公开(公告)号：US5388026A

公开(公告)日：1995-02-07

申请号：US171766

申请日：1993-12-22

申请人： Teruhisa Kanbara ,  Yuichiro Tsubaki ,  Tadashi Sotomura ,  Kenichi Takeyama

发明人： Teruhisa Kanbara ,  Yuichiro Tsubaki ,  Tadashi Sotomura ,  Kenichi Takeyama

IPC分类号： H01G9/02 ,  H01G9/025

CPC分类号： H01G9/025

摘要： An electrolyte of electrolytic capacitor comprises at least one ammonium salt and at least one polyether polyol having a skeletal structure represented by the formula: ##STR1## where, each of Rs independently represents a hydrogen atom, an optionally substituted isocyanate residue or acrylic residue which may be the same as or different from one another; m.sub.1, m.sub.2, m.sub.3, n.sub.1, n.sub.2 and n.sub.3 each represent a positive integer, and the ends of the isocyanate residues or the acrylic residues are 3-dimensionally linked.

摘要翻译： 电解电容器的电解质包含至少一种铵盐和至少一种具有由下式表示的骨架结构的聚醚多元醇：其中，各自各自独立地表示氢原子，任选取代的异氰酸酯残基或丙烯酸残基， 彼此相同或不同; m1，m2，m3，n1，n2和n3各自表示正整数，异氰酸酯残基或丙烯酸残基的末端是三维连接的。

公开(公告)号：US5324599A

公开(公告)日：1994-06-28

申请号：US826000

申请日：1992-01-27

申请人： Noboru Oyama ,  Katsuhiko Naoi ,  Tadashi Sotomura ,  Hiroshi Uemachi ,  Yoshiko Sato ,  Teruhisa Kanbara ,  Kenichi Takeyama

发明人： Noboru Oyama ,  Katsuhiko Naoi ,  Tadashi Sotomura ,  Hiroshi Uemachi ,  Yoshiko Sato ,  Teruhisa Kanbara ,  Kenichi Takeyama

IPC分类号： H01M4/60 ,  H01M10/052 ,  H01M10/0565 ,  H01M6/18

CPC分类号： H01M10/052 ,  H01M10/0565 ,  H01M4/60

摘要： The present invention provides an electrode material comprising a combination of a compound having a disulfide group and a conductive polymer, or a conductive polymer having a disulfide group, wherein an S-S bond of the disulfide group is cleaved by the electrolytic reduction to form a sulfur-metal ion bond or a sulfur-proton bond, and the sulfur-metal ion bond or the sulfur-proton bond re-forms an S-S bond by the electrolytic oxidation. The present invention also provides a lithium rechargeable battery comprising a cathode, a solid electrolyte, and an anode, wherein the cathode is made of a composition containing as its main components lithium thiolate having a sulfur-lithium ion bond capable of forming a disulfide bond by the electrolytic oxidation and a .pi. electron conjugated conductive polymer; or a composition containing as its main component a .pi. electron conjugated conductive polymer having a sulfur-lithium ion bond capable of forming a disulfide bond by electrolytic oxidation; the solid electrolyte is a composition containing a salt containing lithium, or a polymer containing the salt; and the anode is made of a composition containing as its main components aluminium or an alloy containing aluminium, and carbon.

摘要翻译： 本发明提供了包含具有二硫化物的化合物和导电性聚合物的组合的电极材料或具有二硫键的导电性聚合物，其中通过电解还原将二硫键的SS键切割，形成硫 - 金属离子键或硫质子键，硫金属离子键或硫质子键通过电解氧化而重新形成SS键。 本发明还提供一种锂可再充电电池，其包含阴极，固体电解质和阳极，其中阴极由含有能够形成二硫键的硫 - 锂离子键的硫醇锂的组成的组合物制成 电解氧化和π电子共轭导电聚合物; 或含有通过电解氧化形成二硫键的具有硫 - 锂离子键的π电子共轭导电聚合物作为其主要成分的组合物; 固体电解质是含有含锂的盐或含有该盐的聚合物的组合物; 并且阳极由含有铝或含有铝的合金和碳的主要成分的组合物制成。

公开(公告)号：US5275750A

公开(公告)日：1994-01-04

申请号：US916963

申请日：1992-07-20

申请人： Yoshiko Sato ,  Hiroshi Uemachi ,  Teruhisa Kanbara ,  Tadashi Sotomura ,  Kenichi Takeyama

发明人： Yoshiko Sato ,  Hiroshi Uemachi ,  Teruhisa Kanbara ,  Tadashi Sotomura ,  Kenichi Takeyama

IPC分类号： C08F290/06 ,  G02F1/15 ,  H01B1/12 ,  H01G9/02 ,  H01G9/025 ,  H01M10/052 ,  H01M10/0565

CPC分类号： H01G9/025 ,  C08F290/062 ,  H01B1/122 ,  H01M10/052 ,  H01M10/0565 ,  G02F1/1525

摘要： A method of manufacturing a solid polymer electrolyte which comprises polymerizing an ester polymethoxyoxyalkylene, a diester polyoxyalkylene, an oxycompound having a double bond, and an inorganic salt, and the solid polymer electrolyte thus obtained. The electrolyte is suitable for application in electrochemical devices such as primary or secondary battery, condenser or electrochromic display.

摘要翻译： 一种固体高分子电解质的制造方法，其特征在于，聚酯化聚甲氧基氧化烯，二酯聚氧化烯，具有双键的氧化合物和无机盐，以及由此得到的固体高分子电解质。 电解质适用于电化学装置，如一次或二次电池，冷凝器或电致变色显示。

公开(公告)号：US5616274A

公开(公告)日：1997-04-01

申请号：US324521

申请日：1994-10-18

申请人： Teruhisa Kanbara ,  Yuichiro Tsubaki ,  Kenichi Takeyama

发明人： Teruhisa Kanbara ,  Yuichiro Tsubaki ,  Kenichi Takeyama

IPC分类号： H01G9/02 ,  H01G9/025 ,  H01G9/028 ,  H01G9/035

CPC分类号： H01G9/025

摘要： A stable ion-conductive polymer electrolyte for an electrolytic capacitor comprises: a polymer made up of a prepolymer which has a polyol skeletal structure including polyalkylene oxide units, at least one ammonium salt, and at least one organic solvent. The skeletal structure is exemplified as trimethylol propane, trimethylolol ethane or tetramethylol methane.

摘要翻译： 一种用于电解电容器的稳定的离子导电聚合物电解质包括：由预聚物组成的聚合物，其具有包含聚环氧烷单元，至少一种铵盐和至少一种有机溶剂的多元醇骨架结构。 骨架结构的实例是三羟甲基丙烷，三羟甲基乙烷或四羟甲基甲烷。

公开(公告)号：US5538811A

公开(公告)日：1996-07-23

申请号：US62782

申请日：1993-05-14

申请人： Teruhisa Kanbara ,  Kenichi Takeyama ,  Yuichiro Tsubaki

发明人： Teruhisa Kanbara ,  Kenichi Takeyama ,  Yuichiro Tsubaki

IPC分类号： C08L71/02 ,  H01G9/02 ,  H01G9/022 ,  H01G9/025 ,  H01G11/48 ,  H01G11/56 ,  H01M6/18 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  H01M6/16

CPC分类号： H01G9/038 ,  C08L71/02 ,  H01G11/48 ,  H01G11/56 ,  H01G9/022 ,  H01G9/025 ,  H01M10/052 ,  H01M10/0565 ,  H01M6/181 ,  H01M10/0525 ,  Y02E60/13 ,  Y02P70/54

摘要： An ionic conductive polymer electrolyte including a polymer having ether type oxygen in the structure and a plasticizer is provided. The plasticizer is at least one selected from the group consisting of compounds represented by the following general Formulas IV and V:Formula IV:R.sub.1 O--(C.sub.2 H.sub.4 O).sub.n --(C.sub.3 H.sub.6 O).sub.m --Hwherein n+m is 2, 3, 4 or 5, and R.sub.1 =CH.sub.3, C.sub.2 H.sub.5, C.sub.3 H.sub.7 or C.sub.4 H.sub.9 ; andFormula V:R.sub.1 O--(C.sub.2 H.sub.4 O).sub.n --(C.sub.3 H.sub.6 O).sub.m --R.sub.2wherein n+m is 2, 3, 4, or 5 and R.sub.1 =R.sub.2 =CH.sub.3.

摘要翻译： 提供了包含结构中具有醚型氧的聚合物和增塑剂的离子导电聚合物电解质。 增塑剂是选自由以下通式IV和V表示的化合物中的至少一种：式IV：R 1 O-（C 2 H 4 O）n - （C 3 H 6 O）m H，其中n + m为2,3,4或5， 且R1 = CH3，C2H5，C3H7或C4H9; 和式V：R 1 O-（C 2 H 4 O）n - （C 3 H 6 O）m -R 2其中n + m为2,3,4或5，并且R 1 = R 2 = CH 3。

公开(公告)号：US4789610A

公开(公告)日：1988-12-06

申请号：US95146

申请日：1987-09-11

申请人： Shigeo Kondo ,  Tadashi Sotomura ,  Teruhisa Kanbara ,  Satoshi Sekido

发明人： Shigeo Kondo ,  Tadashi Sotomura ,  Teruhisa Kanbara ,  Satoshi Sekido

IPC分类号： H01M4/136 ,  H01M4/58 ,  H01M10/054 ,  H01M10/0562 ,  H01M6/18

CPC分类号： H01M10/0562 ,  H01M4/581

摘要： A solid-electrolyte secondary cell comprising a positive and a negative electrode composed of a copper chevrel compound (Cu.sub.x Mo.sub.6 S.sub.8), and copper ion conductive solid electrolyte is provided. This secondary cell is capable of charging with a current as high as about 1 mA/cm.sup.2, can stand high temperatures of up to 100.degree. C. and maintains its initial performance even after long-time charging and discharging. A cell small in voltage drop during dicharge is also provided by using a heat treated mixture of a copper chevrel compound and a copper ion conductive solid electrolyte represented by the formula K.sub.q Rb.sub.1-q Cu.sub.4 I.sub.2-p Cl.sub.3+3 (0.ltoreq.q.ltoreq.0.5, 0.25.ltoreq.p.ltoreq.1.0) for both positive and negative electrodes.

摘要翻译： 提供了由铜螯合物（CuxMo6S8）和铜离子导电性固体电解质构成的正极和负极的固体电解质二次电池。 该二次电池能够以高达约1mA / cm 2的电流充电，可以承受高达100℃的高温，并且即使在长时间充电和放电之后也保持其初始性能。 通过使用铜螯合物和由KqRb1-qCu4I2-pCl3 + 3（0≤q≤0.5）表示的铜离子导电固体电解质的热处理混合物，也提供了在二次加注期间电压降小的电池 ，0.25

公开(公告)号：US5485346A

公开(公告)日：1996-01-16

申请号：US127547

申请日：1993-09-28

申请人： Teruhisa Kanbara ,  Yuichiro Tsubaki

发明人： Teruhisa Kanbara ,  Yuichiro Tsubaki

IPC分类号： H01G9/02 ,  H01G9/022

CPC分类号： H01G9/022

摘要： An electrolyte for driving an electrolytic capacitor comprising an organic solvent, at least one ammonium carboxylate and, at least one solute selected from the group consisting of quaternary ammonium borates and quaternary ammonium phosphates. An electrolyte further containing a polymer is disclosed. The polymer includes a polyether polyol represented by the following formula: ##STR1## where, 1.sub.1, 1.sub.2, 1.sub.3, m.sub.1, m.sub.2, m.sub.3, n.sub.1, n.sub.2, and n.sub.3 are positive integers, and 2.ltoreq.(1.sub.1 +m.sub.1).times.n.sub.1 .ltoreq.50, 2.ltoreq.(1.sub.2 +m.sub.2).times.n.sub.2 .ltoreq.50 and 2.ltoreq.(1.sub.3 +m.sub.3).times.n.sub.3 .ltoreq.50, andR.sub.1, R.sub.2 and R.sub.3 independently represents a hydrogen atom, which may be substituted one another by the same or different isocyanate residue or acrylic residue, wherein each end of the isocyanate residue or acrylic residue may be three-dimensionally linked.

摘要翻译： 一种用于驱动包括有机溶剂，至少一种羧酸铵和至少一种选自季铵硼酸盐和季铵磷酸盐的溶质的电解电容器的电解质。 公开了还含有聚合物的电解质。 聚合物包括由下式表示的聚醚多元醇：其中，11,12,13，m1，m2，m3，n1，n2和n3为正整数，2为（11 + m1）xn1

公开(公告)号：US5994877A

公开(公告)日：1999-11-30

申请号：US103982

申请日：1998-06-24

申请人： Hajime Seri ,  Yoshinori Yamada ,  Kenichi Takeyama ,  Teruhisa Kanbara

发明人： Hajime Seri ,  Yoshinori Yamada ,  Kenichi Takeyama ,  Teruhisa Kanbara

IPC分类号： G01R31/36 ,  H01M10/44

CPC分类号： G01R31/362 ,  G01R31/3679 ,  G01R31/3624

摘要： The present invention provides methods for detecting a working condition of a non-aqueous electrolyte secondary battery which allow easy and accurate determination of the degree of degradation and remaining capacity of the non-aqueous electrolyte secondary battery by a simple test irrespective of the past charging and discharging history of the battery. In the methods of the present invention, the degree of degradation of battery is quantitatively determined on the basis of the voltage value in charging or discharging at a constant current, or from an equation with that voltage value as variable.

摘要翻译： 本发明提供用于检测非水电解质二次电池的工作状态的方法，其通过简单的测试容易且准确地确定非水电解质二次电池的劣化程度和剩余容量，而不管过去的充电和 放电电池的历史。 在本发明的方法中，电池的劣化程度根据恒定电流充电或放电时的电压值，或者以该电压值为可变的方程定量确定。

公开(公告)号：US5900182A

公开(公告)日：1999-05-04

申请号：US540681

申请日：1995-10-11

申请人： Teruhisa Kanbara ,  Tooru Matsui ,  Kenichi Takeyama

发明人： Teruhisa Kanbara ,  Tooru Matsui ,  Kenichi Takeyama

IPC分类号： H01B1/12 ,  H01G9/02 ,  H01G9/022 ,  H01M6/18 ,  H01M10/40

CPC分类号： H01G9/022 ,  H01B1/122 ,  H01M6/181

摘要： An ion-conductive polymer electrolyte having a high ionic conductivity and a high stability in both of physical and chemical properties is disclosed. It comprises a polymer containing at least one monomer selected from the group consisting of a hydroxyalkyl acrylate, a hydroxyalkyl methacrylate and vinylene carbonate as its polymerizable ingredient, and at least one electrolyte salt. An aluminum electrolytic capacitor and an electric double-layer capacitor configured with the electrolyte are also disclosed.

摘要翻译： 公开了一种离子导电聚合物电解质，其具有高的离子导电性和物理和化学性质的高稳定性。 它包含含有至少一种选自丙烯酸羟烷基酯，甲基丙烯酸羟烷基酯和碳酸亚乙烯酯作为其可聚合成分的单体和至少一种电解质盐的聚合物。 还公开了一种铝电解电容器和配置有电解质的双电层电容器。

公开(公告)号：US6043975A

公开(公告)日：2000-03-28

申请号：US294553

申请日：1999-04-20

申请人： Teruhisa Kanbara ,  Tooru Matsui ,  Kenichi Takeyama

发明人： Teruhisa Kanbara ,  Tooru Matsui ,  Kenichi Takeyama

IPC分类号： H01B1/12 ,  H01G9/02 ,  H01G9/022 ,  H01M6/18 ,  H01G9/00 ,  H01M10/40

CPC分类号： H01G9/022 ,  H01B1/122 ,  H01M6/181

摘要： An ion-conductive polymer electrolyte having a high ionic conductivity and a high stability in both of physical and chemical properties is disclosed. It has a polymer containing at least one monomer selected from the group containing of a hydroxyalkyl acrylate, a hydroxyalkyl methacrylate and vinylene carbonate as its polymerizable ingredient, and at least one electrolyte salt. An aluminum electrolytic capacitor and an electric double-layer capacitor configured with the electrolyte are also disclosed.

摘要翻译： 公开了一种离子导电聚合物电解质，其具有高的离子导电性和物理和化学性质的高稳定性。 它具有含有至少一种选自丙烯酸羟烷基酯，甲基丙烯酸羟烷基酯和碳酸亚乙烯酯作为其可聚合成分的单体和至少一种电解质盐的聚合物。 还公开了一种铝电解电容器和配置有电解质的双电层电容器。