Cationic electrodepositable coating composition and bath thereof and
process for retarding the growth of bacteria for such a bath
    5.
    发明授权
    Cationic electrodepositable coating composition and bath thereof and process for retarding the growth of bacteria for such a bath 失效
    阳离子电沉积涂料组合物及其浴液和用于延缓这种浴液中细菌生长的方法

    公开(公告)号:US6017431A

    公开(公告)日:2000-01-25

    申请号:US102772

    申请日:1998-06-23

    CPC分类号: C09D5/4492

    摘要: Electrodepositable coating composition bath is prepared and maintained to reduce the growth of bacteria in and around the bath. The composition has dispersed in an aqueous medium a resinous phase, said composition having a pH of at least 5, said resinous phase having basic nitrogen groups which are at least partially neutralized with an acid of the formula: ##STR1## wherein R is hydrogen or an alkyl group with one to four carbon atoms. The amount of this acid to neutralize the cationic resinous phase can be an initial amount greater than 90 of the milliequivalents of sulfamic acid based on the total milliequivalents of neutralizing acid in the bath for the electrodeposition coating of articles in the bath. Also, the bath is maintained by post addition of sulfamic acid to a level of greater than 80 weight percent of the milliequivalents of neutralizing acid when the bath has less than or greater than 90 weight percent of the milliequivalents of neutralizing acid in the bath as sulfamic acid.

    摘要翻译: 制备并保持电沉积涂料组合物浴以减少浴中和周围细菌的生长。 所述组合物在水性介质中分散有树脂相,所述组合物的pH值至少为5,所述树脂相具有碱性氮基,其至少部分用下式的酸中和:其中R是氢或烷基 具有一至四个碳原子。 用于中和阳离子树脂相的酸的量可以是基于在浴中的物品的电沉积涂层的浴中的中和酸的总毫克数的大于90毫克的氨基磺酸的初始量。 此外,当浴中含有少于或大于90重量%的中和酸的90重量%时,通过将氨基磺酸酸添加至大于中等酸的毫当量的80重量%的水平来保持浴, 酸。

    Baths for electrophoretic lacquering capable of cathodic deposition with
additives for enhancing surface appearance, and the use of said
additives in coating processes
    7.
    发明授权
    Baths for electrophoretic lacquering capable of cathodic deposition with additives for enhancing surface appearance, and the use of said additives in coating processes 失效
    用于具有阴极沉积的用于电泳涂漆的浴用于增强表面外观的添加剂以及所述添加剂在涂布过程中的用途

    公开(公告)号:US5415750A

    公开(公告)日:1995-05-16

    申请号:US165070

    申请日:1993-12-09

    IPC分类号: C09D5/44 C25D13/10

    CPC分类号: C09D5/4492 Y10S524/901

    摘要: Aqueous baths for electrophoretic lacquering containing binding agents capable of cathodic deposition and containing as additives for enhancing surface appearance, in particular as anti-cratering agents,0.1 to 3% by weight of one or several (meth)acrylic copolymers with an amine number of 15-150 and an OH-number of 15-450, together with0.1 to 2% by weight of one or several polyesters with .beta.-hydroxyalkyl ester groups, with an acid number of 0 to 3 and a weight average molecular weight of 1000 to 10000, and/or together with0.1 to 5% by weight of one or several homopolymers or copolymers of one or several alkylvinyl ethers with 1-5 carbon atoms in the alkyl residue, with a weight average molecular weight of 500 to 10000,whereby the percentages by weight relate to the solids content of the binding agents, and process for the coating of substrates that conduct electricity.

    摘要翻译: 含有能够阴极沉积并含有增强表面外观的添加剂的电泳漆的水浴,特别是作为防起孔剂,0.1至3重量%的胺数为15的一种或几种(甲基)丙烯酸共聚物 -150,OH-数为15-450,以及0.1至2重量%的一种或几种具有β-羟烷基酯基的聚酯,酸值为0至3,重均分子量为1000至10000 ,和/或与0.1至5重量%的烷基残基中的一个或几个烷基乙烯基醚与1-5个碳原子的一种或几种均聚物或共聚物,重均分子量为500至10000,其中百分比 (重量)涉及粘合剂的固体含量,以及用于涂覆导电的基材的方法。

    Process for coating electrically conductive substrates, water-based
coatings and crosslinking agents containing masked NCO groups
    8.
    发明授权
    Process for coating electrically conductive substrates, water-based coatings and crosslinking agents containing masked NCO groups 失效
    用于涂覆导电基材,水性涂料和含有掩蔽的NCO基团的交联剂的方法

    公开(公告)号:US5324402A

    公开(公告)日:1994-06-28

    申请号:US956763

    申请日:1993-02-04

    摘要: The invention relates to a cathodic electro-dipping process wherein the electro-dipping primer employed contains a crosslinking agent which can be obtained by(I) reacting, in a first stage,(a) diphenylmethane diisocyanate and(b) a monoalcohol or a mixture of monoalcohols to give an intermediate product (A) containing isocyanate groups, and(II) reacting this intermediate product (A) in a second stage with(c) a polyol or a mixture of polyols to give an intermediate product (B) containing hydroxyl groups which(III) is reacted in a third stage either with(d) a cycloaliphatic, aliphatic or araliphatic polyisocyanate or a mixture of such polyisocyanates and(e) a monofunctional masking agent or a mixture of such masking agents or with(f) a partially-masked polyisocyanate prepared from (d) and (e)to give a crosslinking agent which is free from isocyanate groups.

    摘要翻译: PCT No.PCT / EP91 / 01011 Sec。 371日期:1993年2月4日 102(e)日期1993年2月4日PCT PCT 1991年5月31日PCT公布。 WO91 / 18952 PCT出版物 日本1991年12月12日。本发明涉及一种阴极电浸法,其中使用的电浸渍底物含有交联剂,其可以通过(I)在第一阶段中使(a)二苯基甲烷二异氰酸酯和( b)一元醇或一元醇的混合物,得到含有异氰酸酯基团的中间产物(A),和(II)使该中间产物(A)在第二阶段与(c)多元醇或多元醇混合物反应,得到 含有羟基的中间产物(B)(III)在第三阶段与(d)脂环族,脂族或芳脂族多异氰酸酯或这些多异氰酸酯的混合物和(e)单官能掩蔽剂或这种掩蔽剂的混合物 (f)由(d)和(e)制备的部分掩蔽的多异氰酸酯,得到不含异氰酸酯基团的交联剂。

    Electrophoretically overcoatable coatings applied by electrocoating
    9.
    发明授权
    Electrophoretically overcoatable coatings applied by electrocoating 失效
    通过电泳涂覆电泳过涂覆涂层

    公开(公告)号:US4882090A

    公开(公告)日:1989-11-21

    申请号:US72269

    申请日:1987-08-17

    摘要: The invention relates to cathodically depositable aqueous electropaints which contain cationic amine-modified epoxy resins and are pigmented with electroconductive carbon black and which, on deposition and crosslinking, provide electrophoretically overcoatable coatings and contain as electroconductive carbon black a carbon black having an iodine absorption of 870-930 mg/g, a specific surface area (BET/N.sub.2) of 850-1,000 m.sup.2 /g, a pore volume (DBP) of 330-390 ml/100 g and an average particle size of 25-35 nm in an amount of 1.5 to 5.1% by weight - based on total solids.

    摘要翻译: PCT No.PCT / EP86 / 00585 Sec。 371日期1987年8月17日 102(e)日期1987年8月17日PCT提交1986年10月13日PCT公布。 出版物WO87 / 02717 日本1987年5月7日。本发明涉及含有阳离子胺改性环氧树脂并用导电炭黑着色的阴极可沉积的含水电极,并且在沉积和交联时,提供电泳可过涂层的涂层并且包含作为导电炭黑的炭黑 碘吸收量为870-930mg / g,比表面积(BET / N 2)为850-1,000m 2 / g,孔体积(DBP)为330-390ml / 100g,平均粒径为25 -35nm,其量为基于总固体的1.5至5.1重量%。