公开(公告)号：US20110136995A1

公开(公告)日：2011-06-09

申请号：US12996252

申请日：2009-06-04

申请人： Ryuji Nakagawa ,  Junko Matsushita ,  Yoichi Ozawa ,  Shojiro Kaita ,  Olivier Tardif

发明人： Ryuji Nakagawa ,  Junko Matsushita ,  Yoichi Ozawa ,  Shojiro Kaita ,  Olivier Tardif

IPC分类号： C08F4/72

CPC分类号： B60C1/00 ,  B60C1/0016 ,  C08F236/10 ,  C08K3/04 ,  C08L9/06 ,  C08F4/52

摘要： This invention relates to an aromatic vinyl compound-conjugated diene compound copolymer capable of giving excellent wear resistance and resistance to wet skid to a tire, and more particularly to an aromatic vinyl compound-conjugated diene compound copolymer obtained by an addition polymerization of an aromatic vinyl compound and a conjugated diene compound in the presence of a polymerization catalyst composition comprising at least one specified metallocene complex selected from the group consisting of a metallocene complex represented by the following general formula (I): (wherein M is a lanthanoid element, scandium or yttrium, and CpR is independently a non-substituted or substituted indenyl, and Ra to Rf are independently an alkyl group having a carbon number of 1-3 or a hydrogen atom, and L is a neutral Lewis base, and w is an integer of 0-3) and so on, wherein a content of cis-1,4 bond in a conjugated diene compound portion is not less than 80%.

摘要翻译： 本发明涉及能够赋予轮胎优异的耐磨性和耐湿滑性的芳香族乙烯基化合物 - 共轭二烯化合物共聚物，更具体地说，涉及通过芳香族乙烯基加成聚合得到的芳族乙烯基化合物 - 共轭二烯化合物共聚物 化合物和共轭二烯化合物，所述聚合催化剂组合物包含至少一种选自由以下通式（I）表示的茂金属络合物的茂金属络合物：（其中M是镧系元素，钪或 钇和CpR独立地为非取代或取代的茚基，Ra至Rf独立地为碳数为1-3的烷基或氢原子，L为中性路易斯碱，w为 0-3）等，其中共轭二烯化合物部分中顺式-1,4键的含量不小于80％。

公开(公告)号：US20090264604A1

公开(公告)日：2009-10-22

申请号：US12227058

申请日：2007-05-02

申请人： Shojiro Kaita ,  Olivier Tardif

发明人： Shojiro Kaita ,  Olivier Tardif

IPC分类号： C07F5/00 ,  B01J31/22 ,  C08F4/72

CPC分类号： C07F17/00 ,  C08F10/00 ,  C08F36/04 ,  C08F112/08 ,  C08F212/08 ,  C08F4/52 ,  C08F4/54 ,  C08F236/06 ,  C08F4/545

摘要： Disclosed are a metallocene complex represented by the general formula (I), (II) or (III), and a polymerization catalyst composition containing such a metallocene complex. In the formulae (I), (II) and (III), M represents a lanthanoid element, scandium or yttrium; CpR independently represents an unsubstituted or substituted indenyl; CpR′ represents an unsubstituted or substituted cyclopentadienyl, indenyl or fluorenyl; Ra-Rf independently represents a hydrogen or an alkyl group having 1-3 carbon atoms; X and X′ respectively represent a hydrogen atom, a halogen atom, an alkoxide group, a thiolate group, an amide group, a silyl group or a hydrocarbon group having 1-20 carbon atoms; L represents a neutral Lewis base; w represents an integer of 0-3; and [B]− represents a non-coordinating anion.

摘要翻译： 公开了由通式（I），（II）或（III）表示的茂金属络合物和含有这种茂金属络合物的聚合催化剂组合物。 在式（I），（II）和（III）中，M表示镧系元素，钪或钇; CpR独立地表示未取代或取代的茚基; CpR'表示未取代或取代的环戊二烯基，茚基或芴基; Ra-Rf独立地表示氢或具有1-3个碳原子的烷基; X和X'分别表示氢原子，卤素原子，醇盐基，硫醇基，酰胺基，甲硅烷基或具有1-20个碳原子的烃基; L代表中性路易斯碱; w表示0-3的整数; 和[B] - 表示非配位阴离子。

公开(公告)号：US20140171596A1

公开(公告)日：2014-06-19

申请号：US14238232

申请日：2012-08-22

申请人： Shojiro Kaita ,  Yasuo Wakatsuki

发明人： Shojiro Kaita ,  Yasuo Wakatsuki

IPC分类号： C08F236/06

CPC分类号： C08F236/06 ,  C08C19/04 ,  C08C19/44 ,  C08F210/02 ,  Y02P20/582 ,  C08F4/52 ,  C08F4/545

摘要： The method for manufacturing a polymer of the present invention is a method for manufacturing a polymer where a hydroxy group is added to a terminal of either one of a homopolymer of a non-conjugated olefin, a homopolymer of a conjugated diene compound, and a copolymer of a conjugated diene compound and a non-conjugated olefin, the method comprising: a first reaction step of reacting a hydrocarbon containing at least either one of the non-conjugated olefin and the conjugated diene compound with an organic aluminum compound, using a rare earth element compound-containing catalyst; a second reaction step of reacting a first reactant obtained from the first reaction step with oxygen; and a third reaction step of reacting a second reactant obtained from the second reaction step with at least either one of water and alcohol.

摘要翻译： 本发明的聚合物的制造方法是在将非共轭烯烃的均聚物，共轭二烯化合物的均聚物和共聚物的共聚物中的任一种的末端添加羟基的聚合物的制造方法 的共轭二烯化合物和非共轭烯烃的方法，该方法包括：使用稀土元素使含有至少一种非共轭烯烃和共轭二烯化合物的烃与有机铝化合物反应的第一反应步骤 含元素化合物的催化剂; 使从第一反应步骤获得的第一反应物与氧反应的第二反应步骤; 和将从第二反应步骤获得的第二反应物与水和醇中的至少一种反应的第三反应步骤。

公开(公告)号：US08163860B2

公开(公告)日：2012-04-24

申请号：US13146600

申请日：2010-01-29

申请人： Shojiro Kaita ,  Nobuyuki Kibino ,  Kazufumi Kai

发明人： Shojiro Kaita ,  Nobuyuki Kibino ,  Kazufumi Kai

IPC分类号： C08F232/04 ,  C08F4/70

CPC分类号： C08F232/08

摘要： The invention relates to a norbornene copolymer having excellent properties such as transparency, heat resistance, low water absorption and electric insulating property, which copolymer comprises a monomer unit represented by formula (1) and formula (2) and having a number average molecular weight (Mn) of 300,000 to 2,000,000. (In the formulae, R1 represents an alkyl group having 1 to 10 carbon atoms; and R2, R3 and R4 independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms.)

摘要翻译： 本发明涉及具有透明性，耐热性，低吸水性和电绝缘性等优异性能的降冰片烯共聚物，该共聚物包括由式（1）和式（2）表示的单体单元，其数均分子量（ Mn）为30万至2,000,000。 （式中，R1表示碳原子数1〜10的烷基，R2，R3，R4分别表示氢原子或碳原子数1〜10的烷基。

公开(公告)号：US07511108B2

公开(公告)日：2009-03-31

申请号：US10564727

申请日：2004-07-01

申请人： Eiju Suzuki ,  Yoichi Ozawa ,  Shojiro Kaita ,  Yasuo Wakatsuki

发明人： Eiju Suzuki ,  Yoichi Ozawa ,  Shojiro Kaita ,  Yasuo Wakatsuki

IPC分类号： C08F136/06 ,  B60C1/00 ,  C08L9/00 ,  C08F4/72

CPC分类号： B60C1/0016 ,  C08L9/00 ,  Y10S152/905 ,  Y10T152/10495 ,  C08F36/04 ,  C08F4/545

摘要： The invention relates to a pneumatic tire having excellent mechanical properties by using a rubber composition containing a polybutadiene rubber having a high cis-1,4 bond content, a low vinyl bond content and proper number average molecular weight and molecular weight distribution, and more particularly to a pneumatic tire characterized in that a rubber composition including a polybutadiene with a cis-1,4 bond content of not less than 99.0% and a vinyl bond content of not more than 0.3% as measured by a Fourier transform infrared spectroscopy is used in any one of tire members.

摘要翻译： 本发明涉及通过使用含有具有高顺式-1,4键含量，低乙烯基键含量和适当数均分子量和分子量分布的聚丁二烯橡胶的橡胶组合物，具有优异的机械性能的充气轮胎，更具体地说， 涉及一种充气轮胎，其特征在于，使用通过傅立叶变换红外光谱法测定的包含顺式-1,4键含量为99.0％以上的聚丁二烯和乙烯基键含量为0.3％以下的橡胶组合物 任何一个轮胎成员。

公开(公告)号：US07056994B2

公开(公告)日：2006-06-06

申请号：US10509123

申请日：2003-03-28

申请人： Shojiro Kaita ,  Zhaomin Hou ,  Yasuo Wakatsuki

发明人： Shojiro Kaita ,  Zhaomin Hou ,  Yasuo Wakatsuki

IPC分类号： C08F4/52 ,  C08F36/04

CPC分类号： C08F136/04 ,  C08L9/00 ,  Y10S526/943 ,  C08F4/54 ,  C08F4/52

摘要： The present invention relates to a catalyst composition for polymerization of a conjugated diene, comprising: (A) a metallocene-type complex represented by a general formula (I): (C5R1R2R3R4R5)aMXb.Lc (where, M represents a rare earth metal; C5R1R2R3R4R5 represents a substituted cyclopentadienyl group; R1 to R5 represent the same or different hydrocarbon groups (except when R1=R2=R3=R4=R5=a methyl group); X represents a hydrogen atom, a halogen atom, an alkoxide group, a thiolate group, an amide group, or a hydrocarbon group having 1 to 20 carbon atoms; L represents a Lewis basic compound; “a” represents an integer of 1, 2, or 3; “b” represents an integer of 0, 1, or 2; and “c” represents an integer of 0, 1, or 2); and (B) an ionic compound composed of a non-coordinating anion and a cation, and/or an aluminoxane. The present invention provides a catalyst composition for polymerization for production of a polymer having a high content of cis-1,4-configuration in microstructure and a narrow molecular weight distribution.

摘要翻译： 本发明涉及共轭二烯的聚合用催化剂组合物，其包含：（A）由通式（I）表示的金属茂型络合物：（C 5 R 1） R 2 O 3 R 3 S 4 R 4 S 5 R 5 S 2 S 2 R 3 S 2 R 3 （其中，M表示稀土金属; C 5 R 1，R 2，R 2， R 3 R 4 R 5表示取代的环戊二烯基; R 1至R 0 > 5个表示相同或不同的烃基（除了当R 1 = R 2 = R 3 = R 0时， 4 = R 5 =甲基）; X表示氢原子，卤素原子，醇盐基，硫醇基，酰胺基或具有1〜 20个碳原子; L表示路易斯碱性化合物;“a”表示1,2或3的整数;“b”表示0,1或2的整数;“c”表示0,1或2的整数 ，或2）; 和（B）由非配位阴离子和阳离子组成的离子化合物和/或铝氧烷。 本发明提供了一种聚合用催化剂组合物，其用于生产具有高度的显微组织中顺式-1,4-构型含量和窄分子量分布的聚合物。

公开(公告)号：US20050233894A1

公开(公告)日：2005-10-20

申请号：US10513686

申请日：2003-05-08

申请人： Shojiro Kaita ,  Zhaomin Hou ,  Yasuo Wakatsuki ,  Yoshiharu Doi

发明人： Shojiro Kaita ,  Zhaomin Hou ,  Yasuo Wakatsuki ,  Yoshiharu Doi

IPC分类号： C08F4/52 ,  C08F4/54 ,  C08F4/60 ,  C08F4/603 ,  C08F36/00 ,  C08F36/04 ,  C08F136/08 ,  C08F212/00 ,  B01J31/00 ,  C08F4/44

CPC分类号： C08F36/04 ,  Y10S526/943 ,  C08F4/52 ,  C08F136/06 ,  C08F4/545

摘要： The present invention relates to a catalyst for polymerization of a conjugated diene or the like, which is composed of a metallocene-type cation complex of a gadolinium compound. Examples of such catalyst include a metallocene-type cation complex of a trivalent gadolinium compound represented by the general formula (I): RaGdXb (wherein, Gd represents gadolinium; R represents a cyclopentadienyl group, a substituted cyclopentadienyl group, an indenyl group, a substituted indenyl group, a fluorenyl group, or a substituted fluorenyl group; X represents an anion; “a” represents an integer of 1 or 2; and “b” represents an integer of 1 or 2). The present invention provides a catalyst by which polymerization of a conjugated diene or copolymerization of a conjugated diene and an aromatic vinyl compound can be carried out efficiently and inexpensively.

摘要翻译： 本发明涉及由钆化合物的茂金属型阳离子络合物构成的共轭二烯等的聚合用催化剂。 这种催化剂的实例包括由通式（I）表示的三价钆化合物的金属茂型阳离子络合物：其中，Gd表示钆; R表示环戊二烯基，取代的环戊二烯基，茚基，取代的茚基，芴基或取代的芴基; X表示阴离子;“a”表示1或2的整数;“b” 表示1或2的整数）。 本发明提供一种共轭二烯的聚合或共轭二烯和芳香族乙烯基化合物的共聚合可以有效且廉价地进行的催化剂。

公开(公告)号：US08969496B2

公开(公告)日：2015-03-03

申请号：US13813370

申请日：2011-07-22

申请人： Shojiro Kaita

发明人： Shojiro Kaita

IPC分类号： C08F4/52 ,  C08F4/72 ,  C08F236/04 ,  C08F210/02 ,  C08F236/06 ,  C08F297/08

CPC分类号： C08F236/06 ,  C08F210/02 ,  C08F236/04 ,  C08F297/08 ,  Y10S526/943 ,  C08F2500/03 ,  C08F4/52 ,  C08F4/545

摘要： The present invention provides a method for controlling the chain structure of a copolymer. The disclosed method is capable of controlling the arrangement of monomeric units in a copolymer, and of selectively forming a random copolymer, tapered copolymer, multiblock copolymer and block copolymer. In the method for controlling the chain structure of a copolymer of a conjugated diene compound and a non-conjugated olefin, the introduction of the conjugated diene compound is controlled in the presence of the non-conjugated olefin so as to control the chain structure of the copolymer.

摘要翻译： 本发明提供一种控制共聚物的链结构的方法。 所公开的方法能够控制共聚物中单体单元的排列，并且可选择性地形成无规共聚物，渐缩共聚物，多嵌段共聚物和嵌段共聚物。 在共轭二烯化合物和非共轭烯烃的共聚物的链结构控制方法中，共轭二烯化合物的引入在非共轭烯烃的存在下进行控制，从而控制 共聚物。

公开(公告)号：US20100190950A1

公开(公告)日：2010-07-29

申请号：US12694444

申请日：2010-01-27

申请人： Hiroaki Tetsuka ,  Mamoru Hagiwara ,  Shojiro Kaita

发明人： Hiroaki Tetsuka ,  Mamoru Hagiwara ,  Shojiro Kaita

IPC分类号： C08G77/06 ,  C08G77/04

CPC分类号： C08F4/70 ,  B01D71/44 ,  B01D71/70 ,  B01D71/82 ,  C08F30/08 ,  C08F32/08 ,  C08F232/08 ,  C08F230/08

摘要： A cycloolefin addition polymer is prepared by addition polymerization of a cycloolefin-functionalized siloxane and optionally norbornene in the presence of catalyst A which is a nickel or palladium complex having a cyclopentadienyl ligand and a methyl, triphenylphosphine or allyl ligand and co-catalyst B, typically tris(pentafluorophenyl)boron or trityltetra(pentafluorophenyl)borate. The polymer is easy to manufacture and has high thermal stability and mechanical strength as well as good gas permeability.

摘要翻译： 通过在催化剂A（其是具有环戊二烯基配体和甲基，三苯基膦或烯丙基配体和助催化剂B的镍或钯配合物）的存在下加成聚合环烯烃官能化的硅氧烷和任选的降冰片烯来制备环烯烃加成聚合物，通常 三（五氟苯基）硼或三苯甲基四（五氟苯基）硼酸盐。 聚合物易于制造，并且具有高热稳定性和机械强度以及良好的透气性。

公开(公告)号：US06683140B2

公开(公告)日：2004-01-27

申请号：US09945666

申请日：2001-09-05

申请人： Shojiro Kaita ,  Zhaomin Hou ,  Yasuo Wakatsuki

发明人： Shojiro Kaita ,  Zhaomin Hou ,  Yasuo Wakatsuki

IPC分类号： C08F452

CPC分类号： C08F36/04 ,  Y10S526/943 ,  C08F4/52

摘要： A catalyst in a solid state for polymerization of a conjugated diene or copolymerization of a conjugated diene and an aromatic vinyl compound, which comprises a metallocene-type cation complex of a rare earth metal compound. The catalyst typically is a trivalent rare earth metal compound represented by the general formula (I): RaMXb wherein M represents a rare earth metal; R represents cyclopentadienyl group, a substituted cyclopentadienyl group, indenyl group, a substituted indenyl group, fluorenyl group, or a substituted fluorenyl group; X represents an anion; symbol “a” represents an integer of 1 or 2; and symbol “b” represents an integer of 1 or 2.

摘要翻译： 用于共轭二烯的聚合的固体催化剂或共轭二烯和芳族乙烯基化合物的共聚合，其包含稀土金属化合物的茂金属型阳离子络合物。 催化剂通常是由通式（I）表示的三价稀土金属化合物：其中M表示稀土金属的RaMXb; R代表环戊二烯基，取代的环戊二烯基，茚基，取代的茚基，芴基或取代的芴基; X表示阴离子; 符号“a”表示1或2的整数; 符号“b”表示1或2的整数。