Process for providing an oxidized penam
    33.
    发明授权
    Process for providing an oxidized penam 失效
    提供氧化的penam的方法

    公开(公告)号:US4410458A

    公开(公告)日:1983-10-18

    申请号:US328267

    申请日:1981-12-07

    摘要: This invention relates to a process for preparing an oxidized penam derivative of the formula: ##STR1## wherein R.sub.1 represents an amino or protected amino radical, andR.sub.3 represents a radical selected from the group consisting of carboxy, protected carboxy, ester, acid amide, acid anhydride, acid halide, acid azide and carboxy salt, wherein a penam derivative of the formula: ##STR2## is oxidized with an oxidizing agent selected from the group consisting of hydrogen peroxide, peracids, hydroperacids, and salts thereof, the improvement which comprises conducting said oxidation in the presence of a catalytic amount of a Group Vb or VIb of the Periodic Table metal compound.

    摘要翻译: 本发明涉及制备下式氧化的penam衍生物的方法:其中R 1表示氨基或保护的氨基,R 3表示选自羧基,被保护的羧基,酯,酰胺, 酸酐,酰卤,叠氮化物和羧基盐,其中下式的阴茎衍生物由下式的氧化剂氧化:过氧化氢,过酸,氢过酸及其盐,其改进包括 在催化量的元素周期表金属化合物的Vb或VIb族的存在下进行所述氧化。

    Product and preparation of 1H-tetrazole-5-thiol derivatives
    37.
    发明授权
    Product and preparation of 1H-tetrazole-5-thiol derivatives 失效
    产品和制备1H-四唑-5-硫醇衍生物

    公开(公告)号:US4110338A

    公开(公告)日:1978-08-29

    申请号:US518956

    申请日:1974-10-29

    IPC分类号: C07D257/04 A61K31/54

    CPC分类号: C07D257/04

    摘要: The process for preparation of and the intermediate compounds such as 1H-tetrazole-5-thiol having the formula ##STR1## wherein R.sub.1 is alkyl, aminoalkyl, acylaminoalkyl, aryl, alkoxycarbonylaminoalkyl, halogen-substituted aryl or alkylamino-substituted aryl and R.sub.2 is hydrogen or arakyl, preferably benzyl. The compound is produced by reacting a substituted thiosemicarbazide with an aralkyl chloride, subjecting the resultant compound to diazotization, and reacting the resultant compound with a Friedel Crafts catalyst. Optionally, this may be further hydrolyzed when R.sub.1 is aminoalkyl and/or converted to conventional salts.

    摘要翻译: 其中R 1为烷基,氨基烷基,酰氨基烷基,芳基,烷氧基羰基氨基烷基,卤素取代的芳基或烷基氨基取代的芳基和R 2为氢的中间体化合物如1H-四唑-5-硫醇的制备方法, 或芳烷基,优选苄基。 该化合物通过使取代的硫代氨基脲与芳烷基氯反应制备,使所得化合物进行重氮化,并使所得化合物与Friedel Crafts催化剂反应。 任选地,当R 1是氨基烷基和/或转化成常规盐时,这可进一步水解。

    EVAPORATED FUEL TREATING APPARATUS
    39.
    发明申请
    EVAPORATED FUEL TREATING APPARATUS 审中-公开
    蒸发燃料处理设备

    公开(公告)号:US20130037006A1

    公开(公告)日:2013-02-14

    申请号:US13566276

    申请日:2012-08-03

    IPC分类号: F02M33/02

    摘要: An evaporated fuel treating apparatus reduces blow-through of evaporated fuel components from an atmosphere port to an outside and has a fluid circulation passage which includes at one end side a first chamber containing granulated carbon or fractured carbon, and heat storage material and at another end side a second chamber containing granulated carbon or fractured carbon and not having the heat storage material. A delay diffusion chamber is disposed between the first chamber and the second chamber, which does not have activated carbon and the heat storage material therein. An adsorption amount of evaporated fuel of granulated or fractured carbon in the second chamber is set to be not less than 2 vol % and not more than 8 vol % of a total adsorption amount of evaporated fuel of granulated or fractured carbon, and a volume of the delay diffusion chamber is larger than that of the second chamber.

    摘要翻译: 蒸发燃料处理装置将蒸发的燃料成分从大气口吹入外部,并且具有流体循环通道,该流体循环通道在一端包括含有颗粒状碳或断裂碳的第一室和储热材料,另一端 一侧包含颗粒状碳或断裂碳并且不具有储热材料的第二室。 延迟扩散室设置在第一室和第二室之间,其中不具有活性炭和其中的蓄热材料。 在第二室中的造粒或断裂碳的蒸发燃料的吸附量设定为不低于造粒或断裂碳的蒸发燃料的总吸附量的2体积%且不大于8体积% 延迟扩散室比第二室大。