公开(公告)号：US20080226915A1

公开(公告)日：2008-09-18

申请号：US11955628

申请日：2007-12-13

申请人： Xiaosong WU ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Xiaosong WU ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B17/02 ,  C08L75/00 ,  B32B17/10 ,  C03C25/34

CPC分类号： C03C25/1065 ,  C03C25/106 ,  C08G18/672 ,  C08G18/724 ,  C09D5/002 ,  C09D175/16 ,  G02B6/02395 ,  G02B6/036 ,  Y10T428/2964 ,  C08G18/48

摘要： Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and processes to coat the optical fiber are described and claimed. The radiation curable coating is a radiation curable Primary Coating composition comprising: an oligomer; a first diluent monomer; a second diluent monomer, a photoinitiator; an antioxidant; and an adhesion promoter; wherein said oligomer is the reaction product of: a hydroxyethyl acrylate; an aromatic isocyanate; an aliphatic isocyanate; a polyol; a catalyst; and an inhibitor, and wherein said oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/mol; wherein a cured film of said radiation curable primary coating composition has a peak tan delta Tg of from about −25° C. to about −45° C. and a modulus of from about 0.50 MPa to about 1.2 MPa.

摘要翻译： 用于光纤的主要涂层的辐射固化涂层，涂覆有所述涂层的光纤和涂覆光纤的方法被描述和要求保护。 可辐射固化涂层是可辐射固化的初级涂料组合物，其包含：低聚物; 第一稀释剂单体; 第二稀释剂单体，光引发剂; 抗氧化剂 和粘合促进剂; 其中所述低聚物是以下物质的反应产物：丙烯酸羟乙酯; 芳香族异氰酸酯; 脂族异氰酸酯; 多元醇 催化剂 和抑制剂，并且其中所述低聚物的数均分子量为至少约4000g / mol至小于或等于约15,000g / mol; 其中所述可辐射固化的初级涂料组合物的固化膜的峰值tanδTg为约-25℃至约-45℃，模量为约0.50MPa至约1.2MPa。

公开(公告)号：US20080226911A1

公开(公告)日：2008-09-18

申请号：US11955525

申请日：2007-12-13

申请人： Xiaosong Wu ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Xiaosong Wu ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B17/02 ,  C08L75/04 ,  B32B17/10 ,  C03C25/34

CPC分类号： C03C25/1065 ,  C03C25/106 ,  C08G18/672 ,  C08G18/724 ,  C08G18/755 ,  C08G18/7621 ,  C09D175/16 ,  G02B6/02395 ,  Y10T428/2964

摘要： Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and methods for the preparation of coated optical fibers. A radiation curable Primary Coating composition comprising: an oligomer; a diluent monomer; a photoinitiator; an antioxidant; and an adhesion promoter; wherein said oligomer is the reaction product of: a hydroxyethyl acrylate; an aromatic isocyanate; an aliphatic isocyanate; a polyol; a catalyst; and an inhibitor, wherein said catalyst is an organo bismuth catalyst; wherein said oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/mol; and wherein a cured film of said radiation curable coating composition has a peak tan delta Tg of from about −25° C. to about −45° C.; and a modulus of from about 0.50 MPa to about 1.2 MPa.

摘要翻译： 用作光纤的主要涂层的辐射固化涂层，涂覆有所述涂层的光纤以及用于制备涂覆的光纤的方法。 一种可辐射固化的初级涂料组合物，其包含：低聚物; 稀释剂单体; 光引发剂; 抗氧化剂 和粘合促进剂; 其中所述低聚物是以下物质的反应产物：丙烯酸羟乙酯; 芳香族异氰酸酯; 脂族异氰酸酯; 多元醇 催化剂 和抑制剂，其中所述催化剂是有机铋催化剂; 其中所述低聚物的数均分子量为至少约4000g / mol至小于或等于约15,000g / mol; 并且其中所述可辐射固化涂料组合物的固化膜具有约-25℃至约-45℃的峰值tanδTg。 和约0.50MPa至约1.2MPa的模量。

公开(公告)号：US07221841B2

公开(公告)日：2007-05-22

申请号：US10966912

申请日：2004-10-15

申请人： David M. Chase ,  Kenneth Dake ,  Kelly A. Hawkinson ,  Jack Kelly ,  Edward J. Murphy

发明人： David M. Chase ,  Kenneth Dake ,  Kelly A. Hawkinson ,  Jack Kelly ,  Edward J. Murphy

IPC分类号： G02B6/02

CPC分类号： C03C25/1065

摘要： An optical fiber comprising a flame retardant UV light-curable tight-buffer coating coated onto the fiber, wherein said tight-buffer coating is substantially halogen-free, and has a limiting oxygen index of at least about 22%, and wherein said tight-buffer coating is removable from said fiber with a strip-force of less than about 1800 grams when the fiber is upjacketed with said coating at a line speed of at least 300 m/min.

摘要翻译： 一种光纤，其包含涂覆在所述纤维上的阻燃UV可光固化的紧缓冲涂层，其中所述紧缓冲涂层基本上不含卤素，并且具有至少约22％的极限氧指数，并且其中所述紧密 - 当纤维用所述涂层以至少300m / min的线速度被覆盖时，缓冲涂层可以以小于约1800克的剥离力从所述纤维中除去。

公开(公告)号：US07155100B2

公开(公告)日：2006-12-26

申请号：US10291132

申请日：2002-11-07

申请人： Edward J. Murphy ,  Nancy L. Coster ,  Keri Lynn Unterzuber ,  Christopher Todd Baker

发明人： Edward J. Murphy ,  Nancy L. Coster ,  Keri Lynn Unterzuber ,  Christopher Todd Baker

IPC分类号： G02B6/02

CPC分类号： G02B6/4436 ,  C03C25/106 ,  C03C25/1065 ,  C09D163/10 ,  G02B6/02395 ,  G02B6/4402 ,  C08L2666/02 ,  C08L2666/14

摘要： An optical fiber comprises a flame retardant tight-buffer coating. The tight-buffer coating has a limiting oxygen index of at least 20% and preferably has a durable tensile strength. Flame retardant, inner primary, outer primary, ink, ink base and single coatings and coating compositions as well as flame-retardant matrix materials are also provided.

公开(公告)号：US6040357A

公开(公告)日：2000-03-21

申请号：US84918

申请日：1998-05-28

申请人： Edward J. Murphy ,  Jeffrey Classey ,  David M. Szum

发明人： Edward J. Murphy ,  Jeffrey Classey ,  David M. Szum

IPC分类号： G02B6/44 ,  C03C25/10 ,  C09D11/10 ,  C09D11/00 ,  C03C17/34 ,  C09D11/02 ,  G02B1/12 ,  G02B6/04

CPC分类号： C09D11/101 ,  C03C25/1055 ,  C03C25/1065

摘要： Provided is radiation-curable ink composition containing a radiation-curable carrier system containing at least one radiation-curable monomer or oligomer and at least one pigment dispersed in the radiation-curable carrier system in an amount sufficient to provide a color which is visible without magnification. The pigment is substantially insoluble in the radiation-curable carrier system whereby the particulate shape of the pigment is substantially retained in the radiation-curable carrier system. The pigment having a particle size that substantially avoids pigment induced microbending of an optical glass fiber coated with the ink coating.

摘要翻译： 本发明提供的辐射固化油墨组合物含有可辐射固化的载体体系，该系统含有至少一种可辐射固化的单体或低聚物和至少一种分散在可辐射固化的载体体系中的颜料，其量足以提供在不放大的情况下可见的颜色 。 颜料基本上不溶于可辐射固化的载体体系，由此颜料的颗粒形状基本上保留在可辐射固化的载体体系中。 该颜料的粒径基本上避免颜料引起涂覆有油墨涂层的光学玻璃纤维的微弯曲。

公开(公告)号：US5891930A

公开(公告)日：1999-04-06

申请号：US694781

申请日：1996-08-09

申请人： Stephen C. Lapin ,  Edward J. Murphy

发明人： Stephen C. Lapin ,  Edward J. Murphy

IPC分类号： C03C25/10 ,  C08F2/50 ,  C08G59/30 ,  C08G59/68 ,  C09D4/06

CPC分类号： C08G59/68 ,  C03C25/106 ,  C08G59/306 ,  C09D4/06

摘要： Provided is a radiation-curable optical glass fiber coating composition adapted to provide the combination of properties of:(i) enhanced resistance to thermal degradation when suitably cured; and(ii) a viscosity sufficient to provide a surface substantially free-of pitting.The composition is formulated from components including:(A) at least one epoxy silicone monomer or oligomer which is crosslinkable via actinic radiation, or mixture thereof;(B) at least one thermoplastic resin which is substantially unreactive to actinic radiation and which is soluble or dispersible in component (A), said thermoplastic resin being present in an amount to provide said composition with a viscosity suitable for application to an optical glass fiber; and(C) a catalytically effective amount of a photoinitiator for catalyzing the crosslinking reaction of component (A) and which is soluble or dispersible in component (A) or a mixture of said component (A) and said thermoplastic resin. Also provided is a method of making the radiation-curable coating composition and a coated optical glass fiber.

摘要翻译： 本发明提供一种可辐射固化光学玻璃纤维涂层组合物，其适用于提供以下特性的组合：（i）当适当固化时增强耐热降解性; 和（ii）足以提供基本上没有点蚀的表面的粘度。 组合物由以下组分配制，包括：（A）至少一种通过光化辐射可交联的环氧硅氧烷单体或低聚物，或其混合物; （B）至少一种对光化辐射基本上不反应并且可溶于或分散在组分（A）中的热塑性树脂，所述热塑性树脂的存在量为所述组合物提供适用于光学玻璃纤维的粘度 ; 和（C）催化有效量的用于催化组分（A）的交联反应并且可溶于或可分散在组分（A）中的光引发剂或所述组分（A）和所述热塑性树脂的混合物。 还提供了制造可辐射固化涂料组合物和涂覆的光学玻璃纤维的方法。

公开(公告)号：US4761435A

公开(公告)日：1988-08-02

申请号：US914989

申请日：1986-10-03

申请人： Edward J. Murphy ,  Ronald S. Conti

发明人： Edward J. Murphy ,  Ronald S. Conti

IPC分类号： C08F2/50 ,  C08F299/04 ,  C09D4/00 ,  C09D4/06 ,  C09D5/00 ,  C08G73/02 ,  C08F265/06

CPC分类号： C09D4/00 ,  C08F299/0435 ,  C09D4/06 ,  Y10S522/904

摘要： Ultraviolet-curable ethylenically unsaturated liquid coating composition are disclosed which consist essentially of:1--polyethylenically unsaturated material in which the ethylenically unsaturated groups are polymerizable groups which are not (meth)acrylate groups;2--a polyamine resin, preferably a polytertiary amine resin; and3--an aryl ketone photosensitizer.

摘要翻译： 公开了紫外线固化型烯属不饱和液体涂料组合物，其基本上由以下物质组成：其中烯属不饱和基团是不是（甲基）丙烯酸酯基团的可聚合基团的1-多烯属不饱和物质; 2-a多胺树脂，优选多胺胺树脂; 和3-芳基酮光敏剂。

公开(公告)号：US4113597A

公开(公告)日：1978-09-12

申请号：US745240

申请日：1976-11-26

申请人： Rafat T. Rabi ,  Edward J. Murphy ,  John A. Basoms

发明人： Rafat T. Rabi ,  Edward J. Murphy ,  John A. Basoms

IPC分类号： C25D13/06 ,  C09D5/44 ,  C25D13/10

CPC分类号： C09D5/4411

摘要： A simplified method for the cathodic electrodeposition of polyamine resin from a dispersion thereof in an aqueous electrocoating bath is provided in which the polyamine is selected to be stably dispersible in water in the form of a salt with a solubilizing acid at a pH of from 6.0-7.5, and this polyamine resin is substantially completely neutralized with carbonic acid and dispersed in water in the form of an amine carbonate or bicarbonate. A unidirectional electrical current is passed through an aqueous electrocoating bath containing the amine carbonate or bicarbonate to deposit the polyamine resin at the cathode and cause the release of carbon dioxide. In preferred practice, a proportion of the amine groups in the polyamine resin within the bath, low enough to maintain the pH of the bath at a pH of about 6.0 or higher, is reacted with a relatively nonvolatile solubilizing acid, and the polyamine resin solids in the electrocoating bath are replenished by adding to bath polyamine resin substantially completely neutralized with carbonic acid.

摘要翻译： 提供了一种用于将多胺树脂从其分散体阴极电沉积在水性电涂浴中的简化方法，其中选择多胺以与6.0％的pH下的增溶酸形式的盐稳定分散在水中， 7.5，并且该聚胺树脂基本上完全被碳酸中和并以碳酸亚烃或碳酸氢盐的形式分散在水中。 单向电流通过含有碳酸胺或碳酸氢盐的水性电泳浴，以在阴极上沉积多胺树脂并引起二氧化碳的释放。 在优选的实践中，浴中多胺树脂中的一部分胺基在低于足以将浴的pH保持在约6.0或更高的pH的条件下与相对不挥发的增溶酸反应，并且多胺树脂固体 在电镀浴中通过加入基本上完全用碳酸中和的浴多胺树脂来补充。

公开(公告)号：US20080085947A1

公开(公告)日：2008-04-10

申请号：US11544677

申请日：2006-10-10

申请人： Jeanette L. Ward ,  Edward J. Murphy ,  Kelly A. Hawkinson ,  James J. Schouten

发明人： Jeanette L. Ward ,  Edward J. Murphy ,  Kelly A. Hawkinson ,  James J. Schouten

IPC分类号： C03C25/10

CPC分类号： C03C25/26 ,  C03C25/326

摘要： Radiation curable compositions suitable for use a optical fiber ribbon matrix materials are provided which have at least two non-silicone urethane(meth)acrylate oligomers, one or more multifunctional diluents and one or more photoinitiators, wherein each of the non-silicone urethane(meth)acrylate oligomers has a number average molecular weight of about 200 or more, but less than about 6000, and the polydispersity index (PDI) of the urethane(meth)acrylate oligomers is from 2:1 to 30:1. The matrix material may be coated and cured on a plurality of optical fibers so as to form an optical fiber ribbon assembly.

摘要翻译： 提供适用于使用光纤带基质材料的辐射固化组合物，其具有至少两种非硅氧烷聚氨酯（甲基）丙烯酸酯低聚物，一种或多种多官能稀释剂和一种或多种光引发剂，其中每种非硅氧烷聚氨酯（甲基） ）丙烯酸酯低聚物的数均分子量为约200以上，但小于约6000，氨基甲酸酯（甲基）丙烯酸酯低聚物的多分散指数（PDI）为2：1〜30：1。 基质材料可以在多根光纤上涂布和固化，以形成光纤带组件。

公开(公告)号：US5011635A

公开(公告)日：1991-04-30

申请号：US353538

申请日：1989-05-18

申请人： Edward J. Murphy ,  John J. Krajewski ,  Robert E. Ansel

发明人： Edward J. Murphy ,  John J. Krajewski ,  Robert E. Ansel

IPC分类号： B29C67/00

CPC分类号： B29C67/0066

摘要： The present invention contemplates a stereolithographic apparatus and method having a liquid organic phase and a fluid phase separated by a membrane that inhibits contact between the phases.

摘要翻译： 本发明考虑了一种立体光刻设备和方法，其具有液体有机相和通过膜分离的流体相，其抑制相之间的接触。