SHALE HYDRATION INHIBITION AGENT AND METHOD OF USE
    41.
    发明申请
    SHALE HYDRATION INHIBITION AGENT AND METHOD OF USE 失效
    SHALE HYDRIC抑制剂及其使用方法

    公开(公告)号:US20090175688A1

    公开(公告)日:2009-07-09

    申请号:US12402944

    申请日:2009-03-12

    IPC分类号: B09B3/00

    摘要: A method of using a water-base wellbore fluid in subterranean wells that penetrate through a subterranean formation containing a shale which swells in the presence of water. The well bore fluid includes, an aqueous based continuous phase, and a shale hydration inhibition agent. One illustrative shale hydration inhibition agent is preferably the reaction product of a hydrogenation reaction of the product of the reaction of an aromatic amine with an aldehyde, preferably formaldehyde. Alternatively the shale hydration inhibition agent may be the reaction product of a hydrogenation reaction of the product of the reaction of aniline and formaldehyde. In one illustrative embodiment, the shale hydration inhibition agent is selected from the class of compounds known as polycycloaliphatic amines. Further the shale hydration inhibition agent may be present in the form of a free-base or in the form of an acid salt of the disclosed amine compounds. The shale hydration inhibition agent is present in sufficient concentration to substantially reduce the swelling of shale drilling cuttings upon contact with the fluid.

    摘要翻译: 一种在地下井中使用水基井眼流体的方法,其渗透包含在水存在下溶胀的页岩的地下地层。 井眼流体包括水基连续相和页岩水化抑制剂。 一种说明性的页岩水化抑制剂优选是芳族胺与醛,优选甲醛的反应产物的氢化反应的反应产物。 或者,页岩水化抑制剂可以是苯胺和甲醛的反应产物的氢化反应的反应产物。 在一个说明性实施方案中,页岩水化抑制剂选自称为多环脂族胺的化合物类别。 此外,页岩水化抑制剂可以以游离碱的形式或所公开的胺化合物的酸式的形式存在。 页岩水化抑制剂以足够的浓度存在,以在与流体接触时大大减少页岩钻屑的膨胀。

    Shale hydration inhibition agent and method of use
    42.
    发明授权
    Shale hydration inhibition agent and method of use 失效
    页岩水化抑制剂及其使用方法

    公开(公告)号:US07514392B2

    公开(公告)日:2009-04-07

    申请号:US11123394

    申请日:2005-05-06

    IPC分类号: C09K8/035

    摘要: A water-base wellbore fluid for use in subterranean wells that penetrate through a subterranean formation containing a shale which swells in the presence of water. The well bore fluid includes, an aqueous based continuous phase, and a shale hydration inhibition agent. One illustrative shale hydration inhibition agent is preferably the reaction product of a hydrogenation reaction of the product of the reaction of an aromatic amine with an aldehyde, preferably formaldehyde. Alternatively the shale hydration inhibition agent may be the reaction product of a hydrogenation reaction of the product of the reaction of aniline and formaldehyde. In one illustrative embodiment, the shale hydration inhibition agent is selected from the class of compounds known as polycycloaliphatic amines. The shale hydration inhibition agent may be present in the form of a free-base or preferably in the form of an acid salt of the disclosed amine compounds. The shale hydration inhibition agent is present in sufficient concentration to substantially reduce the swelling of shale drilling cuttings upon contact with the fluid.

    摘要翻译: 一种用于地下井的水基井筒流体,其穿透包含在水存在下膨胀的页岩的地下地层。 井眼流体包括水基连续相和页岩水化抑制剂。 一种说明性的页岩水化抑制剂优选是芳族胺与醛,优选甲醛的反应产物的氢化反应的反应产物。 或者,页岩水化抑制剂可以是苯胺和甲醛的反应产物的氢化反应的反应产物。 在一个说明性实施方案中,页岩水化抑制剂选自称为多环脂族胺的化合物类别。 页岩水化抑制剂可以以游离碱的形式存在,或者优选以所公开的胺化合物的酸式的形式存在。 页岩水化抑制剂以足够的浓度存在,以在与流体接触时大大减少页岩钻屑的膨胀。

    High performance water-based drilling mud and method of use
    43.
    发明授权
    High performance water-based drilling mud and method of use 有权
    高性能水泥钻井泥浆及其使用方法

    公开(公告)号:US07497262B2

    公开(公告)日:2009-03-03

    申请号:US11672847

    申请日:2007-02-08

    CPC分类号: C09K8/24 C09K2208/12

    摘要: A method of forming a subterranean well and a method of reducing the swelling of shale clay during the drilling of the subterranean well. The method features the use of a water based drilling fluid, wherein the drilling fluid is formulated to include: an aqueous based continuous phase; a weight material; an optional shale hydration inhibition agent and a shale encapsulator. The shale encapsulator has the formula: in which x and y have a value so that the molecular weight of the cation is in the range of about 10,000 to about 200,000 AMU; A is selected from C1-C6 alkyl, C2-C6 ether or C2-C6 amide; R, R′and R″are independently selectable C1-C3 alkyl; and B−is a charge balancing anion to the quaternary amine. The shale hydration inhibition agent and the shale encapsulator may be present in sufficient concentrations to reduce the swelling of the subterranean formation in the presence of water. Conventional additives may be included into the formulation of the drilling fluid, including: fluid loss control agents, alkaline reserve and other pH control agents, bridging agents, lubricants, anti-bit balling agents, corrosion inhibition agents, surfactants, solids suspending agents, and mixtures and combinations of these and other similar additives.

    摘要翻译: 一种形成地下井的方法和在地下井的钻探期间减少页岩粘土的膨胀的方法。 该方法的特征在于使用水基钻井液,其中钻井液被配制为包括:基于水的连续相; 重物料; 可选的页岩水化抑制剂和页岩封隔器。 页岩封装剂具有下式:其中x和y具有使阳离子的分子量在约10,000至约200,000AMU范围内的值; A选自C 1 -C 6烷基,C 2 -C 6醚或C 2 -C 6酰胺; R,R'和R'可独立选择的C 1 -C 3烷基; 而B是与季胺的电荷平衡阴离子。 页岩水化抑制剂和页岩封壳剂可以以足够的浓度存在,以在水的存在下减少地层的溶胀。 常规的添加剂可以包括在钻井液的配方中,包括:流体损失控制剂,碱性储备和其它pH控制剂,桥联剂,润滑剂,抗钻头球磨剂,腐蚀抑制剂,表面活性剂,固体悬浮剂和 这些和其他类似添加剂的混合物和组合。

    Process for making alkaline-earth metal salts of alkaryl sulfonic acids
    44.
    发明授权
    Process for making alkaline-earth metal salts of alkaryl sulfonic acids 失效
    制备烷芳基磺酸的碱土金属盐的方法

    公开(公告)号:US4615841A

    公开(公告)日:1986-10-07

    申请号:US727055

    申请日:1985-04-25

    IPC分类号: C07C309/28 C07C143/24

    CPC分类号: C07C309/00

    摘要: A novel process for making solutions of alkaline-earth metal salts of alkaryl sulfonic acids that contain about 1.5 to less than three weight percent water and that does not require an azeotropic distillation step to reduce the water of the reaction product to this level, comprises reacting an alkaryl sulfonic acid with alkaline-earth metal oxide in an organic solvent in the presence of 0.05 to less than 2.5 weight percent water. Calcium oxide, alkylbenzene sulfonic acids wherein the alkyl groups contain 10 to 14 carbon atoms, solvent mixtures of lower alkanols and non-polar hydrocarbon solvents all are representative of materials useful in the process of the invention, wherein the alkyl benzene sulfonic acid is preferably proportioned into a mixture of the other reactants and the water is supplied in admixture with a small amount of a calcium alkylbenzene sulfonate.

    摘要翻译: 包含约1.5至小于3重量%的水并且不需要共沸蒸馏步骤以将反应产物的水降至该水平的烷芳基磺酸的碱土金属盐的溶液的新方法包括使反应 烷基磺酸与碱土金属氧化物在有机溶剂中,在0.05至小于2.5重量%的水存在下进行。 氧化钙,其中烷基含有10至14个碳原子的烷基苯磺酸,低级链烷醇和非极性烃溶剂的溶剂混合物都是可用于本发明方法的材料的代表,其中烷基苯磺酸优选成比例 加入到其它反应物的混合物中,并且将水与少量的烷基苯磺酸钙混合加入。