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    Catalyst for upgrading inferior acid-containing crude oil, process for manufacturing the same, and application thereof
    7.
    发明授权
    Catalyst for upgrading inferior acid-containing crude oil, process for manufacturing the same, and application thereof 有权
    用于升级劣质含酸原油的催化剂，其制造方法及其应用

    公开(公告)号：US09259711B2

    公开(公告)日：2016-02-16

    申请号：US12993637

    申请日：2009-01-09

    申请人： Jun Long ,  Jiushun Zhang ,  Huiping Tian ,  Yuxia Zhu

    发明人： Jun Long ,  Jiushun Zhang ,  Huiping Tian ,  Yuxia Zhu

    IPC分类号： C10G11/04 ,  B01J21/14 ,  B01J21/16 ,  B01J23/02 ,  B01J35/10 ,  B01J37/03 ,  B01J37/30 ,  C10G29/04 ,  C10G45/04

    CPC分类号： B01J21/14 ,  B01J21/16 ,  B01J23/02 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/03 ,  B01J37/30 ,  C10G11/04 ,  C10G29/04 ,  C10G45/04

    摘要： The present invention relates to a mesopore material of a catalyst for upgrading acid-containing crude oil. Said mesopore material is an amorphous material containing alkaline earth oxide, silica and alumina, and has an anhydrous chemical formula of (0-0.3)Na2O.(1-50)MO.(6-58)Al2O3.(40-92)SiO2, based on the weight percent of the oxides, wherein M is one or more selected from Mg, Ca and Ba. Said mesopore material has a specific surface area of 200-400 m2/g, a pore volume of 0.5-2.0 ml/g, an average pore diameter of 8-20 nm, and a most probable pore size of 5-15 nm. The present invention further relates to a process for manufacturing said mesopore material and the use thereof. The catalyst prepared from the mesopore material provided in the present invention is suitable for the catalytic upgrading of inferior acid-containing crude oil and for the removal of organic acids, carbon residues and metals in the crude oil, and thus has very good economic benefits.

    摘要翻译： 本发明涉及一种用于升级含酸原油的催化剂的中孔材料。 所述中孔材料是含有碱土金属氧化物，二氧化硅和氧化铝的无定形材料，具有无水化学式（0-0.3）Na2O（1-50）MO。（6-58）Al2O3。（40-92）SiO2 ，基于氧化物的重量百分数，其中M是选自Mg，Ca和Ba中的一种或多种。 所述中孔材料的比表面积为200-400m2 / g，孔体积为0.5-2.0ml / g，平均孔径为8-20nm，最可能的孔径为5-15nm。 本发明还涉及一种制造所述中孔材料的方法及其用途。 由本发明提供的中孔材料制备的催化剂适用于劣质含酸原油的催化提质和原油中有机酸，碳残余物和金属的去除，具有非常好的经济效益。

    FCC Catalyst Compositions Containing Boron Oxide
    9.
    发明申请
    FCC Catalyst Compositions Containing Boron Oxide 有权
    含有氧化硼的FCC催化剂组合物

    公开(公告)号：US20150174560A1

    公开(公告)日：2015-06-25

    申请号：US14134614

    申请日：2013-12-19

    申请人： BASF Corporation

    发明人： Robert McGuire, JR. ,  Gary M. Smith ,  Bilge Yilmaz

    IPC分类号： B01J29/08 ,  C10G11/04

    CPC分类号： B01J29/088 ,  B01J21/02 ,  B01J21/04 ,  B01J21/16 ,  B01J23/755 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/04 ,  B01J2229/126 ,  B01J2229/186 ,  B01J2229/26 ,  C10G11/04 ,  C10G11/05 ,  C10G11/18

    摘要： Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

    摘要翻译： 描述了流化催化裂化（FCC）组合物，制造和使用方法。 FCC催化剂组合物包含含有非沸石组分和一种或多种氧化硼组分的颗粒。 在实施方案中，FCC催化剂组合物含有沸石组分和任选的稀土组分和过渡氧化铝。 FCC催化组合物可以包含含有一种或多种氧化硼组分的第一颗粒类型和与含有第二种基质组分的第二种颗粒类型和沸石混合的第一种基质组分。 FCC催化剂组合物可用于裂解烃进料，特别是含有高V和Ni的渣油进料，导致较低的氢气和焦炭产率。