Method for Reducing Depositions in Polymerization Vessels
    33.
    发明申请
    Method for Reducing Depositions in Polymerization Vessels 有权
    降低聚合容器沉积的方法

    公开(公告)号:US20090062484A1

    公开(公告)日:2009-03-05

    申请号:US12179375

    申请日:2008-07-24

    Abstract: The method of polymerization includes the steps of a) providing a catalyst system, b) providing at least one monomer or comonomer mixture in a reaction vessel, c) introducing the catalyst into the reaction vessel, and d) polymerizing the at least one monomer or comonomer mixture to produce an isoolefin polymer. The catalyst may be soluble in the diluent used for polymerization. The polymerization contact surfaces of the reaction vessel have an arithmetic average surface roughness of less than 0.3 μm (12 microinches).

    Abstract translation: 聚合方法包括以下步骤:a)提供催化剂体系,b)在反应容器中提供至少一种单体或共聚单体混合物,c)将催化剂引入反应容器中,和d)聚合至少一种单体或 共聚单体混合物以产生异烯烃聚合物。 催化剂可溶于用于聚合的稀释剂中。 反应容器的聚合接触表面的算术平均表面粗糙度小于0.3μm(12微英寸)。

    Carbocationic catalysts and process for using said catalysts
    35.
    发明授权
    Carbocationic catalysts and process for using said catalysts 失效
    羧酸催化剂和使用所述催化剂的方法

    公开(公告)号:US5418303A

    公开(公告)日:1995-05-23

    申请号:US263104

    申请日:1994-06-21

    CPC classification number: B01J31/0212 B01J31/0231 Y10S526/943

    Abstract: A carbocationic catalyst composition comprising an initiator of water, a tertiary alkyl or aralkyl halide, ester, ether, carboxylic acid, acid halide or a polymeric halide and a co-initiator of an alkoxy metal halide, is used to produce narrow molecular weight distribution olefin polymers particularly isobutylene/para-methyl-styrene copolymers.

    Abstract translation: 使用包含水的引发剂,叔烷基或芳烷基卤化物,酯,醚,羧酸,酰卤或聚合卤化物和烷氧基金属卤化物的共引发剂的碳阳离子催化剂组合物来制备窄分子量分布烯烃 聚合物特别是异丁烯/对甲基苯乙烯共聚物。

    Carbocationic catalysts and process for using said catalysts
    36.
    发明授权
    Carbocationic catalysts and process for using said catalysts 失效
    羧酸催化剂和使用所述催化剂的方法

    公开(公告)号:US5350819A

    公开(公告)日:1994-09-27

    申请号:US44529

    申请日:1993-04-08

    CPC classification number: C08F10/00 C08F10/10 C08F110/10

    Abstract: A living carbocationic catalyst composition comprising an initiator of a tertiary alkyl halide, a tertiary aralkyl halide or polymeric halide a co-initiator of an alkyl aluminum or alkyl boron, a proton scavenger and a solvent medium with a dielectric constant between 2.5 and 3.25 is used to produce narrow molecular weight distribution polymers particularly isobutylene polymers.

    Abstract translation: 使用包含叔烷基卤化物的引发剂,叔芳烷基卤化物或聚合卤化物,烷基铝或烷基硼的共引发剂,质子清除剂和介电常数在2.5和3.25之间的溶剂介质的活性碳阳离子催化剂组合物 以产生窄分子量分布聚合物,特别是异丁烯聚合物。

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