Abstract:
A method for processing an inferior gasoline and a system for processing the same. In the method, a full range gasoline is subjected to a directional sulfur transfer reaction, then is cut to obtain a light gasoline fraction, a medium gasoline fraction and a heavy gasoline fraction; the light gasoline fraction is treated to obtain an alkylated light gasoline; the medium gasoline fraction is treated to obtain a raffinate oil and an extracted oil; the raffinate oil is treated to obtain an esterified medium gasoline; the heavy gasoline fraction is mixed with the extracted oil to obtain a mixed oil, and an one-stage hydrodesulfurization reaction, a two-stage hydrodesulfurization reaction, H2S-removal and a hydrocarbon isomerization/aromatization reaction are carried out successively to obtain a treated heavy gasoline; blending the alkylated light gasoline, the esterified medium gasoline and the treated heavy gasoline to obtain a clean gasoline.
Abstract:
The present invention pertains to the field of molecular sieve synthesis, and relates to a synthesis method of ZSM-5 type molecular sieves. In this method, natural minerals, i.e., natural kaolin and natural diatomite, are used as the total silicon source and aluminum source required for the molecular sieve synthesis, and these two natural minerals are calcinated and subjected to acidic (alkaline) treatment before they are mixed at a certain ratio, and then crystallized under hydrothermal conditions to obtain the product, a ZSM-5 type molecular sieve. The ZSM-5 type molecular sieve obtained by the method according to the present invention is a hierarchical porous material having a crystallinity of 70% to 120% as compared to conventional ZSM-5 type molecular sieves synthesized by using pure chemical reagents, and the silica-to-alumina ratio in the molecular sieve product may be adjusted by varying the ratio of the two minerals in the raw materials for the synthesis. According to the present invention, the range of raw materials for the preparation of molecular sieve materials is broadened, and therefore not only the cost for the molecular sieve production is greatly reduced but also the greenness in the production process of the molecular sieve material is significantly improved.
Abstract:
The present invention provides a method for preparing a mordenite, which is a method for preparing the mordenite through a hydrothermal crystallization by using natural aluminosilicate minerals as total silicon sources and total aluminum sources, comprising the steps of: subjecting the natural aluminosilicate minerals to activation treatment which is an activation by sub-molten salt and an activation by thermal treatment; selecting and mixing the activated natural aluminosilicate minerals according to the silicon-to-aluminum ratio of the targeted mordenite, adding thereto deionized water, sodium hydroxide, crystal seed, a templating agent to obtain a reaction mixture; adjusting the reaction mixture by using an inorganic acid to have a pH of 10-13, and then aging it at 40-80° C. for 6-24 hours; and subjecting the aged reaction mixture to hydrothermal crystallization, and then filtering, washing, drying and calcinating the crystallized product to obtain the mordenite. The method for preparing a mordenite provided in the present invention enlarges the sources of raw materials for a molecular sieve, has a low cost and a simple process route, and can largely reduce the cost for synthesizing a molecular sieve.
Abstract:
The present invention relates to the well drilling field in petrochemical industry, and discloses a high-density water-based drilling fluid suitable for horizontal shale gas wells comprising a nano-plugging agent, a bionic wall bracing agent, a bionic shale inhibitor, a filler, an emulsifier, and an amphiphobic wettability reversal agent, wherein, the nano-plugging agent is modified silicon dioxide nano-particle, and its modifying group includes a modifying copolymer chain; the bionic wall bracing agent is carboxymethyl chitosan with a dopamine-derived group grafted on its main chain; the bionic shale inhibitor is composed of structural units of arginine and structural units of lysine; the filler consists of calcium carbonate of 1,600-2,500 mesh, calcium carbonate of 1,050-1,500 mesh, and calcium carbonate of 500-1,000 mesh at a weight ratio of 1:0.55-6:0.55-6; and the amphiphobic wettability reversal agent is a dual-cation fluorocarbon surfactant. The drilling fluid provided herein is suitable for use in shale gas mining.
Abstract:
The present invention relates to the well drilling field in petroleum industry, in particular to an additive composition suitable for viscosity reduction of oil-based drilling fluids, an oil-based drilling fluid and use thereof. The double-block copolymer mainly consists of a block A and a block B, wherein, the block A is composed of structural units represented by formula (1), the block B is composed of structural units represented by formula (2), and the number-average molecular weight of the block A is 1,500-10,000. The double-block copolymer provided in the present invention can be used as a viscosity reducer in oil-based drilling fluids, especially can be used as a viscosity reducer in high-density clay-free oil-based drilling fluids, and can greatly decrease the apparent viscosity and plastic viscosity of oil-based drilling fluids in high-temperature and high-pressure reservoir while maintaining appropriate shearing force, so as to increase the drilling rate and reduce drilling difficulties.
Abstract:
The present invention provides a method for processing low-grade heavy oil, comprising: providing a riser-bed reactor; preheating the low-grade heavy oil and injecting it into the riser reactor to react with solid catalyst particles at the temperature of 550-610° C.; oil-gas, after reacting with the solid catalyst particles in the riser reactor, being introduced into the fluidized bed reactor to continue to react at temperature of 440-520° C. and weight hourly space velocity of 0.5-5 h−1; and the oil-gas, after reacting in the fluidized bed reactor, being separated from coked solid catalyst particles carried therein, and the separated oil-gas being introduced into a fractionation system. The method can effectively remove carbon residues, heavy metals, asphaltenes and other impurities from the low-grade heavy oil, and obtain high liquid product yield in a simple process.
Abstract:
The present invention provides a nuclear magnetic resonance logging instrument probe with double-layered magnets and an antenna excitation method, the nuclear magnetic resonance logging instrument probe includes: a probe framework and a shielding layer arranged in the probe framework; a plurality of main magnets are provided above and below the shielding layer, respectively; central axes of the main magnets are parallel with each other, and distances between the central axes of each of the main magnets and a central axis of the probe framework are the same; a distance between central axes of any two main magnets is not smaller than a first preset value; and an antenna is provided at outer side of each main magnety. In the present invention, circumferential recognizing capability of the nuclear magnetic resonance logging instrument probe can be improved and three-dimensional (radial, axial and circumferential) stratum detection can be achieved.
Abstract:
The present subject matter relates to the drilling fluid field, and discloses a bionic drilling fluid and a method for preparation of the bionic drilling fluid. The bionic drilling fluid comprises a specific bionic wall bracing agent, a bionic shale inhibitor, a filtrate reducer, and an amphiphilic reservoir protectant, wherein, the filtrate reducer comprises microcrystalline cellulose. The bionic drilling fluid provided in the present subject matter can effectively solve the problem of well wall instability, and has great industrial application prospects.
Abstract:
The present invention relates to the field of petrochemical drilling and discloses a drilling fluid additive composition. The composition contains rheological modifier, emulsifier and tackifier. Among them, the rheological modifier is dimer acid-organic amine copolymer comprising structural units from dimer acid, structural units from alkylamine and structural units from arylamine; the tackifier is modified polysiloxane nano-particles, and the modifying group Z on the polysiloxane nano-particles is the emulsifier is one or more of the compounds represented by the following Formula (1). The present invention further provides a high temperature resistant clay-free whole-oil-based drilling fluid containing the foregoing composition. Through synergistic effect of the rheological modifier, the emulsifier and the tackifier in the composition, the present invention obtains a clay-free whole-oil-based drilling fluid with desirable suspending power and temperature resistance.
Abstract:
The present invention provides a method for preparing a mordenite, which is a method for preparing the mordenite through a hydrothermal crystallization by using natural aluminosilicate minerals as total silicon sources and total aluminum sources, comprising the steps of: subjecting the natural aluminosilicate minerals to activation treatment which is an activation by sub-molten salt and an activation by thermal treatment; selecting and mixing the activated natural aluminosilicate minerals according to the silicon-to-aluminum ratio of the targeted mordenite, adding thereto deionized water, sodium hydroxide, crystal seed, a templating agent to obtain a reaction mixture; adjusting the reaction mixture by using an inorganic acid to have a pH of 10-13, and then aging it at 40-80° C. for 6-24 hours; and subjecting the aged reaction mixture to hydrothermal crystallization, and then filtering, washing, drying and calcinating the crystallized product to obtain the mordenite. The method for preparing a mordenite provided in the present invention enlarges the sources of raw materials for a molecular sieve, has a low cost and a simple process route, and can largely reduce the cost for synthesizing a molecular sieve.