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41.发明申请UV CROSS-LINKED POLYMER FUNCTIONALIZED MOLECULAR SIEVE/POLYMER MIXED MATRIX MEMBRANES 审中-公开紫外线交联聚合物官能化分子筛/聚合物混合基质膜公开(公告)号：US20080295691A1
公开(公告)日：2008-12-04
申请号：US11756988
申请日：2007-06-01
IPC分类号： B01D46/24
CPC分类号： B01D69/141 , B01D53/228 , B01D67/0006 , B01D69/125 , B01D2323/345 , B01D2325/02
摘要： The present invention discloses methods of separating gases using high performance UV cross-linked polymer functionalized molecular sieve/polymer mixed matrix membranes (MMMs) with either no macrovoids or voids of less than several angstroms at the interface of the polymer matrix and the molecular sieves. These UV cross-linked MMMs were prepared by incorporating polyethersulfone (PES) functionalized molecular sieves such as AIPO-14 and UZM-25 small pore microporous molecular sieves into a continuous UV cross-linkable polyimide polymer matrix followed by UV cross-linking. The UV cross-linked MMMs in the form of symmetric dense film, asymmetric flat sheet membrane, or asymmetric hollow fiber membranes have good flexibility, high mechanical strength, and exhibit significantly enhanced selectivity and permeability over polymer membranes made from corresponding continuous polyimide polymer matrices for carbon dioxide/methane and hydrogen/methane separations. The MMMs of the present invention are suitable for a variety of liquid, gas, and vapor separations.
摘要翻译： 本发明公开了使用高分子量UV交联聚合物官能化分子筛/聚合物混合基质膜（MMM）分离气体的方法，在聚合物基质和分子筛的界面处没有大孔或小于几埃的空隙。 这些UV交联MMM通过将聚醚砜（PES）官能化分子筛如AIPO-14和UZM-25小孔微孔分子筛掺入连续的可UV交联的聚酰亚胺聚合物基质中，然后进行UV交联来制备。 对称致密膜，不对称平板膜或不对称中空纤维膜形式的UV交联MMMs具有良好的柔韧性，高机械强度，并且在由相应的连续聚酰亚胺聚合物基质制成的聚合物膜上表现出显着增强的选择性和渗透性 二氧化碳/甲烷和氢气/甲烷分离。 本发明的MMM适用于各种液体，气体和蒸气分离。
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42.发明授权Mixed matrix membranes incorporating surface-functionalized molecular sieve nanoparticles 失效掺入表面官能化分子筛纳米颗粒的混合基质膜公开(公告)号：US08394453B2
公开(公告)日：2013-03-12
申请号：US12904673
申请日：2010-10-14
申请人： Chunqing Liu , Stephen T. Wilson , Beth McCulloch
发明人： Chunqing Liu , Stephen T. Wilson , Beth McCulloch
IPC分类号： B05D5/00
CPC分类号： B01D67/0079 , B01D69/148 , B01D71/028 , Y02C10/10
摘要： Mixed matrix membranes that are capable of separation and purification of gas mixtures are disclosed. These membranes comprise polymers that include dispersed therein nanomolecular sieve particles. In a preferred embodiment, the nanomolecular sieve particles contain attached functional groups to prevent their agglomeration.
摘要翻译： 公开了能够分离和纯化气体混合物的混合基质膜。 这些膜包括分散在纳米分子筛颗粒中的聚合物。 在优选的实施方案中，纳米分子筛颗粒含有附着的官能团以防止其结合。
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43.发明授权Crosslinked organic-inorganic hybrid membranes and their use in gas separation 有权交联的有机 - 无机杂化膜及其在气体分离中的应用公开(公告)号：US07790803B2
公开(公告)日：2010-09-07
申请号：US12131392
申请日：2008-06-02
IPC分类号： C07B37/00
CPC分类号： C08L1/20 , B01D53/228 , B01D67/0079 , B01D71/00 , B01D71/16 , B01D71/52 , B01D71/70 , B01D2257/102 , B01D2257/504 , C08B7/00 , C08G65/33306 , C08G65/33351 , C08G65/336 , C08G2650/58 , C08L71/02 , Y02C10/10 , Y02P20/152
摘要： The present invention is for crosslinked membranes and in particular for crosslinked poly(ethylene oxide)-cellulose acetate-silsesquioxane (PEO-CA-Si) organic-inorganic hybrid membranes and their use in gas separation. These crosslinked PEO-CA-Si membranes were prepared by in-situ sol-gel co-condensation of crosslinkable PEO-organotrialkoxysilane and CA-organotrialkoxysilane polymers in the presence of acetic acid catalyst during the formation of membranes. The crosslinkable PEO- and CA-organotrialkoxysilane polymers were synthesized via the reaction between the hydroxyl groups on PEO (or on CA) and the isocyanate on organotrialkoxysilane to form urethane linkages under mild conditions. The crosslinked PEO-CA-Si membranes exhibited both increased selectivity of CO2/N2 and CO2 permeability as compared to a CA membrane, suggesting that these membranes are very promising for gas separations such as CO2/N2 separation.
摘要翻译： 本发明涉及交联膜，特别是交联聚（环氧乙烷） - 醋酸纤维素 - 倍半硅氧烷（PEO-CA-Si）有机 - 无机混合膜及其在气体分离中的应用。 这些交联的PEO-CA-Si膜通过在形成膜期间在乙酸催化剂存在下通过可交联的PEO-有机三烷氧基硅烷和CA-有机三烷氧基硅烷聚合物的原位溶胶 - 凝胶共缩合制备。 通过PEO（或CA）上的羟基与有机三烷氧基硅烷上的异氰酸酯之间的反应合成可交联PEO-和CA-有机三烷氧基硅烷聚合物，以在温和条件下形成氨基甲酸酯键。 与CA膜相比，交联的PEO-CA-Si膜显示出增加的CO 2 / N 2选择性和CO 2渗透性，这表明这些膜对于气体分离如CO 2 / N 2分离是非常有希望的。
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公开(公告)号：US07637983B1
公开(公告)日：2009-12-29
申请号：US11427834
申请日：2006-06-30
IPC分类号： B01D53/22
CPC分类号： B01D53/228 , B01D53/02 , B01D67/0079 , B01D69/148 , B01D71/00 , B01D71/56 , B01D71/64 , B01D2253/204 , B01J20/22 , B01J20/226 , B01J20/26 , B01J20/28026 , B01J20/28033 , B01J20/2808 , B01J2220/44
摘要： Metal-organic framework (MOF)-polymer mixed matrix membranes (MOF-MMMs) have been prepared by dispersing high surface area MOFs (e.g. IRMOF-1) into a polymer matrix (e.g. Matrimid 5218). The MOFs allow the polymer to infiltrate the pores of the MOFs, which improves the interfacial and mechanical properties of the polymer and in turn affects permeability. Pure gas permeation tests show the incorporation of 20 wt-% of IRMOF-1 in Matrimid 5218 polyimide matrix results in 280% improvement in CO2 permeability without a loss of CO2/CH4 selectivity compared to those of the pure Matrimid 5218 membrane. This type of MOF-MMMs has significantly improved gas separation performance with dramatically high CO2 permeability (>35 barrer) and higher than 29 CO2/CH4 selectivity at 50° C. under 100 psig pressure, which are attractive candidates for practical gas separation applications such as CO2 removal from natural gas.
摘要翻译： 已经通过将高表面积MOF（例如IRMOF-1）分散到聚合物基质（例如Matrimid 5218）中制备了金属 - 有机骨架（MOF） - 聚合物混合基质膜（MOF-MMM）。 MOFs允许聚合物渗透MOFs的孔隙，这改善了聚合物的界面和机械性能，进而影响渗透性。 纯气体渗透测试显示，与Matrimid 5218聚酰亚胺基质相比，掺入20wt％的IRMOF-1导致CO 2渗透率提高280％，而与纯Matrimid 5218膜相比，CO 2 / CH 4选择性降低。 这种类型的MOF-MMM具有显着改善的气体分离性能，在100psig压力下，在50℃下具有显着高的CO 2渗透性（> 35巴勒）和高于29 CO 2 / CH 4选择性，这是实际气体分离应用的有吸引力的候选物 作为从天然气中去除二氧化碳。
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45.发明授权Ionic liquid-solid-polymer mixed matrix membranes for gas separations 有权用于气体分离的离子液体 - 固体 - 聚合物混合基质膜公开(公告)号：US07943543B1
公开(公告)日：2011-05-17
申请号：US11537294
申请日：2006-09-29
CPC分类号： B01D53/228 , B01D67/0009 , B01D67/0011 , B01D67/0079 , B01D69/148 , B01D71/64 , B01D71/82 , B01D2323/08 , B01D2323/21 , B01D2323/46 , B01D2325/02 , Y02C10/10
摘要： New ionic liquid-solid-polymer mixed matrix membranes were proposed for gas separations such as CO2 removal from natural gas or N2. For the new mixed matrix membranes, the solids such as carbon molecular sieves, microporous molecular sieves, MCM-41 type of mesoporous molecular sieves, or polymer of intrinsic microporosity (PIM) are coated (or impregnated) with ionic liquids such as 1-butyl-3-methyl imidazolium bis[trifluoromethylsulfonyl]amide. The ionic liquids coated or impregnated solids are then dispersed in the continuous polymer matrix to form mixed matrix membranes. These hybrid mixed matrix membranes will combine the properties of the continuous polymer phase, the ionic liquids, and the dispersed ionic liquids coated or impregnated solids phase, which will possibly open up new opportunities for gas separation processes such as CO2 separation from natural gas or flue gas.
摘要翻译： 提出了新的离子液固固体混合基质膜用于气体分离，例如从天然气或N2中除去二氧化碳。 对于新的混合基质膜，将诸如碳分子筛，微孔分子筛，MCM-41型介孔分子筛或本征微孔聚合物（PIM）的固体用离子液体例如1-丁基 -3-甲基咪唑双[三氟甲磺酰基]酰胺。 然后将离子液体涂覆或浸渍的固体分散在连续聚合物基质中以形成混合基质膜。 这些混合混合基质膜将结合连续聚合物相，离子液体和分散的离子液体涂覆或浸渍的固体相的性质，这可能为气体分离过程（例如从天然气或烟道中分离CO 2）开辟新的机会 加油站。
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46.发明申请Crosslinked Organic-Inorganic Hybrid Membranes and Their Use in Gas Separation 有权交联有机无机杂化膜及其在气体分离中的应用公开(公告)号：US20090299015A1
公开(公告)日：2009-12-03
申请号：US12131392
申请日：2008-06-02
IPC分类号： C08L1/12
CPC分类号： C08L1/20 , B01D53/228 , B01D67/0079 , B01D71/00 , B01D71/16 , B01D71/52 , B01D71/70 , B01D2257/102 , B01D2257/504 , C08B7/00 , C08G65/33306 , C08G65/33351 , C08G65/336 , C08G2650/58 , C08L71/02 , Y02C10/10 , Y02P20/152
摘要： The present invention is for crosslinked membranes and in particular for crosslinked poly(ethylene oxide)-cellulose acetate-silsesquioxane (PEO-CA-Si) organic-inorganic hybrid membranes and their use in gas separation. These crosslinked PEO-CA-Si membranes were prepared by in-situ sol-gel co-condensation of crosslinkable PEO-organotrialkoxysilane and CA-organotrialkoxysilane polymers in the presence of acetic acid catalyst during the formation of membranes. The crosslinkable PEO- and CA-organotrialkoxysilane polymers were synthesized via the reaction between the hydroxyl groups on PEO (or on CA) and the isocyanate on organotrialkoxysilane to form urethane linkages under mild conditions. The crosslinked PEO-CA-Si membranes exhibited both increased selectivity of CO2/N2 and CO2 permeability as compared to a CA membrane, suggesting that these membranes are very promising for gas separations such as CO2/N2 separation.
摘要翻译： 本发明涉及交联膜，特别是交联聚（环氧乙烷） - 醋酸纤维素 - 倍半硅氧烷（PEO-CA-Si）有机 - 无机混合膜及其在气体分离中的应用。 这些交联的PEO-CA-Si膜通过在形成膜期间在乙酸催化剂存在下通过可交联的PEO-有机三烷氧基硅烷和CA-有机三烷氧基硅烷聚合物的原位溶胶 - 凝胶共缩合制备。 通过PEO（或CA）上的羟基与有机三烷氧基硅烷上的异氰酸酯之间的反应合成可交联PEO-和CA-有机三烷氧基硅烷聚合物，以在温和条件下形成氨基甲酸酯键。 与CA膜相比，交联的PEO-CA-Si膜显示出增加的CO 2 / N 2选择性和CO 2渗透性，这表明这些膜对于气体分离如CO 2 / N 2分离是非常有希望的。
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47.发明申请Mixed Matrix Membranes Containing Low Acidity Nano-Sized SAPO-34 Molecular Sieves 审中-公开含低酸度纳米尺寸SAPO-34分子筛的混合基质膜公开(公告)号：US20090149313A1
公开(公告)日：2009-06-11
申请号：US11954017
申请日：2007-12-11
申请人： Chunqing Liu , Stephen T. Wilson , Lisa M. Knight
发明人： Chunqing Liu , Stephen T. Wilson , Lisa M. Knight
IPC分类号： B01J20/28
CPC分类号： B01D67/0079 , B01D53/228 , B01D69/147 , B01D69/148 , B01D2256/24 , B01D2257/504 , B01D2323/21 , Y02C10/10
摘要： The present invention discloses mixed matrix membranes (MMMs) containing polymer-functionalized low acidity, ultra low silica-to-alumina ratio, nano-sized SAPO-34 small pore molecular sieves and a continuous polymer matrix and methods for making and using these membranes. The surface functionalization of these molecular sieves provides a desired interfacial adhesion between SAPO-34 nano-particles and the continuous polymer matrix, which results in either no macrovoids or voids of less than 5 angstroms at the interface of the continuous polymer matrix and SAPO-34 in the MMMs. These MMMs, in the form of symmetric dense film, asymmetric flat sheet membrane, or asymmetric hollow fiber membranes, have good flexibility and high mechanical strength, and exhibit remarkably enhanced CO2 permeability (or CO2 permeance) and maintained CO2/CH4 selectivity over the continuous polymer matrices for CO2/CH4 separation. The MMMs of the present invention are suitable for a variety of liquid, gas, and vapor.
摘要翻译： 本发明公开了含有聚合物官能化低酸度，超低二氧化硅与氧化铝比的纳米级SAPO-34小孔分子筛和连续聚合物基质的混合基质膜（MMM）以及制备和使用这些膜的方法。 这些分子筛的表面官能化提供SAPO-34纳米颗粒和连续聚合物基质之间期望的界面粘合，其导致在连续聚合物基质和SAPO-34的界面处不存在小于5埃的大孔或空隙 在MMM中。 这些以对称致密膜，不对称平板膜或不对称中空纤维膜形式的MMM具有良好的柔韧性和高机械强度，并且显示出显着提高的CO 2渗透性（或CO 2渗透性）并且保持CO 2 / CH 4选择性超过连续 用于CO2 / CH4分离的聚合物基质。 本发明的MMM适用于各种液体，气体和蒸气。
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48.发明申请UV CROSS-LINKED POLYMER FUNCTIONALIZED MOLECULAR SIEVE/POLYMER MIXED MATRIX MEMBRANES 审中-公开紫外线交联聚合物官能化分子筛/聚合物混合基质膜公开(公告)号：US20080296527A1
公开(公告)日：2008-12-04
申请号：US11757008
申请日：2007-06-01
IPC分类号： B01D3/18
CPC分类号： B01D67/0079 , B01D67/0088 , B01D67/009 , B01D67/0093 , B01D69/148 , B01D71/028 , B01D2323/30 , B01D2323/345 , B01D2323/36 , B01D2325/022
摘要： The present invention discloses high performance UV cross-linked polymer functionalized molecular sieve/polymer mixed matrix membranes (MMMs) with either no macrovoids or voids of less than several angstroms at the interface of the polymer matrix and the molecular sieves. These UV cross-linked MMMs were prepared by incorporating polyethersulfone (PES) functionalized molecular sieves such as AlPO-14 and UZM-25 small pore microporous molecular sieves into a continuous UV cross-linkable polyimide polymer matrix followed by UV cross-linking. The UV cross-linked MMMs in the form of symmetric dense film, asymmetric flat sheet membrane, or asymmetric hollow fiber membranes have good flexibility, high mechanical strength, and exhibit significantly enhanced selectivity and permeability over polymer membranes made from corresponding continuous polyimide polymer matrices for carbon dioxide/methane and hydrogen/methane separations. The MMMs of the present invention are suitable for a variety of liquid, gas, and vapor separations.
摘要翻译： 本发明公开了在聚合物基质和分子筛的界面处没有大孔或小于几埃的空隙的高性能UV交联聚合物官能化分子筛/聚合物混合基质膜（MMM）。 通过将聚醚砜（PES）官能化分子筛如AlPO-14和UZM-25小孔微孔分子筛掺入连续的可UV交联的聚酰亚胺聚合物基质中，然后进行紫外线交联，制备这些UV交联的MMM。 对称致密膜，不对称平板膜或不对称中空纤维膜形式的UV交联MMMs具有良好的柔韧性，高机械强度，并且在由相应的连续聚酰亚胺聚合物基质制成的聚合物膜上表现出显着增强的选择性和渗透性 二氧化碳/甲烷和氢气/甲烷分离。 本发明的MMM适用于各种液体，气体和蒸气分离。
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49.发明授权Cross-linkable and cross-linked mixed matrix membranes and methods of making the same 有权可交联和交联的混合基质膜及其制备方法公开(公告)号：US07806962B2
公开(公告)日：2010-10-05
申请号：US12193897
申请日：2008-08-19
IPC分类号： B01D53/22
CPC分类号： B01D53/228 , B01D67/0004 , B01D67/009 , B01D69/02 , B01D69/141 , B01D71/64 , B01D2323/30 , B01D2323/345 , Y02C10/10 , Y02C20/20 , Y10S55/05
摘要： The present invention is for novel high performance cross-linkable and cross-linked mixed matrix membranes and the use of such membranes for separations such as for CO2/CH4, H2/CH4 and propylene/propane separations. More specifically, the invention involves the preparation of cross-linkable and cross-linked mixed matrix membranes (MMMs). The cross-linkable MMMs were prepared by incorporating microporous molecular sieves or soluble high surface area microporous polymers (PIMs) as dispersed microporous fillers into a continuous cross-linkable polymer matrix. The cross-linked MMMs were prepared by UV-cross-linking the cross-linkable MMMs containing cross-linkable polymer matrix such as BP-55 polyimide. Pure gas permeation test results demonstrated that both types of MMMs exhibited higher performance for CO2/CH4 and H2/CH4 separations than those of the corresponding cross-linkable and cross-linked pure polymer matrices.
摘要翻译： 本发明是用于新型高性能可交联和交联的混合基质膜，以及这种膜用于分离的用途，例如用于CO 2 / CH 4，H 2 / CH 4和丙烯/丙烷分离。 更具体地，本发明涉及可交联和交联的混合基质膜（MMM）的制备。 通过将微孔分子筛或可溶性高表面积微孔聚合物（PIM）作为分散的微孔填料掺入连续可交联的聚合物基质中来制备可交联的MMM。 交联的MMM通过UV-交联含有可交联聚合物基质如BP-55聚酰亚胺的可交联MMM制备。 纯气体渗透测试结果表明，两种类型的MMM对于CO 2 / CH 4和H 2 / CH 4分离显示出比相应的可交联和交联纯聚合物基质更高的性能。
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50.发明授权Cross-linkable and cross-linked mixed matrix membranes and methods of making the same 失效可交联和交联的混合基质膜及其制备方法公开(公告)号：US07485173B1
公开(公告)日：2009-02-03
申请号：US11300775
申请日：2005-12-15
CPC分类号： B01D53/228 , B01D67/0004 , B01D67/009 , B01D69/02 , B01D69/141 , B01D71/64 , B01D2323/30 , B01D2323/345 , Y02C10/10 , Y02C20/20 , Y10S55/05
摘要： The present invention is for novel high performance cross-linkable and cross-linked mixed matrix membranes and the use of such membranes for separations such as for CO2/CH4, H2/CH4 and propylene/propane separations. More specifically, the invention involves the preparation of cross-linkable and cross-linked mixed matrix membranes (MMMs). The cross-linkable MMMs were prepared by incorporating microporous molecular sieves or soluble high surface area microporous polymers (PIMs) as dispersed microporous fillers into a continuous cross-linkable polymer matrix. The cross-linked MMMs were prepared by UV-cross-linking the cross-linkable MMMs containing cross-linkable polymer matrix such as BP-55 polyimide. Pure gas permeation test results demonstrated that both types of MMMs exhibited higher performance for CO2/CH4 and H2/CH4 separations than those of the corresponding cross-linkable and cross-linked pure polymer matrices.
摘要翻译： 本发明是用于新型高性能可交联和交联的混合基质膜，以及这种膜用于分离的用途，例如用于CO 2 / CH 4，H 2 / CH 4和丙烯/丙烷分离。 更具体地，本发明涉及可交联和交联的混合基质膜（MMM）的制备。 通过将微孔分子筛或可溶性高表面积微孔聚合物（PIM）作为分散的微孔填料掺入连续可交联的聚合物基质中来制备可交联的MMM。 交联的MMM通过UV-交联含有可交联聚合物基质如BP-55聚酰亚胺的可交联MMM制备。 纯气体渗透测试结果表明，两种类型的MMM对于CO 2 / CH 4和H 2 / CH 4分离显示出比相应的可交联和交联纯聚合物基质更高的性能。
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