公开(公告)号：US5324599A

公开(公告)日：1994-06-28

申请号：US826000

申请日：1992-01-27

申请人： Noboru Oyama ,  Katsuhiko Naoi ,  Tadashi Sotomura ,  Hiroshi Uemachi ,  Yoshiko Sato ,  Teruhisa Kanbara ,  Kenichi Takeyama

发明人： Noboru Oyama ,  Katsuhiko Naoi ,  Tadashi Sotomura ,  Hiroshi Uemachi ,  Yoshiko Sato ,  Teruhisa Kanbara ,  Kenichi Takeyama

IPC分类号： H01M4/60 ,  H01M10/052 ,  H01M10/0565 ,  H01M6/18

CPC分类号： H01M10/052 ,  H01M10/0565 ,  H01M4/60

摘要： The present invention provides an electrode material comprising a combination of a compound having a disulfide group and a conductive polymer, or a conductive polymer having a disulfide group, wherein an S-S bond of the disulfide group is cleaved by the electrolytic reduction to form a sulfur-metal ion bond or a sulfur-proton bond, and the sulfur-metal ion bond or the sulfur-proton bond re-forms an S-S bond by the electrolytic oxidation. The present invention also provides a lithium rechargeable battery comprising a cathode, a solid electrolyte, and an anode, wherein the cathode is made of a composition containing as its main components lithium thiolate having a sulfur-lithium ion bond capable of forming a disulfide bond by the electrolytic oxidation and a .pi. electron conjugated conductive polymer; or a composition containing as its main component a .pi. electron conjugated conductive polymer having a sulfur-lithium ion bond capable of forming a disulfide bond by electrolytic oxidation; the solid electrolyte is a composition containing a salt containing lithium, or a polymer containing the salt; and the anode is made of a composition containing as its main components aluminium or an alloy containing aluminium, and carbon.

摘要翻译： 本发明提供了包含具有二硫化物的化合物和导电性聚合物的组合的电极材料或具有二硫键的导电性聚合物，其中通过电解还原将二硫键的SS键切割，形成硫 - 金属离子键或硫质子键，硫金属离子键或硫质子键通过电解氧化而重新形成SS键。 本发明还提供一种锂可再充电电池，其包含阴极，固体电解质和阳极，其中阴极由含有能够形成二硫键的硫 - 锂离子键的硫醇锂的组成的组合物制成 电解氧化和π电子共轭导电聚合物; 或含有通过电解氧化形成二硫键的具有硫 - 锂离子键的π电子共轭导电聚合物作为其主要成分的组合物; 固体电解质是含有含锂的盐或含有该盐的聚合物的组合物; 并且阳极由含有铝或含有铝的合金和碳的主要成分的组合物制成。

公开(公告)号：US07722996B2

公开(公告)日：2010-05-25

申请号：US10924548

申请日：2004-08-24

申请人： Susumu Kobayashi ,  Toshihiro Matsumoto ,  Takeshi Tomizawa ,  Katsuzou Kokawa ,  Teruhisa Kanbara

发明人： Susumu Kobayashi ,  Toshihiro Matsumoto ,  Takeshi Tomizawa ,  Katsuzou Kokawa ,  Teruhisa Kanbara

IPC分类号： H01M8/00 ,  H01M8/14 ,  H01M8/04

CPC分类号： H01M8/04007 ,  H01M8/04022 ,  H01M8/04029 ,  H01M8/04119 ,  H01M8/04149 ,  H01M8/04156 ,  H01M8/04164 ,  H01M8/04291 ,  H01M8/0612 ,  H01M8/0662

摘要： A polymer electrolyte fuel cell system is disclosed, comprising a fuel cell having a predetermined power generation portion configured to operate at a predetermined temperature to generate an electric power using a fuel gas and an oxidizing gas supplied to said fuel cell, and a humidifier configured to humidify the fuel gas and the oxidizing gas, wherein the humidifier is configured to humidify the fuel gas and the oxidizing gas to allow the fuel gas and the oxidizing gas to have dew points higher than the predetermined temperature, the humidified fuel gas and oxidizing gas having the dew points higher than the operating temperature being supplied to the fuel cell.

摘要翻译： 公开了一种聚合物电解质燃料电池系统，其包括：燃料电池，其具有被配置为在预定温度下操作的预定发电部分，以使用供应到所述燃料电池的燃料气体和氧化气体产生电力;以及加湿器， 对燃料气体和氧化气体进行加湿，其中，所述加湿器被配置为对所述燃料气体和所述氧化气体进行加湿，以使所述燃料气体和所述氧化气体具有高于所述预定温度的露点，所述加湿燃料气体和氧化气体具有 露点高于供给燃料电池的工作温度。

公开(公告)号：US6043975A

公开(公告)日：2000-03-28

申请号：US294553

申请日：1999-04-20

申请人： Teruhisa Kanbara ,  Tooru Matsui ,  Kenichi Takeyama

发明人： Teruhisa Kanbara ,  Tooru Matsui ,  Kenichi Takeyama

IPC分类号： H01B1/12 ,  H01G9/02 ,  H01G9/022 ,  H01M6/18 ,  H01G9/00 ,  H01M10/40

CPC分类号： H01G9/022 ,  H01B1/122 ,  H01M6/181

摘要： An ion-conductive polymer electrolyte having a high ionic conductivity and a high stability in both of physical and chemical properties is disclosed. It has a polymer containing at least one monomer selected from the group containing of a hydroxyalkyl acrylate, a hydroxyalkyl methacrylate and vinylene carbonate as its polymerizable ingredient, and at least one electrolyte salt. An aluminum electrolytic capacitor and an electric double-layer capacitor configured with the electrolyte are also disclosed.

摘要翻译： 公开了一种离子导电聚合物电解质，其具有高的离子导电性和物理和化学性质的高稳定性。 它具有含有至少一种选自丙烯酸羟烷基酯，甲基丙烯酸羟烷基酯和碳酸亚乙烯酯作为其可聚合成分的单体和至少一种电解质盐的聚合物。 还公开了一种铝电解电容器和配置有电解质的双电层电容器。

公开(公告)号：US5388026A

公开(公告)日：1995-02-07

申请号：US171766

申请日：1993-12-22

申请人： Teruhisa Kanbara ,  Yuichiro Tsubaki ,  Tadashi Sotomura ,  Kenichi Takeyama

发明人： Teruhisa Kanbara ,  Yuichiro Tsubaki ,  Tadashi Sotomura ,  Kenichi Takeyama

IPC分类号： H01G9/02 ,  H01G9/025

CPC分类号： H01G9/025

摘要： An electrolyte of electrolytic capacitor comprises at least one ammonium salt and at least one polyether polyol having a skeletal structure represented by the formula: ##STR1## where, each of Rs independently represents a hydrogen atom, an optionally substituted isocyanate residue or acrylic residue which may be the same as or different from one another; m.sub.1, m.sub.2, m.sub.3, n.sub.1, n.sub.2 and n.sub.3 each represent a positive integer, and the ends of the isocyanate residues or the acrylic residues are 3-dimensionally linked.

摘要翻译： 电解电容器的电解质包含至少一种铵盐和至少一种具有由下式表示的骨架结构的聚醚多元醇：其中，各自各自独立地表示氢原子，任选取代的异氰酸酯残基或丙烯酸残基， 彼此相同或不同; m1，m2，m3，n1，n2和n3各自表示正整数，异氰酸酯残基或丙烯酸残基的末端是三维连接的。

公开(公告)号：US4789610A

公开(公告)日：1988-12-06

申请号：US95146

申请日：1987-09-11

申请人： Shigeo Kondo ,  Tadashi Sotomura ,  Teruhisa Kanbara ,  Satoshi Sekido

发明人： Shigeo Kondo ,  Tadashi Sotomura ,  Teruhisa Kanbara ,  Satoshi Sekido

IPC分类号： H01M4/136 ,  H01M4/58 ,  H01M10/054 ,  H01M10/0562 ,  H01M6/18

CPC分类号： H01M10/0562 ,  H01M4/581

摘要： A solid-electrolyte secondary cell comprising a positive and a negative electrode composed of a copper chevrel compound (Cu.sub.x Mo.sub.6 S.sub.8), and copper ion conductive solid electrolyte is provided. This secondary cell is capable of charging with a current as high as about 1 mA/cm.sup.2, can stand high temperatures of up to 100.degree. C. and maintains its initial performance even after long-time charging and discharging. A cell small in voltage drop during dicharge is also provided by using a heat treated mixture of a copper chevrel compound and a copper ion conductive solid electrolyte represented by the formula K.sub.q Rb.sub.1-q Cu.sub.4 I.sub.2-p Cl.sub.3+3 (0.ltoreq.q.ltoreq.0.5, 0.25.ltoreq.p.ltoreq.1.0) for both positive and negative electrodes.

摘要翻译： 提供了由铜螯合物（CuxMo6S8）和铜离子导电性固体电解质构成的正极和负极的固体电解质二次电池。 该二次电池能够以高达约1mA / cm 2的电流充电，可以承受高达100℃的高温，并且即使在长时间充电和放电之后也保持其初始性能。 通过使用铜螯合物和由KqRb1-qCu4I2-pCl3 + 3（0≤q≤0.5）表示的铜离子导电固体电解质的热处理混合物，也提供了在二次加注期间电压降小的电池 ，0.25

公开(公告)号：US07276310B2

公开(公告)日：2007-10-02

申请号：US10817033

申请日：2004-04-02

申请人： Susumu Kobayashi ,  Toshihiro Matsumoto ,  Takeshi Tomizawa ,  Katsuzou Kokawa ,  Teruhisa Kanbara

发明人： Susumu Kobayashi ,  Toshihiro Matsumoto ,  Takeshi Tomizawa ,  Katsuzou Kokawa ,  Teruhisa Kanbara

IPC分类号： H01M2/08 ,  H10M8/02

CPC分类号： H01M8/0273 ,  H01M8/0263 ,  H01M8/0276 ,  H01M8/241 ,  H01M8/242 ,  H01M8/2483

摘要： A configuration of an electrolyte membrane for a fuel cell is provided, which can be sealed reliably and easily between the separators. The sealing configuration is between the separators and between a peripheral portion of the electrolyte membrane and the respective separators. The sealing configuration includes a frame having an elastic modulus of greater than about 2,000 MPa and less than about 2,000,000 MPa and an elastic body having an elastic modulus of greater than 0 MPa and less than about 200 MPa. In one embodiment, the separators or portions thereof may themselves constitute the at least one elastic body. In another embodiment, the electrolyte membrane may be held by two frames lying on opposite sides of the electrolyte membrane, with the at least one elastic body arranged between the first and second frames sandwiching the membrane and also between the frames and the respective separators.

摘要翻译： 提供了一种用于燃料电池的电解质膜的结构，其可以在隔板之间可靠且容易地被密封。 密封结构位于隔板之间，并且在电解质膜的周边部分和各个隔板之间。 密封结构包括具有大于约2,000MPa且小于约2,000,000MPa的弹性模量的框架和弹性模量大于0MPa且小于约200MPa的弹性体。 在一个实施例中，分离器或其部分本身可以构成至少一个弹性体。 在另一个实施例中，电解质膜可以由位于电解质膜的相对侧上的两个框架保持，其中至少一个弹性体布置在夹住膜的第一和第二框架之间以及框架与各个隔板之间。

公开(公告)号：US5900182A

公开(公告)日：1999-05-04

申请号：US540681

申请日：1995-10-11

申请人： Teruhisa Kanbara ,  Tooru Matsui ,  Kenichi Takeyama

发明人： Teruhisa Kanbara ,  Tooru Matsui ,  Kenichi Takeyama

IPC分类号： H01B1/12 ,  H01G9/02 ,  H01G9/022 ,  H01M6/18 ,  H01M10/40

CPC分类号： H01G9/022 ,  H01B1/122 ,  H01M6/181

摘要： An ion-conductive polymer electrolyte having a high ionic conductivity and a high stability in both of physical and chemical properties is disclosed. It comprises a polymer containing at least one monomer selected from the group consisting of a hydroxyalkyl acrylate, a hydroxyalkyl methacrylate and vinylene carbonate as its polymerizable ingredient, and at least one electrolyte salt. An aluminum electrolytic capacitor and an electric double-layer capacitor configured with the electrolyte are also disclosed.

摘要翻译： 公开了一种离子导电聚合物电解质，其具有高的离子导电性和物理和化学性质的高稳定性。 它包含含有至少一种选自丙烯酸羟烷基酯，甲基丙烯酸羟烷基酯和碳酸亚乙烯酯作为其可聚合成分的单体和至少一种电解质盐的聚合物。 还公开了一种铝电解电容器和配置有电解质的双电层电容器。

公开(公告)号：US5485346A

公开(公告)日：1996-01-16

申请号：US127547

申请日：1993-09-28

申请人： Teruhisa Kanbara ,  Yuichiro Tsubaki

发明人： Teruhisa Kanbara ,  Yuichiro Tsubaki

IPC分类号： H01G9/02 ,  H01G9/022

CPC分类号： H01G9/022

摘要： An electrolyte for driving an electrolytic capacitor comprising an organic solvent, at least one ammonium carboxylate and, at least one solute selected from the group consisting of quaternary ammonium borates and quaternary ammonium phosphates. An electrolyte further containing a polymer is disclosed. The polymer includes a polyether polyol represented by the following formula: ##STR1## where, 1.sub.1, 1.sub.2, 1.sub.3, m.sub.1, m.sub.2, m.sub.3, n.sub.1, n.sub.2, and n.sub.3 are positive integers, and 2.ltoreq.(1.sub.1 +m.sub.1).times.n.sub.1 .ltoreq.50, 2.ltoreq.(1.sub.2 +m.sub.2).times.n.sub.2 .ltoreq.50 and 2.ltoreq.(1.sub.3 +m.sub.3).times.n.sub.3 .ltoreq.50, andR.sub.1, R.sub.2 and R.sub.3 independently represents a hydrogen atom, which may be substituted one another by the same or different isocyanate residue or acrylic residue, wherein each end of the isocyanate residue or acrylic residue may be three-dimensionally linked.

摘要翻译： 一种用于驱动包括有机溶剂，至少一种羧酸铵和至少一种选自季铵硼酸盐和季铵磷酸盐的溶质的电解电容器的电解质。 公开了还含有聚合物的电解质。 聚合物包括由下式表示的聚醚多元醇：其中，11,12,13，m1，m2，m3，n1，n2和n3为正整数，2为（11 + m1）xn1

公开(公告)号：US07572539B2

公开(公告)日：2009-08-11

申请号：US10920546

申请日：2004-08-18

申请人： Susumu Kobayashi ,  Toshihiro Matsumoto ,  Takeshi Tomizawa ,  Katsuzou Kokawa ,  Teruhisa Kanbara

发明人： Susumu Kobayashi ,  Toshihiro Matsumoto ,  Takeshi Tomizawa ,  Katsuzou Kokawa ,  Teruhisa Kanbara

IPC分类号： H01M2/08

CPC分类号： H01M8/1004 ,  H01M8/0263 ,  H01M8/0273 ,  H01M8/0276 ,  H01M8/241 ,  H01M8/2483

摘要： A polymer electrolyte fuel cell has an MEA-gasket assembly including an MEA having a polymer electrolyte membrane, a pair of catalyst layers, and a pair of gas diffusion electrodes, and a pair of gaskets provided on peripheral portions of surfaces on both sides of the MEA with gaps between the respectively adjacent gaskets and gas diffusion electrodes. A pair of electrically conductive separators is disposed to sandwich the MEA-gasket assembly with groove-shaped cell reaction gas passages on inner surfaces of the separators, each of the cell reaction gas passages running sequentially across a first portion of a respective gasket of the pair of gaskets, a first portion of a respective gap of the gaps, a respective gas diffusion electrode of the pair of gas diffusion electrodes, a second portion of the respective gap, and a second portion of the respective gasket. Each of the gaps is at least partially closed by a closure.

摘要翻译： 聚合物电解质燃料电池具有包含具有聚合物电解质膜的MEA，一对催化剂层和一对气体扩散电极的MEA-垫片组件，以及一对垫圈，其设置在 MEA在相邻的垫圈和气体扩散电极之间具有间隙。 一对导电隔板被设置成将MEA-垫圈组件与分隔件的内表面上的槽状电池反应气体通道夹在中间，每个电池反应气体通道依次跨过该对的各个垫圈的第一部分 垫片的间隙的相应间隙的第一部分，一对气体扩散电极的相应气体扩散电极，相应间隙的第二部分和相应垫圈的第二部分。 每个间隙至少部分地被封闭封闭。

公开(公告)号：US20050084734A1

公开(公告)日：2005-04-21

申请号：US10920546

申请日：2004-08-18

申请人： Susumu Kobayashi ,  Toshihiro Matsumoto ,  Takeshi Tomizawa ,  Katsuzou Kokawa ,  Teruhisa Kanbara

发明人： Susumu Kobayashi ,  Toshihiro Matsumoto ,  Takeshi Tomizawa ,  Katsuzou Kokawa ,  Teruhisa Kanbara

IPC分类号： H01M2/08 ,  H01M4/94 ,  H01M8/00 ,  H01M8/02 ,  H01M8/10 ,  H01M8/24

CPC分类号： H01M8/1004 ,  H01M8/0263 ,  H01M8/0273 ,  H01M8/0276 ,  H01M8/241 ,  H01M8/2483

摘要： A polymer electrolyte fuel cell has an MEA-gasket assembly including an MEA having a polymer electrolyte membrane, a pair of catalyst layers, and a pair of gas diffusion electrodes, and a pair of gaskets provided on peripheral portions of surfaces on both sides of the MEA with gaps between the respectively adjacent gaskets and gas diffusion electrodes. A pair of electrically conductive separators is disposed to sandwich the MEA-gasket assembly with groove-shaped cell reaction gas passages on inner surfaces of the separators, each of the cell reaction gas passages running sequentially across a first portion of a respective gasket of the pair of gaskets, a first portion of a respective gap of the gaps, a respective gas diffusion electrode of the pair of gas diffusion electrodes, a second portion of the respective gap, and a second portion of the respective gasket. Each of the gaps is at least partially closed by a closure.

摘要翻译： 聚合物电解质燃料电池具有包含具有聚合物电解质膜的MEA，一对催化剂层和一对气体扩散电极的MEA-垫片组件，以及一对垫圈，其设置在 MEA在相邻的垫圈和气体扩散电极之间具有间隙。 一对导电隔板被设置成将MEA-垫圈组件与分隔件的内表面上的槽状电池反应气体通道夹在中间，每个电池反应气体通道依次跨过该对的各个垫圈的第一部分 垫片的间隙的相应间隙的第一部分，一对气体扩散电极的相应气体扩散电极，相应间隙的第二部分和相应垫圈的第二部分。 每个间隙至少部分地被封闭封闭。