公开(公告)号：US08153546B2

公开(公告)日：2012-04-10

申请号：US12661705

申请日：2010-03-23

Applicant: James F. Brazdil ,  Mark A. Toft ,  Michael J. Seely ,  Charles J. Besecker ,  Robert A. Gustaferro

Inventor： James F. Brazdil ,  Mark A. Toft ,  Michael J. Seely ,  Charles J. Besecker ,  Robert A. Gustaferro

IPC: B01J23/10 ,  B01J21/08

CPC classification number: B01J23/8878 ,  B01J23/002 ,  B01J23/8871 ,  B01J23/8876 ,  B01J35/002 ,  B01J37/031 ,  B01J2523/00 ,  C07C253/26 ,  Y02P20/52 ,  B01J2523/12 ,  B01J2523/13 ,  B01J2523/15 ,  B01J2523/22 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/14 ,  B01J2523/67 ,  C07C255/08

Abstract: A catalytic composition useful for the conversion of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile, and mixtures thereof. The catalytic composition comprising a complex of metal oxides comprising bismuth, molybdenum, iron, cerium and other promoter elements, wherein the X-ray diffraction pattern of the catalytic composition has X-ray diffraction peaks at 2θ angle 28±0.3 degrees and 2θ angle 26.5±0.3 degrees, and wherein the ratio of the intensity of the most intense x-ray diffraction peak within 2θ angle 28±0.3 degrees to the intensity of most intense x-ray diffraction peak within 2θ angle 26.5±0.3 degrees is defined as X/Y, and wherein X/Y is greater than or equal to 0.7.

Abstract translation: 用于将选自丙烯，异丁烯或其混合物的烯烃转化成丙烯腈，甲基丙烯腈及其混合物的催化组合物。 所述催化剂组合物包含包含铋，钼，铁，铈和其它助催化剂元素的金属氧化物的复合物，其中所述催化剂组合物的X射线衍射图在2θ处具有X射线衍射峰; 角度28±0.3度和2度; 角度26.5±0.3度，并且其中最强烈的x射线衍射峰的强度在2θ范围内; 角度28±0.3度，最大强度x射线衍射峰值在2和之内; 角度26.5±0.3度被定义为X / Y，并且其中X / Y大于或等于0.7。

公开(公告)号：US20090142254A1

公开(公告)日：2009-06-04

申请号：US11999332

申请日：2007-12-04

Applicant: Bhagya CHANDRA Sutradhar ,  Thomas L. Szabo ,  Muin S. Haddad ,  Mark A. Toft ,  Christos Paparizos ,  Lina K. Bodiwala

Inventor： Bhagya CHANDRA Sutradhar ,  Thomas L. Szabo ,  Muin S. Haddad ,  Mark A. Toft ,  Christos Paparizos ,  Lina K. Bodiwala

IPC: C01B19/00 ,  C01G30/00 ,  C01G31/02

CPC classification number: B01J35/0006 ,  B01J23/002 ,  B01J37/0045 ,  B01J37/0236 ,  B01J37/08 ,  B01J2523/00 ,  C01G39/006 ,  C01P2006/12 ,  C07C253/24 ,  Y02P20/52 ,  C07C255/08 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68

Abstract: The present invention comprises a method for preparing a mixed oxide catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutene by ammoxidation in a gaseous phase via methods of heating or calcining precursor solid mixture to obtain mixed metal oxide catalyst compositions that exhibit catalytic activity.

Abstract translation: 本发明包括通过加热或煅烧前体固体混合物的方法制备用于在丙烯或异丁烯中通过氨氧化制备丙烯腈或甲基丙烯腈的混合氧化物催化剂的方法，以获得具有催化活性的混合金属氧化物催化剂组合物。

公开(公告)号：US4888438A

公开(公告)日：1989-12-19

申请号：US264751

申请日：1988-10-31

Applicant: Linda C. Glaeser ,  James F. Brazdil, Jr. ,  Mark A. Toft

Inventor： Linda C. Glaeser ,  James F. Brazdil, Jr. ,  Mark A. Toft

IPC: B01J23/85 ,  B01J23/88 ,  B01J37/04

CPC classification number: B01J23/8872 ,  B01J23/85 ,  B01J23/887 ,  B01J23/8876 ,  B01J23/8877 ,  B01J23/8878 ,  B01J37/04 ,  C07C253/24 ,  Y02P20/52

Abstract: Disclosed is ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalyst compositions useful in the process are also disclosed.

Abstract translation: 公开了使用（1）烷烃:NH 3的摩尔比在2至16和烷烃：O 2的摩尔比在1至10的范围内和（2）a（a）的情况下，使用NH 3和O 2使C3至C5无环烷烃氨氧化 颗粒催化剂组合物的混合物，第一种特别有效促进从石蜡形成不饱和腈和烯烃，第二催化剂组合物特别有效促进烯烃转化为不饱和腈。 还公开了可用于该方法的催化剂组合物。

公开(公告)号：US4883895A

公开(公告)日：1989-11-28

申请号：US348438

申请日：1989-05-08

Applicant: James F. Brazdil, Jr. ,  Linda C. Glaeser ,  Mark A. Toft

Inventor： James F. Brazdil, Jr. ,  Linda C. Glaeser ,  Mark A. Toft

IPC: B01J27/199 ,  B01J37/04

CPC classification number: B01J23/002 ,  B01J27/199 ,  B01J37/04 ,  B01J2523/00

Abstract: Disclosed is the reaction of propane and isobutane with O.sub.2 and NH.sub.3 to make .alpha.,.beta.-unsaturated nitriles and olefins, using certain complex metal oxide catalyst compositions and an excess of the paraffin over both the O.sub.2 and the NH.sub.3. Also disclosed are suitable catalyst compositions for such reactions.

Abstract translation: 公开了丙烷和异丁烷与O 2和NH 3反应以制备α，β-不饱和腈和烯烃，使用某些复合金属氧化物催化剂组合物和过量的O 2和NH 3上的链烷烃。 还公开了用于这种反应的合适的催化剂组合物。

公开(公告)号：US4866194A

公开(公告)日：1989-09-12

申请号：US270856

申请日：1988-11-14

Applicant: Linda C. Glaeser ,  James F. Brazdil, Jr. ,  Mark A. Toft

Inventor： Linda C. Glaeser ,  James F. Brazdil, Jr. ,  Mark A. Toft

IPC: B01J23/22 ,  B01J23/31 ,  B01J27/199 ,  C07C253/24

CPC classification number: B01J23/002 ,  B01J23/22 ,  B01J23/31 ,  B01J27/199 ,  C07C253/24 ,  B01J2523/00 ,  Y02P20/52

Abstract: Disclosed is ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated mononitrile. Catalyst compositions useful in the process are also disclosed.

公开(公告)号：US4814478A

公开(公告)日：1989-03-21

申请号：US173967

申请日：1988-03-28

Applicant: Linda C. Glaeser ,  James F. Brazdil, Jr. ,  Mark A. Toft

Inventor： Linda C. Glaeser ,  James F. Brazdil, Jr. ,  Mark A. Toft

IPC: B01J23/881 ,  B01J23/887 ,  C07C253/24 ,  C07C120/14

CPC classification number: C07C253/24 ,  B01J23/881 ,  B01J23/8876 ,  Y02P20/52

Abstract: Disclosed is ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst comosition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalyst compositions useful in the process are also disclosed.

Abstract translation: 公开了使用（1）烷烃:NH 3的摩尔比在2至16和烷烃：O 2的摩尔比在1至10的范围内和（2）a（a）的情况下，使用NH 3和O 2使C3至C5无环烷烃氨氧化 颗粒催化剂组合物的混合物，第一种特别有效促进从石蜡形成不饱和腈和烯烃，第二种催化剂组合特别有效促进烯烃转化为不饱和腈。 还公开了可用于该方法的催化剂组合物。