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    High temperature isomerization of (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene
    42.
    发明授权
    High temperature isomerization of (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene 有权
    （E）-1-氯-3,3,3-三氟丙烯与（Z）-1-氯-3,3,3-三氟丙烯的高温异构化

    公开(公告)号：US09162947B2

    公开(公告)日：2015-10-20

    申请号：US14204637

    申请日：2014-03-11

    Applicant: Honeywell International Inc.

    Inventor： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh S. Tung

    IPC: C07C17/358 ,  C07C21/02 ,  C07C21/18

    CPC classification number: C07C17/358 ,  C07B35/08 ,  C07B2200/09 ,  C07C5/22 ,  C07C17/007 ,  C07C21/18

    Abstract: Disclosed are processes for a high temperature isomerization reaction converting (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene. In certain aspects of the invention, such a process includes contacting a feed stream with a heated surface, where the feed stream includes (E)-1-chloro-3,3,3-trifluoropropene or mixture of (E)-1-chloro-3,3,3-trifluoropropene with (Z)-1-chloro-3,3,3-trifluoropropene. The resulting product stream includes (Z)-1-chloro-3,3,3-trifluoropropene and (E)-1-chloro-3,3,3-trifluoropropene, where the ratio of (Z) isomer to (E) isomer in the product stream is higher than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.

    Abstract translation: 公开了将（E）-1-氯-3,3,3-三氟丙烯转化为（Z）-1-氯-3,3,3-三氟丙烯的高温异构化反应方法。 在本发明的某些方面，这种方法包括使进料流与加热的表面接触，其中进料流包含（E）-1-氯-3,3,3-三氟丙烯或（E）-1-氯 -3,3,3-三氟丙烯与（Z）-1-氯-3,3,3-三氟丙烯。 所得产物流包含（Z）-1-氯-3,3,3-三氟丙烯和（E）-1-氯-3,3,3-三氟丙烯，其中（Z）异构体与（E）异构体 在产品流中比进料流高。 产物流中的（E）和（Z）异构体可以彼此分离。

    INTEGRATED PROCESS FOR THE PRODUCTION OF 1-CHLORO-3,3,3-TRIFLUOROPROPENE
    44.
    发明申请
    INTEGRATED PROCESS FOR THE PRODUCTION OF 1-CHLORO-3,3,3-TRIFLUOROPROPENE 有权
    用于生产1-氯代-3,3,3-三氟乙烯的综合方法

    公开(公告)号：US20150197468A1

    公开(公告)日：2015-07-16

    申请号：US14609462

    申请日：2015-01-30

    Applicant: Honeywell International Inc.

    Inventor： Stephen A. Cottrell ,  Hsueh Sung Tung ,  Konstantin A. Pokrovski

    IPC: C07C17/25

    CPC classification number: C07C17/383 ,  C07C17/206 ,  C07C17/25 ,  C07C17/38 ,  C07C21/18 ,  Y02P20/125

    Abstract: The present invention is directed to processes for the production of 1233zd from 240fa and HF, with or without a catalyst, at a commercial scale. The 240fa and HF are fed to a reactor operating at high pressure. The resulting product stream comprising 1233zd, HCl, HF, and other byproducts is treated to one or more purification techniques including phase separation and one or more distillations to provide purified 1233zd, which meets commercial product specifications, i.e., having a GC purity of 99.5% or greater.

    Abstract translation: 本发明涉及以商业规模从240fa和HF生产1233zd（有或没有催化剂）的方法。 将240fa和HF进料到在高压下操作的反应器。 将包含1233zd，HCl，HF和其他副产物的所得产物流处理成一种或多种纯化技术，包括相分离和一种或多种蒸馏以提供满足商业产品规格的纯化的1233zd，即GC纯度为99.5％ 或更大。

    Process for the production of HCFC-1233zd
    46.
    发明授权
    Process for the production of HCFC-1233zd 有权
    生产HCFC-1233zd的工艺

    公开(公告)号：US08921621B2

    公开(公告)日：2014-12-30

    申请号：US13757963

    申请日：2013-02-04

    Applicant: Honeywell International Inc.

    Inventor： Stephen A. Cottrell ,  Hsueh Sung Tung ,  Konstantin A. Pokrovski ,  Haiyou Wang ,  Daniel C. Merkel

    IPC: C07C17/25 ,  C07C17/20 ,  C07C21/18 ,  C07C17/38 ,  C07C17/383 ,  C07C17/23

    CPC classification number: C07C17/23 ,  C07C17/20 ,  C07C17/206 ,  C07C17/25 ,  C07C17/38 ,  C07C17/383 ,  C07C21/18

    Abstract: A process for the manufacture of 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) at commercial scale from the reaction of HCC-240 and HF is disclosed. In one embodiment, HCC-240fa and HF are fed to a reactor operating at high pressure. Several different reactor designs useful in this process include; a stirred-tank reactor (batch and/or continuous flow); a plug flow reactor; a static mixer used as a reactor; at least one of the above reactors operating at high pressure; optionally combined with a distillation column running at a lower pressure; and combinations of the above; and/or with a distillation column. The resulting product stream consisting of 1233zd, HCl, HF, and other byproducts is partially condensed to recover HF by phase separation. The recovered HF phase is recycled to the reactor. The HCl is scrubbed from the vapor stream and recovered as an aqueous solution. The remaining organic components including the desired HCFC-1233zd are scrubbed, dried and distilled to meet commercial product specifications.

    Abstract translation: 公开了从HCC-240和HF的反应制造商业规模的1-氯-3,3,3-三氟丙烯（HCFC-1233zd）的方法。 在一个实施方案中，将HCC-240fa和HF加入到在高压下操作的反应器中。 在这个过程中有用的几种不同的反应器设计包括： 搅拌釜反应器（批次和/或连续流动）; 活塞流反应器; 用作反应器的静态混合器; 上述反应器中的至少一个在高压下运行; 任选地与在较低压力下运行的蒸馏塔组合; 和上述的组合; 和/或用蒸馏塔。 由1233zd，HCl，HF和其他副产物组成的产物流部分冷凝，通过相分离回收HF。 将回收的HF相循环至反应器。 将HCl从蒸汽流中洗涤并作为水溶液回收。 将包括所需HCFC-1233zd在内的剩余有机组分进行洗涤，干燥和蒸馏以满足商业产品规格。

    METHODS TO SEPARATE HALOGENTATED OLEFINS FROM 2-CHLORO-1,1,1,2-TETRAFLUOROPROPANE USING A SOLID ADSORBENT
    47.
    发明申请
    METHODS TO SEPARATE HALOGENTATED OLEFINS FROM 2-CHLORO-1,1,1,2-TETRAFLUOROPROPANE USING A SOLID ADSORBENT 有权
    使用固体吸附剂从2-氯代-1,1,1,2-四氢呋喃中分离出氢化烯烃的方法

    公开(公告)号：US20140303413A1

    公开(公告)日：2014-10-09

    申请号：US14308753

    申请日：2014-06-19

    Applicant: Honeywell International Inc.

    Inventor： Daniel C. Merkel ,  Konstantin A. Pokrovski ,  Hsueh Sung Tung

    IPC: C07C17/389

    CPC classification number: C07C17/389 ,  B01D15/00 ,  C07C21/18

    Abstract: The present invention provides a method for separating halocarbons. In particular, the invention provides a method for separating halogenated olefin impurities from 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) using a solid adsorbent, particularly activated carbon. More particularly the invention pertains to a method for separating 2-chloro-3,3,3-trifluoro-propene (HCFO-1233xf) from HCFC-244bb, which are useful as intermediates in the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf).

    Abstract translation: 本发明提供一种分离卤代烃的方法。 特别地，本发明提供了使用固体吸附剂，特别是活性炭从2-氯-1,1,1,2-四氟丙烷（HCFC-244bb）分离卤代烯烃杂质的方法。 更具体地说，本发明涉及从HCFC-244bb中分离出2-氯-3,3,3-三氟丙烯（HCFO-1233xf）的方法，它们可用作制备2,3,3,3-三氟丙烯 四氟丙烯（HFO-1234yf）。

    CONTINUOUS LOW-TEMPERATURE PROCESS TO PRODUCE TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPENE
    50.
    发明申请
    CONTINUOUS LOW-TEMPERATURE PROCESS TO PRODUCE TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPENE 有权
    连续低温生产反式-1-氯代-3,3,3-三氟丙烯的方法

    公开(公告)号：US20140206910A1

    公开(公告)日：2014-07-24

    申请号：US14195899

    申请日：2014-03-04

    Applicant: Honeywell International Inc.

    Inventor： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh Sung Tung

    IPC: C07C17/20 ,  C07C17/358

    CPC classification number: C07C17/20 ,  B01D3/009 ,  C01B7/0706 ,  C01B7/0712 ,  C07C17/206 ,  C07C17/25 ,  C07C17/358 ,  C07C17/383 ,  C07C21/18 ,  Y02P20/582

    Abstract: Disclosed is process for the production of (E) 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd(E)) by conducting a continuous reaction without the use of a catalyst. Also disclosed is an integrated system including one or more reactors for producing hydrofluoro olefins, particularly 1233zd(E). The manufacturing process includes six major unit operations: (1) a fluorination reaction of HCC-240fa (in continuous or semi-batch mode) using HF with simultaneous removal of by-product HCl and the product 1233zd(E); (2) recycle of unreacted HCC-240fa and HF together with under-fluorinated by-products back to (1); (3) separation and purification of by-product HCl; (4) separation of excess HF back to (1); (5) purification of final product, 1233zd(E); and (6) isomerization of by-product 1233zd(Z) to 1233zd(E) to maximize the process yield.

    Abstract translation: 公开了通过在不使用催化剂的情况下进行连续反应来制备（E）1-氯-3,3,3-三氟丙烯（HCFO-1233zd（E））的方法。 还公开了一种集成系统，其包括用于制备氢氟烯烃的一个或多个反应器，特别是1233zd（E）。 制造过程包括六个主要单元操作：（1）使用HF同时除去副产物HCl和产物1233zd（E）的HCC-240fa（连续或半间歇模式）的氟化反应; （2）将未反应的HCC-240fa和HF与未氟化的副产物一起回收至（1）; （3）副产物HCl的分离和纯化; （4）将过量的HF分离回（1）; （5）最终产物的纯化，1233zd（E）; 和（6）副产物1233zd（Z）异构化为1233zd（E）以使工艺产率最大化。

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