公开(公告)号：US07990602B2

公开(公告)日：2011-08-02

申请号：US12617290

申请日：2009-11-12

申请人： Satoshi Tatsuura ,  Ryojiro Akashi ,  Naoki Hiji

发明人： Satoshi Tatsuura ,  Ryojiro Akashi ,  Naoki Hiji

IPC分类号： G02F1/153 ,  G02F1/15 ,  G09G3/19 ,  H04N9/16

CPC分类号： G02F1/153 ,  G02F1/13473 ,  G02F2203/34 ,  G09G3/006 ,  G09G3/38 ,  G09G2300/023

摘要： A display medium includes: a pair of substrates; an electrode arranged between the pair of substrates and on one substrate of the pair of substrates; a multilayered structure including plural color-forming layers arranged between one substrate of the pair of substrates and the electrode, each of the plural color-forming layers containing an electroconductive sheet-like porous body and an electrochromic dye which is retained by the porous body and is reversibly colored or decolored by at least one of an electrochemical oxidation reaction or a reduction reaction, and the colors when the electrochromic dyes in the respective plural color-forming layers are colored being different from one another; and an electrolytic material included in a region between the pair of substrates.

摘要翻译： 显示介质包括：一对基板; 布置在所述一对基板之间的电极和所述一对基板的一个基板上; 多层结构，包括布置在一对基板的一个基板和电极之间的多个成色层，多个成色层中的每一个包含导电片状多孔体和由多孔体保留的电致变色染料， 通过电化学氧化反应或还原反应中的至少一种可逆地着色或脱色，并且当各个成色层中的电致变色染料着色时的颜色彼此不同; 以及包含在所述一对基板之间的区域中的电解质材料。

公开(公告)号：US06850356B2

公开(公告)日：2005-02-01

申请号：US10752698

申请日：2004-01-08

申请人： Jun Kawahara ,  Masahiro Moriyama ,  Ryojiro Akashi

发明人： Jun Kawahara ,  Masahiro Moriyama ,  Ryojiro Akashi

IPC分类号： G02F1/17 ,  G02F1/19 ,  G02B26/00

CPC分类号： G02F1/19

摘要： The present invention relates to an optical element including at least; two substrates oppositely arranged; a liquid disposed between the facing surfaces of the substrates; and a chargeable polymer disposed between the facing surfaces of the substrates for swelling or contracting by absorbing or releasing the liquid when an electric field is applied, wherein (1) an area of each adhering fixing portion is smaller than a maximum sectional area of the chargeable polymer particle at the time of maximum swelling, and (2) a non-adhesive portion surrounds each adhering fixing portion, and the non-adhesive portion is disposed at least at a largest outer circumference of the chargeable polymer particle at the time of maximum swelling and extends inside the largest outer circumference of the chargeable polymer at the time of maximum swelling.

摘要翻译： 本发明涉及一种光学元件，至少包括： 两个基板相对布置; 设置在基板的相对表面之间的液体; 以及设置在基板的相对表面之间的可充电聚合物，用于当施加电场时通过吸收或释放液体而膨胀或收缩，其中（1）每个粘附固定部分的面积小于可充电的最大截面面积 聚合物颗粒在最大膨胀时，和（2）非粘合部分围绕每个粘附固定部分，并且非粘合部分至少设置在可充电聚合物颗粒的最大外周处于最大膨胀时 并且在最大膨胀时在可计量聚合物的最大外圆周内延伸。

公开(公告)号：US06780647B2

公开(公告)日：2004-08-24

申请号：US09966079

申请日：2001-10-01

申请人： Shoichiro Fujiwara ,  Masato Mikami ,  Takashi Uematsu ,  Ryojiro Akashi

发明人： Shoichiro Fujiwara ,  Masato Mikami ,  Takashi Uematsu ,  Ryojiro Akashi

IPC分类号： G01N2125

CPC分类号： G01N21/7703 ,  C12Q1/54 ,  C12Q1/58 ,  G01N21/47 ,  G01N2021/7723 ,  G01N2333/904 ,  G01N2333/908

摘要： Provided is a sensor material including at least a stimulus-responsive high polymer gel, a bio-substance-responsive material and a light modulation material. A sensor having at least the sensor material and an optical waveguide is also provided. Furthermore, provided are a detection method for a bio-substance using the sensor material in which a change in tone is detected on the basis of swelling or shrinking of the stimulus-responsive high polymer gel, and a detection method for transmitting light using a sensor material in which transmitting light is detected on the basis of swelling or shrinking of the stimulus-responsive high polymer gel.

摘要翻译： 提供了至少包括刺激响应高聚物凝胶，生物物质响应材料和光调制材料的传感器材料。 还提供了至少具有传感器材料和光波导的传感器。 此外，提供了使用其中基于刺激响应性高分子凝胶的膨胀或收缩来检测色调变化的传感器材料的生物物质的检测方法，以及使用传感器传输光的检测方法 基于刺激响应性高分子凝胶的膨胀或收缩检测透射光的材料。

公开(公告)号：US06579596B1

公开(公告)日：2003-06-17

申请号：US09058357

申请日：1998-04-10

申请人： Ryojiro Akashi ,  Akinori Komura ,  Takashi Uematsu

发明人： Ryojiro Akashi ,  Akinori Komura ,  Takashi Uematsu

IPC分类号： B32B2728

CPC分类号： C08J7/16 ,  Y10T428/24802 ,  Y10T428/31855 ,  Y10T428/31938

摘要： Disclosed are a composite material comprising a substrate having a three-dimensional structure which has, on substantially entire surface thereof, regions where a polymerizable unsaturated compound is graft-bonded and regions where the polymerizable unsaturated compound is not graft-bonded, a method for graft polymerization comprising the steps of reacting the surface of the substrate having a three-dimensional structure with droplets of a solution containing a graft polymerization initiator in a suspension or an emulsion comprising the solution containing a graft polymerization initiator and a solvent immiscible with the solution containing the graft polymerization initiator so as to form polymerization initiating regions on the surface of the substrate and thereafter graft-polymerizing a polymerizable unsaturated compound to the surface part where the polymerization initiating regions are formed, and a composite material comprising a substrate which has, on substantially entire surface thereof, regions where a polymerizable unsaturated compound is graft-bonded and regions where the polymerizable unsaturated compound is not graft-bonded.

摘要翻译： 公开了一种复合材料，其包含具有三维结构的基材，其基本上整个表面上具有接枝聚合的不饱和化合物的区域和可接枝的不饱和化合物的区域，接枝的方法 聚合反应包括以下步骤：将具有三维结构的基材表面与含有接枝聚合引发剂的溶液的悬浮液或乳液反应，所述液体包含含有接枝聚合引发剂的溶液和与含有接枝聚合引发剂的溶液不混溶的溶剂 接枝聚合引发剂，以在基材表面上形成聚合引发区，然后将可聚合不饱和化合物接枝聚合到形成聚合引发区的表面部分;以及复合材料，其包含基材，其基本上整体上 surfa 其中可聚合不饱和化合物被接枝的区域和可聚合的不饱和化合物不接枝的区域。

公开(公告)号：US06414052B1

公开(公告)日：2002-07-02

申请号：US09722724

申请日：2000-11-28

申请人： Akinori Komura ,  Ryojiro Akashi ,  Takashi Uematsu ,  Jun Kawahara ,  Masahiro Moriyama

发明人： Akinori Komura ,  Ryojiro Akashi ,  Takashi Uematsu ,  Jun Kawahara ,  Masahiro Moriyama

IPC分类号： C08F204

CPC分类号： C08F20/06 ,  C08F2/10 ,  C08F2/44 ,  C08F292/00

摘要： Polymeric particles of a desired particle size improved with the dispersion state of a pigment contained in the high polymeric particles can be obtained by a production method, which includes solution-polymerizing monomers having polymerizable unsaturated bonds in the presence of ionic particles sulfonic group or carboxyl group on the surface thereof.

摘要翻译： 可以通过包括在离子粒子磺酸基或羧基的存在下具有可聚合不饱和键的溶液聚合单体的制备方法获得期望粒径的聚合物颗粒，其中包含在高聚物颗粒中的颜料的分散状态可以获得 在其表面上。

公开(公告)号：US06295167B1

公开(公告)日：2001-09-25

申请号：US09318126

申请日：1999-05-25

申请人： Takashi Uematsu ,  Ryojiro Akashi ,  Akinori Komura

发明人： Takashi Uematsu ,  Ryojiro Akashi ,  Akinori Komura

IPC分类号： G02B106

CPC分类号： G02B5/0226 ,  G02B5/0268 ,  G02B5/0278 ,  G02B26/004

摘要： An optical material has a polymer gel whose volume is reversibly changed by absorbing or releasing a liquid in response to an external stimulus and a light scattering member covering at least a part of the surface of the polymer gel.

摘要翻译： 光学材料具有通过响应于外部刺激吸收或释放液体并且覆盖聚合物凝胶的至少一部分表面的光散射构件而可逆地改变体积的聚合物凝胶。

公开(公告)号：US06287485B1

公开(公告)日：2001-09-11

申请号：US09207921

申请日：1998-12-09

申请人： Ryojiro Akashi ,  Akinori Komura ,  Takashi Uematsu

发明人： Ryojiro Akashi ,  Akinori Komura ,  Takashi Uematsu

IPC分类号： G02F100

CPC分类号： G02B26/00 ,  G02F1/0147 ,  G02F1/17 ,  G02F1/172

摘要： A volume-modulation coloration producing material which is characterized by high contrast, high response and excellent durability; a composition including this material; an optical element and a method for optical modulation using the composition are disclosed. The volume-modulation coloration producing material includes a polymer gel capable of swelling-contracting by absorbing or desorbing a liquid when an external stimulus is given, and a pigment contained in the material at a concentration equal to or higher than a saturation absorption concentration. The volume-modulation coloration producing composition, which includes the volume-modulation coloration producing material and a liquid, exhibits a reversible volume change to swell or contract by the application of a stimulus such as, for example, heat, light, an electric current, an electric field, change in pH, change in ionic concentration, absorption or desorption of a substance and addition of a solvent. The pigment in the gel is in a diffused state (a) when the polymer gel is swollen while the pigment in the gel is in a flocculated state, (b) when the polymer gel is contracted so that the absorption efficiency of the light of the coloration producing material in a swollen state is higher than the absorption efficiency of the light of the coloration producing material in a contracted state.

摘要翻译： 体积调制着色产生材料，其特征在于高对比度，高响应性和优异的耐久性; 包含该材料的组合物; 公开了一种使用该组合物的光学元件和用于光学调制的方法。 体积调制着色产生材料包括能够通过在给予外部刺激时吸收或解吸液体而膨胀收缩的聚合物凝胶，以及以等于或高于饱和吸收浓度的材料中所含的颜料。 包括体积调制着色产生材料和液体的体积调制着色组合物通过施加诸如热，光，电流的刺激而呈现出可逆的体积变化以膨胀或收缩， 电场，pH的变化，离子浓度的变化，物质的吸收或解吸附加溶剂。 当凝胶中的颜料处于絮凝状态时，凝胶中的颜料处于扩散状态（a），同时聚合物凝胶溶胀，而（b）当聚合物凝胶收缩时，使得聚合物凝胶的光吸收效率 处于膨胀状态的着色产生材料高于收缩状态下着色产生材料的光的吸收效率。

公开(公告)号：US5620781A

公开(公告)日：1997-04-15

申请号：US457309

申请日：1995-06-01

申请人： Ryojiro Akashi ,  Akinori Inoue

发明人： Ryojiro Akashi ,  Akinori Inoue

IPC分类号： B41M5/28 ,  C09K19/38 ,  G02F1/133 ,  G02F1/1333 ,  B32B9/00

CPC分类号： B41M5/281 ,  C09K19/3852 ,  G02F1/132 ,  G02F1/133365 ,  Y10T428/24802

摘要： An erasable display medium comprising a substrate having thereon at least one liquid crystal polymer layer comprising a side chain type liquid crystal polymer which repeatedly and reversibly switches from a transparent state and a light-scattered state by the action of at least one of heat, an electrical field, and a magnetic field is disclosed, said side chain type liquid crystal polymer being a copolymer comprising a repeating unit represented by formula (I): ##STR1## and a repeating unit represented by formula (II): ##STR2## or a copolymer comprising a repeating unit represented by formula (III): ##STR3## and a repeating unit represented by formula (IV): ##STR4## wherein R.sup.a and R.sup.b each represent a hydrogen atom, a methyl group, or a halogen atom; A, D, and E each represent a specific liquid crystal molecule residue; B represents a group composed of one or more of a hydroxyl group, a halogen atom, an alkyl group, an alkenyl group, a substituted or unsubstituted phenyl group, a heterocyclic group, an amino group, a cyano group, --COOR.sup.2, --OCOR.sup.2, and --CONR.sup.2 R.sup.3, wherein R.sup.2 and R.sup.3 each represent a hydrogen atom, an alkyl group having from 1 to 30 carbon atoms which may be substituted with a halogen atom or a heterocyclic group, an alkenyl group, an alicyclic group, a hydroxyalkyl group, a hetero atom-containing alkyl group, or a substituted or unsubstituted phenyl group; and k, m, and n each represent an integer of from 1 to 30.

摘要翻译： 一种可擦除显示介质，包括其上具有至少一个液晶聚合物层的液晶聚合物层，所述至少一个液晶聚合物层包含侧链型液晶聚合物，所述侧链型液晶聚合物通过至少一种热反射和可逆地从透明状态和光散射状态转变， 所述侧链型液晶聚合物是包含由式（I）表示的重复单元：（I）和由式（II）表示的重复单元的共聚物：

公开(公告)号：US5498450A

公开(公告)日：1996-03-12

申请号：US151193

申请日：1993-11-12

申请人： Ryojiro Akashi ,  Masanobu Ninomiya

发明人： Ryojiro Akashi ,  Masanobu Ninomiya

IPC分类号： C09K19/54 ,  C09K19/52

CPC分类号： C09K19/544 ,  Y10T428/1073 ,  Y10T428/2495 ,  Y10T428/31551

摘要： A liquid crystal-polymer composite film comprising (1) a high-molecular weight compound containing at least one kind of monomer units providing a side chain having a liquid crystal nature and at least one kind of monomer units providing a side chain having no liquid crystal nature and (2) a low-molecular weight liquid crystal, the high-molecular weight compound (1) and the low-molecular weight liquid crystal (2) being in separate phases, and the monomer units providing a side chain having no liquid crystal nature being crosslinked; and an electro-optical element comprising a pair of substrates each having an electrode having interposed therebetween a liquid crystal-polymer composite film comprising (2) a low-molecular weight liquid crystal and (1) a high-molecular weight compound in separate phases, the substrates each having a surface comprising a material having a reactive group on the side in contact with the composite film, the reactive group being chemically bonded to the high-molecular weight compound (1) in the composite film.

摘要翻译： 一种液晶聚合物复合膜，其包含（1）含有至少一种提供具有液晶性的侧链的单体单元的高分子化合物和至少一种提供无液晶的侧链的单体单元 性质和（2）低分子量液晶，高分子量化合物（1）和低分子量液晶（2）分离相，提供无液晶的侧链的单体单元 自然交联; 以及电子光学元件，其包括一对基板，每个基板具有介于其间的电极，液晶聚合物复合膜包括（2）低分子量液晶和（1）分离相中的高分子量化合物， 所述基材各自具有包含在与所述复合膜接触的一侧上具有反应性基团的材料的表面，所述反应性基团与所述复合膜中的高分子量化合物（1）化学键合。

公开(公告)号：US5354498A

公开(公告)日：1994-10-11

申请号：US987991

申请日：1992-12-09

申请人： Ryojiro Akashi ,  Akinori Inoue ,  Yutaka Akasaki

发明人： Ryojiro Akashi ,  Akinori Inoue ,  Yutaka Akasaki

IPC分类号： C09K19/38 ,  C09K19/54 ,  G02F1/1334 ,  C09K19/52 ,  C09K19/56 ,  G02F1/13

CPC分类号： C09K19/3852 ,  C09K19/3842 ,  C09K19/544 ,  G02F1/1334

摘要： A phase separation liquid crystal polymer for displays, optical shutters and memories is disclosed, having on the side chains thereof at least one liquid crystal component and at least one non-liquid crystal component, said liquid crystal component and non-liquid crystal component being present in separate phases. The polymer has an increased degree of freedom in control of physical properties and exhibits improved resolving power, improved contrast, and improved rate of response.

摘要翻译： 公开了一种用于显示器，光学快门和存储器的相分离液晶聚合物，其侧链上至少有一个液晶组分和至少一个非液晶组分，所述液晶组分和非液晶组分存在 在不同的阶段。 聚合物在物理性质的控制方面具有增加的自由度，并且显示出改进的分辨能力，改善的对比度和提高的响应速度。