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公开(公告)号:US07557170B2
公开(公告)日:2009-07-07
申请号:US12179375
申请日:2008-07-24
CPC分类号: C08F210/12 , C08F2/01 , C08F2/14 , C08F236/08 , C08F2500/02 , C08F2500/03
摘要: The method of polymerization includes the steps of a) providing a catalyst system, b) providing at least one monomer or comonomer mixture in a reaction vessel, c) introducing the catalyst into the reaction vessel, and d) polymerizing the at least one monomer or comonomer mixture to produce an isoolefin polymer. The catalyst may be soluble in the diluent used for polymerization. The polymerization contact surfaces of the reaction vessel have an arithmetic average surface roughness of less than 0.3 μm (12 microinches).
摘要翻译: 聚合方法包括以下步骤:a)提供催化剂体系,b)在反应容器中提供至少一种单体或共聚单体混合物,c)将催化剂引入反应容器中,和d)聚合至少一种单体或 共聚单体混合物以产生异烯烃聚合物。 催化剂可溶于用于聚合的稀释剂中。 反应容器的聚合接触表面的算术平均表面粗糙度小于0.3μm(12微英寸)。
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公开(公告)号:US20090062496A1
公开(公告)日:2009-03-05
申请号:US12179368
申请日:2008-07-24
IPC分类号: C08F210/00 , B01J19/00
CPC分类号: C08F210/12 , C08F2/01 , C08F2/14 , C08F236/08 , C08F2500/02 , C08F2500/03
摘要: Provided is a method for reducing depositions in polymerization vessels, where the method includes the steps of providing a reaction vessel having polymerization contact surfaces, polishing a majority of the polymerization contact surfaces to have an average percent excess surface areas (SAxs) of 2% or less, introducing a catalyst system and at least one monomer or comonomer mixture in the reaction vessel, and polymerizing the at least one monomer or comonomer mixture. The catalyst may be soluble in the diluent used for polymerization. The method may be useful for low temperature polymerization systems.
摘要翻译: 提供了一种用于减少聚合容器中的沉积的方法,其中该方法包括提供具有聚合接触表面的反应容器的步骤,抛光大部分聚合接触表面以具有2%的平均百分比过剩表面积(SAxs)或2% 在反应容器中引入催化剂体系和至少一种单体或共聚单体混合物,并聚合至少一种单体或共聚单体混合物。 催化剂可溶于用于聚合的稀释剂中。 该方法可用于低温聚合体系。
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公开(公告)号:US20090062484A1
公开(公告)日:2009-03-05
申请号:US12179375
申请日:2008-07-24
IPC分类号: C08F2/01
CPC分类号: C08F210/12 , C08F2/01 , C08F2/14 , C08F236/08 , C08F2500/02 , C08F2500/03
摘要: The method of polymerization includes the steps of a) providing a catalyst system, b) providing at least one monomer or comonomer mixture in a reaction vessel, c) introducing the catalyst into the reaction vessel, and d) polymerizing the at least one monomer or comonomer mixture to produce an isoolefin polymer. The catalyst may be soluble in the diluent used for polymerization. The polymerization contact surfaces of the reaction vessel have an arithmetic average surface roughness of less than 0.3 μm (12 microinches).
摘要翻译: 聚合方法包括以下步骤:a)提供催化剂体系,b)在反应容器中提供至少一种单体或共聚单体混合物,c)将催化剂引入反应容器中,和d)聚合至少一种单体或 共聚单体混合物以产生异烯烃聚合物。 催化剂可溶于用于聚合的稀释剂中。 反应容器的聚合接触表面的算术平均表面粗糙度小于0.3μm(12微英寸)。
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4.
公开(公告)号:US08178465B2
公开(公告)日:2012-05-15
申请号:US13005325
申请日:2011-01-12
申请人: Timothy D. Shaffer , Michael F. McDonald , David Y. Chung , Robert N. Webb , Deborah J. Davis , Pamela J. Wright
发明人: Timothy D. Shaffer , Michael F. McDonald , David Y. Chung , Robert N. Webb , Deborah J. Davis , Pamela J. Wright
CPC分类号: C08F210/12 , C08F2/04 , C08F2/12 , C08F236/08 , C08F2500/04 , C08F4/00
摘要: The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.
摘要翻译: 本公开提供了一种方法和聚合体系,以在催化剂体系中利用多形态(16,26)来产生异构烯烃聚合物(72)以控制多分散性(MWD)。 本公开还提供了催化剂体系(20),其包含通过路易斯酸(24),引发剂(22)和多形态(26)的组合形成的多种活性催化剂络合物(34),以及使用 催化剂体系或工艺。 聚异构体(16,26)可以促进或模拟具有不同聚合速率的不同活性催化剂复合物(34)的形成,即不同的传播速率,链转移或终止,如通过相对存在导致的不同多分散性所观察到的 不同比例的多形态。
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公开(公告)号:US07402636B1
公开(公告)日:2008-07-22
申请号:US11728324
申请日:2007-03-23
申请人: Timothy D. Shaffer , Michael F. McDonald , David Y. Chung , Robert N. Webb , Deborah J. Davis , Pamela J. Wright
发明人: Timothy D. Shaffer , Michael F. McDonald , David Y. Chung , Robert N. Webb , Deborah J. Davis , Pamela J. Wright
CPC分类号: C08F10/10 , C08F2/005 , C08F2/14 , C08F210/10 , Y10S526/92 , C08F236/08
摘要: The disclosure provides a slurry polymerization system and method to decrease polymer deposition on reactor surfaces using an oxygenate such as alcohol (16) supplied to the polymerization medium (32) separate from the catalyst feed (34).
摘要翻译: 本公开提供了一种使用供应到与催化剂进料(34)分离的聚合介质(32)的含氧化合物(16)来减少反应器表面上的聚合物沉积的淤浆聚合系统和方法。
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6.
公开(公告)号:US20080234447A1
公开(公告)日:2008-09-25
申请号:US11728306
申请日:2007-03-23
申请人: Timothy D. Shaffer , Michael F. McDonald , David Y. Chung , Robert N. Webb , Deborah J. Davis , Pamela J. Wright
发明人: Timothy D. Shaffer , Michael F. McDonald , David Y. Chung , Robert N. Webb , Deborah J. Davis , Pamela J. Wright
CPC分类号: C08F210/12 , C08F2/04 , C08F2/12 , C08F236/08 , C08F2500/04 , C08F4/00
摘要: The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.
摘要翻译: 本公开提供了一种方法和聚合体系,以在催化剂体系中利用多形态(16,26)来产生异构烯烃聚合物(72)以控制多分散性(MWD)。 本公开还提供了催化剂体系(20),其包含通过路易斯酸(24),引发剂(22)和多形态(26)的组合形成的多种活性催化剂络合物(34),以及使用 催化剂体系或工艺。 聚异构体(16,26)可以促进或模拟具有不同聚合速率的不同活性催化剂复合物(34)的形成,即不同的传播速率,链转移或终止,如通过相对存在导致的不同多分散性所观察到的 不同比例的多形态。
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7.
公开(公告)号:US20110111950A1
公开(公告)日:2011-05-12
申请号:US13005325
申请日:2011-01-12
申请人: Timothy D. Shaffer , Michael F. McDonald , David Y. Chung , Robert N. Webb , Deborah J. Davis , Pamela J. Wright
发明人: Timothy D. Shaffer , Michael F. McDonald , David Y. Chung , Robert N. Webb , Deborah J. Davis , Pamela J. Wright
IPC分类号: B01J31/14
CPC分类号: C08F210/12 , C08F2/04 , C08F2/12 , C08F236/08 , C08F2500/04 , C08F4/00
摘要: The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.
摘要翻译: 本公开提供了一种方法和聚合体系,以在催化剂体系中利用多形态(16,26)来产生异构烯烃聚合物(72)以控制多分散性(MWD)。 本公开还提供了催化剂体系(20),其包含通过路易斯酸(24),引发剂(22)和多形态(26)的组合形成的多种活性催化剂络合物(34),以及使用 催化剂体系或工艺。 聚异构体(16,26)可以促进或模拟具有不同聚合速率的不同活性催化剂复合物(34)的形成,即不同的传播速率,链转移或终止,如通过相对存在导致的不同多分散性所观察到的 不同比例的多形态。
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8.
公开(公告)号:US07893176B2
公开(公告)日:2011-02-22
申请号:US11728306
申请日:2007-03-23
申请人: Timothy D. Shaffer , Michael F. McDonald , David Y. Chung , Robert N. Webb , Deborah J. Davis , Pamela J. Wright
发明人: Timothy D. Shaffer , Michael F. McDonald , David Y. Chung , Robert N. Webb , Deborah J. Davis , Pamela J. Wright
CPC分类号: C08F210/12 , C08F2/04 , C08F2/12 , C08F236/08 , C08F2500/04 , C08F4/00
摘要: The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.
摘要翻译: 本公开提供了一种方法和聚合体系,以在催化剂体系中利用多形态(16,26)来产生异构烯烃聚合物(72)以控制多分散性(MWD)。 本公开还提供了催化剂体系(20),其包含通过路易斯酸(24),引发剂(22)和多形态(26)的组合形成的多种活性催化剂络合物(34),以及使用 催化剂体系或工艺。 聚异构体(16,26)可以促进或模拟具有不同聚合速率的不同活性催化剂复合物(34)的形成,即不同的传播速率,链转移或终止,如通过相对存在导致的不同多分散性所观察到的 不同比例的多形态。
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9.
公开(公告)号:US08513367B2
公开(公告)日:2013-08-20
申请号:US13294276
申请日:2011-11-11
申请人: Timothy D. Shaffer , Pamela J. Wright , Limin Song
IPC分类号: C08F2/12 , C08F8/20 , C08F210/12 , B01J19/18
CPC分类号: B01J19/285 , B01J19/1825 , B01J19/2425 , B01J2219/00247 , B01J2219/00254 , C08F210/12 , C08F2/002 , C08F2/01 , C08F236/08 , C08F2500/21
摘要: Method of reducing fouling in an elastomer polymerization process that includes providing a reactor capable of housing an industrial-scale elastomer polymerization reaction, and applying a mechanical force to the reactor so as to create a vibration in at least one wall of the reactor, in which fouling is reduced in the reactor. In one embodiment the reaction is an industrial scale butyl polymerization reaction and the reactor is a butyl polymerization reactor.
摘要翻译: 在弹性体聚合方法中减少结垢的方法,其包括提供能够容纳工业规模的弹性体聚合反应的反应器,以及向反应器施加机械力以在反应器的至少一个壁中产生振动,其中 反应器中污染减少。 在一个实施方案中,反应是工业规模的丁基聚合反应,反应器是丁基聚合反应器。
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公开(公告)号:US07981991B2
公开(公告)日:2011-07-19
申请号:US11788598
申请日:2007-04-20
IPC分类号: C08F210/00 , C08F12/02 , C08F10/00 , C08F4/44 , B01J19/00
CPC分类号: B01J19/0066 , B01J19/18 , B01J2219/00006 , B01J2219/00081 , B01J2219/00085 , B01J2219/0011 , B01J2219/00114 , B01J2219/00168 , C08F6/003 , C08F10/10 , C08F110/10 , C08F210/10 , C08F210/12 , C08L23/20 , C08F2/14 , C08F212/00 , C08F236/20
摘要: Methods for producing elastomers or elastomeric compositions are provided. One or more C4 to C7 isoolefins and one or more comonomers can be polymerized in the presence of a diluent comprising one or more hydrofluorocarbons to provide a slurry comprising polymer product, unreacted monomer and the diluent. The slurry can be extruded to separate at least a portion of the diluent from the polymer product. The separated diluent can be recycled for polymerizing the one or more C4 to C7 isoolefins.
摘要翻译: 提供了生产弹性体或弹性体组合物的方法。 一种或多种C 4至C 7异烯烃和一种或多种共聚单体可在包含一种或多种氢氟烃的稀释剂存在下聚合以提供包含聚合物产物,未反应单体和稀释剂的浆料。 可以将浆料挤出以将至少一部分稀释剂与聚合物产物分离。 分离的稀释剂可以再循环用于聚合一种或多种C4至C7异烯烃。
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