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    1-Acyloxymethyl-4,5-dichloro-imidazole derivatives and their use as herbicides
    45.
    发明授权
    1-Acyloxymethyl-4,5-dichloro-imidazole derivatives and their use as herbicides 失效
    1-酰氧基甲基-4,5-二氯 - 咪唑衍生物及其作为除草剂的用途

    公开(公告)号：US4187101A

    公开(公告)日：1980-02-05

    申请号：US946252

    申请日：1978-09-27

    申请人： Florin Seng ,  Klaus Sasse ,  Gunther Beck ,  Ludwig Eue ,  Robert R. Schmidt

    发明人： Florin Seng ,  Klaus Sasse ,  Gunther Beck ,  Ludwig Eue ,  Robert R. Schmidt

    IPC分类号： A01N43/50 ,  C07D233/68 ,  C07D233/90 ,  C07D487/14 ,  A01N9/22

    CPC分类号： C07D487/14 ,  A01N43/50 ,  C07D233/68 ,  C07D233/90

    摘要： 1-Acyloxymethyl-4,5-dichloro-imidazole-2-carboxylic acid derivatives of the formula ##STR1## in which X represents trifluoromethyl, cyano or a group ##STR2## in which R.sup.1 represents a saturated or unsaturated aliphatic radical, which can be carrying one or more substituents selected from halogen, alkoxy with 1 to 6 carbon atoms and alkylmercapto with 1 to 6 carbon atoms, R.sup.2 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group, R.sup.3 represents alkyl with 1 to 8 carbon atoms or alkenyl or alkynyl each with up to 8 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents selected from alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms, phenyl (which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, trifluoromethyl and alkoxy with 1 to 4 carbon atoms), furyl or thienyl, or represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms, or represents phenyl which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms and trifluoromethyl or, R.sup.2 and R.sup.3 conjointly with the adjoining nitrogen atoms form an optionally substituted 5-membered to 7-membered heterocyclic ring in which 1 to 3 ring members may be selected from oxygen, sulfur and nitrogen, and R represents alkyl with 1 to 6 carbon atoms, plant protective compositions containing the same as active ingredients together with diluents, and methods for protecting plants by applying such novel 1-acyloxymethyl-4,5-dichloro-imidazole-2-carboxylic acid derivatives to a plant or its habitat.

    摘要翻译： 其中X表示三氟甲基，氰基或其中R 1表示饱和或不饱和脂肪族基团的基团，其中X表示三氟甲基，氰基或者其中R 1表示饱和或不饱和脂肪族基团的基团的1-芳氧基甲基-4,5-二氯 - 咪唑-2-羧酸衍生物， 其可以携带一个或多个选自卤素，具有1至6个碳原子的烷氧基和具有1至6个碳原子的烷基巯基的取代基，R 2表示氢，具有1至8个碳原子的烷基，具有至多8个碳原子的烯基或甲酰基 基团，R 3表示具有1至8个碳原子的烷基或各自具有至多8个碳原子的烯基或炔基，这些烷基，烯基和炔基中的每一个可以携带一个或多个选自具有1至4个碳原子的烷氧基的取代基 原子，具有1至4个碳原子的烷基巯基，苯基（其可任选地携带一个或多个选自卤素，具有1至4个碳原子的烷基，三氟甲基和具有1至4个碳原子的烷氧基）的取代基，呋喃基或噻吩基，或表示环烷基 与5到 任选被具有1至6个碳原子的烷基取代的环中的7个碳原子，或表示可以任选携带一个或多个选自卤素，具有1至4个碳原子的烷基，具有1至4个碳原子的烷氧基的取代基的苯基， 具有1至4个碳原子的烷基巯基和三氟甲基，或者R 2和R 3与相邻的氮原子一起形成任选取代的5元至7元杂环，其中1至3个环成员可以选自氧，硫和氮， R表示具有1-6个碳原子的烷基，含有与活性成分一起含有稀释剂的植物保护组合物，以及通过应用这种新颖的1-酰氧基甲基-4,5-二氯 - 咪唑-2-羧酸衍生物保护植物的方法 到植物或其栖息地。

    4,5-Dichloro-imidazole derivatives and their use as herbicides
    46.
    发明授权
    4,5-Dichloro-imidazole derivatives and their use as herbicides 失效

    公开(公告)号：US4185991A

    公开(公告)日：1980-01-29

    申请号：US945288

    申请日：1978-09-25

    申请人： Klaus Sasse ,  Gunther Beck ,  Ludwig Eue ,  Robert R. Schmidt

    发明人： Klaus Sasse ,  Gunther Beck ,  Ludwig Eue ,  Robert R. Schmidt

    IPC分类号： A01N43/50 ,  C07D233/68 ,  C07D233/90 ,  C07D487/14 ,  A01N9/22

    CPC分类号： C07D487/14 ,  A01N43/50 ,  C07D233/68 ,  C07D233/90

    摘要： A 4,5-dichloro-imidazole derivative of the formula ##STR1## in which X represents trifluoromethyl, cyano or a ##STR2## or ##STR3## in which R.sup.1 represents a saturated or unsaturated aliphatic radical, which can be carrying one or more substituents selected from halogen, alkoxy with 1 to 6 carbon atoms and alkylmercapto with 1 to 6 carbon atoms,R.sup.2 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group,R.sup.3 represents hydrogen, alkyl with 1 to 8 carbon atoms or alkenyl or alkynyl each with up to 8 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents selected from alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms, phenyl (which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, trifluoromethyl and alkoxy with 1 to 4 carbon atoms), furyl or thienyl, or represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms, or represents phenyl which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms and trifluoromethyl, orR.sup.2 and R.sup.3 conjointly with the adjoining nitrogen atom form an optionally substituted 5-membered to 7-membered heterocyclic ring in which 1 to 3 ring members may be selected from oxygen, sulphur and nitrogen, andR represents alkyl with 1 to 12 carbon atoms or alkenyl or alkynyl each with up to 12 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents selected from halogen, alkoxy with 1 to 6 carbon atoms, alkylmercapto with 1 to 6 carbon atoms, cycloalkyl with 5 to 7 carbon atoms in the ring and phenyl (which itself optionally carries one or more substituents selected from alkyl with 1 to 6 carbon atoms, alkoxy with 1 to 6 carbon atoms, halogen and trifluoromethyl), or represents cycloalkyl with 5 to 7 carbon atoms in the ring or represents a phenyl radical which is at least disubstituted; and the use of such novel 4,5-dichloro-imidazole derivatives as plant protection agents especially as a herbicide, plant growth regulant, insecticide or acaricide.

    1-Acyloxymethyl-4,5-dichloro-imidazole-2-carboxylic acid derivatives and their use as plant protection agents
    47.
    发明授权
    1-Acyloxymethyl-4,5-dichloro-imidazole-2-carboxylic acid derivatives and their use as plant protection agents 失效
    1-氧代甲基-4,5-二氯 - 咪唑-2-羧酸衍生物及其作为植物保护剂的用途

    公开(公告)号：US4177055A

    公开(公告)日：1979-12-04

    申请号：US835093

    申请日：1977-09-21

    申请人： Florin Seng ,  Klaus Sasse ,  Gunther Beck ,  Ludwig Eue ,  Robert R. Schmidt

    发明人： Florin Seng ,  Klaus Sasse ,  Gunther Beck ,  Ludwig Eue ,  Robert R. Schmidt

    IPC分类号： A01N43/50 ,  C07D233/68 ,  C07D233/90 ,  C07D487/14 ,  A01N9/22

    CPC分类号： C07D487/14 ,  A01N43/50 ,  C07D233/68 ,  C07D233/90

    摘要： Novel 1-acyloxymethyl-4,5-dichloro-imidazole-2-carboxylic acid derivatives of the formula ##STR1## in which X represents trifluoromethyl, cyano or a group ##STR2## in which R.sup.1 represents an optionally substituted saturated or unsaturated aliphatic radical, R.sup.2 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group, R.sup.3 represents alkyl with 1 to 8 carbon atoms or alkenyl or alkynyl each with up to 8 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents, or represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms, or represents phenyl which may optionally carry one or more substituents, or R.sup.2 and R.sup.3 conjointly with the adjoining nitrogen atom form an optionally substituted 5- to 7-membered heterocyclic ring in which 1 to 3 ring members may be selected from oxygen, sulfur and nitrogen, and R represents alkyl with 1 to 6 carbon atoms, plant protective compositions containing the same as active ingredients together with diluents, and methods for protecting plants by applying such novel 1-acyloxymethyl-4,5-dichloro-imidazole-2-carboxylic acid derivatives to a plant or its habitat.

    摘要翻译： 具有式（I）的新颖的1-酰氧基甲基-4,5-二氯 - 咪唑-2-羧酸衍生物，其中X表示三氟甲基，氰基或基团，其中R 1表示任选取代的饱和或不饱和的 脂族基团，R 2表示氢，具有1至8个碳原子的烷基，具有至多8个碳原子的烯基或甲酰基，R 3表示具有1至8个碳原子的烷基或具有至多8个碳原子的链烯基或炔基， 这些烷基，烯基和炔基中的每一个可以携带一个或多个取代基，或代表环中具有5至7个碳原子的环烷基，其任选被具有1至6个碳原子的烷基取代，或表示可以任选携带的苯基 一个或多个取代基，或者R 2和R 3与相邻的氮原子结合形成任选取代的5至7元杂环，其中1至3个环成员可以选自氧，硫和氮，R代表a1 具有1至6个碳原子的烷基，含有与活性成分一起的稀释剂的植物保护性组合物，以及通过将这种新颖的1-酰氧基甲基-4,5-二氯 - 咪唑-2-羧酸衍生物施用于植物来保护植物的方法 或其栖息地。

    2,4-Bis-(trifluoromethyl)-6-nitrophenol compounds and herbicidal compositions
    49.
    发明授权
    2,4-Bis-(trifluoromethyl)-6-nitrophenol compounds and herbicidal compositions 失效
    2,4-二 - （三氟甲基）-6-硝基苯酚化合物和除草组合物

    公开(公告)号：US4057419A

    公开(公告)日：1977-11-08

    申请号：US625276

    申请日：1975-10-23

    申请人： Klaus Wagner ,  Ludwig Eue ,  Robert R. Schmidt ,  Ernst Roos

    发明人： Klaus Wagner ,  Ludwig Eue ,  Robert R. Schmidt ,  Ernst Roos

    IPC分类号： C07C205/26 ,  C07C205/37 ,  C07C205/43 ,  C07C205/48 ,  C07C309/66 ,  A01N9/20 ,  A01N9/24 ,  C07C79/22 ,  C07C87/00

    CPC分类号： C07C205/26 ,  C07C205/37 ,  C07C205/43 ,  C07C205/48 ,  C07C309/66

    摘要： Novel 2,4-bis-(trifluoromethyl)-6-nitrophenol compounds of the formula ##STR1## in which X is hydrogen; M; HNR.spsp.+.sup.1 R.sup.2 R.sup.3 ; --COR.sup.4 ; --COOR.sup.5 ; N,N-dimethylaminocarbonyl; --SO.sub.2 R.sup.6 or --CO--NH--R.sup.7 ;M is an equivalent of an alkali metal or alkaline earth metal,R.sup.1, r.sup.2 and R.sup.3 (individually) are hydrogen, alkyl, alkoxyalkyl, alkenyl, hydroxyalkyl, cycloalkyl, phenyalkyl, phenyl or substituted phenyl, R.sup.4 and R.sup.5 individually are alkyl, substituted alkyl, alkenyl, phenyl or substituted phenyl,R.sup.6 is alkyl, substituted alkyl, phenyl, substituted phenyl or dimethylamino, andR.sup.7 is alkyl, alkenyl, cycloalkyl, phenyl or substituted phenyl;Are outstandingly effective selective herbicides.

    摘要翻译： 新颖的式（IMAGE）的2,4-双（三氟甲基）-6-硝基苯酚化合物，其中X是氢; M; HNR + 1R2R3; -COR4; -COOR5; N，N-二甲基氨基羰基; -SO 2 R 6或-CO-NH-R 7; M是碱金属或碱土金属的当量，R 1，R 2和R 3（各自）是氢，烷基，烷氧基烷基，烯基，羟基烷基，环烷基，苯烷基，苯基或取代的苯基，R4和R5分别是烷基， ，烯基，苯基或取代的苯基，R6是烷基，取代的烷基，苯基，取代的苯基或二甲基氨基，R7是烷基，烯基，环烷基，苯基或取代的苯基; 是非常有效的选择性除草剂。

    2,4-Bis-(trifluoromethyl)-6-nitrophenol compounds and herbicidal compositions
    50.
    发明授权
    2,4-Bis-(trifluoromethyl)-6-nitrophenol compounds and herbicidal compositions 失效
    2,4-二 - （三氟甲基）-6-硝基苯酚化合物和除草组合物

    公开(公告)号：US3943180A

    公开(公告)日：1976-03-09

    申请号：US489206

    申请日：1974-07-17

    申请人： Klaus Wagner ,  Ludwig Eue ,  Robert R. Schmidt ,  Ernst Roos

    发明人： Klaus Wagner ,  Ludwig Eue ,  Robert R. Schmidt ,  Ernst Roos

    IPC分类号： C07C205/26 ,  C07C205/37 ,  C07C205/43 ,  C07C205/48 ,  C07C79/26 ,  C07C39/26

    CPC分类号： C07C205/48 ,  C07C205/26 ,  C07C205/37 ,  C07C205/43

    摘要： Novel 2,4-bis-(trifluoromethyl)-6-nitrophenol compounds of the formula ##SPC1##In whichX is hydrogen; M; HN.sup.+R.sup.1 R.sup.2 R.sup.3 ; --COR.sup.4 ; --COOR.sup.5 ; N,N-dimethylaminocarbonyl; --SO.sub.2 R.sup.6 or --CO--NH--R.sup.7 ;M is an equivalent of an alkali metal or alkaline earth metal,R.sup.1, r.sup.2 and R.sup.3 (individually) are hydrogen, alkyl, alkoxyalkyl, alkenyl, hydroxyalkyl, cycloalkyl, phenyalkyl, phenyl or substituted phenyl,R.sup.4 and R.sup.5 individually are alkyl, substituted alkyl, alkenyl, phenyl or substituted phenyl,R.sup.6 is alkyl, substituted alkyl, phenyl, substituted phenyl or dimethylamino, andR.sup.7 is alkyl, alkenyl, cycloalkyl, phenyl or substituted phenyl; are outstandingly effective selective herbicides.

    摘要翻译： 新型的2,4-二（三氟甲基）-6-硝基苯酚化合物，其中X是氢; M; HN + R1R2R3; -COR4; -COOR5; N，N-二甲基氨基羰基; -SO 2 R 6或-CO-NH-R 7; M是碱金属或碱土金属的当量，R 1，R 2和R 3（各自）是氢，烷基，烷氧基烷基，烯基，羟基烷基，环烷基，苯烷基，苯基或取代的苯基，R4和R5分别是烷基， ，烯基，苯基或取代的苯基，R6是烷基，取代的烷基，苯基，取代的苯基或二甲基氨基，R7是烷基，烯基，环烷基，苯基或取代的苯基; 是非常有效的选择性除草剂。