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36 条记录 (耗时 0.025 秒)

    Polymer with dispersed fine metal particles, process for producing same, metal ion-containing polymer for use in the production, and process for producing same
    31.
    发明授权
    Polymer with dispersed fine metal particles, process for producing same, metal ion-containing polymer for use in the production, and process for producing same 失效
    具有分散的金属微粒的聚合物，其制备方法，用于生产的含金属离子的聚合物及其制备方法

    公开(公告)号：US07645811B2

    公开(公告)日：2010-01-12

    申请号：US10527711

    申请日：2003-09-10

    申请人： Akikazu Matsumoto ,  Toru Odani

    发明人： Akikazu Matsumoto ,  Toru Odani

    IPC分类号： C08G79/00

    CPC分类号： C23C18/14 ,  C08F2/44 ,  C08F36/00 ,  C08K3/08 ,  C23C18/1641 ,  C23C18/1658 ,  C23C18/44 ,  C08L13/00

    摘要： A lamellar crystalline organic polymer containing acidic groups and/or ammonium salt thereof, such as ammonium salt of polymuconic acid, is mixed with a substance containing a metal ion such as alkali metal ion, to prepare a metal ion-containing polymer having a structure in which the metal ion is intercalated between the layers of the lamellar crystalline organic polymer having acidic groups. Subsequently, metal ion exchange reaction is conducted if necessary. Thereafter, the metal ion is reduced to produce fine metal particles. Thus, a crystalline organic polymer in which fine metal particles are dispersed in a crystalline organic polymer is obtained.

    摘要翻译： 将含有酸性基团和/或其铵盐的层状结晶性有机聚合物如聚赖氨酸的铵盐与含有金属离子如碱金属离子的物质混合，制备具有结构的金属离子的聚合物 其中金属离子插入具有酸性基团的层状结晶有机聚合物的层之间。 随后，如果需要进行金属离子交换反应。 此后，金属离子被还原以产生精细的金属颗粒。 因此，得到其中细金属颗粒分散在结晶有机聚合物中的结晶有机聚合物。

    Photoresponsive polymer, built-up type diacetylene polymer, crystal of ammonium carboxylate, and method of manufacturing them
    32.
    发明授权
    Photoresponsive polymer, built-up type diacetylene polymer, crystal of ammonium carboxylate, and method of manufacturing them 失效
    光响应聚合物，聚合型乙炔聚合物，羧酸铵的结晶及其制造方法

    公开(公告)号：US07981968B2

    公开(公告)日：2011-07-19

    申请号：US12382527

    申请日：2009-03-18

    申请人： Akikazu Matsumoto ,  Toru Odani

    发明人： Akikazu Matsumoto ,  Toru Odani

    IPC分类号： C08F8/30 ,  C08F20/00 ,  C07C69/74 ,  C07C63/04

    CPC分类号： C08G61/08 ,  C08G73/00

    摘要： A crystal of carboxyl acid and at least one compound selected from the group consisting of amine and ammonia are mixed in an absence of a liquid medium. The carboxyl acid is conjugated diene such as (Z,Z)-muconic acid, the conjugated diene including a carboxyl group. The at least one nitrogen-containing compound selected from the group consisting of amine and ammonia is primary amine represented by RCH2NH2, where R is an aryl group, or is a normal alkyl group that contains five or more carbon atoms. Moreover, such amine that is a bivalent group and that is represented by —Ar—N═N—Ar′—, where Ar and Ar′ are independently aromatic hydrocarbon bivalent groups, is intercalated in a layered crystal of a polymer such as polymuconic acid, the layered crystal including a carboxyl group. In this way, a novel photoresponsive polymer is obtained.

    摘要翻译： 在不存在液体介质的情况下，将羧酸晶体和至少一种选自胺和氨的化合物混合。 羧酸是共轭二烯，如（Z，Z） - 木聚糖酸，共轭二烯包括羧基。 所述至少一种选自胺和氨的含氮化合物是由RCH 2 NH 2表示的伯胺，其中R是芳基，或是含有5个或更多个碳原子的正烷基。 此外，作为二价基团的由Ar和Ar'独立地为芳香族烃二价基团的-Ar-N = N-Ar'表示的胺插入聚合物如多粘多糖酸的层状结晶中 包括羧基的层状晶体。 以这种方式获得新的光响应聚合物。

    Photoresponsive polymer,built-up type diacetylene polymer, crystal of ammonium carboxylate, and method of manufacturing them
    34.
    发明申请
    Photoresponsive polymer,built-up type diacetylene polymer, crystal of ammonium carboxylate, and method of manufacturing them 失效
    光响应聚合物，积聚型乙炔聚合物，铵晶体

    公开(公告)号：US20090253870A1

    公开(公告)日：2009-10-08

    申请号：US12382527

    申请日：2009-03-18

    申请人： Akikazu Matsumoto ,  Toru Odani

    发明人： Akikazu Matsumoto ,  Toru Odani

    IPC分类号： C08F265/02

    CPC分类号： C08G61/08 ,  C08G73/00

    摘要： A crystal of carboxyl acid and at least one compound selected from the group consisting of amine and ammonia are mixed in an absence of a liquid medium. The carboxyl acid is conjugated diene such as (Z,Z)-muconic acid, the conjugated diene including a carboxyl group. The at least one nitrogen-containing compound selected from the group consisting of amine and ammonia is primary amine represented by RCH2NH2, where R is an aryl group, or is a normal alkyl group that contains five or more carbon atoms. Moreover, such amine that is a bivalent group and that is represented by —Ar—N═N—Ar′—, where Ar and Ar′ are independently aromatic hydrocarbon bivalent groups, is intercalated in a layered crystal of a polymer such as polymuconic acid, the layered crystal including a carboxyl group. In this way, a novel photoresponsive polymer is obtained.Also obtained is a crystal of ammonium carboxylate including at least one kind of carboxyl acid and at least one kind of amine, at least one kind of compound selected from (i) the at least one kind of carboxyl acid and (ii) the at least one kind of amine being a diacetylene derivative. The crystal of ammonium carboxylate is subjected to light or heat, to obtain a built-up type diacetylene polymer.

    摘要翻译： 在不存在液体介质的情况下，将羧酸晶体和至少一种选自胺和氨的化合物混合。 羧酸是共轭二烯，如（Z，Z） - 木聚糖酸，共轭二烯包括羧基。 所述至少一种选自胺和氨的含氮化合物是由RCH 2 NH 2表示的伯胺，其中R是芳基，或是含有5个或更多个碳原子的正烷基。 此外，作为二价基团的由Ar和Ar'独立地为芳香族烃二价基团的-Ar-NN-Ar'-表示的胺插入聚合物如多粘多糖酸的层状结晶中， 包括羧基的层状晶体。 以这种方式获得新的光响应聚合物。 还得到了包含至少一种羧酸和至少一种胺的至少一种羧酸铵的结晶，至少一种选自（i）至少一种羧酸的化合物和（ii）至少一种 一种胺为二乙炔衍生物。 将羧酸铵的结晶经受光或热，得到积聚型的乙炔聚合物。

    Polymer with dispersed fine metal particles, process for producing same, metal ion-containing polymer for use in the production, and process for producing same
    36.
    发明申请
    Polymer with dispersed fine metal particles, process for producing same, metal ion-containing polymer for use in the production, and process for producing same 失效
    具有分散的金属微粒的聚合物，其制备方法，用于生产的含金属离子的聚合物及其制备方法

    公开(公告)号：US20060154999A1

    公开(公告)日：2006-07-13

    申请号：US10527711

    申请日：2003-09-10

    申请人： Akikazu Matsumoto ,  Toru Odani

    发明人： Akikazu Matsumoto ,  Toru Odani

    IPC分类号： C08G79/00

    CPC分类号： C23C18/14 ,  C08F2/44 ,  C08F36/00 ,  C08K3/08 ,  C23C18/1641 ,  C23C18/1658 ,  C23C18/44 ,  C08L13/00

    摘要： A lamellar crystalline organic polymer containing acidic groups and/or ammonium salt thereof, such as ammonium salt of polymuconic acid, is mixed with a substance containing a metal ion such as alkali metal ion, to prepare a metal ion-containing polymer having a structure in which the metal ion is intercalated between the layers of the lamellar crystalline organic polymer having acidic groups. Subsequently, metal ion exchange reaction is conducted if necessary. Thereafter, the metal ion is reduced to produce fine metal particles. Thus, a crystalline organic polymer in which fine metal particles are dispersed in a crystalline organic polymeris obtained.

    摘要翻译： 将含有酸性基团和/或其铵盐的层状结晶性有机聚合物如聚赖氨酸的铵盐与含有金属离子如碱金属离子的物质混合，制备具有结构的金属离子的聚合物 其中金属离子插入具有酸性基团的层状结晶有机聚合物的层之间。 随后，如果需要进行金属离子交换反应。 此后，金属离子被还原以产生精细的金属颗粒。 因此，得到金属颗粒分散在结晶有机聚合物中的结晶有机聚合物。