanotubes are doped with nano-sized metallic catalyst particles uniformly to a degree of 0.3-5 mg/cm2. The carbon nanotubes are grown over a carbon substrate using chemical vapor deposition or plasma enhanced chemical vapor deposition. Since the carbon nanotubes have a large specific surface area, and metallic catalyst particles are uniformly distributed over the internal and external walls thereof, the reaction efficiency in an electrode becomes maximal when the carbon nanotubes are used for the electrode of a fuel cell. The carbon nanotubes fabricated using the method can be applied to form a large electrode. The carbon nanotubes grown over the carbon substrate can be readily applied to an electrode of a fuel cell, providing economical advantages and simplifying the overall electrode manufacturing process. A fuel cell using as the carbon nanotubes for its electrode provides improved performance.

摘要翻译： 提供了用于燃料电池的碳纳米管，其制造方法和使用该碳纳米管作为其电极的燃料电池。 碳纳米管的内壁和外壁均匀掺杂有纳米尺寸的金属催化剂颗粒至0.3-5mg / cm2的程度。 使用化学气相沉积或等离子体增强化学气相沉积在碳衬底上生长碳纳米管。 由于碳纳米管具有大的比表面积，并且金属催化剂颗粒均匀地分布在其内壁和外壁上，所以当将碳纳米管用于燃料电池的电极时，电极中的反应效率最大。 使用该方法制造的碳纳米管可以应用于形成大电极。 生长在碳基板上的碳纳米管可以容易地应用于燃料电池的电极，提供经济的优点并简化整个电极的制造过程。 使用作为其电极的碳纳米管的燃料电池提供改进的性能。

公开(公告)号：US08173096B2

公开(公告)日：2012-05-08

申请号：US12911352

申请日：2010-10-25

申请人： Hyuk Chang ,  Chan-ho Pak ,  Jian Nong Wang

发明人： Hyuk Chang ,  Chan-ho Pak ,  Jian Nong Wang

IPC分类号： C09C1/44

CPC分类号： H01M4/926 ,  B01J21/18 ,  B82Y30/00 ,  C01B32/05 ,  H01M4/92 ,  H01M4/921 ,  H01M2008/1095 ,  Y10S977/734 ,  Y10S977/737 ,  Y10S977/843 ,  Y10S977/847 ,  Y10S977/888

摘要： A carbon nanosphere has at least one opening. The carbon nanosphere is obtained by preparing a carbon nanosphere and treating it with an acid to form the opening. The carbon nanosphere with at least one opening has higher utilization of a surface area and electrical conductivity and lower mass transfer resistance than a conventional carbon nanotube, thus allowing for higher current density and cell voltage with a smaller amount of metal catalyst per unit area of a fuel cell electrode.

摘要翻译： 碳纳米球具有至少一个开口。 碳纳米球通过制备碳纳米球并用酸处理以形成开口获得。 具有至少一个开口的碳纳米球具有比常规碳纳米管更高的表面积利用率和导电性和较低的传质阻力，从而允许较高的电流密度和电池电压，每单位面积的金属催化剂量 燃料电池电极。

公开(公告)号：US07854913B2

公开(公告)日：2010-12-21

申请号：US11443160

申请日：2006-05-31

申请人： Sang-hoon Joo ,  Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim ,  Hyung-ik Lee

发明人： Sang-hoon Joo ,  Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim ,  Hyung-ik Lee

IPC分类号： B01J19/08 ,  H01M8/00

CPC分类号： H01M4/926 ,  B82Y30/00 ,  C01B32/00

摘要： A mesoporous carbon is prepared by mixing a carbon precursor, an acid, and a solvent to obtain a carbon precursor mixture; impregnating an ordered mesoporous silica (OMS) with the carbon precursor mixture; carbonizing the impregnated OMS at 800 to 1300° C. by irradiating microwave energy with a power of 100 to 2000 W thereon to form an OMS-carbon composite; and removing the mesoporous silica from the OMS-carbon composite. The method of preparing a mesoporous carbon can significantly reduce a carbonization time by carbonizing a carbon precursor using microwave energy in a silica template compared to a conventional method using a heat treatment. A supported catalyst and a fuel cell include the mesoporous carbon.

摘要翻译： 通过混合碳前体，酸和溶剂来制备介孔碳以获得碳前体混合物; 用碳前体混合物浸渍有序介孔二氧化硅（OMS）; 通过在其上照射100至2000W的功率的微波能量来在800至1300℃下将浸渍的OMS碳化，以形成OMS-碳复合材料; 并从OMS-碳复合材料中除去介孔二氧化硅。 制备介孔碳的方法与使用热处理的常规方法相比，通过使用微波能量在二氧化硅模板中碳化碳前体可显着降低碳化时间。 载体催化剂和燃料电池包括介孔碳。

公开(公告)号：US20100004121A1

公开(公告)日：2010-01-07

申请号：US11029496

申请日：2005-01-06

申请人： Hyuk Chang ,  Chan-ho Pak ,  Jian Nong Wang

发明人： Hyuk Chang ,  Chan-ho Pak ,  Jian Nong Wang

IPC分类号： B01J21/18 ,  B01J23/42

CPC分类号： H01M4/926 ,  B01J21/185 ,  B01J23/42 ,  B01J35/006 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1076 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B2202/02 ,  C01B2202/06 ,  C01B2202/34 ,  C01B2202/36 ,  H01M4/8846 ,  H01M4/921 ,  H01M2008/1095

摘要： The present invention is related to a short carbon nanotube for a catalyst support. In particular, the short carbon nanotube may be opened at both ends, a length of less than about 300 nm, and an aspect ratio in the range of about 1 to about 15. The short carbon nanotube has a broad surface area and better electric conductivity and is opened at both ends, thereby impregnating a metallic catalyst into the inner side of the carbon nanotube. Also, a catalyst impregnated carbon nanotube has a broad effective specific surface area, and thus, has an improved efficiency of catalyst utilization, can reduce an amount of the catalyst used and can efficiently diffuse a fuel. Accordingly, when catalyst impregnated carbon nanotube is used in a fuel cell, etc., improvements can be made in the pricing, power density of an electrode, and energy density of a fuel cell.

摘要翻译： 本发明涉及一种用于催化剂载体的短碳纳米管。 特别地，短碳纳米管可以在两端开口，长度小于约300nm，纵横比在约1至约15的范围内。短碳纳米管具有宽的表面积和更好的导电性 并且在两端开口，从而将金属催化剂浸渍到碳纳米管的内侧。 此外，催化剂浸渍的碳纳米管具有广泛的有效比表面积，因此具有提高的催化剂利用效率，可以减少所用催化剂的量并且可以有效地扩散燃料。 因此，当在燃料电池等中使用催化剂浸渍碳纳米管时，可以在燃料电池的定价，电力功率密度和能量密度方面进行改进。

公开(公告)号：US20070270305A1

公开(公告)日：2007-11-22

申请号：US11708600

申请日：2007-02-21

申请人： Chan-ho Pak ,  Dae-jong Yoo ,  Sang-hoon Joo ,  Hyuk Chang ,  Seol-ah Lee

发明人： Chan-ho Pak ,  Dae-jong Yoo ,  Sang-hoon Joo ,  Hyuk Chang ,  Seol-ah Lee

IPC分类号： B01J31/00

CPC分类号： H01M4/926 ,  H01M4/8657 ,  H01M4/8814 ,  H01M4/885 ,  H01M4/92 ,  H01M4/921 ,  H01M8/1007 ,  H01M8/1011 ,  Y02E60/523 ,  Y02P70/56

摘要： A method of preparing a supported catalyst, the method comprising mixing a first catalytic metal precursor and a first solvent to obtain a first catalytic metal precursor mixture; mixing a carbon support for catalyst and the first catalytic metal precursor mixture, and drying the mixture to obtain a primary supported catalyst precursor; subjecting the primary supported catalyst precursor to a hydrogen reduction heat treatment, to obtain a primary supported catalyst; mixing the primary supported catalyst and a polyhydric alcohol to obtain a primary supported catalyst mixture; mixing a second catalytic metal precursor and a second solvent to obtain a second catalytic metal precursor mixture; mixing the primary supported catalyst mixture and the second catalytic metal precursor mixture to obtain a secondary supported catalyst precursor mixture; and adjusting the pH of the secondary supported catalyst precursor mixture, and then heating the secondary supported catalyst precursor mixture to obtain a supported catalyst, a supported catalyst prepared by the method, an electrode comprising the supported catalyst, and a fuel cell including the electrode are provided. A supported catalyst having a desired amount of loaded catalytic metal particles can be obtained by preparing a primary supported catalyst containing catalytic metal particles that are obtained by a primary gas phase reduction reaction of a portion of the final loading amount of catalytic metal, and reducing the remaining portion of the catalytic metal by a secondary liquid phase reduction reaction. The supported catalyst contains catalytic metal particles having a very small average particle size, which are uniformly distributed on a carbon support at a high concentration, and thus exhibits maximal catalyst activity. A fuel cell produced using the supported catalyst has improved efficiency.

摘要翻译： 一种制备负载型催化剂的方法，所述方法包括混合第一催化金属前体和第一溶剂以获得第一催化金属前体混合物; 混合催化剂用碳载体和第一催化金属前体混合物，干燥混合物得到主要负载型催化剂前体; 对初级负载催化剂前体进行氢还原热处理，得到主要负载型催化剂; 将主要负载型催化剂和多元醇混合，得到主要负载型催化剂混合物; 混合第二催化金属前体和第二溶剂以获得第二催化金属前体混合物; 将主要负载的催化剂混合物和第二催化金属前体混合物混合，得到二次负载催化剂前体混合物; 调节二次负载型催化剂前体混合物的pH，然后加热二次负载型催化剂前体混合物，得到负载型催化剂，通过该方法制备的负载催化剂，包含负载型催化剂的电极和包含该电极的燃料电池 提供。 具有所需量的负载的催化金属颗粒的负载型催化剂可以通过制备含有催化金属颗粒的主负载催化剂获得，所述催化金属颗粒是通过催化金属的最终负载量的一部分一次气相还原反应获得的， 催化金属的剩余部分通过二次液相还原反应。 载体催化剂含有平均粒径非常小的催化金属颗粒，其以高浓度均匀分布在碳载体上，因此表现出最大的催化剂活性。 使用负载型催化剂制造的燃料电池具有提高的效率。

公开(公告)号：US07220697B2

公开(公告)日：2007-05-22

申请号：US10992211

申请日：2004-11-19

申请人： Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim

发明人： Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim

IPC分类号： B01J21/18 ,  B01J23/40 ,  C01B31/08 ,  C01B31/02 ,  D01F9/12

CPC分类号： B01J35/1061 ,  B01J21/18 ,  B01J23/42 ,  B01J29/0308 ,  B01J37/06 ,  B01J37/084 ,  C01B32/00 ,  H01M4/9083 ,  H01M4/926

摘要： The present invention is related to a mesoporous carbon molecular sieve, which can be used as a catalyst carrier capable of improving the activity of a supported catalyst and a method of preparing the same. Additionally, the invention is related to a supported catalyst employing the mesoporous carbon molecular sieve as a carrier, and a fuel cell employing the supported catalyst. The mesoporous carbon molecular sieve has an average primary particle size of less than about 500 nm, an average mesopore size in the range of about 3 nm to about 6 nm, and a surface area in the range of about 500 m2/g to about 2000 m2/g.

摘要翻译： 本发明涉及可用作能够提高负载型催化剂的活性的催化剂载体的介孔碳分子筛及其制备方法。 另外，本发明涉及使用中孔碳分子筛作为载体的负载催化剂和使用负载型催化剂的燃料电池。 介孔碳分子筛的平均一次粒径小于约500nm，平均中孔尺寸在约3nm至约6nm的范围内，表面积在约500μm2范围内， /约至约2000m 2 / g。

公开(公告)号：US20060239890A1

公开(公告)日：2006-10-26

申请号：US11262812

申请日：2005-11-01

申请人： Hyuk Chang ,  Chan-ho Pak ,  Jian Wang

发明人： Hyuk Chang ,  Chan-ho Pak ,  Jian Wang

IPC分类号： C01B31/02 ,  H01M4/96

CPC分类号： H01M4/926 ,  B01J21/18 ,  B82Y30/00 ,  C01B32/05 ,  H01M4/92 ,  H01M4/921 ,  H01M2008/1095 ,  Y10S977/734 ,  Y10S977/737 ,  Y10S977/843 ,  Y10S977/847 ,  Y10S977/888

摘要： A carbon nanosphere has at least one opening. The carbon nanosphere is obtained by preparing a carbon nanosphere and treating it with an acid to form the opening. The carbon nanosphere with at least one opening has higher utilization of a surface area and electrical conductivity and lower mass transfer resistance than a conventional carbon nanotube, thus allowing for higher current density and cell voltage with a smaller amount of metal catalyst per unit area of a fuel cell electrode.

公开(公告)号：US09466843B2

公开(公告)日：2016-10-11

申请号：US13190850

申请日：2011-07-26

申请人： Chan-ho Pak ,  Dae-jong Yoo ,  Hyuk Chang ,  Dong-jin Ham ,  Sueng-hoon Han ,  Gang-hong Bae ,  Jae-sung Lee

发明人： Chan-ho Pak ,  Dae-jong Yoo ,  Hyuk Chang ,  Dong-jin Ham ,  Sueng-hoon Han ,  Gang-hong Bae ,  Jae-sung Lee

IPC分类号： H01M4/90 ,  H01M4/92 ,  H01M4/88 ,  H01M8/10

CPC分类号： H01M4/92 ,  H01M4/8803 ,  H01M4/8817 ,  H01M4/921 ,  H01M4/925 ,  H01M2008/1095 ,  Y02E60/50

摘要： An electrode catalyst for a fuel cell, a membrane electrode assembly including the electrode catalyst, and a fuel cell including the electrode catalyst. The electrode catalyst has excellent electrochemical activity compared to the currently commercially available Pt/C catalyst and is much cheaper than a catalyst using platinum. The electrode catalyst includes tungsten carbide having a specific surface area of about 10 to about 30 m2/g, and a metal catalyst comprising palladium (Pd) or palladium alloy.

摘要翻译： 用于燃料电池的电极催化剂，包括电极催化剂的膜电极组件和包括电极催化剂的燃料电池。 与目前市售的Pt / C催化剂相比，电极催化剂具有优异的电化学活性，并且比使用铂的催化剂便宜得多。 电极催化剂包括比表面积为约10至约30m 2 / g的碳化钨和包含钯（Pd）或钯合金的金属催化剂。

公开(公告)号：US09180431B2

公开(公告)日：2015-11-10

申请号：US13360892

申请日：2012-01-30

申请人： Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim

发明人： Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim

IPC分类号： B01J35/10 ,  H01M8/10 ,  B01J21/18 ,  B01J29/03 ,  B01J37/00 ,  C01B31/00 ,  H01M4/90

CPC分类号： B01J21/18 ,  B01J29/0308 ,  B01J35/1066 ,  B01J37/0018 ,  C01B32/00 ,  H01M4/9016 ,  H01M4/9083 ,  H01M8/1011 ,  Y02E60/523 ,  Y02P70/56

摘要： A hierarchical mesoporous carbon is provided in which a total volume of mesopores of the hierarchical mesoporous carbon is 80% or greater of a total volume of pores of the hierarchical mesoporous carbon; a volume of mesopores with a average diameter greater than 20 nm and no greater than 50 nm is 3% or greater of the total volume of the pores; and a volume of mesopores with a average diameter greater than 2 nm and no greater than 10 nm is 65% or greater of the total volume of the pores. The hierarchical mesoporous carbon, which also contains macropores, has an optimized mesoporous distribution characteristic, and has an increased total volume of pores, thereby having a significantly improved catalytic activity when used as a catalyst support. When such a supported catalyst is used in a fuel cell, supply of fuel and transporting of byproducts are facilitated.

摘要翻译： 提供了分级介孔碳，其中分层介孔碳的介孔的总体积为分级介孔碳的总体积的80％或更大; 平均直径大于20nm且不大于50nm的介孔的体积为孔的总体积的3％或更大; 并且平均直径大于2nm且不大于10nm的体积的介孔为孔的总体积的65％或更大。 还含有大孔的层状中孔碳具有优化的介孔分布特征，并且具有增加的孔体积，从而当用作催化剂载体时具有显着改善的催化活性。 当这种负载型催化剂用于燃料电池中时，燃料的供应和副产物的运输便利。