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公开(公告)号：US20180099925A1
公开(公告)日：2018-04-12
申请号：US15290024
申请日：2016-10-11
IPC分类号： C07C253/26 , B01J23/887
CPC分类号： C07C253/26 , B01J23/002 , B01J23/8876 , B01J23/8878 , B01J37/031 , B01J37/035 , B01J37/04 , B01J37/08 , B01J2523/00 , C07C205/00 , C07C253/18 , C07C255/00 , Y02P20/52 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/14 , B01J2523/3712 , B01J2523/67 , C07C255/08
摘要： A catalytic composition and process useful for the conversion of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile, hydrogen cyanide and acetonitrile and mixtures thereof, wherein the catalyst exhibiting increased selectivity to hydrogen cyanide compared to prior art catalysts.
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公开(公告)号：US20160340296A1
公开(公告)日：2016-11-24
申请号：US15225956
申请日：2016-08-02
IPC分类号： C07C253/26 , B01J23/887 , G01N23/20 , B01J23/00
CPC分类号： C07C253/26 , B01J21/08 , B01J23/002 , B01J23/8876 , B01J23/8878 , B01J35/002 , B01J37/0045 , B01J37/031 , B01J2523/00 , G01N23/20 , Y02P20/52 , B01J2523/14 , B01J2523/22 , B01J2523/3712 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/41 , C07C255/08
摘要： Catalytic compositions are provided that are effective for providing increased acrylonitrile product without a significant decrease in hydrogen cyanide and/or acetonitrile production and provide an overall increase in production of acrylonitrile, hydrogen cyanide and acetonitrile. The catalytic compositions include a complex of metal oxides and include at least about 15% m-phase plus t-phase by weight and have a weight ratio of m-phase to m-phase plus t-phase of 0.45 or greater.
摘要翻译： 提供催化组合物，其对于提供增加的丙烯腈产物是有效的，而不显着降低氰化氢和/或乙腈生产，并提供丙烯腈，氰化氢和乙腈的总体生产增加。 催化剂组合物包括金属氧化物的复合物，并且包括至少约15％的m相加上t相，并且m相与m相加上t相的重量比为0.45以上。
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3.发明授权Method of making mixed metal oxide catalysts for ammoxidation and/or oxidation of lower alkane hydrocarbons 失效制备用于低级烷烃的氨氧化和/或氧化的混合金属氧化物催化剂的方法公开(公告)号：US08658817B2
公开(公告)日：2014-02-25
申请号：US12737604
申请日：2009-07-28
申请人： Charles J. Besecker , Bhagya Chandra Sutradhar , Mark A. Toft , James F. Brazdil , Muin S. Haddad , Christos Paparizos , Michael J. Seely
发明人： Charles J. Besecker , Bhagya Chandra Sutradhar , Mark A. Toft , James F. Brazdil , Muin S. Haddad , Christos Paparizos , Michael J. Seely
IPC分类号： C07C255/03 , B01J27/057 , B01J21/00
CPC分类号： C07C253/24 , B01J23/002 , B01J23/28 , B01J27/0576 , B01J27/132 , B01J37/0045 , B01J2523/00 , Y02P20/52 , C07C255/08 , B01J2523/11 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/23 , B01J2523/3712 , B01J2523/3725 , B01J2523/64
摘要： The present invention comprises a method for preparing a mixed oxide catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane by ammoxidation in a gaseous phase via methods of contacting any one of the antimony compound, the molybdenum compound, and the vanadium compound with hydrogen peroxide prior to combining with source compounds for the remaining elements in the catalyst.
摘要翻译： 本发明包括通过使任何一种锑化合物，钼化合物和钒化合物与氢气接触的方法，通过气相通过氨氧化制备用于由丙烷或异丁烷生产丙烯腈或甲基丙烯腈的混合氧化物催化剂的方法 在与源化合物组合之前用于催化剂中的剩余元素。
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公开(公告)号：US20120130112A1
公开(公告)日：2012-05-24
申请号：US13351292
申请日：2012-01-17
申请人： James F. Brazdil , Mark A. Toft , Michael J. Seely , Charles J. Besecker , Robert A. Gustaferro
发明人： James F. Brazdil , Mark A. Toft , Michael J. Seely , Charles J. Besecker , Robert A. Gustaferro
IPC分类号： C07C253/26
CPC分类号： B01J23/8878 , B01J23/002 , B01J23/8871 , B01J23/8876 , B01J35/002 , B01J37/031 , B01J2523/00 , C07C253/26 , Y02P20/52 , B01J2523/12 , B01J2523/13 , B01J2523/15 , B01J2523/22 , B01J2523/3712 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/14 , B01J2523/67 , C07C255/08
摘要： Olefins selected from the group consisting of propylene, isobutylene or mixtures thereof, are converted to acrylonitrile, methacrylonitrile, and mixtures thereof in a process comprising reacting in the vapor phase at an elevated temperature and pressure said olefin with a molecular oxygen containing gas and ammonia in the presence of a catalytic composition comprising a complex of metal oxides comprising bismuth, molybdenum, iron, cerium and other promoter elements, wherein the X-ray diffraction pattern of the catalytic composition has X-ray diffraction peaks at 2θ angle 28±0.3 degrees and 2θ angle 26.5±0.3 degrees, and wherein the ratio of the intensity of the most intense x-ray diffraction peak within 2θ angle 28±0.3 degrees to the intensity of most intense x-ray diffraction peak within 2θ angle 26.5±0.3 degrees is defined as X/Y, and wherein X/Y is greater than or equal to 0.7.
摘要翻译： 将选自丙烯，异丁烯或其混合物的烯烃转化为丙烯腈，甲基丙烯腈及其混合物，其方法包括在高温和高压下在气相中使所述烯烃与含分子氧的气体和氨反应 含有铋，钼，铁，铈等助催化剂元素的金属氧化物络合物的催化剂组合物的存在，其中催化剂组合物的X射线衍射图在2θ处具有X射线衍射峰; 角度28±0.3度和2度; 角度26.5±0.3度，并且其中最强烈的x射线衍射峰的强度在2θ范围内; 角度28±0.3度，最大强度x射线衍射峰值在2和之内; 角度26.5±0.3度被定义为X / Y，并且其中X / Y大于或等于0.7。
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公开(公告)号：US20110237821A1
公开(公告)日：2011-09-29
申请号：US12661720
申请日：2010-03-23
申请人： James F. Brazdil , Mark A. Toft , Michael J. Seely , Charles J. Besecker , Robert A. Gustaferro
发明人： James F. Brazdil , Mark A. Toft , Michael J. Seely , Charles J. Besecker , Robert A. Gustaferro
IPC分类号： C07C253/18 , B01J23/10 , B01J21/02 , B01J27/192
CPC分类号： C07C253/26 , B01J23/002 , B01J23/8871 , B01J23/8876 , B01J23/8878 , B01J35/002 , B01J37/031 , B01J2523/00 , Y02P20/52 , B01J2523/12 , B01J2523/13 , B01J2523/15 , B01J2523/22 , B01J2523/3712 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/14 , B01J2523/67 , C07C255/08
摘要： A catalytic composition useful for the conversion of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile, and mixtures thereof. The catalytic composition comprising a complex of metal oxides comprising bismuth, molybdenum, iron, cerium and other promoters, wherein the ratio of cerium to iron in the composition is greater than or equal to 0.8 and less than or equal to 5.
摘要翻译： 用于将选自丙烯，异丁烯或其混合物的烯烃转化成丙烯腈，甲基丙烯腈及其混合物的催化组合物。 所述催化剂组合物包含包含铋，钼，铁，铈和其它助催化剂的金属氧化物的复合物，其中所述组合物中铈与铁的比例大于或等于0.8且小于或等于5。
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公开(公告)号：US20110233460A1
公开(公告)日：2011-09-29
申请号：US13065134
申请日：2011-03-15
IPC分类号： C09K3/00 , B01J23/10 , B01J21/08 , B01J23/887
CPC分类号： C07C253/26 , B01J23/002 , B01J23/883 , B01J35/002 , B01J37/031 , B01J37/04 , B01J37/08 , B01J2523/00 , Y02P20/52 , B01J2523/12 , B01J2523/13 , B01J2523/15 , B01J2523/22 , B01J2523/3712 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/14 , B01J2523/67 , C07C255/08
摘要： A process and novel catalyst for the production of acrylonitrile, acetonitrile and hydrogen cyanide characterized by the relative yields of acrylonitrile, acetonitrile and hydrogen cyanide produced in the process and by the catalyst, which are defined by the following: α=[(% AN+(3×% HCN)+(1.5×% ACN))+% PC]×100 wherein % AN is the Acrylonitrile Yield and % AN≧81, % HCN is the Hydrogen Cyanide Yield, % ACN is the Acetonitrile Yield, % PC is the Propylene Conversion, and α is greater than 100.
摘要翻译： 用于生产丙烯腈，乙腈和氰化氢的方法和新型催化剂，其特征在于在该方法和催化剂中产生的丙烯腈，乙腈和氰化氢的相对产率，其由下列定义：α= [（％AN +（ 3×％HCN）+（1.5×ACN））+％PC]×100其中％AN为丙烯腈收率，％AN≥81，％HCN为氰化氢产率，％ACN为乙腈产率，％PC为 丙烯转化率，α大于100。
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公开(公告)号：US5079207A
公开(公告)日：1992-01-07
申请号：US620814
申请日：1990-12-03
申请人： James F. Brazdil , Linda C. Glaeser , Mark A. Toft
发明人： James F. Brazdil , Linda C. Glaeser , Mark A. Toft
IPC分类号： B01J23/84 , B01J23/847 , B01J23/85 , B01J23/89 , B01J27/057 , B01J27/198 , C07B61/00 , C07C253/24 , C07C253/26 , C07C255/07
CPC分类号： C07C253/26 , B01J23/8472 , Y02P20/52
摘要： Disclosed is a process for making an .alpha., .beta.-unsaturated monoitrile by the catalytic reaction of a paraffin containing 3-5 carbon atoms with molecular oxygen and ammonia by catalytic contact of the foregoing reactants in a reaction zone with a metal oxide catalyst containing the elements indicated by the empirical formula,V.sub.v A.sub.a D.sub.d Sn.sub.m Sb.sub.n Cu.sub.c O.sub.x (formula 1)in the relative atomic proportions indicated by the subscripts, whereA is selected from Te and BiD is one or more optional elements selected from Mo, W, Ti, Ge, Ce, La, Cr, Mn, Mg, Ca, Co, Ni, Fe, Nb, Ta, Ag, Zn, Cd, B, P, Na, K and Cs, anda is 0.001 to 30d is zero to 30c is 0.001 to 30m is 0.1 to 60n is 0.1 to 60n/v is>12 and
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公开(公告)号：US4866195A
公开(公告)日：1989-09-12
申请号：US234644
申请日：1988-08-22
IPC分类号： B01J37/04
CPC分类号： C07C253/24 , B01J37/04
摘要： Ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalytic compositions useful in the process are disclosed.
摘要翻译： 使用（1）烷烃：NH 3的摩尔比为2至16，烷烃：O 2的摩尔比在1至10范围内，使用NH 3和O 2对C3至C5无环烷烃进行氨氧化，和（2）混合物 颗粒催化剂组合物，第一种特别有效促进从石蜡形成不饱和腈和烯烃，第二催化剂组合物特别有效促进烯烃转化为不饱和腈。 公开了在该方法中有用的催化组合物。
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公开(公告)号：US4837233A
公开(公告)日：1989-06-06
申请号：US50268
申请日：1987-05-15
IPC分类号： B01J27/199 , B01J23/18 , B01J23/22 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/31 , B01J23/847 , B01J23/88 , B01J27/057 , B01J27/192 , B01J27/198 , B01J37/04 , C07C67/00 , C07C253/00 , C07C253/24 , C07C255/08
CPC分类号： B01J23/002 , B01J23/18 , B01J23/22 , B01J23/24 , B01J23/28 , B01J23/8472 , B01J23/887 , B01J23/8871 , B01J23/8876 , B01J23/8877 , B01J27/057 , B01J27/192 , B01J27/198 , B01J37/04 , C07C253/24 , B01J2523/00 , Y02P20/52
摘要： Ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkano:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst composition, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalytic compositions useful in the process are disclosed.
摘要翻译： 使用（1）烷烃：NH 3的摩尔比为2至16，烷烃：O 2的摩尔比在1至10的范围内，使用NH 3和O 2将C3至C5无环烷烃氨氧化为（2） 颗粒催化剂组合物，第一种特别有效促进从石蜡形成不饱和腈和烯烃，第二催化剂组合物特别有效促进烯烃转化为不饱和腈。 公开了在该方法中有用的催化组合物。
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公开(公告)号：US4767739A
公开(公告)日：1988-08-30
申请号：US39859
申请日：1987-04-20
IPC分类号： B01J27/199 , B01J23/22 , B01J23/30 , B01J23/85 , B01J23/88 , B01J23/89 , B01J27/057 , B01J27/198 , B01J37/04 , C07B61/00 , C07C67/00 , C07C253/00 , C07C255/08 , B01J23/18
CPC分类号： B01J23/8876 , B01J23/85 , B01J23/887 , B01J23/8877 , B01J37/04 , C07C253/24 , Y02P20/52
摘要： Disclosed is ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalyst compositions useful in the process are also disclosed.
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