公开(公告)号：US20170247304A1

公开(公告)日：2017-08-31

申请号：US15587824

申请日：2017-05-05

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh S. Tung

IPC分类号： C07C17/358 ,  C07C5/22 ,  C07B35/08 ,  C07C21/18 ,  C07C17/007

CPC分类号： C07C17/358 ,  C07B35/08 ,  C07B2200/09 ,  C07C5/22 ,  C07C17/007 ,  C07C21/18

摘要： Disclosed are processes for a high temperature isomerization reaction converting (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene. In certain aspects of the invention, such a process includes contacting a feed stream with a heated surface, where the feed stream includes (E)-1-chloro-3,3,3-trifluoropropene or mixture of (E)-1-chloro-3,3,3-trifluoropropene with (Z)-1-chloro-3,3,3-trifluoropropene. The resulting product stream includes (Z)-1-chloro-3,3,3-trifluoropropene and (E)-1-chloro-3,3,3-trifluoropropene, where the ratio of (Z) isomer to (E) isomer in the product stream is higher than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.

公开(公告)号：US06781022B1

公开(公告)日：2004-08-24

申请号：US09786791

申请日：2001-05-08

申请人： Ali Katrib ,  Damien Mey ,  Gilbert Maire

发明人： Ali Katrib ,  Damien Mey ,  Gilbert Maire

IPC分类号： B01J2106

CPC分类号： C07B35/08 ,  B01J23/28 ,  B01J23/30 ,  B01J37/18

摘要： The objective of the present invention is a polyvalent bifunctional catalyst and the process of its realization. A catalyst characterized by the fact that it contains, over a TiO2 support, an oxide or a mixture of metallic oxides of MC2 type obtained by reduction of the corresponding MC3 oxides, the metal(s) forming the MO2 oxides are chosen from the group formed by W and Mo.

摘要翻译： 本发明的目的是多价双功能催化剂及其实现方法。 一种催化剂，其特征在于，其包含TiO 2载体上通过还原相应的MC 3氧化物而获得的MC2型金属氧化物的氧化物或混合物，形成MO 2氧化物的金属选自形成的基团 由W和Mo

公开(公告)号：US09994504B2

公开(公告)日：2018-06-12

申请号：US15587824

申请日：2017-05-05

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh S. Tung

IPC分类号： C07C17/358 ,  C07C21/18 ,  C07C17/007 ,  C07B35/08 ,  C07C5/22

CPC分类号： C07C17/358 ,  C07B35/08 ,  C07B2200/09 ,  C07C5/22 ,  C07C17/007 ,  C07C21/18

摘要： Disclosed are processes for a high temperature isomerization reaction converting (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene. In certain aspects of the invention, such a process includes contacting a feed stream with a heated surface, where the feed stream includes (E)-1-chloro-3,3,3-trifluoropropene or mixture of (E)-1-chloro-3,3,3-trifluoropropene with (Z)-1-chloro-3,3,3-trifluoropropene. The resulting product stream includes (Z)-1-chloro-3,3,3-trifluoropropene and (E)-1-chloro-3,3,3-trifluoropropene, where the ratio of (Z) isomer to (E) isomer in the product stream is higher than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.

公开(公告)号：US09650320B2

公开(公告)日：2017-05-16

申请号：US14886628

申请日：2015-10-19

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh S. Tung

IPC分类号： C07C17/358

CPC分类号： C07C17/358 ,  C07B35/08 ,  C07B2200/09 ,  C07C5/22 ,  C07C17/007 ,  C07C21/18

摘要： Disclosed are processes for a high temperature isomerization reaction converting (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene. In certain aspects of the invention, such a process includes contacting a feed stream with a heated surface, where the feed stream includes (E)-1-chloro-3,3,3-trifluoropropene or mixture of (E)-1-chloro-3,3,3-trifluoropropene with (Z)-1-chloro-3,3,3-trifluoropropene. The resulting product stream includes (Z)-1-chloro-3,3,3-trifluoropropene and (E)-1-chloro-3,3,3-trifluoropropene, where the ratio of (Z) isomer to (E) isomer in the product stream is higher than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.

公开(公告)号：US20140288336A1

公开(公告)日：2014-09-25

申请号：US14204637

申请日：2014-03-11

申请人： Honeywell International Inc.

发明人： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh S. Tung

IPC分类号： C07C17/358

CPC分类号： C07C17/358 ,  C07B35/08 ,  C07B2200/09 ,  C07C5/22 ,  C07C17/007 ,  C07C21/18

摘要： Disclosed are processes for a high temperature isomerization reaction converting (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene. In certain aspects of the invention, such a process includes contacting a feed stream with a heated surface, where the feed stream includes (E)-1-chloro-3,3,3-trifluoropropene or mixture of (E)-1-chloro-3,3,3-trifluoropropene with (Z)-1-chloro-3,3,3-trifluoropropene. The resulting product stream includes (Z)-1-chloro-3,3,3-trifluoropropene and (E)-1-chloro-3,3,3-trifluoropropene, where the ratio of (Z) isomer to (E) isomer in the product stream is higher than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.

摘要翻译： 公开了将（E）-1-氯-3,3,3-三氟丙烯转化为（Z）-1-氯-3,3,3-三氟丙烯的高温异构化反应方法。 在本发明的某些方面，这种方法包括使进料流与加热的表面接触，其中进料流包含（E）-1-氯-3,3,3-三氟丙烯或（E）-1-氯 -3,3,3-三氟丙烯与（Z）-1-氯-3,3,3-三氟丙烯。 所得产物流包含（Z）-1-氯-3,3,3-三氟丙烯和（E）-1-氯-3,3,3-三氟丙烯，其中（Z）异构体与（E）异构体 在产品流中比进料流高。 产物流中的（E）和（Z）异构体可以彼此分离。

公开(公告)号：US20160185692A1

公开(公告)日：2016-06-30

申请号：US14886628

申请日：2015-10-19

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh S. Tung

IPC分类号： C07C17/358

CPC分类号： C07C17/358 ,  C07B35/08 ,  C07B2200/09 ,  C07C5/22 ,  C07C17/007 ,  C07C21/18

摘要： Disclosed are processes for a high temperature isomerization reaction converting (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene. In certain aspects of the invention, such a process includes contacting a feed stream with a heated surface, where the feed stream includes (E)-1-chloro-3,3,3-trifluoropropene or mixture of (E)-1-chloro-3,3,3-trifluoropropene with (Z)-1-chloro-3,3,3-trifluoropropene. The resulting product stream includes (Z)-1-chloro-3,3,3-trifluoropropene and (E)-1-chloro-3,3,3-trifluoropropene, where the ratio of (Z) isomer to (E) isomer in the product stream is higher than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.

摘要翻译： 公开了将（E）-1-氯-3,3,3-三氟丙烯转化为（Z）-1-氯-3,3,3-三氟丙烯的高温异构化反应方法。 在本发明的某些方面，这种方法包括使进料流与加热的表面接触，其中进料流包含（E）-1-氯-3,3,3-三氟丙烯或（E）-1-氯 -3,3,3-三氟丙烯与（Z）-1-氯-3,3,3-三氟丙烯。 所得产物流包含（Z）-1-氯-3,3,3-三氟丙烯和（E）-1-氯-3,3,3-三氟丙烯，其中（Z）异构体与（E）异构体 在产品流中比进料流高。 产物流中的（E）和（Z）异构体可以彼此分离。

公开(公告)号：US09162947B2

公开(公告)日：2015-10-20

申请号：US14204637

申请日：2014-03-11

申请人： Honeywell International Inc.

发明人： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh S. Tung

IPC分类号： C07C17/358 ,  C07C21/02 ,  C07C21/18

CPC分类号： C07C17/358 ,  C07B35/08 ,  C07B2200/09 ,  C07C5/22 ,  C07C17/007 ,  C07C21/18

摘要： Disclosed are processes for a high temperature isomerization reaction converting (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene. In certain aspects of the invention, such a process includes contacting a feed stream with a heated surface, where the feed stream includes (E)-1-chloro-3,3,3-trifluoropropene or mixture of (E)-1-chloro-3,3,3-trifluoropropene with (Z)-1-chloro-3,3,3-trifluoropropene. The resulting product stream includes (Z)-1-chloro-3,3,3-trifluoropropene and (E)-1-chloro-3,3,3-trifluoropropene, where the ratio of (Z) isomer to (E) isomer in the product stream is higher than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.

摘要翻译： 公开了将（E）-1-氯-3,3,3-三氟丙烯转化为（Z）-1-氯-3,3,3-三氟丙烯的高温异构化反应方法。 在本发明的某些方面，这种方法包括使进料流与加热的表面接触，其中进料流包含（E）-1-氯-3,3,3-三氟丙烯或（E）-1-氯 -3,3,3-三氟丙烯与（Z）-1-氯-3,3,3-三氟丙烯。 所得产物流包含（Z）-1-氯-3,3,3-三氟丙烯和（E）-1-氯-3,3,3-三氟丙烯，其中（Z）异构体与（E）异构体 在产品流中比进料流高。 产物流中的（E）和（Z）异构体可以彼此分离。

公开(公告)号：US20130006008A1

公开(公告)日：2013-01-03

申请号：US13508935

申请日：2010-12-01

申请人： Toshio Somyo ,  Toru Uekawa ,  Tatsuya Mori

发明人： Toshio Somyo ,  Toru Uekawa ,  Tatsuya Mori

IPC分类号： C07C253/30

CPC分类号： C07C253/30 ,  C07B35/08 ,  C07B2200/09 ,  C07C2601/02 ,  C07C255/31

摘要： A method for producing a (Z)-cyanoalkenyl-cyclopropanecarboxylic acid compound, which includes the step of isomerizing an (E)-cyanoalkenyl-cyclopropanecarboxylic acid compound (1) into a (Z)-cyanoalkenyl-cyclopropanecarboxylic acid compound (2) in the presence of at least one isomerizing catalyst selected from the group consisting of bromine, hydrogen bromide, brominated carboxylic acids, brominated phosphorus compounds, N-brominated imide compounds, N-brominated amide compounds, brominated alkylsilane compounds, thionyl bromide, brominated boron compounds, brominated aluminum compounds, thiol compounds, disulfide compounds, thiocarboxylic acid compounds, nitric acid and nitrate salts: wherein R1 and R2 represent, R1 represents an alkyl group which may have a substituent, or a halogen atom, and R2 represents a hydrogen atom, an alkyl group which may have a substituent, or a benzyl group which may have a substituent.

摘要翻译： （Z） - 氰基链烯基 - 环丙烷羧酸化合物的制造方法，其包括将（E） - 氰基链烯基 - 环丙烷羧酸化合物（1）异构化为（Z） - 氰基链烯基 - 环丙烷羧酸化合物（2） 存在至少一种异构化催化剂，其选自溴，溴化氢，溴化羧酸，溴化磷化合物，N-溴化酰亚胺化合物，N-溴化酰胺化合物，溴化烷基硅烷化合物，亚硫酰溴，溴化硼化合物，溴化 铝化合物，硫醇化合物，二硫化物，硫代羧酸化合物，硝酸和硝酸盐：其中R1和R2表示，R1表示可以具有取代基的烷基或卤素原子，R2表示氢原子，烷基 可以具有取代基的基团，或可以具有取代基的苄基。

公开(公告)号：US20240182393A1

公开(公告)日：2024-06-06

申请号：US18282838

申请日：2022-03-18

申请人： INTERNATIONAL FLAVORS & FRAGRANCES INC.

发明人： ANTONIO LEYVA-PÉREZ ,  MARTA MON-CONEJERO ,  SERGIO SANZ-NAVARRO

IPC分类号： C07C41/32 ,  C07B35/08 ,  C07C29/56 ,  C11B9/00

CPC分类号： C07C41/32 ,  C07B35/08 ,  C07C29/56 ,  C11B9/0015 ,  C11B9/0061 ,  C07B2200/09

摘要： This disclosure relates to a process for making fragrance ingredient or fragrance intermediate which involves isomerizing a starting material comprising a terminal alkene to form a product comprising an internal alkene in the presence of a ruthenium catalyst at a temperature of at least about 120° C.

公开(公告)号：US20160102037A1

公开(公告)日：2016-04-14

申请号：US14921117

申请日：2015-10-23

申请人： Elevance Renewable Sciences, Inc.

发明人： Paul A. Bertin ,  Jordan R. Quinn

IPC分类号： C07C51/09 ,  C07C67/00

CPC分类号： C07C51/09 ,  C07B35/08 ,  C07C1/26 ,  C07C5/25 ,  C07C5/2562 ,  C07C51/295 ,  C07C51/34 ,  C07C67/00 ,  C07C67/303 ,  C07C67/333 ,  C07C67/347 ,  C07C67/475 ,  C07C2531/24 ,  C07C69/533 ,  C07C55/02 ,  C07C69/593 ,  C07C11/08 ,  C07C11/02 ,  C07C69/44

摘要： A method of isomerizing a substance includes combining a substance including a terminal alkenyl group and a substance including a fluorosulfonic acid group in a reaction mixture, and forming a substance including a 2-alkenyl group from the substance including a terminal alkenyl group in the reaction mixture. The method may be used to functionalize a substance, as the substance including a 2-alkenyl group can be reacted with a functionalizing agent to form a substance including a first functional group. The methods may be used to form a dicarboxylic acid, such as suberic acid, from a renewable feedstock.

摘要翻译： 异构化物质的方法包括在反应混合物中组合包含末端烯基的物质和包含氟磺酸基团的物质，并且在反应混合物中从包含末端烯基的物质形成包含2-链烯基的物质 。 该方法可以用于官能化物质，因为包括2-链烯基的物质可以与官能化剂反应以形成包括第一官能团的物质。 该方法可用于从可再生原料形成二羧酸，例如辛二酸。