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    Calixarene bisphosphite ligand for use in hydroformylation processes
    31.
    发明授权
    Calixarene bisphosphite ligand for use in hydroformylation processes 有权
    用于加氢甲酰化方法的杯芳烃二亚磷酸酯配体

    公开(公告)号：US07906688B2

    公开(公告)日：2011-03-15

    申请号：US12593296

    申请日：2008-04-03

    申请人： Michael A. Brammer ,  Wei-Jun Peng ,  John M. Maher

    发明人： Michael A. Brammer ,  Wei-Jun Peng ,  John M. Maher

    IPC分类号： C07C45/50 ,  C07F9/02 ,  B01J31/00

    CPC分类号： C07C45/50 ,  C07F9/65746 ,  C07F15/0073 ,  C07C47/02

    摘要： A calixarene bisphosphite composition for use as a ligand in a transition metal-ligand complex catalyst and in a complex catalyst precursor. The ligand is especially useful in catalysts and catalyst precursors for hydroformylation processes wherein a raffinate stream comprising a mixture of alpha, beta, and iso-olefinic isomers is hydroformylated in the presence of carbon monoxide, hydrogen, and the transition metal-ligand complex catalyst to form a mixture of linear and branched aldehyde products. The complex catalyst selectively converts the alpha and beta olefin reactants more rapidly than the iso-olefin reactant resulting in an improved molar ratio of normal (linear) to branched aldehyde products. The unconverted iso-olefinic isomer is thereafter readily separated from the aldehyde product mixture.

    摘要翻译： 用作过渡金属 - 配体配合物催化剂和复合催化剂前体中的配体的杯芳烃二亚磷酸酯组合物。 该配体特别可用于加氢甲酰化方法的催化剂和催化剂前体，其中包含α，β和异烯属异构体的混合物的残液流在一氧化碳，氢气和过渡金属 - 配体配合物催化剂存在下加氢甲酰化， 形成直链和支链醛产物的混合物。 复合催化剂选择性地将α和β烯烃反应物转化成比异烯烃反应物更快的速率，导致正常（线性）对支链醛产物的改善的摩尔比。 然后将未转化的异烯烃异构体从醛产物混合物中容易地分离。

    METHODS AND ASSEMBLIES FOR LIQUID-PHASE REACTIONS
    32.
    发明申请
    METHODS AND ASSEMBLIES FOR LIQUID-PHASE REACTIONS 有权
    液相反应的方法和装配

    公开(公告)号：US20110060173A1

    公开(公告)日：2011-03-10

    申请号：US12717800

    申请日：2010-03-04

    申请人： John D. Myers

    发明人： John D. Myers

    IPC分类号： B01D53/14 ,  B01D47/14 ,  C07C19/03

    CPC分类号： B01D53/1418 ,  B01D53/1406 ,  B01D53/1487 ,  B01D53/77 ,  B01D53/78 ,  B01D2252/10 ,  B01D2252/103 ,  B01D2252/2021 ,  B01D2252/504 ,  B01D2257/2045 ,  B01D2257/708 ,  B01D2257/80 ,  C07C17/16 ,  Y02P20/582 ,  C07C19/03

    摘要： Methods and assemblies for improving the reaction kinetics of, conserving reactants utilized in, and/or producing a more pure reaction product of, liquid-phase reactions that involve volatile reactants and products are provided. The methods and assemblies herein provide for a feed of reaction liquid to two or more absorption zones, wherein the temperature and/or feed rate of the liquid is independently adjusted prior to introduction into at least one of the two or more absorption zones. More particularly, the temperature and feed rate of the liquid as delivered to each absorption zone can be adjusted independently to optimize the absorption of at least a portion of any gaseous reactants and byproducts from the gaseous product stream and/or to optimize reaction zone conditions. Reaction kinetics may thus be improved, or substantially maintained.

    摘要翻译： 提供了用于改善用于和/或生产涉及挥发性反应物和产物的液相反应的更纯的反应产物的反应动力学的保护反应动力学的方法和装置。 本文的方法和组件提供了将反应液体进料到两个或更多个吸收区域，其中在引入两个或更多个吸收区域中的至少一个吸收区域之前，液体的温度和/或进料速率被独立地调节。 更具体地，可以独立地调节输送到每个吸收区域的液体的温度和进料速率，以优化来自气态产物流的至少一部分气态反应物和副产物的吸收和/或优化反应区条件。 反应动力学因此可以得到改善或基本维持。

    PHOSPHORUS-CONTAINING COMPOUNDS USEFUL FOR MAKING HALOGEN-FREE, IGNITION-RESISTANT POLYMERS
    35.
    发明申请
    PHOSPHORUS-CONTAINING COMPOUNDS USEFUL FOR MAKING HALOGEN-FREE, IGNITION-RESISTANT POLYMERS 有权
    用于制备无卤素，耐点火聚合物的含磷化合物有用

    公开(公告)号：US20110054079A1

    公开(公告)日：2011-03-03

    申请号：US12939773

    申请日：2010-11-04

    申请人： Joseph Gan

    发明人： Joseph Gan

    IPC分类号： C08L63/00

    CPC分类号： C08L61/00 ,  C07F9/657172 ,  C08G59/1488 ,  C08G59/304 ,  C08G59/3254 ,  C08G79/04 ,  C08K5/53 ,  C08K5/5313 ,  C08L61/14 ,  C08L63/00 ,  C08L63/04 ,  C09K21/12 ,  C09K21/14

    摘要： Phosphorus-containing compounds are disclosed which are obtainable by reacting: a benzoxazine ring-containing compound comprising the reaction product of: (A) at least one organophosphorus compound having a group selected from the group H—P═O; the group P—H and the group P—OH; and (B) at least one compound having the following Formula (I): [R′(Y)m′]m(X—O—R″)n  Formula (I) wherein R′ is an organic group; Y is a functional group selected from the group consisting of hydroxy, carboxylic acid, and amine; X is a hydrocarbylene group; R″ is hydrogen or a hydrocarbyl group having from 1 to 8 carbon atoms, R is alkyl or aryl group having from 1 to 12 carbon atoms; m′, m and n are, independently, numbers equal to or greater than 1. These compounds are useful for making flame retardant epoxy and polyurethane resins and ignition resistant thermoplastic resins, each of which is useful for a variety of end uses requiring flame retardancy or ignition resistance. Flame retardant epoxy resins may be used to make electrical laminates. Flame retardant polyurethane is useful for making rigid polyurethane foam used in construction and flexible polyurethane foam used to make vehicle upholstery. Ignition resistant thermoplastic resins are useful for making television cabinets, computer monitors, printer housings, automotive parts, and housings and parts for appliances. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.

    摘要翻译： 公开了含磷化合物，其可通过以下反应获得：含有苯并恶嗪环的化合物，其包含以下反应产物：（A）至少一种选自H-P = O的基团的有机磷化合物; P-H族和P-OH基; 和（B）至少一种具有下式（I）的化合物：[R'（Y）m'] m（X-O-R“）n其中R'是有机基团的式（I） Y是选自羟基，羧酸和胺的官能团; X是亚烃基; R“是氢或具有1至8个碳原子的烃基，R是具有1至12个碳原子的烷基或芳基; m'，m和n独立地等于或大于1.这些化合物可用于制备阻燃环氧树脂和聚氨酯树脂和耐点火热塑性树脂，其各自可用于需要阻燃性的各种最终用途 或点火电阻。 阻燃环氧树脂可用于制造电气层压板。 阻燃聚氨酯可用于制造用于建筑的硬质聚氨酯泡沫和用于制造车辆装饰的柔性聚氨酯泡沫。 耐点火热塑性树脂可用于制作电视机柜，电脑显示器，打印机外壳，汽车零件以及家用电器的外壳和零件。 本发明特别适用于需要或期望低溴或低卤素含量的最终用途。

    PHOSPHORUS-CONTAINING COMPOUNDS USEFUL FOR MAKING HALOGEN-FREE, IGNITION-RESISTANT POLYMERS
    36.
    发明申请
    PHOSPHORUS-CONTAINING COMPOUNDS USEFUL FOR MAKING HALOGEN-FREE, IGNITION-RESISTANT POLYMERS 有权
    用于制备无卤素，耐点火聚合物的含磷化合物有用

    公开(公告)号：US20110054078A1

    公开(公告)日：2011-03-03

    申请号：US12939725

    申请日：2010-11-04

    申请人： Joseph Gan

    发明人： Joseph Gan

    IPC分类号： C07F9/6564 ,  C07F9/576

    CPC分类号： C08L61/00 ,  C07F9/657172 ,  C08G59/1488 ,  C08G59/304 ,  C08G59/3254 ,  C08G79/04 ,  C08K5/53 ,  C08K5/5313 ,  C08L61/14 ,  C08L63/00 ,  C08L63/04 ,  C09K21/12 ,  C09K21/14

    摘要： Phosphorus-containing compounds are disclosed which are obtainable by reacting: (A) at least one organophosphorus compound having a group selected from the group H—P═O; the group P—H and the group P—OH; and (B) at least one compound having the following Formula (I): [R′(Y)m′]m(X—O—R″)n   Formula (I) wherein R′ is an organic group; Y is a functional group selected from the group consisting of hydroxy, carboxylic acid, and amine; X is a hydrocarbylene group; R″ is hydrogen or a hydrocarbyl group having from 1 to 8 carbon atoms, R is alkyl or aryl group having from 1 to 12 carbon atoms; m′, m and n are, independently, numbers equal to or greater than 1; and (C) a thermosetting or thermoplastic composition. These compounds are useful for making flame retardant epoxy and polyurethane resins and ignition resistant thermoplastic resins, each of which is useful for a variety of end uses requiring flame retardancy or ignition resistance. Flame retardant epoxy resins may be used to make electrical laminates. Flame retardant polyurethane is useful for making rigid polyurethane foam used in construction and flexible polyurethane foam used to make vehicle upholstery. Ignition resistant thermoplastic resins are useful for making television cabinets, computer monitors, printer housings, automotive parts, and housings and parts for appliances. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.

    摘要翻译： 公开了含磷化合物，其可通过以下方法获得：（A）至少一种具有选自H-P = O的基团的有机磷化合物; P-H族和P-OH基; 和（B）至少一种具有下式（I）的化合物：[R'（Y）m'] m（X-O-R“）n其中R'是有机基团的式（I） Y是选自羟基，羧酸和胺的官能团; X是亚烃基; R“是氢或具有1至8个碳原子的烃基，R是具有1至12个碳原子的烷基或芳基; m'，m和n独立地为等于或大于1的数; 和（C）热固性或热塑性组合物。 这些化合物可用于制备阻燃环氧树脂和聚氨酯树脂和耐点火热塑性树脂，其各自可用于需要阻燃性或耐点火性的各种最终用途。 阻燃环氧树脂可用于制造电气层压板。 阻燃聚氨酯可用于制造用于建筑的硬质聚氨酯泡沫和用于制造车辆装饰的柔性聚氨酯泡沫。 耐点火热塑性树脂可用于制作电视机柜，电脑显示器，打印机外壳，汽车零件以及家用电器的外壳和零件。 本发明特别适用于其中需要或期望低溴或低卤素含量的最终用途。

    PHOSPHORUS-CONTAINING COMPOUNDS USEFUL FOR MAKING HALOGEN-FREE, IGNITION-RESISTANT POLYMERS
    37.
    发明申请
    PHOSPHORUS-CONTAINING COMPOUNDS USEFUL FOR MAKING HALOGEN-FREE, IGNITION-RESISTANT POLYMERS 有权
    用于制备无卤素，耐点火聚合物的含磷化合物有用

    公开(公告)号：US20110054077A1

    公开(公告)日：2011-03-03

    申请号：US12939666

    申请日：2010-11-04

    申请人： Joseph Gan

    发明人： Joseph Gan

    IPC分类号： C07F9/547 ,  C08K5/53

    CPC分类号： C08L61/00 ,  C07F9/657172 ,  C08G59/1488 ,  C08G59/304 ,  C08G59/3254 ,  C08G79/04 ,  C08K5/53 ,  C08K5/5313 ,  C08L61/14 ,  C08L63/00 ,  C08L63/04 ,  C09K21/12 ,  C09K21/14

    摘要： Phosphorus-containing compounds are disclosed which are obtainable by reacting: (A) at least one organophosphorus compound having a group selected from the group H—P═O; the group P—H and the group P—OH; and (B) at least one compound having the following Formula (I): [R′(Y)m′]m(X—O—R″)n  Formula (I) wherein R′ is an organic group; Y is a functional group selected from the group consisting of hydroxy, carboxylic acid, and amine; X is a hydrocarbylene group; R″ is hydrogen or a hydrocarbyl group having from 1 to 8 carbon atoms, R is alkyl or aryl group having from 1 to 12 carbon atoms; m′, m and n are, independently, numbers equal to or greater than 1. These compounds are useful for making flame retardant epoxy and polyurethane resins and ignition resistant thermoplastic resins, each of which is useful for a variety of end uses requiring flame retardancy or ignition resistance. Flame retardant epoxy resins may be used to make electrical laminates. Flame retardant polyurethane is useful for making rigid polyurethane foam used in construction and flexible polyurethane foam used to make vehicle upholstery. Ignition resistant thermoplastic resins are useful for making television cabinets, computer monitors, printer housings, automotive parts, and housings and parts for appliances. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.

    摘要翻译： 公开了含磷化合物，其可通过以下方法获得：（A）至少一种具有选自H-P = O的基团的有机磷化合物; P-H族和P-OH基; 和（B）至少一种具有下式（I）的化合物：[R'（Y）m'] m（X-O-R“）n其中R'是有机基团的式（I） Y是选自羟基，羧酸和胺的官能团; X是亚烃基; R“是氢或具有1至8个碳原子的烃基，R是具有1至12个碳原子的烷基或芳基; m'，m和n独立地等于或大于1.这些化合物可用于制备阻燃环氧树脂和聚氨酯树脂和耐点火热塑性树脂，其各自可用于需要阻燃性的各种最终用途 或点火电阻。 阻燃环氧树脂可用于制造电气层压板。 阻燃聚氨酯可用于制造用于建筑的硬质聚氨酯泡沫和用于制造车辆装饰的柔性聚氨酯泡沫。 耐点火热塑性树脂可用于制作电视机柜，电脑显示器，打印机外壳，汽车零件以及家用电器的外壳和零件。 本发明特别适用于其中需要或期望低溴或低卤素含量的最终用途。

    Blends of styrenic block copolymers and propylene-alpha olefin copolymers
    40.
    发明授权
    Blends of styrenic block copolymers and propylene-alpha olefin copolymers 有权
    苯乙烯嵌段共聚物和丙烯-α烯烃共聚物的共混物

    公开(公告)号：US07893159B2

    公开(公告)日：2011-02-22

    申请号：US12097856

    申请日：2006-12-22

    申请人： Andy C. Chang

    发明人： Andy C. Chang

    IPC分类号： C08L53/02

    CPC分类号： C08L23/142 ,  C08F210/06 ,  C08L23/14 ,  C08L23/16 ,  C08L53/00 ,  C08L53/02 ,  C08L53/025 ,  C08L2314/02 ,  C08L2666/04 ,  C08L2666/24 ,  C08L2666/06 ,  C08L2666/02 ,  C08F210/16 ,  C08F2500/15 ,  C08F2500/20 ,  C08F2500/11

    摘要： The present invention includes a composition comprising a propylene-alpha olefin copolymer having at least seventy weight percent units derived from propylene, and from ten to twenty five weight percent units derived from ethylene or a C4-C10 alpha olefin, the propylene-alpha olefin copolymer exhibiting a heat of fusion of less than 37 Joules/gram and a melt flow rate of from 0.1 to 100 gram/10 minutes; and a styrenic block copolymer, wherein the weight ratio of the propylene-alpha olefin copolymer to the styrenic block copolymer is from 3:7 to 7:3. The composition exhibits tensile modulus of less than 20 MPa, tensile strength of at least 5 MPa, and elongation at break of at least 900% with low relative immediate set.

    摘要翻译： 本发明包括包含丙烯-α烯烃共聚物的组合物，其具有至少70重量％衍生自丙烯的单元和10至25重量％的衍生自乙烯或C 4 -C 10α-烯烃的单元，丙烯-α烯烃共聚物 表现出小于37焦耳/克的熔融热，熔体流动速率为0.1至100克/ 10分钟; 和苯乙烯嵌段共聚物，其中丙烯-α烯烃共聚物与苯乙烯嵌段共聚物的重量比为3:7至7:3。 组合物的拉伸模量小于20MPa，拉伸强度至少为5MPa，断裂伸长率为900％以上，相对立即设定低。