公开(公告)号：US4303764A

公开(公告)日：1981-12-01

申请号：US166643

申请日：1980-07-07

申请人： David Z. Becher ,  Roger M. Christenson ,  Richard L. Coalson ,  Percy E. Pierce ,  Karl F. Schimmel

发明人： David Z. Becher ,  Roger M. Christenson ,  Richard L. Coalson ,  Percy E. Pierce ,  Karl F. Schimmel

IPC分类号： C08F8/00 ,  C09B67/46 ,  C09D7/45 ,  C08F220/34

CPC分类号： C09D7/02 ,  C08F8/00 ,  C09B67/0091

摘要： Pigment dispersants for use in coating compositions wherein the dispersant is the polymerization product of (i) an alkyl methacrylate having from 3 to 8 carbon atoms in the alkyl group, (ii) a hardening monomer selected from the group consisting of a styrene, methyl methacrylate, ethyl methacrylate and mixtures thereof, (iii) an ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof or a monomer having a double bond alpha-beta to a carbonyl group and which provides carboxyl functionality when reacted with water, alcohol, amine or anhydride, (iv) a monomer having a double bond alpha-beta to a carbonyl group and at least one hydroxyl group or a monomer which provides such groups when further reacted with an acid or an epoxide, and (v) a compound providing an amine or amine salt functional moiety. The dispersants are useful for dispersing pigments in coating compositions containing a wide variety of film-forming resins.

摘要翻译： 用于涂料组合物的颜料分散剂，其中分散剂是（i）烷基中具有3-8个碳原子的甲基丙烯酸烷基酯的聚合产物，（ii）选自苯乙烯，甲基丙烯酸甲酯 ，甲基丙烯酸乙酯及其混合物，（iii）选自丙烯酸，甲基丙烯酸，衣康酸，巴豆酸，马来酸，富马酸及其混合物的烯属不饱和羧酸或具有双键α-烯烃的单体， 当与水，醇，胺或酸酐反应时提供羧基官能团，（iv）具有羰基和至少一个羟基的双键α-β的单体或提供这种基团的单体 当与酸或环氧化物进一步反应时，和（v）提供胺或胺盐官能部分的化合物。 分散剂可用于将颜料分散在含有多种成膜树脂的涂料组合物中。

公开(公告)号：US4302562A

公开(公告)日：1981-11-24

申请号：US178247

申请日：1980-08-14

申请人： David Z. Becher ,  Roger M. Christenson ,  Richard L. Coalson ,  Percy E. Pierce ,  Karl F. Schimmel

发明人： David Z. Becher ,  Roger M. Christenson ,  Richard L. Coalson ,  Percy E. Pierce ,  Karl F. Schimmel

IPC分类号： C08F8/00 ,  C09B67/46 ,  C09D7/45 ,  C08F220/34

CPC分类号： C09D7/02 ,  C08F8/00 ,  C09B67/0091

摘要： Pigment dispersants for use in coating compositions wherein the dispersant is the polymerization product of (i) an alkyl methacrylate having from 3 to 8 carbon atoms in the alkyl group, (ii) a hardening monomer selected from the group consisting of a styrene, methyl methacrylate, ethyl methacrylate and mixtures thereof, (iii) an ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof or a monomer having a double bond alpha-beta to a carbonyl group and which provides carboxyl functionality when reacted with water, alcohol, amine or anhydride, (iv) a monomer having a double bond alpha-beta to a carbonyl group and at least one hydroxyl group or a monomer which provides such groups when further reacted with an acid or an epoxide, and (v) a compound providing an amine or amine salt functional moiety. The dispersants are useful for dispersing pigments in coating compositions containing a wide variety of film-forming resins.

公开(公告)号：US4256560A

公开(公告)日：1981-03-17

申请号：US77248

申请日：1979-09-19

申请人： Stephen L. Buchwalter ,  Robert D. Jerabek ,  Lee-Pei H. Chou ,  Roger M. Christenson

发明人： Stephen L. Buchwalter ,  Robert D. Jerabek ,  Lee-Pei H. Chou ,  Roger M. Christenson

IPC分类号： C08G59/40 ,  C08G59/50 ,  C08L63/00 ,  C09D5/44 ,  C09D133/14 ,  C09D133/26 ,  C25D13/06 ,  C08L63/10

CPC分类号： C09D133/14 ,  C08G59/4042 ,  C08G59/50 ,  C09D133/26 ,  C09D5/4453 ,  C08L63/00

摘要： Curable resinous compositions containing primary and/or secondary amine groups which are non-volatile under curing conditions and containing alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties which are reacted with a primary and/or secondary amine which are volatile under curing conditions are disclosed. The compositions are depositable on a substrate to form films.

摘要翻译： 含有伯胺和/或仲胺基团的可固化的树脂组合物，其在固化条件下是非挥发性的，并且在与固化条件下挥发的伯胺和/或仲胺反应的羰基部分中含有α，β-烯属不饱和部分 被披露。 组合物可沉积在基底上以形成膜。

公开(公告)号：US4141810A

公开(公告)日：1979-02-27

申请号：US889311

申请日：1978-03-23

申请人： Stephen L. Buchwalter ,  Joseph F. Bosso ,  Roger M. Christenson

发明人： Stephen L. Buchwalter ,  Joseph F. Bosso ,  Roger M. Christenson

IPC分类号： C08G59/00 ,  C08G59/14 ,  C09D5/44 ,  C25D13/06

CPC分类号： C09D5/4434 ,  C09D5/4423

摘要： A method of cationic electrodeposition on an electroconductive substrate is disclosed. The method of the invention employs as the electrocoating vehicle an aqueous dispersion of a quaternary ammonium carbonate-containing resin. Electrodeposition of the resin is accomplished without generating harmful acid from the counter ion. The carbonate counter ion is continuously evolved from the electrodeposition bath at the anode as carbon dioxide.The quaternary ammonium carbonate-containing polymers are also useful as feed resins for controlling the pH of aqueous dispersions of acidified cationic resins used in electrodeposition. Upon electrodeposition, these resins generate acid which can build up to undesirable levels in the electrodeposition bath. The quaternary ammonium carbonate-containing polymers are relatively basic and when fed into the bath react with the acid to form the corresponding quaternary ammonium salt of the acid releasing carbon dioxide. This controls the pH of the bath and provides additional cationic resin for electrodeposition.Utilizing the polymeric quaternary ammonium carbonates in this manner minimizes the need for controlling acid build-up in the electrodeposition bath by conventional techniques such as by treating the bath with ultrafiltration or electrodialysis.

公开(公告)号：US4081341A

公开(公告)日：1978-03-28

申请号：US744532

申请日：1976-11-24

申请人： Roger M. Christenson ,  Joseph F. Bosso ,  Marvis E. Hartman ,  Wen-Hsuan Chang

发明人： Roger M. Christenson ,  Joseph F. Bosso ,  Marvis E. Hartman ,  Wen-Hsuan Chang

IPC分类号： C08G59/00 ,  C08G59/14 ,  C09D5/44 ,  C09D163/00 ,  C09D175/00 ,  C25D13/22 ,  C25D13/10 ,  C25D13/24

CPC分类号： C09D5/4473

摘要： Quaternary ammonium hydroxide-containing polymers and their use in cationic electrodeposition are disclosed. The quaternary ammonium hydroxide-containing polymers are particularly useful as feed resins for controlling the pH of aqueous dispersions of acidified cationic resins used in electrodeposition. Upon electrodeposition, such resins generate acid which can build up to undesirable levels in the electrodeposition bath. The quaternary ammonium hydroxide-containing polymers are strong bases and when fed into the bath react with the acid to form the corresponding quaternary ammonium salt. This controls the pH of the bath at acceptable levels and provides additional cationic resin for electrodeposition. Utilizing the invention in this manner minimizes the need for controlling acid build-up in the electrodeposition bath by conventional techniques such as by treating the bath with ultrafiltration or electrodialysis.The quaternary ammonium hydroxide-containing polymers are also useful as electrodeposition resins themselves in that they electrodeposit without generating acid counter ion.

摘要翻译： 公开了含季铵氢氧化物的聚合物及其在阳离子电沉积中的用途。 含季铵氢氧化物的聚合物特别可用作用于控制用于电沉积的酸化阳离子树脂的水性分散体的pH的进料树脂。 电沉积后，这种树脂产生的酸可以在电沉积浴中产生不希望的水平。 含氢氧化季铵的聚合物是强碱，当进入浴时与酸反应形成相应的季铵盐。 这将浴的pH控制在可接受的水平，并提供额外的阳离子树脂用于电沉积。 以这种方式利用本发明使通过常规技术例如通过用超滤或电渗析处理浴来控制电沉积浴中的酸积累的需要最小化。

公开(公告)号：US3991216A

公开(公告)日：1976-11-09

申请号：US604512

申请日：1975-08-13

申请人： Roger M. Christenson ,  Rudolf Maska

发明人： Roger M. Christenson ,  Rudolf Maska

IPC分类号： B05D7/22 ,  C08F8/32 ,  C09D157/00 ,  B65D1/12

CPC分类号： B05D7/22 ,  C08F8/44 ,  C09D157/00 ,  C08F2800/20

摘要： Water-based coating compositions for use as internal sanitary liners for metal containers containing beer, carbonated and noncarbonated soft drinks, and fruit juices consist essentially of aqueous dispersions of amine-solubilized interpolymers, said interpolymers being formed from substituted carboxylic acid amide units; ethylenically unsaturated acid units; hardening units from monomers such as styrene, vinyl toluene or alkyl methacrylates having from 1 to 4 carbon atoms and flexibilizing units from certain alkyl acrylates or methacrylates. The interpolymers are solubilized by neutralizing the acid units of the interpolymer with monomeric amines. In order to produce a stable composition, the amount of amine utilized in neutralizing the acid groups of the interpolymer should be sufficient to produce at least 0.200 milliequivalents of salt per gram of resin solids. These compositions provide containers with cured liners which do not impart undesirable turbidity or taste characteristics to the beer, soft drink, or fruit juices packaged therein.

摘要翻译： 用作含有啤酒，碳酸和非碳酸软饮料的金属容器的内部卫生衬里的水性涂料组合物和果汁基本上由胺溶解的互聚物的水分散体组成，所述互聚物由取代的羧酸酰胺单元形成; 烯属不饱和酸单元; 来自单体如苯乙烯，乙烯基甲苯或具有1至4个碳原子的甲基丙烯酸烷基酯的单体的硬化单元和来自某些丙烯酸烷基酯或甲基丙烯酸烷基酯的柔性单元。 互聚物通过用单体胺中和互聚物的酸单元来溶解。 为了产生稳定的组合物，用于中和互聚物的酸基团的胺的量应足以产生每克树脂固体至少0.200毫当量的盐。 这些组合物为容器提供固化的衬垫，其不会对包装在其中的啤酒，软饮料或果汁产生不利的浊度或味道特性。