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公开(公告)号:US06689201B1
公开(公告)日:2004-02-10
申请号:US09869358
申请日:2001-06-28
IPC分类号: C09D1102
CPC分类号: C09D11/328
摘要: A compound of Formula (1) and salts thereof are useful as dyes for ink jet printing inks. In the formula (1), A is optionally substituted phenyl (other than carboxyl substituted); R1 and R2 are each independently optionally substituted alkyl or optionally substituted alkoxy; and R4 and R5 are each independently H, alkyl or optionally substituted aryl. In formula (1) at least one of R1 and R2 carries an —OH group.
摘要翻译: 式(1)的化合物及其盐可用作喷墨印刷油墨的染料。在式(1)中,A是任选取代的苯基(除了取代的羧基); R 1和R 2各自独立地是任选取代的烷基或任选取代的烷氧基; R 4和R 5各自独立地为H,烷基或任选取代的芳基。 在式(1)中,R 1和R 2中的至少一个携带-OH基团。
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公开(公告)号:US6057264A
公开(公告)日:2000-05-02
申请号:US913984
申请日:1997-12-03
申请人: Roy Bradbury
发明人: Roy Bradbury
CPC分类号: B41M5/385 , B41M5/3854 , B41M5/388 , B41M5/39 , Y10S428/913 , Y10S428/914
摘要: A thermal transfer sheet comprising a substrate having a coating comprising a substituted hindered indoline dye and a process for the use of such transfer sheets in dye diffusion thermal transfer printing.
摘要翻译: PCT No.PCT / GB96 / 00475 Sec。 371日期1997年12月3日第 102(e)日期1997年12月3日PCT 1996年3月1日PCT公布。 公开号WO96 / 30214 PCT 日期1996年10月3日一种热转印片,其包含具有包含取代的受阻染的二氢吲哚染料的涂层的基底和在染料扩散热转印中使用这种转印片的方法。
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公开(公告)号:US5296448A
公开(公告)日:1994-03-22
申请号:US107161
申请日:1993-08-17
申请人: Roy Bradbury , Alan Butters
发明人: Roy Bradbury , Alan Butters
IPC分类号: B41M5/382 , B41M5/025 , B41M5/26 , B41M5/388 , B41M5/50 , B41M5/52 , C09B35/34 , D06P5/13 , D06P5/24 , G03C8/40 , B41M5/035 , B41M5/38
CPC分类号: B41M5/388 , C09B35/34 , D06P5/007 , Y10S428/913 , Y10S428/914
摘要: A thermal transfer printing sheet comprising a substrate having a coating of a disazo dye of Formula (1): ##STR1## wherein: R is selected from --H; --CN; --NO.sub.2 ; --COT.sup.1 ; --SO.sub.2 T.sup.1 ; --COOT.sup.1 ;--SO.sub.2 F; and --SO.sub.2 Cl;eachR.sup.1 is independently selected from --H; --F, --Cl, --Br; and --CF.sub.3 ;n is 1, 2 or 3;R.sup.2 is --H or C.sub.1-4 -alkyl;R.sup.3 is --CN;R.sup.4 is a straight or branched chain C.sub.1-6 -alkyl;R.sup.5 is ##STR2## (sec.butyl); and R.sup.6 is selected from --H; C.sub.1-4 -alkyl; and --NHCOT.sup.1 ;wherein T.sup.1 is C.sub.1-4 -alkyl or phenyl.
摘要翻译: 一种热转印片,其包含具有式(1)的双偶氮染料的涂层的基材:(*化学结构*)式1其中:R选自-H; -CN; -NO2; -COT1; -SO2T1; -COOT1; -SO2F; 和-SO 2 Cl; 每个R 1独立地选自-H; -F,-Cl,-Br; 和-CF 3; n为1,2或3; R2是-H或C 1-4 - 烷基; R3是-CN; R4是直链或支链C 1-6 - 烷基; R5是(*化学结构*)(仲丁基); 并且R 6选自-H; C 1-4 - 烷基; 和-NHCOT1; 其中T1是C1-4 - 烷基或苯基。
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公开(公告)号:US4977135A
公开(公告)日:1990-12-11
申请号:US380127
申请日:1989-07-14
申请人: Roy Bradbury , Peter A. Gemmell , Richard A. Hann
发明人: Roy Bradbury , Peter A. Gemmell , Richard A. Hann
IPC分类号: B41J31/00 , B41M5/035 , B41M5/26 , B41M5/30 , B41M5/382 , B41M5/385 , B41M5/388 , B41M5/39 , B41M5/395 , B41M5/40 , B41M5/50 , B41M5/52
CPC分类号: B41M5/3858 , B41M5/3852 , B41M5/388 , Y10S428/913 , Y10S428/914 , Y10T428/31786
摘要: A thermal transfer printing sheet suitable for use in a thermal transfer printing process, comprising a substrate having a coating comprising a binder and an anthraquinone of the Formula I: ##STR1## or a mixture of an anthraquinone dye of the Formula I and a disazo dye of Formula II:A-N=N-B-N=N-E IIwherein:Z is hydrogen or an optionally substituted aliphatic or an optionally substituted aryl radical;A is the residue of a diazotizable phenylamino or naphthylamine, A-NH.sub.2, carrying no more than one unsaturated electron-withdrawing group;B is an optionally substituted thiophen-2,5-ylene or thiazol-2,5-xylene; andE is the residue of an aromatic coupling component E-X wherein X is an atom or group displaceable by a diazotized aromatic amine.
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公开(公告)号:US20110014435A1
公开(公告)日:2011-01-20
申请号:US11990083
申请日:2006-07-31
CPC分类号: C07D231/48 , C09B33/22 , C09D11/037 , C09D11/328 , C09D11/40 , Y10T428/24802
摘要: A process for printing an image on a substrate, the process comprising applying to the substrate an ink composition which comprises a liquid medium and a compound selected from the group consisting of compounds of Formula (1I), compounds of Formula (1II), compounds of Formula (1III) and compounds of Formula (1IV): wherein: A and D each independently represent optionally substituted aryl or optionally substituted heteroaryl; E represents optionally substituted pyrazolyl; Z represents H, halogen, nitro, cyano, hydroxy, amino, carboxy, optionally substituted alkyl, optionally substituted alkoxy or optionally substituted aryloxy; and p is an integer from 0 to 5. Preferably, the printing process is ink jet printing. Also provided are compounds of Formula (1I), (1II), (1III) and (1IV) and ink compositions comprising the same.
摘要翻译: 一种用于在基材上印刷图像的方法,所述方法包括将包含液体介质的油墨组合物和选自式(II)的化合物,式(III)化合物,式(III)化合物, 式(III)和式(1IV)的化合物:其中:A和D各自独立地表示任选取代的芳基或任选取代的杂芳基; E表示任选取代的吡唑基; Z表示H,卤素,硝基,氰基,羟基,氨基,羧基,任选取代的烷基,任选取代的烷氧基或任选取代的芳氧基; 并且p是0至5的整数。优选地,印刷过程是喷墨印刷。 还提供了式(1I),(1II),(III)和(IIV)的化合物和包含其的油墨组合物。
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36.
公开(公告)号:US20090208713A1
公开(公告)日:2009-08-20
申请号:US12224619
申请日:2007-04-27
CPC分类号: C09B31/28 , C09D11/328 , Y10T428/24802 , Y10T428/24934
摘要: A compound selected from the group consisting of compounds of Formula (1) and compounds of Formula (2) or a salt thereof: wherein: A is an optionally substituted alpha naphthyl group of formula X, wherein * is the point of attachment to the azo group in Formula (1) or (2); B is optionally substituted phenylene or naphthylene; n is 0 or 1; and D is an optionally substituted pyrazolyl group. The compound is useful in an ink for ink jet printing. Also provided are printing processes, ink compositions and ink-jet cartridges for use in an ink-jet printer and substrates printed using an ink-jet printer.
摘要翻译: 选自式(1)的化合物和式(2)的化合物或其盐的化合物:其中:A是式X的任选取代的α-萘基,其中*是与偶氮的连接点 式(1)或(2)中的基团; B是任选取代的亚苯基或亚萘基; n为0或1; D是任选取代的吡唑基。 该化合物可用于喷墨印刷用油墨。 还提供了用于喷墨打印机的印刷工艺,油墨组合物和喷墨盒以及使用喷墨打印机印刷的基材。
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公开(公告)号:US20090142554A1
公开(公告)日:2009-06-04
申请号:US12083832
申请日:2006-10-13
申请人: Gavin Wright , Rachel Anne James , Roy Bradbury , Lynn Bradbury
发明人: Gavin Wright , Rachel Anne James , Roy Bradbury , Lynn Bradbury
IPC分类号: C09D11/02 , C07D213/84 , C07D213/73 , C07D213/81 , C07D403/12 , C07D215/22 , B05D5/00 , B41M5/00 , G01D11/00
CPC分类号: C09B29/0007 , C09B29/3639 , C09D11/328 , Y10T428/24802
摘要: A process for printing an image on a substrate by means of an ink-jet printer which comprises applying thereto a composition comprising a liquid medium and a mono-azo compound of Formula (1) and salts thereof: wherein: D is an optionally substituted aryl group carrying at least one direct substituent selected from the group consisting of —SO3H, —CO2H, —PO3H2 or an optionally substituted nitrogen heteroaryl group carrying at least one direct substituent selected from the group consisting of —SO3H, —CO2H, —PO3H2; R1 is H: optionally substituted alkyl: amino: —NR4R5; wherein R4 is H, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl; and R5 is optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl: —OR6; wherein R6 is H or optionally substituted alkyl: or —SR7; wherein R7 is optionally substituted alkyl; R2 and R3 are each independently preferably amino: —NR4R5; wherein R4 is H, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl; and R5 is optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl: hydroxy —OR6; wherein R6 is H or optionally substituted alkyl: or —SR7; wherein R7 is optionally substituted alkyl; X is H, or an electron withdrawing group, or X together with R3 forms an optionally substituted five or six membered carbocycle. Also compositions and inks, compounds and ink-jet printer cartridges.
摘要翻译: 一种通过喷墨打印机在基片上印刷图像的方法,该方法包括向其施涂包含液体介质和式(1)的单偶氮化合物及其盐的组合物:其中:D为任选取代的芳基 携带至少一个选自-SO 3 H,-CO 2 H,-PO 3 H 2的任选取代的氮杂芳基和至少一个选自-SO 3 H,-CO 2 H,-PO 3 H 2, R 1为H:任选取代的烷基:氨基:-NR 4 R 5; 其中R 4为H,任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基; 和R 5是任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基:-OR 6; 其中R 6是H或任选取代的烷基:或-SR 7; 其中R 7为任选取代的烷基; R2和R3各自独立地优选为氨基:-NR4R5; 其中R 4为H,任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基; 任选取代的酰基,任选取代的芳基,任选取代的杂环基:羟基-OR 6; 其中R 6是H或任选取代的烷基:或-SR 7; 其中R 7为任选取代的烷基; X是H或吸电子基团,或X与R3一起形成任选取代的五或六元碳环。 还有组合物和油墨,化合物和喷墨打印机墨盒。
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公开(公告)号:US20080026191A1
公开(公告)日:2008-01-31
申请号:US11878100
申请日:2007-07-20
申请人: Clive Foster , Roy Bradbury , Lynn Bradbury
发明人: Clive Foster , Roy Bradbury , Lynn Bradbury
IPC分类号: C09D11/02 , B41M5/00 , C09B62/347 , C09B62/447
CPC分类号: C09B29/3647 , C09B31/14 , C09B33/22 , C09D11/328 , Y10T428/24802
摘要: The invention provides a compound of Formula (1-1) or Formula (1-2) or a salt thereof: wherein: Ar1 and Ar2 each independently represent an optionally substituted aryl or heteroaryl group with the proviso that where Ar1 is phenyl substituted with and azo group it is substituted with the azo group at the para position; R represents H, optionally substituted alkyl, or optionally substituted aryl; Q is a substituent, which may be another OH group; n is an integer from 1 to 4; m is an integer from 0 to 4, wherein each Q may be the same or different in the case where m is more than 1; and n+m is not greater than 4; with the proviso that the compound is not one of the following compounds (i) and (ii) and the salt is not a salt thereof: Also provided by the invention are ink compositions, printing processes, especially ink jet printing processes, printed substrates, ink cartridges and the like.
摘要翻译: 本发明提供式(1-1)或式(1-2)的化合物或其盐:其中:Ar 1和Ar 2各自独立地表示任选地 取代的芳基或杂芳基,条件是其中Ar 1是被和偶氮基取代的苯基,它在对位被偶氮基取代; R表示H,任选取代的烷基或任选取代的芳基; Q是取代基,其可以是另一个OH基团; n是1至4的整数; m是0至4的整数,其中每个Q在m大于1的情况下可以相同或不同; 并且n + m不大于4; 条件是该化合物不是以下化合物(i)和(ii)中的一种,并且盐不是其盐。本发明还提供油墨组合物,印刷方法,特别是喷墨印刷方法,印刷基材, 墨盒等。
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公开(公告)号:US20050217535A1
公开(公告)日:2005-10-06
申请号:US10513750
申请日:2003-05-08
申请人: Prahalad Mistry , Roy Bradbury
发明人: Prahalad Mistry , Roy Bradbury
CPC分类号: C09D11/328 , C09B31/28 , Y10T428/24802
摘要: A composition comprising a liquid medium and a compound of Formula (1) or salt thereof: wherein: A is optionally substituted phenyl or naphthyl provided A is not 2-sulpho-4-methoxyphenyl; B is optionally substituted phenylene or naphthylene; n is 0 or 1; D is a pyrazolonyl group; and wherein the liquid medium comprises an organic solvent. Also claimed are inks comprising said compositions and processes for printing.
摘要翻译: 包含液体介质和式(1)化合物或其盐的组合物:其中:A是任选取代的苯基或萘基,所述A不是2-磺基-4-甲氧基苯基; B是任选取代的亚苯基或亚萘基; n为0或1; D是吡唑啉酮基; 并且其中所述液体介质包含有机溶剂。 还要求保护的是包含所述组合物和印刷方法的油墨。
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公开(公告)号:US06406526B1
公开(公告)日:2002-06-18
申请号:US09446413
申请日:2000-03-09
IPC分类号: C09D1102
CPC分类号: C09D11/328 , C09B29/363
摘要: A dye of Formula (1) or tautomer thereof: wherein: A is di-, tri-, tetra-, or penta-substituted phenyl; R1 is methyl; R2 is H, CN, alkyl, substituted alkyl, alkenyl, substituted alkenyl, alkynyl, substituted alkynyl, aryl, substituted aryl or a carbonamido group; and R3 is 5- or 6-membered ring comprising carbon atoms and one or two O, N and/or S atoms, wherein the ring may be substituted are useful as a component for inks, especially, ink jet printing inks and provide good storage stability, and high color strength. Inks containing the dye of formula (1) with a water dissipatable polymer in an aqueous medium produce images having high light-fastness and water-fastness and may be printed on various substrates, including paper, overhead transparencies and textiles, and may be applied using ink jet printers.
摘要翻译: 式(1)的染料或其互变异构体:其中:A是二,三,四或五取代的苯基; R 1是甲基; R 2是H,CN,烷基,取代的烷基,烯基,取代的链烯基, 炔基,取代的炔基,芳基,取代的芳基或碳酰氨基; 和R 3是包含碳原子和一个或两个O,N和/或S原子的5-或6-元环,其中所述环可以被取代,可用作油墨的组分,特别是喷墨印刷油墨,并且提供良好的储存稳定性 ,色彩强度高。 在水性介质中含有具有可分散水分子的式(1)染料的油墨产生具有高耐光牢度和耐水性的图像,并且可以印刷在各种基材上,包括纸,高架透明胶片和纺织品,并且可以使用 喷墨打印机。
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