公开(公告)号：US07897207B2

公开(公告)日：2011-03-01

申请号：US11679155

申请日：2007-02-26

申请人： Chunqing Liu ,  Stephen T. Wilson

发明人： Chunqing Liu ,  Stephen T. Wilson

IPC分类号： B05D5/00

CPC分类号： B01D53/228 ,  B01D67/0079 ,  B01D69/148 ,  B01D71/028 ,  B01D71/64 ,  Y02C10/10

摘要： Nano-molecular sieve-polymer mixed matrix membranes (MMMs) for CO2 removal from natural gas have been prepared by incorporating dispersible template-free nano-molecular sieves into polymer matrices such as Matrimid 5218 polyimide matrix or Ultem 1000 polyetherimide matrix. The nano-molecular sieves used in this invention include template-free nano-AlPO-18, nano-AlPO-5, nano-Silicalite, nano-SAPO-34, and PEG-functionalized nano-Silicalite. These template-free nano-molecular sieves were synthesized by an organic ligand grafting method.

摘要翻译： 通过将分散无模板的纳米分子筛掺入聚合物基质如Matrimid 5218聚酰亚胺基体或Ultem 1000聚醚酰亚胺基体中，已经制备了用于从天然气中去除CO 2的纳米分子筛 - 聚合物混合基质膜（MMM）。 用于本发明的纳米分子筛包括无模板的纳米AlPO-18，纳米AlPO-5，纳米硅沸石，纳米SAPO-34和PEG官能化纳米硅沸石。 这些无模板的纳米分子筛是通过有机配体接枝方法合成的。

公开(公告)号：US20110023716A1

公开(公告)日：2011-02-03

申请号：US12904673

申请日：2010-10-14

申请人： Chunqing Liu ,  Stephen T. Wilson ,  Beth Mc Culloch

发明人： Chunqing Liu ,  Stephen T. Wilson ,  Beth Mc Culloch

IPC分类号： B01D53/22

CPC分类号： B01D67/0079 ,  B01D69/148 ,  B01D71/028 ,  Y02C10/10

摘要： Mixed matrix membranes that are capable of separation and purification of gas mixtures are disclosed. These membranes comprise polymers that include dispersed therein nanomolecular sieve particles. In a preferred embodiment, the nanomolecular sieve particles contain attached functional groups to prevent their agglomeration.

摘要翻译： 公开了能够分离和纯化气体混合物的混合基质膜。 这些膜包括分散在纳米分子筛颗粒中的聚合物。 在优选的实施方案中，纳米分子筛颗粒含有附着的官能团以防止其结合。

公开(公告)号：US07867474B2

公开(公告)日：2011-01-11

申请号：US12036893

申请日：2008-02-25

申请人： Gregory J. Lewis ,  Lisa M. Knight ,  Mark A. Miller ,  Stephen T. Wilson

发明人： Gregory J. Lewis ,  Lisa M. Knight ,  Mark A. Miller ,  Stephen T. Wilson

IPC分类号： C01B39/48

CPC分类号： B01J29/06 ,  B01J29/70 ,  C01B39/48

摘要： A series of crystalline layered and microporous compositions have been prepared. Compositions that have a layered structure and are identified as UZM-13, UZM-17 and UZM-19. Upon calcination at a temperature of about 400° C. to about 600° C., these compositions form a microporous crystalline zeolite with a three dimensional framework which has been identified as UZM-25. A process for preparing all these compositions and processes for using these compositions are also disclosed.

摘要翻译： 已经制备了一系列结晶层状和微孔组合物。 具有分层结构并被识别为UZM-13，UZM-17和UZM-19的组合物。 在约400℃至约600℃的温度下煅烧时，这些组合物形成具有三维框架的微孔结晶沸石，其已被鉴定为UZM-25。 还公开了制备所有这些组合物和使用这些组合物的方法的方法。

公开(公告)号：US20100326273A1

公开(公告)日：2010-12-30

申请号：US12875878

申请日：2010-09-03

申请人： Chunqing Liu ,  Stephen T. Wilson ,  Jeffrey J. Chiou ,  David A. Lesch ,  Santi Kulprathipanja

发明人： Chunqing Liu ,  Stephen T. Wilson ,  Jeffrey J. Chiou ,  David A. Lesch ,  Santi Kulprathipanja

IPC分类号： B01D53/22

CPC分类号： B01D67/0079 ,  B01D53/228 ,  B01D69/148 ,  B01D71/027 ,  B01D71/16 ,  B01D71/52 ,  B01D71/60 ,  B01D71/64 ,  B01D2323/30

摘要： This invention discloses a composition of, a method of making, and an application of high plasticization-resistant chemically cross-linked organic-inorganic hybrid membranes such as cross-linked cellulose acetate-cellulose triacetate-polyurethanepropylsilsesquioxane membranes. These cross-linked membranes with covalently interpolymer-chain-connected hybrid networks were prepared via a sol-gel condensation polymerization of cross-linkable organic polymer-organosilicon alkoxide precursor membrane materials. CO2 plasticization tests on these cross-linked membranes demonstrate extremely high CO2 plasticization resistance under CO2 pressure up to 5516 kPa (800 psig). These new cross-linked membranes can be used not only for gas separations such as CO2/CH4 and CO2/N2 separations, O2/N2 separation, olefin/paraffin separations (e.g. propylene/propane separation), iso/normal paraffins separations, but also for liquid separations such as desalination.

公开(公告)号：US07846496B2

公开(公告)日：2010-12-07

申请号：US11679121

申请日：2007-02-26

申请人： Chunqing Liu ,  Stephen T. Wilson ,  Beth McCulloch

发明人： Chunqing Liu ,  Stephen T. Wilson ,  Beth McCulloch

IPC分类号： B05D5/00

CPC分类号： B01D67/0079 ,  B01D69/148 ,  B01D71/028 ,  Y02C10/10

摘要： Mixed matrix membranes that are capable of separation and purification of gas mixtures are disclosed. These membranes comprise polymers that include dispersed therein nanomolecular sieve particles. In a preferred embodiment, the nanomolecular sieve particles contain attached functional groups to prevent their agglomeration.

摘要翻译： 公开了能够分离和纯化气体混合物的混合基质膜。 这些膜包括分散在纳米分子筛颗粒中的聚合物。 在优选的实施方案中，纳米分子筛颗粒含有附着的官能团以防止其结合。

公开(公告)号：US20100270234A1

公开(公告)日：2010-10-28

申请号：US12833193

申请日：2010-07-09

申请人： Chunqing Liu ,  Stephen T. Wilson ,  Jeffrey J. Chiou ,  David A. Lesch ,  Santi Kulprathipanja

发明人： Chunqing Liu ,  Stephen T. Wilson ,  Jeffrey J. Chiou ,  David A. Lesch ,  Santi Kulprathipanja

IPC分类号： B01D71/06 ,  C08J5/22

CPC分类号： B01D71/16 ,  B01D53/228 ,  B01D67/0006 ,  B01D67/0079 ,  B01D71/54 ,  B01D2323/30 ,  C08J5/2275 ,  C08J2375/04 ,  Y02P20/152

摘要： This invention discloses a composition of, a method of making, and an application of high plasticization-resistant chemically cross-linked organic-inorganic hybrid membranes such as cross-linked cellulose acetate-cellulose triacetate-polyurethanepropylsilsesquioxane membranes. These cross-linked membranes with covalently interpolymer-chain-connected hybrid networks were prepared via a sol-gel condensation polymerization of cross-linkable organic polymer-organosilicon alkoxide precursor membrane materials. CO2 plasticization tests on these cross-linked membranes demonstrate extremely high CO2 plasticization resistance under CO2 pressure up to 5516 kPa (800 psig). These new cross-linked membranes can be used not only for gas separations such as CO2/CH4 and CO2/N2 separations, O2/N2 separation, olefin/paraffin separations (e.g. propylene/propane separation), iso/normal paraffins separations, but also for liquid separations such as desalination.

摘要翻译： 本发明公开了一种组合物，制备和应用高增塑性化学交联的有机 - 无机杂化膜的组合物，例如交联的乙酸纤维素 - 三乙酸纤维素 - 聚氨酯丙基倍半硅氧烷膜。 通过可交联的有机聚合物 - 有机硅醇盐前体膜材料的溶胶 - 凝胶缩聚制备了具有共价互聚物链连接的杂化网络的这些交联膜。 这些交联膜上的二氧化碳增塑试验在二氧化碳压力高达5516 kPa（800 psig）下表现出极高的二氧化碳增塑性。 这些新的交联膜不仅可用于气体分离，如CO2 / CH4和CO2 / N2分离，O2 / N2分离，烯烃/石蜡分离（如丙烯/丙烷分离），异/正链烷烃分离， 用于液体分离，如脱盐。

公开(公告)号：US07578987B2

公开(公告)日：2009-08-25

申请号：US11157102

申请日：2005-06-20

申请人： Stephen T. Wilson

发明人： Stephen T. Wilson

IPC分类号： C01B39/54 ,  C01B37/06 ,  C01B37/08

CPC分类号： C07C1/20 ,  B01J29/84 ,  B01J29/85 ,  C01B39/54 ,  Y02P20/52 ,  Y02P30/42 ,  Y10S423/30 ,  C07C11/06 ,  C07C11/04 ,  C07C11/02

摘要： A process for producing an ElAPO molecular sieve with essentially pure CHA framework having an average crystal size less than about 5 micrometers is disclosed. When El is silicon, the process allows for a broad range of silicon content, and produces a catalyst with a high selectivity for the conversion of methanol to olefins. The process includes making a crystalline metallo-aluminophosphate molecular sieve of the formula (ElxAlyPz)O2from a mixture comprising an aluminum source, a phosphorous source, water, an El source, a fluorine source and an organic template source wherein the molar ratio of the organic template source to phosphorous is less than about 0.5; crystallizing the molecular sieve at a temperature between 100 C and 250 C and calcining in air.

摘要翻译： 公开了具有平均晶体尺寸小于约5微米的具有基本上纯CHA骨架的ElAPO分子筛的方法。 当El是硅时，该方法允许宽范围的硅含量，并产生具有高甲醇转化为烯烃的高选择性的催化剂。 该方法包括从包含铝源，磷源，水，El源，氟源和有机模板源的混合物制备式（ElxAlyPz）O 2的结晶金属铝磷酸盐分子筛，其中有机 模板源到磷小于约0.5; 在100℃和250℃之间的温度下使分子筛结晶并在空气中煅烧。

公开(公告)号：US20090197426A1

公开(公告)日：2009-08-06

申请号：US12356201

申请日：2009-01-20

申请人： Hayim Abrevaya ,  Richard R. Willis ,  Stephen T. Wilson

发明人： Hayim Abrevaya ,  Richard R. Willis ,  Stephen T. Wilson

IPC分类号： H01L21/31 ,  B01J29/04

CPC分类号： C01B39/026 ,  H01L21/31695

摘要： A process for forming a zeolite beta dielectric layer onto a substrate such as a silicon wafer has been developed. The zeolite beta is characterized in that it has an aluminum concentration from about 0.1 to about 2.0 wt. %, and has crystallites from about 5 to about 40 nanometers. The process involves first dealuminating a starting zeolite beta, then preparing a slurry of the dealuminated zeolite beta followed by coating a substrate, e.g. silicon wafer with the slurry, heating to form a zeolite beta film and treating the zeolite beta with a silylating agent.

摘要翻译： 已经开发了用于在诸如硅晶片的基底上形成沸石β电介质层的工艺。 沸石β的特征在于其铝浓度为约0.1至约2.0重量％。 并具有约5至约40纳米的微晶。 该方法首先对起始沸石β进行脱铝，然后制备脱铝沸石β的浆料，然后涂覆底物，例如。 硅晶片与浆料，加热形成沸石β膜并用甲硅烷基化剂处理沸石β。

公开(公告)号：US20090152763A1

公开(公告)日：2009-06-18

申请号：US11954454

申请日：2007-12-12

申请人： Chunqing Liu ,  Stephen T. Wilson ,  David A. Lesch

发明人： Chunqing Liu ,  Stephen T. Wilson ,  David A. Lesch

IPC分类号： B29D7/01

CPC分类号： B01D69/148 ,  B01D67/0079 ,  B01D69/06 ,  B01D71/028 ,  B01D2325/022

摘要： The present invention discloses an approach for making mixed matrix membranes (MMMS) and methods for using these membranes. These MMMs contain a continuous polymer matrix and dispersed microporous molecular sieve particles. This invention also pertains to control of the thickness of the thin dense selective mixed matrix membrane layer that is equal to or greater than the particle size of the largest molecular sieve particles for making large scale asymmetric MMMs. In particular, the invention is directed to making asymmetric flat sheet MMM by a phase inversion technique. The MMMs of the present invention exhibit at least 20% increase in selectivity compared to the polymer membranes prepared from their corresponding continuous polymer matrices. The MMMs of the present invention are suitable for a variety of liquid, gas, and vapor separations.

摘要翻译： 本发明公开了一种制备混合基质膜（MMMS）的方法和使用这些膜的方法。 这些MMM含有连续的聚合物基质和分散的微孔分子筛颗粒。 本发明还涉及等于或大于用于制造大规模不对称MMM的最大分子筛颗粒的粒度的薄致密选择性混合基质膜层的厚度的控制。 特别地，本发明涉及通过相位反转技术制造不对称平板MMM。 与由其相应的连续聚合物基质制备的聚合物膜相比，本发明的MMM显示出至少20％的选择性增加。 本发明的MMM适用于各种液体，气体和蒸气分离。

公开(公告)号：US20090152755A1

公开(公告)日：2009-06-18

申请号：US11954463

申请日：2007-12-12

申请人： Chunqing Liu ,  Stephen T. Wilson ,  David A. Lesch

发明人： Chunqing Liu ,  Stephen T. Wilson ,  David A. Lesch

IPC分类号： D04H3/16

CPC分类号： B01D69/148 ,  B01D67/0079 ,  B01D69/08 ,  B01D69/087 ,  B01D71/028

摘要： The present invention discloses a method for making mixed matrix membranes (MMMs) and methods for using these membranes. These MMMs contain a continuous polymer matrix and dispersed microporous molecular sieve particles. This invention also pertains to control the thickness of the thin dense selective mixed matrix layer equal to or greater than the particle size of the largest molecular sieve particles for making large scale asymmetric MMMs. In particular, the invention is directed to make asymmetric hollow fiber MMM by a phase inversion technique. The MMMs of the present invention exhibit at least 20% increase in selectivity compared to the polymer membranes prepared from their corresponding continuous polymer matrices. The MMMs of the present invention are suitable for a variety of liquid, gas, and vapor separations.

摘要翻译： 本发明公开了一种制备混合基质膜（MMM）的方法和使用这些膜的方法。 这些MMM含有连续的聚合物基质和分散的微孔分子筛颗粒。 本发明还涉及控制等于或大于用于制造大规模非对称MMM的最大分子筛颗粒的粒度的薄致密选择性混合基质层的厚度。 特别地，本发明涉及通过相位反转技术制造不对称中空纤维MMM。 与由其相应的连续聚合物基质制备的聚合物膜相比，本发明的MMM显示出至少20％的选择性增加。 本发明的MMM适用于各种液体，气体和蒸气分离。